ES2154111A1 - Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo). - Google Patents

Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo).

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Publication number
ES2154111A1
ES2154111A1 ES009701978A ES9701978A ES2154111A1 ES 2154111 A1 ES2154111 A1 ES 2154111A1 ES 009701978 A ES009701978 A ES 009701978A ES 9701978 A ES9701978 A ES 9701978A ES 2154111 A1 ES2154111 A1 ES 2154111A1
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Spain
Prior art keywords
formula
stabilizers
bisphosphites
translation
machine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009701978A
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English (en)
Other versions
ES2154111B1 (es
Inventor
Horst Zinke
Karl Josef Kuhn
Wolfgang Wehner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Galata Chemicals GmbH
Original Assignee
Witco Vinyl Additives GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Witco Vinyl Additives GmbH filed Critical Witco Vinyl Additives GmbH
Publication of ES2154111A1 publication Critical patent/ES2154111A1/es
Application granted granted Critical
Publication of ES2154111B1 publication Critical patent/ES2154111B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317Phosphonic compounds, e.g. R—P(:O)(OR')2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/08Esters of oxyacids of phosphorus
    • C07F9/141Esters of phosphorous acids
    • C07F9/1411Esters of phosphorous acids with hydroxyalkyl compounds with further substituents on alkyl
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/08Esters of oxyacids of phosphorus
    • C07F9/141Esters of phosphorous acids
    • C07F9/144Esters of phosphorous acids with cycloaliphatic alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6561Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574Esters of oxyacids of phosphorus
    • C07F9/65742Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574Esters of oxyacids of phosphorus
    • C07F9/65746Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/52Phosphorus bound to oxygen only
    • C08K5/524Esters of phosphorous acids, e.g. of H3PO3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/042Metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)

Abstract

"Bisfosfitosmonómeros y oligómeros como estabilizadores del poli (cloruro de vinilo). Se describen composiciones que contienen (i) un material polimérico halogenado y (ii) por lo menos un fosfito de la fórmula I **FORMULA 1** en la que n es un número de 1 a 6, R es un eslabón bivalente de las fórmulas **FORMULA 2** **FORMULA 3** m es un número de 1 a 5, R{Sub,1}, R{sub,2}, R{sub,3} y R{sub,4}, con independencia entre sí, significan alquilo C{sub,4}-C{sub,22}, fenilalquilo C{sub,7}-C{sub,9}, cicloalquilo C{sub,5}-C{sub,8} o (alquil C{sub,1}-C{sub,4})- cicloalquilo C{sub,5}-C{sub,8} o bien R{sub,1} y R{sub,2} y/o R{sub,3} y R{sub,4}, juntos, significan alquileno C{sub,2}- C{sub,9} o un grupo de la fórmula **FORMULA 4** así como nuevos compuestos de la fórmula I y su utilización como estabilizadores.
ES009701978A 1996-09-25 1997-09-22 Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo). Expired - Fee Related ES2154111B1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH234396 1996-09-25

Publications (2)

Publication Number Publication Date
ES2154111A1 true ES2154111A1 (es) 2001-03-16
ES2154111B1 ES2154111B1 (es) 2001-10-16

Family

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ES009701978A Expired - Fee Related ES2154111B1 (es) 1996-09-25 1997-09-22 Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo).

Country Status (7)

Country Link
KR (1) KR100509258B1 (es)
BE (1) BE1012645A5 (es)
DK (1) DK110297A (es)
ES (1) ES2154111B1 (es)
NL (1) NL1007102C2 (es)
TW (1) TW402619B (es)
ZA (1) ZA978530B (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5914758B2 (ja) * 2012-06-22 2016-05-11 ドーヴァー ケミカル コーポレイション 脂環式ポリホスファイトポリマー安定剤

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3283037A (en) * 1963-09-12 1966-11-01 Eastman Kodak Co Bis(cyclic 2, 2-dimethyltrimethylene) 1, 4-cyclohexanedimethylene phosphite
US4088709A (en) * 1977-07-01 1978-05-09 Eastman Kodak Company Phosphorus stabilized-polyester-polycarbonate molding compositions
DD229995A1 (de) * 1984-12-13 1985-11-20 Greiz Doelau Chemie Fluessiges cadmiumfreies stabilisatorsystem fuer formmassen des polyvinylchlorids
EP0437886A2 (en) * 1990-01-19 1991-07-24 EUROPEAN VINYLS CORPORATION (ITALIA) S.p.A. Stabilizer composition for polymers of vinyl chloride and polymeric compositions containing such compositions
EP0635512A1 (en) * 1993-07-22 1995-01-25 General Electric Company Cyclic phosphites as polymer stabilizers

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1236184B (de) * 1961-08-07 1967-03-09 Pure Chem Ltd Verfahren zur Herstellung von gegebenenfalls verschaeumten Polyurethanen
US3714116A (en) * 1970-04-08 1973-01-30 Raychem Corp Polyimide compositions
BE766399A (fr) * 1970-04-29 1971-10-28 Union Carbide Corp Polymeres ethyleniques thermostables
US3886114A (en) * 1973-08-24 1975-05-27 Vanderbilt Co R T Synergistic antioxidant combination

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3283037A (en) * 1963-09-12 1966-11-01 Eastman Kodak Co Bis(cyclic 2, 2-dimethyltrimethylene) 1, 4-cyclohexanedimethylene phosphite
US4088709A (en) * 1977-07-01 1978-05-09 Eastman Kodak Company Phosphorus stabilized-polyester-polycarbonate molding compositions
DD229995A1 (de) * 1984-12-13 1985-11-20 Greiz Doelau Chemie Fluessiges cadmiumfreies stabilisatorsystem fuer formmassen des polyvinylchlorids
EP0437886A2 (en) * 1990-01-19 1991-07-24 EUROPEAN VINYLS CORPORATION (ITALIA) S.p.A. Stabilizer composition for polymers of vinyl chloride and polymeric compositions containing such compositions
EP0635512A1 (en) * 1993-07-22 1995-01-25 General Electric Company Cyclic phosphites as polymer stabilizers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
National Polychemicals, Inc. Neth. Appl. 6410226, 11.03.1965. Columbus, OH (EE.UU) Chemical Abstracts, Vol. 63, 1965, resumen no 5850e, resumen. *
TCHERKERZOFF, N. New organic phosphorus compounds. Rev. Ins. Franc. Petrole Ann. Combust. liquides. 1963, 18 (3) 438-70. Columbus, OH (EE.UU): Chemical Abstracts, Vol. 59, resumen No 12800g, resumen. *

Also Published As

Publication number Publication date
NL1007102C2 (nl) 2000-11-14
DK110297A (da) 1998-03-26
MX9707315A (es) 1998-08-30
ES2154111B1 (es) 2001-10-16
KR19980024936A (ko) 1998-07-06
KR100509258B1 (ko) 2005-12-14
ZA978530B (en) 1998-03-25
BE1012645A5 (fr) 2001-02-06
NL1007102A1 (nl) 1998-03-26
TW402619B (en) 2000-08-21

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