ES2156509A1 - Oxido acido con caracteristicas micro y mesoporosas: itq-36. - Google Patents

Oxido acido con caracteristicas micro y mesoporosas: itq-36.

Info

Publication number
ES2156509A1
ES2156509A1 ES009802283A ES9802283A ES2156509A1 ES 2156509 A1 ES2156509 A1 ES 2156509A1 ES 009802283 A ES009802283 A ES 009802283A ES 9802283 A ES9802283 A ES 9802283A ES 2156509 A1 ES2156509 A1 ES 2156509A1
Authority
ES
Spain
Prior art keywords
cations
acidity
treatment
itq
micro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009802283A
Other languages
English (en)
Other versions
ES2156509B1 (es
Inventor
Lara Antonio Chica
Canos Avelino Corma
Segui Vicente Fornes
Morales Urbano Diaz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Original Assignee
Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES009802283A priority Critical patent/ES2156509B1/es
Application filed by Consejo Superior de Investigaciones Cientificas CSIC, Universidad Politecnica de Valencia filed Critical Consejo Superior de Investigaciones Cientificas CSIC
Priority to DE69927054T priority patent/DE69927054T2/de
Priority to DK99953986T priority patent/DK1146015T3/da
Priority to MXPA01004163A priority patent/MXPA01004163A/es
Priority to CA002348387A priority patent/CA2348387C/en
Priority to PCT/ES1999/000344 priority patent/WO2000024673A1/es
Priority to CN99815121.1A priority patent/CN1244494C/zh
Priority to BRPI9915200-2A priority patent/BR9915200B1/pt
Priority to EP99953986A priority patent/EP1146015B1/en
Priority to US09/830,819 priority patent/US6555090B1/en
Priority to AT99953986T priority patent/ATE303343T1/de
Priority to ES99953986T priority patent/ES2249035T3/es
Priority to JP2000578249A priority patent/JP2002528368A/ja
Priority to NO20012048A priority patent/NO20012048L/no
Publication of ES2156509A1 publication Critical patent/ES2156509A1/es
Application granted granted Critical
Publication of ES2156509B1 publication Critical patent/ES2156509B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/049—Pillared clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Non-Insulated Conductors (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

"Oxido ácido con características micro y mesoporosas: ITQ-36". La invención trata de un material cristalino microporoso, con un difractograma de rayos X característico, constituido por tetraedros de oxígeno y un metal (T+4 y T+3) con posibilidad de introducir acidez superficial producida por la sustitución en la red de algunos cationes T+4 por cationes T+3, lo que da lugar a una deficiencia de carga estructural que puede ser compensada por protones, acidez Brönsted, y/o cationes de alta relación carga radio, acidez Lewis. El método de preparación se basa en la síntesis de un gel, su tratamiento hidrotermal en condiciones controladas, y el tratamiento del material laminar resultante con una solución de un compuesto orgánico, preferentemente de cadena hidrocarbonada larga, que contenga un grupo aceptor de protones. Este material hinchado es sometido a un tratamiento específico para la formación de pilares interlaminares de óxidos poliméricos, obteniendo un material pilareado que mantiene la separación entre las láminas, incluso después de la calcinación.
ES009802283A 1998-10-27 1998-10-27 Oxido acido con caracteristicas micro y mesoporosas: itq-36. Expired - Fee Related ES2156509B1 (es)

Priority Applications (14)

Application Number Priority Date Filing Date Title
ES009802283A ES2156509B1 (es) 1998-10-27 1998-10-27 Oxido acido con caracteristicas micro y mesoporosas: itq-36.
AT99953986T ATE303343T1 (de) 1998-10-27 1999-10-26 Saures oxid mit mikro- und mesoporösen eigenschaften
MXPA01004163A MXPA01004163A (es) 1998-10-27 1999-10-26 Oxido acido con caracteristicas micro y mesoporosas: itq-36.
CA002348387A CA2348387C (en) 1998-10-27 1999-10-26 Acid oxide with micro and mesoporous characteristics: itq-36
PCT/ES1999/000344 WO2000024673A1 (es) 1998-10-27 1999-10-26 Oxido acido con caracteristicas micro y mesoporosas: itq-36
CN99815121.1A CN1244494C (zh) 1998-10-27 1999-10-26 具有微孔和间隙孔特性的酸性氧化物
BRPI9915200-2A BR9915200B1 (pt) 1998-10-27 1999-10-26 material de óxido laminar em pilares, processo para sua preparação, composição catalìtica, seu uso, composto catalìtico e seu uso.
EP99953986A EP1146015B1 (en) 1998-10-27 1999-10-26 Acid oxide with micro and mesoporous characteristics: itq-36
DE69927054T DE69927054T2 (de) 1998-10-27 1999-10-26 Saures oxid mit mikro- und mesoporösen eigenschaften
DK99953986T DK1146015T3 (da) 1998-10-27 1999-10-26 Surt oxid med mikro- og mesoporöse egenskaber
ES99953986T ES2249035T3 (es) 1998-10-27 1999-10-26 Oxido acido que presenta caracteristicas micro y mesoporosas: itq-36.
JP2000578249A JP2002528368A (ja) 1998-10-27 1999-10-26 ミクロおよびメソポーラス特性を有する酸オキシドｉｔｑ−３６
US09/830,819 US6555090B1 (en) 1998-10-27 1999-10-26 Acid oxide with micro and mesoporous characteristics: ITQ-36
NO20012048A NO20012048L (no) 1998-10-27 2001-04-26 Surt oksid med mikro- og mesoporöse egenskaper: ITQ-36

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009802283A ES2156509B1 (es) 1998-10-27 1998-10-27 Oxido acido con caracteristicas micro y mesoporosas: itq-36.

Publications (2)

Publication Number Publication Date
ES2156509A1 true ES2156509A1 (es) 2001-06-16
ES2156509B1 ES2156509B1 (es) 2002-02-01

Family

ID=8305635

Family Applications (2)

Application Number Title Priority Date Filing Date
ES009802283A Expired - Fee Related ES2156509B1 (es) 1998-10-27 1998-10-27 Oxido acido con caracteristicas micro y mesoporosas: itq-36.
ES99953986T Expired - Lifetime ES2249035T3 (es) 1998-10-27 1999-10-26 Oxido acido que presenta caracteristicas micro y mesoporosas: itq-36.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES99953986T Expired - Lifetime ES2249035T3 (es) 1998-10-27 1999-10-26 Oxido acido que presenta caracteristicas micro y mesoporosas: itq-36.

Country Status (13)

Country Link
US (1) US6555090B1 (es)
EP (1) EP1146015B1 (es)
JP (1) JP2002528368A (es)
CN (1) CN1244494C (es)
AT (1) ATE303343T1 (es)
BR (1) BR9915200B1 (es)
CA (1) CA2348387C (es)
DE (1) DE69927054T2 (es)
DK (1) DK1146015T3 (es)
ES (2) ES2156509B1 (es)
MX (1) MXPA01004163A (es)
NO (1) NO20012048L (es)
WO (1) WO2000024673A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2156827B1 (es) * 1999-07-15 2002-03-01 Univ Valencia Politecnica Oxido acido microporoso con propiedades cataliticas. itq-18.
US6471939B1 (en) * 2001-05-29 2002-10-29 Exxonmobil Research And Engineering Company Synthetic porous crystalline material ITQ-12, its synthesis and use
EP1410844A1 (en) * 2002-10-15 2004-04-21 Centre National De La Recherche Scientifique (Cnrs) Silicon-based porous catalytic system for oligomerising light olefins
US7122500B2 (en) 2003-09-22 2006-10-17 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
WO2006083422A1 (en) 2005-01-31 2006-08-10 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, its making and use in coversion processes
EP1880760A4 (en) * 2005-04-21 2010-10-06 China Petroleum & Chemical HYDROGENATION CATALYST AND ITS APPLICATION
CN100388977C (zh) * 2005-04-21 2008-05-21 中国石油化工股份有限公司 以氧化硅-氧化铝为载体的含氟、磷加氢催化剂及其制备
US10590000B1 (en) * 2013-08-16 2020-03-17 United States Of America As Represented By The Administrator Of National Aeronautics And Space Administration High temperature, flexible aerogel composite and method of making same
WO2018019983A1 (en) * 2016-07-29 2018-02-01 Basf Se Process for the preparation of a zeolitic material having a fau-type framework structure and use thereof in the selective catalytic reduction of nox

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992011934A1 (en) * 1991-01-11 1992-07-23 Mobil Oil Corporation Layered oxide materials and swollen and pillared forms thereof
WO1997017290A1 (en) * 1995-11-08 1997-05-15 Shell Internationale Research Maatschappij B.V. Oxide materials and catalyst compositions containing them

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992011934A1 (en) * 1991-01-11 1992-07-23 Mobil Oil Corporation Layered oxide materials and swollen and pillared forms thereof
WO1997017290A1 (en) * 1995-11-08 1997-05-15 Shell Internationale Research Maatschappij B.V. Oxide materials and catalyst compositions containing them

Also Published As

Publication number Publication date
CA2348387A1 (en) 2000-05-04
NO20012048D0 (no) 2001-04-26
JP2002528368A (ja) 2002-09-03
DE69927054D1 (de) 2005-10-06
NO20012048L (no) 2001-06-20
EP1146015B1 (en) 2005-08-31
US6555090B1 (en) 2003-04-29
WO2000024673A1 (es) 2000-05-04
CA2348387C (en) 2009-04-07
ES2249035T3 (es) 2006-03-16
ES2156509B1 (es) 2002-02-01
CN1244494C (zh) 2006-03-08
ATE303343T1 (de) 2005-09-15
CN1332700A (zh) 2002-01-23
MXPA01004163A (es) 2002-06-04
BR9915200B1 (pt) 2009-12-01
DE69927054T2 (de) 2006-06-14
DK1146015T3 (da) 2005-11-21
BR9915200A (pt) 2002-01-29
EP1146015A1 (en) 2001-10-17

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