ES2158005T3 - Metalocenos y su aplicacion en la polimerizacion de olefinas. - Google Patents

Metalocenos y su aplicacion en la polimerizacion de olefinas.

Info

Publication number
ES2158005T3
ES2158005T3 ES95103708T ES95103708T ES2158005T3 ES 2158005 T3 ES2158005 T3 ES 2158005T3 ES 95103708 T ES95103708 T ES 95103708T ES 95103708 T ES95103708 T ES 95103708T ES 2158005 T3 ES2158005 T3 ES 2158005T3
Authority
ES
Spain
Prior art keywords
metalocenos
application
olefin polymerization
mean
replaced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95103708T
Other languages
English (en)
Inventor
Herwig Mag Dr Schottenberger
Jens Dr Reussner
Michael Mag Dr Buchmeiser
Wolfgang Dipl-Ing Dr Neissl
Olaf Mag Elsner
Herbert Mag Angleitner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Technology Oy
Original Assignee
Borealis Technology Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Application granted granted Critical
Publication of ES2158005T3 publication Critical patent/ES2158005T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Abstract

LA INVENCION SE REFIERE A METALOCENO DE LA FORMULA DONDE M ES UN METAL DE GRUPO TI, ZR, HF, V, NB, TA O UN ELEMENTO A PARTIR DEL GRUPO DE LOS LANTANIDOS, X1 Y X2 SIGNIFICAN GRUPOS ALQUIL, ALCOXI, ARIL, ARILOXI, ALQUENIL, ARILALQUIL, ALQUILARIL O ARILALQUENIL, HIDROGENO O HALOGENO Y L1 Y L2 SIGNFICAN UN HIDROCARBURO, QUE PUEDE FORMAR CON M UNA ESTRUCTURA SANDWICH, DONDE AL MENOS L1 O L2 SON SUSTITUIDOS POR MEDIO DE UN RESTO FERROCENO O RESTO RUTENOCENO O SER CONDENSADOS. R1 ES C, SI, GE O SN O EL MIEMBRO DE PUENTE CONOCIDO A(R1)NB PARA UN RESTO BIFENILENO INSUSTITUIDO O SUSTITUIDO CON A Y/O B, A Y B TIENEN EL SIGNIFICADO DE X1 Y X2, N ES UNA CIFRA COMPLETA DESDE 0 HASTA 4.
ES95103708T 1994-03-22 1995-03-15 Metalocenos y su aplicacion en la polimerizacion de olefinas. Expired - Lifetime ES2158005T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0059494A AT401520B (de) 1994-03-22 1994-03-22 Metallocene und deren einsatz für die olefinpolymerisation
DE4417542A DE4417542A1 (de) 1994-03-22 1994-05-19 Metallocene und deren Einsatz für die Olefinpolymerisation

Publications (1)

Publication Number Publication Date
ES2158005T3 true ES2158005T3 (es) 2001-09-01

Family

ID=39561791

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95103708T Expired - Lifetime ES2158005T3 (es) 1994-03-22 1995-03-15 Metalocenos y su aplicacion en la polimerizacion de olefinas.

Country Status (8)

Country Link
US (1) US5521265A (es)
EP (1) EP0673946B1 (es)
JP (1) JPH0841088A (es)
AT (2) AT401520B (es)
DE (2) DE4417542A1 (es)
ES (1) ES2158005T3 (es)
FI (1) FI951314A (es)
NO (1) NO951086L (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK0685494T3 (da) 1994-06-03 1999-02-15 Pcd Polymere Ag Katalysatorbærere, understøttede metallocenkatalysatorer og deres anvendelse til fremstilling af polyolefiner
DE4431643C2 (de) 1994-07-22 2002-08-08 Borealis Polymere Holding Ag Verfahren zur Herstellung von Silizium-verbrückten unsymmetrischen Cyclopentadienyl-, Indenyl- und Fluorenyl-Ligandsystemen
JP3850048B2 (ja) * 1994-12-08 2006-11-29 東ソー株式会社 有機遷移金属化合物およびそれを用いたポリオレフィンの製造方法
DE69636348T2 (de) * 1995-12-05 2007-07-05 Asahi Kasei Chemicals Corp. Mikroporöse polyethylenmembran mit niedriger schmelztemperatur
US5959044A (en) * 1996-07-08 1999-09-28 Villar; Juan Carlos Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems
GB9716653D0 (en) * 1997-08-07 1997-10-15 Bp Chem Int Ltd Novel transition metal complexes
DE19735259A1 (de) * 1997-08-14 1999-02-18 Studiengesellschaft Kohle Mbh Ein- und mehrkernige Übergangsmetallkomplexe mit an einzelne Metallatome gebundenen Pentalenliganden
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
EP1056792B1 (en) 1998-02-17 2003-07-23 ExxonMobil Chemical Patents Inc. Ethylene copolymerization process
JP3572570B2 (ja) * 1999-02-01 2004-10-06 オーテックス株式会社 カチオン重合性有機物質用の重合開始剤
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
IT1318436B1 (it) * 2000-03-31 2003-08-25 Enichem Spa Ciclopentadieni sostituiti policiclici e metodo per la loropreparazione.
KR100393169B1 (ko) * 2000-07-07 2003-07-31 한화석유화학 주식회사 바이페닐기가 치환된 시클로펜타디에닐기를 함유한메탈로센 촉매 및 이를 이용한 올레핀 중합방법
KR100503359B1 (ko) * 2002-10-16 2005-07-26 주식회사 엘지화학 스티렌 중합체 제조용 메탈로센 촉매 및 이를 이용한스티렌 중합체의 제조방법
US20050107559A1 (en) * 2003-11-14 2005-05-19 Coates Geoffrey W. Ethylene-C4-C20-alkene copolymers
WO2015123171A2 (en) * 2014-02-11 2015-08-20 Univation Technologies, Llc Producing polyolefin products
USD962124S1 (en) 2020-05-14 2022-08-30 DC Comics Vehicle body, vehicle body toy replica, and/or other replica

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NO164547C (no) * 1983-06-06 1990-10-17 Exxon Research Engineering Co Katalysatorsystem og en polymeringsprosess som benytter systemet.
ATE54926T1 (de) * 1985-12-23 1990-08-15 Loctite Ireland Ltd Ferriceniumsalz als katalysator fuer vinylether.
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
US5008302A (en) * 1987-12-01 1991-04-16 Ciba-Geigy Corporation Titanocenes, the use thereof, and N-substituted pyrroles
DE3808268A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
JP2854886B2 (ja) * 1989-08-10 1999-02-10 三井化学株式会社 プロピレンとブテンの共重合体
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
JP2927885B2 (ja) * 1990-05-24 1999-07-28 三井化学株式会社 シンジオタクチックポリα―オレフィンの製造方法
EP0485823B1 (de) * 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
DE4211086A1 (de) * 1992-04-03 1993-10-07 Basf Ag Katalysatorsysteme zur Polymerisation von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen
TW294669B (es) * 1992-06-27 1997-01-01 Hoechst Ag
ES2114978T3 (es) * 1992-08-03 1998-06-16 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos con ligandos indenilo de substitucion especial.
ES2153368T3 (es) * 1992-08-03 2001-03-01 Targor Gmbh Procedimiento para la obtencion de un polimero de olefina bajo empleo de metalocenos especiales.

Also Published As

Publication number Publication date
AT401520B (de) 1996-09-25
ATA59494A (de) 1996-02-15
FI951314A0 (fi) 1995-03-21
EP0673946B1 (de) 2001-06-27
NO951086D0 (no) 1995-03-21
NO951086L (no) 1995-09-25
DE4417542A1 (de) 1995-11-23
US5521265A (en) 1996-05-28
EP0673946A3 (de) 1997-05-21
DE59509358D1 (de) 2001-08-02
ATE202568T1 (de) 2001-07-15
FI951314A (fi) 1995-09-23
EP0673946A2 (de) 1995-09-27
JPH0841088A (ja) 1996-02-13

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