ES2147446T3 - Procedimiento de adicion de oro en dos etapas para preparar un catalizador del acetato de vinilo. - Google Patents

Procedimiento de adicion de oro en dos etapas para preparar un catalizador del acetato de vinilo.

Info

Publication number
ES2147446T3
ES2147446T3 ES97921112T ES97921112T ES2147446T3 ES 2147446 T3 ES2147446 T3 ES 2147446T3 ES 97921112 T ES97921112 T ES 97921112T ES 97921112 T ES97921112 T ES 97921112T ES 2147446 T3 ES2147446 T3 ES 2147446T3
Authority
ES
Spain
Prior art keywords
catalyst
gold
vinyl acetate
stages
prepare
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97921112T
Other languages
English (en)
Inventor
Ioan Nicolau
Azael T Flores
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CNA Holdings LLC
Original Assignee
Hoechst Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/696,413 external-priority patent/US5691267A/en
Application filed by Hoechst Celanese Corp filed Critical Hoechst Celanese Corp
Application granted granted Critical
Publication of ES2147446T3 publication Critical patent/ES2147446T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCEDIMIENTO PARA PREPARAR UN CATALIZADOR, EN DONDE SE IMPREGNA UN PORTADOR DEL CATALIZADOR CON COMPUESTOS SOLUBLES EN AGUA DE PALADIO Y ORO, SEGUIDOS POR LA FIJACION Y LA REDUCCION ENTONCES, DE LOS COMPUESTOS FIJADOS DE PALADIO Y ORO AL METAL DE PALADIDO Y ORO, SEGUIDO POR LA IMPREGNACION DEL PORTADOR CON UNA SEGUNDA CANTIDAD DE UN COMPUESTO SOLUBLE EN AGUA DE ORO. SE FIJA LA SEGUNDA CANTIDAD DE COMPUESTO DE ORO, REDUCIDA ENTONCES A METAL DE ORO. SE IMPREGNA ENTONCES EL CATALIZADOR CON UN ACETATO DE METAL ALCALINO, COMO UN ACETATO DE POTASIO. EL CATALIZADOR PUEDE EMPLEARSE PARA SINTETIZAR ESTERES INSATURADOS, COMO UN ACETATO DE VINILO.
ES97921112T 1996-04-16 1997-04-08 Procedimiento de adicion de oro en dos etapas para preparar un catalizador del acetato de vinilo. Expired - Lifetime ES2147446T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63327596A 1996-04-16 1996-04-16
US08/696,413 US5691267A (en) 1996-04-16 1996-08-13 Two step gold addition method for preparing a vinyl acetate catalyst

Publications (1)

Publication Number Publication Date
ES2147446T3 true ES2147446T3 (es) 2000-09-01

Family

ID=27091839

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97921112T Expired - Lifetime ES2147446T3 (es) 1996-04-16 1997-04-08 Procedimiento de adicion de oro en dos etapas para preparar un catalizador del acetato de vinilo.

Country Status (16)

Country Link
EP (1) EP0898494B1 (es)
JP (1) JP4049395B2 (es)
CN (1) CN1090995C (es)
AT (1) ATE193844T1 (es)
AU (1) AU712296B2 (es)
BR (1) BR9708622A (es)
CA (1) CA2249326C (es)
CZ (1) CZ291511B6 (es)
DE (1) DE69702313T2 (es)
ES (1) ES2147446T3 (es)
IN (1) IN192421B (es)
NO (1) NO316996B1 (es)
NZ (1) NZ332307A (es)
PL (1) PL329443A1 (es)
TR (1) TR199802087T2 (es)
WO (1) WO1997038790A1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6034030A (en) * 1994-02-22 2000-03-07 Celanese International Corporation Vinyl acetate catalyst preparation method
US5948724A (en) * 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
US5859287A (en) * 1997-10-30 1999-01-12 Celanese International Corporation Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals
TW201236755A (en) 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
KR100932575B1 (ko) 2004-12-20 2009-12-17 셀라니즈 인터내셔날 코포레이션 촉매용 개질된 지지체 물질
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US8884052B2 (en) 2011-12-15 2014-11-11 Celanese International Corporation Production of diacetoxyethylene by direct acetoxylation
DE102012003232A1 (de) * 2012-02-20 2013-08-22 Clariant Produkte (Deutschland) Gmbh Nachvergoldung von Pd-Au-gecoateten Schalenkatalysatoren
DE102012008715A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Herstellung von Schalenkatalysatoren in einer Beschichtungsvorrichtung
DE102012008714A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Vorimprägnierung von Schalenkatalysatoren mit einem Acetat
CN102775298A (zh) * 2012-08-06 2012-11-14 南京林业大学 一种羧酸乙烯酯的制备方法
CN114073985B (zh) * 2020-08-19 2024-03-29 中国石油化工股份有限公司 醋酸乙烯催化剂、其制备方法和应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
US5314858A (en) * 1992-10-14 1994-05-24 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate

Also Published As

Publication number Publication date
CZ333198A3 (cs) 1999-08-11
BR9708622A (pt) 2000-01-04
DE69702313T2 (de) 2001-01-25
IN192421B (es) 2004-04-24
TR199802087T2 (xx) 1999-01-18
PL329443A1 (en) 1999-03-29
DE69702313D1 (de) 2000-07-20
CN1090995C (zh) 2002-09-18
CZ291511B6 (cs) 2003-03-12
NZ332307A (en) 1999-10-28
WO1997038790A1 (en) 1997-10-23
NO316996B1 (no) 2004-07-19
EP0898494B1 (en) 2000-06-14
EP0898494A1 (en) 1999-03-03
AU712296B2 (en) 1999-11-04
CA2249326C (en) 2006-06-06
AU2724097A (en) 1997-11-07
CN1216482A (zh) 1999-05-12
ATE193844T1 (de) 2000-06-15
NO984809D0 (no) 1998-10-15
JP2000508580A (ja) 2000-07-11
JP4049395B2 (ja) 2008-02-20
CA2249326A1 (en) 1997-10-23
NO984809L (no) 1998-12-08

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