ES2142591T3 - Dispersiones acuosas, no gelificantes, de poliuretanos anionicos y proceso para su fabricacion. - Google Patents

Dispersiones acuosas, no gelificantes, de poliuretanos anionicos y proceso para su fabricacion.

Info

Publication number
ES2142591T3
ES2142591T3 ES96918340T ES96918340T ES2142591T3 ES 2142591 T3 ES2142591 T3 ES 2142591T3 ES 96918340 T ES96918340 T ES 96918340T ES 96918340 T ES96918340 T ES 96918340T ES 2142591 T3 ES2142591 T3 ES 2142591T3
Authority
ES
Spain
Prior art keywords
dispersions
prepolymer
water
polyurethane
diisocyanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96918340T
Other languages
English (en)
Inventor
Youlu Duan
Sonja Stammler
Scott Rhein
Lowell Lindquist
Lincoln Mo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HB Fuller Licensing and Financing Inc
Original Assignee
HB Fuller Licensing and Financing Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/480,780 external-priority patent/US5610232A/en
Priority claimed from US08/561,197 external-priority patent/US5872182A/en
Application filed by HB Fuller Licensing and Financing Inc filed Critical HB Fuller Licensing and Financing Inc
Application granted granted Critical
Publication of ES2142591T3 publication Critical patent/ES2142591T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/722—Combination of two or more aliphatic and/or cycloaliphatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/833—Chemically modified polymers by nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/838—Chemically modified polymers by compounds containing heteroatoms other than oxygen, halogens, nitrogen, sulfur, phosphorus or silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00—Compositions for adhesives
    • C08G2170/80—Compositions for aqueous adhesives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

DISPERSIONES ACUOSAS ADHESIVAS DE POLIURETANOS ANIONICOS QUE PRESENTAN ALTA RESITENCIA TERMICA Y BAJA TEMPERATURA DE ACTIVACION, AUN CUANDO SON EMPLEADAS SIN ADICION DE UN RETICULANTE. EL POLIURETANO ES EL PRODUCTO DE REACCION DEL AGUA Y UN PREPOLIMERO DE POLIURETANO TERMINADO POR UN ISOCIANATO. EL PREPOLIMERO DE POLIURETANO ES EL PRODUCTO DE REACCION DE UN COMPONENTE POLIOL Y UN COMPONENTE DIISOCIANATO, INCLUYENDO EL COMPONENTE POLIOL: UN POLIOL POLIESTER SULFONADO, UN ACIDO HIDROXICARBOXILICO DE FORMULA (HO) SUB,X}R(COOH) SUB,Y} DONDE (R) REPRESENTA UN RADICAL HIDROCARBURO LINEAL O RAMIFICADO QUE CONTIENE ENTRE 1 Y 12 ATOMOS DE CARBONO, Y X E Y REPRESENTAN VALORES ENTRE 1 Y 3, Y OPCIONALMENTE, UN DIOL ALIFATICO DE BAJO PESO MOLECULAR CON UN PESO MOLECULAR DE ENTRE 60 Y 400, UN POLIOL NO SULFONADO, Y SELECCIONANDOSE EL COMPONENTE DIISOCIANATO DE ENTRE EL GRUPO QUE CONSISTE EN DIISOCIANATOS AROMATICOS, DIISOCIANATO DE ISOFORONA, DIISOCIANATO DE HEXAMETILENO, Y MEZCLAS DE ESTOS. LAS DISPERSIONES SE PREPARAN MEZCLANDO PREPOLIMERO Y AGUA A UNA TEMPERATURA DE AL MENOS 60 (GRADOS) C DURANTE UN TIEMPO SUFICIENTE PARA QUE LOS GRUPOS ISOCIANATO REACCIONEN COMPLETAMENTE CON EL AGUA EN UNA REACCION DE AUTOEXTENSION, TIPICAMENTE AL MENOS 0.5 HORAS. LAS DISPERSIONES DE LA INVENCION PROPORCIONAN UNIONES ADHESIVAS DE MAS ALTA RESISTENCIA QUE DISPERSIONES DE PREPOLIMERO IDENTICAS EXTENDIDAS CON UN EXTENDEDOR DE CADENA DIAMINA, EN LUGAR DE AGUA, TRAS LA DISPERSION. LA COMPOSICION ADHESIVA PUEDE TAMBIEN SER MODIFICADA PARA INCLUIR UN POLIMERO O COPOLIMERO DISPERSO DE UN MONOMERO DE INSATURACION ETILENICA. TALES COMPOSICIONES PUEDEN SER OBTENIDAS PREPARANDO EL POLIURETANO SULFONADO EN PRESENCIA DE UN MONOMERO DE INSATURACION ETILENICA Y POSTERIORMENTE SOMETIENDO LA MEZCLA A POLIMERIZACION POR RADICALES LIBRES.
ES96918340T 1995-06-07 1996-06-07 Dispersiones acuosas, no gelificantes, de poliuretanos anionicos y proceso para su fabricacion. Expired - Lifetime ES2142591T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/480,780 US5610232A (en) 1993-09-24 1995-06-07 Aqueous non-gelling, anionic polyurethane dispersions and process for their manufacture
US08/561,197 US5872182A (en) 1994-09-09 1995-11-21 Water-based polyurethanes for footwear

Publications (1)

Publication Number Publication Date
ES2142591T3 true ES2142591T3 (es) 2000-04-16

Family

ID=27046708

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96918340T Expired - Lifetime ES2142591T3 (es) 1995-06-07 1996-06-07 Dispersiones acuosas, no gelificantes, de poliuretanos anionicos y proceso para su fabricacion.

Country Status (10)

Country Link
EP (1) EP0830402B1 (es)
JP (1) JPH11507675A (es)
KR (1) KR19990022511A (es)
AT (1) ATE188496T1 (es)
AU (1) AU695629B2 (es)
CA (1) CA2219378A1 (es)
DE (1) DE69606033T2 (es)
ES (1) ES2142591T3 (es)
NZ (1) NZ310261A (es)
WO (1) WO1996040811A1 (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5834554A (en) * 1996-03-05 1998-11-10 H. B. Fuller Licensing & Financing, Inc. Laminating adhesives for flexible packaging
KR100543602B1 (ko) * 1997-12-31 2006-09-07 주식회사 케이씨씨 자동차 상도용 우레탄 변성 폴리에스터 폴리올 수분산 수지의제조방법 및 이를 함유하는 수용성 도료 조성물
US6180244B1 (en) 1998-02-17 2001-01-30 3M Innovative Properties Company Waterbased thermoforming adhesives
CN1306547A (zh) * 1998-06-24 2001-08-01 阿克佐诺贝尔公司 离子型聚氨酯
US6287698B1 (en) * 1998-12-08 2001-09-11 H. B. Fuller Licensing & Financing, Inc. Process for improving hydrolysis resistance of polyurethane dispersion adhesives and bonded assemblies produced therefrom
US20020061970A1 (en) * 2000-09-14 2002-05-23 Hidenori Sawada Resin composition for coating material
TWI227256B (en) * 2000-10-25 2005-02-01 Dainippon Ink & Chemicals Aqueous dispersions of polyurethane resins and aqueous adhesives
JP5754068B2 (ja) * 2000-10-25 2015-07-22 Dic株式会社 ポリウレタン樹脂水性分散体
JP5376190B2 (ja) * 2000-11-15 2013-12-25 Ｄｉｃ株式会社 ポリウレタン水性分散体
JP5358863B2 (ja) * 2000-11-15 2013-12-04 Ｄｉｃ株式会社 ポリウレタン水性分散体
ITMI20011424A1 (it) * 2001-07-05 2003-01-05 Ausimont Spa Dispersioni di polimeri fluorurati
US6695968B2 (en) * 2001-09-10 2004-02-24 Baker Hughes Incorporated Removal of water solubilized organics
NO331147B1 (no) * 2001-09-10 2011-10-24 Baker Hughes Inc Fremgangsmåte for å fjerne oppløste organiske stoffer fra en vannlignende flytende fase.
KR100503072B1 (ko) * 2002-10-25 2005-07-21 삼성전자주식회사 오버코트층 형성용 조성물 및 이를 채용한 유기감광체
US8128998B2 (en) 2004-01-12 2012-03-06 Ecolab Usa Inc. Polyurethane coating cure enhancement using ultrafine zinc oxide
US7527861B2 (en) 2004-01-12 2009-05-05 Ecolab, Inc. Jobsite-renewable multilayer floor finish with enhanced hardening rate
US7655718B2 (en) 2004-01-12 2010-02-02 Ecolab Inc. Polyurethane coating cure enhancement using zinc carbonate initiators
WO2005070985A1 (en) * 2004-01-12 2005-08-04 Ecolab Inc. Polyurethane coating cure enhancement using zirconium carbonate
JP4783553B2 (ja) * 2004-02-18 2011-09-28 三井化学ポリウレタン株式会社 ポリウレタン水性分散系の製造方法
DE102004036606A1 (de) * 2004-07-28 2006-03-23 Henkel Kgaa Packmittel
US20070037955A1 (en) * 2005-08-15 2007-02-15 Richards James L Polymeric diluents for structural adhesives
EP2186841A1 (de) * 2008-11-14 2010-05-19 Bayer MaterialScience AG Vernetzbare Polyurethan-Dispersionen
FR2967402B1 (fr) * 2010-11-15 2014-03-07 Arjowiggins Palalda Materiau fibreux d'emballage thermoscellant adapte a l'usage medical
CN103145940A (zh) * 2013-03-19 2013-06-12 陕西科技大学 一种制备水性聚氨酯的方法
JP6952494B2 (ja) * 2017-05-25 2021-10-20 住友化学株式会社 接着剤組成物及び偏光板

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3630045A1 (de) * 1986-09-04 1988-03-17 Bayer Ag Klebstoff und die verwendung des klebstoffs zur herstellung von verklebungen
DE3728140A1 (de) * 1987-08-22 1989-03-02 Bayer Ag Waessrige loesungen oder dispersionen von polyisocyanat-polyadditionsprodukten, ein verfahren zur herstellung der waessrigen loesungen oder dispersionen sowie ihre verwendung als klebstoff
JPH02128316A (ja) * 1988-11-08 1990-05-16 Toyobo Co Ltd 磁気記録媒体
DE4227355A1 (de) * 1992-08-19 1994-02-24 Hoechst Ag Wasserverdünnbare Zweikomponenten-Überzugsmasse
US5608000A (en) * 1993-09-24 1997-03-04 H. B. Fuller Licensing & Financing, Inc. Aqueous polyurethane dispersion adhesive compositions with improved heat resistance
KR960704957A (ko) * 1993-09-24 1996-10-09 로날드 에이. 페올 수성 음이온 폴리우레탄 분산물(aqueous anionic polyurethane dispersions)

Also Published As

Publication number Publication date
AU695629B2 (en) 1998-08-20
WO1996040811A1 (en) 1996-12-19
ATE188496T1 (de) 2000-01-15
EP0830402A1 (en) 1998-03-25
JPH11507675A (ja) 1999-07-06
NZ310261A (en) 1999-04-29
DE69606033D1 (de) 2000-02-10
DE69606033T2 (de) 2000-07-13
KR19990022511A (ko) 1999-03-25
AU6102796A (en) 1996-12-30
EP0830402B1 (en) 2000-01-05
CA2219378A1 (en) 1996-12-19

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