ES2140221T3 - Procedimiento para preparar un catalizador de acetato de vinilo empleando un borato de metal alcalino. - Google Patents

Procedimiento para preparar un catalizador de acetato de vinilo empleando un borato de metal alcalino.

Info

Publication number
ES2140221T3
ES2140221T3 ES97909050T ES97909050T ES2140221T3 ES 2140221 T3 ES2140221 T3 ES 2140221T3 ES 97909050 T ES97909050 T ES 97909050T ES 97909050 T ES97909050 T ES 97909050T ES 2140221 T3 ES2140221 T3 ES 2140221T3
Authority
ES
Spain
Prior art keywords
alkaline metal
gold
vinyl acetate
paladium
metal borate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97909050T
Other languages
English (en)
Inventor
Ioan Nicolau
Philip M Colling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CNA Holdings LLC
Original Assignee
Hoechst Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Celanese Corp filed Critical Hoechst Celanese Corp
Application granted granted Critical
Publication of ES2140221T3 publication Critical patent/ES2140221T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN METODO DE PREPARACION DE UN CATALIZADOR PARA LA SINTESIS DE ESTER INSATURADO, EN EL QUE SE IMPREGNA UN TRANSPORTADOR CATALITICO CON UNA SAL DE PALADIO HIDROSOLUBLE Y UN COMPUESTO DE ORO HIDROSOLUBLE, MEDIANTE PRECIPITACION DE DICHAS SALES CON UNA COMPOSICION FIJADORA QUE CONTIENE UN BORATO DE METAL ALCALINO, PARA FORMAR COMPUESTOS DE PALADIO Y ORO INSOLUBLES EN AGUA. LOS COMPUESTOS DE PALADIO Y ORO FIJADOS SON REDUCIDOS A PALADIO Y ORO METALICOS CON ETILENO O HIDRAZINA, SEGUIDO DE IMPREGNACION DEL TRANSPORTADOR CON UN ACETATO DE METAL ALCALINO, COMO ACETATO POTASICO. EL CATALIZADOR DE SINTESIS DE ESTER INSATURADO SE PUEDE EMPLEAR PARA SINTETIZAR ACETATO VINILICO CON EXTREMOS PESADOS REDUCIDOS.
ES97909050T 1996-04-01 1997-03-18 Procedimiento para preparar un catalizador de acetato de vinilo empleando un borato de metal alcalino. Expired - Lifetime ES2140221T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US62779196A 1996-04-01 1996-04-01

Publications (1)

Publication Number Publication Date
ES2140221T3 true ES2140221T3 (es) 2000-02-16

Family

ID=24516151

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97909050T Expired - Lifetime ES2140221T3 (es) 1996-04-01 1997-03-18 Procedimiento para preparar un catalizador de acetato de vinilo empleando un borato de metal alcalino.

Country Status (20)

Country Link
EP (1) EP0891224B1 (es)
JP (1) JP2000517234A (es)
KR (1) KR20000005155A (es)
CN (1) CN1215353A (es)
AR (1) AR006430A1 (es)
AT (1) ATE186852T1 (es)
AU (1) AU711265B2 (es)
BR (1) BR9708398A (es)
CA (1) CA2249187A1 (es)
CZ (1) CZ315998A3 (es)
DE (1) DE69700836T2 (es)
ES (1) ES2140221T3 (es)
ID (1) ID19633A (es)
NO (1) NO984523L (es)
NZ (1) NZ332100A (es)
PL (1) PL329048A1 (es)
TR (1) TR199801966T2 (es)
WO (1) WO1997036678A1 (es)
YU (1) YU10897A (es)
ZA (1) ZA972700B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19734974A1 (de) 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
DE19754991C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
US6534438B1 (en) 2000-07-26 2003-03-18 Bp Chemicals Limited Catalyst composition
TW201236755A (en) 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
KR100670492B1 (ko) 2004-11-29 2007-01-16 삼성에스디아이 주식회사 리튬 이차전지용 캔 및 이를 이용한 리튬 이차전지
EP2380661A3 (en) 2004-12-20 2012-02-01 Celanese International Corporation Modified support materials for catalysts
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
GB201110850D0 (en) 2011-03-04 2011-08-10 Johnson Matthey Plc Catalyst and mehtod of preparation
CN104549501B (zh) * 2013-10-28 2017-05-17 中国石油化工股份有限公司 双醋酸亚乙酯法醋酸乙烯催化剂及醋酸乙烯合成方法
DE102014223246A1 (de) * 2014-11-14 2016-05-19 Wacker Chemie Ag Verfahren zur Herstellung von Vinylacetat

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE149096T1 (de) * 1992-03-30 1997-03-15 Union Carbide Chem Plastic Verfahren für die herstellung eines katalysators für die bereitung von alkenylalkanoaten
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
DE4323981C1 (de) * 1993-07-16 1995-03-09 Hoechst Ag Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat

Also Published As

Publication number Publication date
EP0891224A1 (en) 1999-01-20
NO984523L (no) 1998-11-19
ID19633A (id) 1998-07-23
CA2249187A1 (en) 1997-10-09
EP0891224B1 (en) 1999-11-24
NO984523D0 (no) 1998-09-28
CZ315998A3 (cs) 1999-07-14
AR006430A1 (es) 1999-08-25
ZA972700B (en) 1998-09-28
KR20000005155A (ko) 2000-01-25
WO1997036678A1 (en) 1997-10-09
BR9708398A (pt) 1999-08-03
TR199801966T2 (xx) 1999-01-18
CN1215353A (zh) 1999-04-28
AU711265B2 (en) 1999-10-07
JP2000517234A (ja) 2000-12-26
ATE186852T1 (de) 1999-12-15
PL329048A1 (en) 1999-03-01
DE69700836D1 (de) 1999-12-30
AU2079697A (en) 1997-10-22
YU10897A (sh) 1999-06-15
DE69700836T2 (de) 2000-05-04
NZ332100A (en) 2000-03-27

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