ES2158201T3 - Alcoxisilacicloalcanos, su procedimiento de preparacion y su utilizacion para la polimerizacion de olefinas. - Google Patents
Alcoxisilacicloalcanos, su procedimiento de preparacion y su utilizacion para la polimerizacion de olefinas.Info
- Publication number
- ES2158201T3 ES2158201T3 ES96112400T ES96112400T ES2158201T3 ES 2158201 T3 ES2158201 T3 ES 2158201T3 ES 96112400 T ES96112400 T ES 96112400T ES 96112400 T ES96112400 T ES 96112400T ES 2158201 T3 ES2158201 T3 ES 2158201T3
- Authority
- ES
- Spain
- Prior art keywords
- alcoxisilacicloalcanos
- olefin polymerization
- preparation procedure
- sila
- alkoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title 1
- 239000011777 magnesium Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000002370 organoaluminium group Chemical group 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1876—Preparation; Treatments not provided for in C07F7/20 by reactions involving the formation of Si-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
LA INVENCION SE REFIERE A ALCOXISILACICLOALCANOS, SU PROCEDIMIENTO DE PREPARACION Y SU UTILIZACION EN POLIMERIZACION DE LAS OLEFINAS. LA INTRODUCCION DE ESTOS ALCOXISILACICLOALCANOS EN EL MEDIO DE POLIMERIZACION DE LAS OLEFINAS PERMITE DETERMINAR EL INDICE DE INSOLUBILIDAD EN EL HEPTANO DEL POLIMERO FINALMENTE FORMADO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9511025A FR2738826B1 (fr) | 1995-09-20 | 1995-09-20 | Alcoxysilacycloalcanes, leur procede de preparation et leur utilisation pour la polymerisation des olefines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2158201T3 true ES2158201T3 (es) | 2001-09-01 |
Family
ID=9482744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96112400T Expired - Lifetime ES2158201T3 (es) | 1995-09-20 | 1996-08-01 | Alcoxisilacicloalcanos, su procedimiento de preparacion y su utilizacion para la polimerizacion de olefinas. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6228961B1 (es) |
| EP (1) | EP0765881B1 (es) |
| JP (1) | JPH09110886A (es) |
| CN (1) | CN1068006C (es) |
| AT (1) | ATE201689T1 (es) |
| CA (1) | CA2183897A1 (es) |
| DE (1) | DE69613069T2 (es) |
| ES (1) | ES2158201T3 (es) |
| FR (1) | FR2738826B1 (es) |
| NO (1) | NO313804B1 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2793799B1 (fr) * | 1999-05-18 | 2003-07-25 | Atofina | Polymerisation des olefines en presence de dialcoxysilacyclohexanes |
| US6624264B2 (en) | 1995-09-20 | 2003-09-23 | Atofina | Alkoxysilacycloalkanes, process for their preparation and their use for the polymerization of olefins |
| KR101040388B1 (ko) * | 2007-01-30 | 2011-06-09 | 주식회사 엘지화학 | 트리옥사실로칸을 포함하는 올레핀 중합용 촉매 및 이를이용한 올레핀 중합 방법 |
| WO2009061581A1 (en) * | 2007-11-06 | 2009-05-14 | Dow Corning Corporation | Method for producing silacyclo materials |
| US7790819B1 (en) | 2009-04-13 | 2010-09-07 | Formosa Plastics Corporation, U.S.A. | Bicyclic organosilicon compounds as electron donors for polyolefin catalysts |
| US7619049B1 (en) | 2009-04-13 | 2009-11-17 | Formosa Plastics Corporation, U.S.A. | Cyclic organosilicon compounds as electron donors for polyolefin catalysts |
| US10654947B2 (en) * | 2011-10-28 | 2020-05-19 | Formosa Plastics Corporation, Usa | Cyclic organosilicon compounds as electron donors in Zeigler-Natta catalyst systems for producing propylene polymer having high melt-flowability |
| US8575283B1 (en) | 2012-06-28 | 2013-11-05 | Formosa Plastics Corporation, U.S.A. | Heterocyclic organic compounds as electron donors for polyolefin catalysts |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| US9777084B2 (en) | 2016-02-19 | 2017-10-03 | Formosa Plastics Corporation, Usa | Catalyst system for olefin polymerization and method for producing olefin polymer |
| US11427660B2 (en) | 2016-08-17 | 2022-08-30 | Formosa Plastics Corporation, Usa | Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| WO2018164658A1 (en) * | 2017-03-06 | 2018-09-13 | W.R. Grace & Co.-Conn. | Electron donors for ziegler-natta precatalyst preparation and catalyst system for olefin polymerization |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| CN109942619B (zh) * | 2019-03-26 | 2021-08-10 | 山东东岳有机硅材料股份有限公司 | 1-甲基-1-乙氧基-硅杂环戊烷的合成方法 |
| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
| US20250109218A1 (en) | 2023-09-29 | 2025-04-03 | Formosa Plastics Corporation, U.S.A. | Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors |
| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2464231A (en) * | 1945-06-18 | 1949-03-15 | Continental Oil Co | Method for preparing pentamethylene silicone polymers |
| US3468922A (en) * | 1965-11-09 | 1969-09-23 | Monsanto Co | Process for preparing 1,3-bis-(silyl)-1,3-diaza-2-silacycloalkanes |
| US3509194A (en) * | 1966-07-08 | 1970-04-28 | Monsanto Co | 1,3-disilyl-1,3,2-diazasilacycloalkanes and process of preparing |
| GB1268400A (en) * | 1969-11-17 | 1972-03-29 | Midland Silicones Ltd | Organosilicon compounds |
| US3694427A (en) * | 1971-03-12 | 1972-09-26 | Dow Corning Ltd | Curable silox anol-silacyclobutane composition |
| US4011360A (en) * | 1974-04-10 | 1977-03-08 | Chomerics, Inc. | Electrically conductive silicone rubber stock |
| US4526954A (en) * | 1983-12-28 | 1985-07-02 | Union Carbide Corporation | Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen |
| KR940010330B1 (ko) | 1986-06-17 | 1994-10-22 | 아모코 코포레이션 | 유리한 개질제 성분을 포함하는 알파-올레핀 중합 촉매 시스템 |
| US4777278A (en) * | 1987-10-08 | 1988-10-11 | Akzo America Inc. | Synthesis of alkyl cycloalkyl dialkoxysilanes |
| DE3821483C2 (de) | 1988-06-25 | 1996-04-11 | Witco Gmbh | Verfahren zur Herstellung von Diorganodialkoxysilanen |
| JP2565547B2 (ja) | 1988-07-04 | 1996-12-18 | 大和製衡株式会社 | 電磁振動物品搬送装置 |
| DE69130185T2 (de) * | 1990-02-28 | 1999-05-27 | Shin-Etsu Chemical Co., Ltd., Tokio/Tokyo | Butadienyl enthaltende Siloxane und ein Verfahren zu deren Herstellung |
| US5773537A (en) * | 1992-05-19 | 1998-06-30 | Basf Aktiengesellschaft | Ziegler-natta catalyst systems containing specific organosilicon compounds |
| US5296624A (en) * | 1992-11-25 | 1994-03-22 | Huls America, Inc. | Preparation of sterically-hindered organosilanes |
| US5868961A (en) * | 1993-06-28 | 1999-02-09 | Shin-Etsu Chemical Co., Ltd. | Silacyclohexane compound, a method of preparing it and a liquid crystal composition containing it |
| EP0773241B1 (en) * | 1994-01-31 | 2001-09-12 | Toho Titanium Co., Ltd. | Solid catalyst component for polymerizing olefins and catalyst for polymerization of olefins |
| JPH07292029A (ja) | 1994-04-28 | 1995-11-07 | Toho Titanium Co Ltd | オレフィン類重合用触媒および重合方法 |
-
1995
- 1995-09-20 FR FR9511025A patent/FR2738826B1/fr not_active Expired - Fee Related
-
1996
- 1996-08-01 ES ES96112400T patent/ES2158201T3/es not_active Expired - Lifetime
- 1996-08-01 DE DE69613069T patent/DE69613069T2/de not_active Expired - Fee Related
- 1996-08-01 EP EP96112400A patent/EP0765881B1/fr not_active Expired - Lifetime
- 1996-08-01 AT AT96112400T patent/ATE201689T1/de not_active IP Right Cessation
- 1996-08-21 CA CA002183897A patent/CA2183897A1/fr not_active Abandoned
- 1996-09-19 US US08/715,915 patent/US6228961B1/en not_active Expired - Fee Related
- 1996-09-19 NO NO19963929A patent/NO313804B1/no not_active IP Right Cessation
- 1996-09-20 CN CN96122575A patent/CN1068006C/zh not_active Expired - Fee Related
- 1996-09-20 JP JP8250491A patent/JPH09110886A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69613069D1 (de) | 2001-07-05 |
| NO963929D0 (no) | 1996-09-19 |
| CN1068006C (zh) | 2001-07-04 |
| FR2738826A1 (fr) | 1997-03-21 |
| EP0765881A1 (fr) | 1997-04-02 |
| NO313804B1 (no) | 2002-12-02 |
| FR2738826B1 (fr) | 1997-10-17 |
| EP0765881B1 (fr) | 2001-05-30 |
| ATE201689T1 (de) | 2001-06-15 |
| JPH09110886A (ja) | 1997-04-28 |
| US6228961B1 (en) | 2001-05-08 |
| NO963929L (no) | 1997-03-21 |
| CA2183897A1 (fr) | 1997-03-21 |
| DE69613069T2 (de) | 2001-11-08 |
| CN1153782A (zh) | 1997-07-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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