ES2160044A1 - Oxidacion de *-pineno. - Google Patents

Oxidacion de *-pineno.

Info

Publication number
ES2160044A1
ES2160044A1 ES009900565A ES9900565A ES2160044A1 ES 2160044 A1 ES2160044 A1 ES 2160044A1 ES 009900565 A ES009900565 A ES 009900565A ES 9900565 A ES9900565 A ES 9900565A ES 2160044 A1 ES2160044 A1 ES 2160044A1
Authority
ES
Spain
Prior art keywords
mcm
alpha
catalysts
utilization
materials containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009900565A
Other languages
English (en)
Other versions
ES2160044B1 (es
Inventor
Canos Avelino Corma
Marcelo Eduardo Domine
Rogel Manuel Susarte
Garcia Fernando Rey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to ES9900565A priority Critical patent/ES2160044B1/es
Priority to JP2000604945A priority patent/JP2002538952A/ja
Priority to BR0010512-0A priority patent/BR0010512A/pt
Priority to PCT/ES2000/000087 priority patent/WO2000054880A1/es
Priority to CN 00807698 priority patent/CN1351519A/zh
Priority to EP00909371A priority patent/EP1172142A1/en
Publication of ES2160044A1 publication Critical patent/ES2160044A1/es
Application granted granted Critical
Publication of ES2160044B1 publication Critical patent/ES2160044B1/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)

Abstract

"Oxidación de {al}-pineno". En la presente invención se describe uso de catalizadores sólidos mesoporosos tipo MCM-41 basados en sílice que además contienen Ti en su composición y empleando hidroperóxidos orgánicos como agentes oxidantes, en la oxidación de {al}-pineno.
ES9900565A 1999-03-16 1999-03-16 Oxidacion de *-pineno. Expired - Lifetime ES2160044B1 (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES9900565A ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.
JP2000604945A JP2002538952A (ja) 1999-03-16 2000-03-13 Ｔｉ含有ＭＣＭ−４１型中間細孔性物質およびα−ピネン酸化用触媒としてのその使用
BR0010512-0A BR0010512A (pt) 1999-03-16 2000-03-13 Uso de materiais mesoporosos tipo mcm-41 como catalisadores na oxidação de "alfa"-pineno e processo para a oxidação de "alfa"-pineno
PCT/ES2000/000087 WO2000054880A1 (es) 1999-03-16 2000-03-13 MATERIALES MESOPOROSOS TIPO MCM-41 CONTENIENDO TITANIO Y SU USO COMO CATALIZADORES EN LA OXIDACIÓN DE α PINENO
CN 00807698 CN1351519A (zh) 1999-03-16 2000-03-13 α－蒎烯的氧化
EP00909371A EP1172142A1 (en) 1999-03-16 2000-03-13 Mcm-41 type microporous materials containing titanium and their utilization as catalysts in alpha-pinene oxidation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9900565A ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.

Publications (2)

Publication Number Publication Date
ES2160044A1 true ES2160044A1 (es) 2001-10-16
ES2160044B1 ES2160044B1 (es) 2002-06-16

Family

ID=8307719

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9900565A Expired - Lifetime ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.

Country Status (6)

Country Link
EP (1) EP1172142A1 (es)
JP (1) JP2002538952A (es)
CN (1) CN1351519A (es)
BR (1) BR0010512A (es)
ES (1) ES2160044B1 (es)
WO (1) WO2000054880A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100415427B1 (ko) * 2001-08-07 2004-01-16 인천정유 주식회사 금속/Ａｌ-ＭＣＭ-41 이원촉매 및 이의 제조방법과금속/Ａｌ-ＭＣＭ-41 이원촉매를 이용한 불포화탄화수소의 수소화반응
EP1625106A4 (en) * 2003-05-08 2010-09-08 Flexitral Inc NEW FRAGRANCE DERIVATIVES
CN101885671A (zh) * 2010-07-01 2010-11-17 杭州格林香料化学有限公司 一种连续合成龙脑烯醛的生产方法
CN104190392B (zh) * 2014-07-25 2017-04-12 广西梧州松脂股份有限公司 钛基催化剂的制备方法
PL237108B1 (pl) * 2018-02-27 2021-03-22 Univ West Pomeranian Szczecin Tech Sposób utleniania alfa-pinenu
WO2020241052A1 (ja) * 2019-05-29 2020-12-03 住友化学株式会社 チタン含有珪素酸化物の製造方法、エポキシドの製造方法、及びチタン含有珪素酸化物
CN113181967B (zh) * 2021-04-28 2023-07-14 昆明理工大学 磺酸化钛改性的kit-6固体酸催化剂在合成龙脑中的应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994029022A1 (es) * 1993-06-15 1994-12-22 Consejo Superior Investigaciones Cientificas Material de estructura tipo zeolita de poros ultragrandes con una red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994029022A1 (es) * 1993-06-15 1994-12-22 Consejo Superior Investigaciones Cientificas Material de estructura tipo zeolita de poros ultragrandes con una red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CORMA, A. et al., One step synthesis of highly active and selective epoxidation catalysts formed by organic-inorganic Ti containing mesoporous composites. Chem. Commun. (Cambridge) 1998, (17), paginas 1899-1900, todo el documento. *
MASCHMEYER, I. et al., Developments in silica-supported organometallic catalysis. Silsesquioxanes and mesoporous MCM-41 silicates. NATO ASI Ser., Ser. C (1997), 498 (New Trends in Materials Chemistry), paginas 461-494, todo el documento. *
ON. D. TRONG et al., Catalytic epoxidation of alpha-pinene over bifunctional mesoporous molecular sieves. Catal. Lett. (1997), Vol. 44, no 3,4, paginas 171-176, ISSN 1011-372X, todo el documento. *

Also Published As

Publication number Publication date
CN1351519A (zh) 2002-05-29
ES2160044B1 (es) 2002-06-16
WO2000054880A1 (es) 2000-09-21
JP2002538952A (ja) 2002-11-19
EP1172142A1 (en) 2002-01-16
BR0010512A (pt) 2002-04-02

Similar Documents

Publication Publication Date Title
AU2002220715A1 (en) Indolsulfonyl compounds useful in the treatment of cns disorders
WO2002064096A3 (en) Methods of using pyrimidine-based antiviral agents
IL155806A0 (en) Novel benzazepines and related heterocyclic derivatives which are useful as orexin receptor antagonists
BE2015C026I2 (en) 2-phenyl-1-[-(2-aminoethoxy)-benzyl -indole in combination with estrogens
IL144147A0 (en) Regulators of the pct or smoothened pathway, compositions and uses related thereto
WO2001032646A3 (en) Sulfonamide derivatives
CA2388476A1 (en) Bicyclic imidazo-5-yl-amine derivatives
WO2004033418A3 (en) Sulfonylamino-acetic derivatives and their use as orexin receptor antagonists
GB0111186D0 (en) Novel compounds
IL162851A0 (en) 4-(Piperidyl-and pyrrolidyl-alkyl-ureido)-quinolines as urotensin ii receptor antagonists
PL307245A1 (en) Catalysts and their application in oxidation of saturated hydrocarbons
WO2004026836A3 (en) 1-pyridin-4-yl-urea derivatives
CA2361402A1 (en) Bis-sulfonamides
WO2002070464A3 (en) Hydrazones and their therapeutic use
ES2160044A1 (es) Oxidacion de *-pineno.
WO2002030357A3 (en) Compounds and methods for modulating ccr4 function
AU2001289714A1 (en) Benzofuran derivatives and their use as antibacterial agents
WO2002024665A8 (en) Arylalkane-sulfonamides having endothelin-antagonist activity
DE60225155D1 (de) 3-substituierte 6,7-dihydroxytetrahydroisochinolin-derivate zur verwendung als antibkaterielle mittel
MY140724A (en) Novel arylethene-sulfonamides
EP1269978A3 (de) Verwendung von Bis-Resorcinyltriazinderivaten in kosmetischen oder dermatologischen Zubereitungen
WO2002060382A3 (en) Novel compounds and uses thereof
ES2159224A1 (es) Procedimiento para la preparacion de titanosilicatos mesoporosos tipo mcm-48, y su uso como catalizadores en reacciones de oxidacion selectiva.
ZA200102392B (en) 1,2-Substituted 2,3-dihydro-1H-5,9-dioxacyclohepta [f] inden-7-ones and 7-substituted benzo [b] [1,4] dioxepin-3-ones.
AU7655600A (en) 1,4-dioxacycloalkane-2-one and 1,4-dioxacycloalkene-2-one

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 20011016

Kind code of ref document: A1

Effective date: 20011016