ES2127932T3 - Copolimeros de bloques elastomericos solidos. - Google Patents

Copolimeros de bloques elastomericos solidos.

Info

Publication number
ES2127932T3
ES2127932T3 ES94920820T ES94920820T ES2127932T3 ES 2127932 T3 ES2127932 T3 ES 2127932T3 ES 94920820 T ES94920820 T ES 94920820T ES 94920820 T ES94920820 T ES 94920820T ES 2127932 T3 ES2127932 T3 ES 2127932T3
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ES
Spain
Prior art keywords
polymer
units
block copolymers
block
conjugated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94920820T
Other languages
English (en)
Inventor
Ellen Bernice Brandes
Frederick Charles Loveless
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of ES2127932T3 publication Critical patent/ES2127932T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/023—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/005—Modified block copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/94—Hydrogenation of a polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Ink Jet (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyethers (AREA)

Abstract

SE MUESTRAN COPOLIMEROS DE BLOQUE ELASTOMERICO SOLIDOS NOVEDOSOS CON UNA ESTABILIDAD TERMICA Y OXIDATIVA EXCELENTES, DONDE LOS BLOQUES TERMINALES SON CADA UNO UN POLIMERO (D POLIMERO) DE AL MENOS UN DIENO D CONJUGADO, QUE ES UN HIDROCARBURO QUE CONTIENE UNA ESTRUCTURA DE DIENO 1,3-CONJUGADO DONDE 2- Y 3ATOMOS DE CARBON SE AÑADEN CADA UNO AL GRUPO DEL LADO HIDROCARBILO, POR EJEMPLO, 2,3-DIMETIL-1,3-BUTADIENO, CON UNA PREPONDERANCIA DE UNIDADES D POLIMERIZADAS DE 1,4 UNIDADES; Y AL MENOS UN BLOQUE INTERIOR POLIMERO HIDROGENADO (I POLIMERO) DE AL MENOS UN DIENO I CONJUGADO QUE ES UN HIDROCARBURO QUE CONTIENE UNA ESTRUCTURA DE DIENO 1,3-CONJUGADO, DONDE UNO DE LOS ATOMOS DE CARBONO 2- Y 3- SE FIJA ADICIONALMENTE AL GRUPO DE LADO HIDROCARBILO Y EL OTRO AL ATOMO DE HIDROGENO, POR EJEMPLO ISOPRENO. LOS COPOLIMEROS DE BLOQUE PUEDEN PREPARASE HIDROGENANDO SELECTIVA Y SUSTANCIALMENTE TODAS LAS UNIDADES DE POLIMERO I DE UN COPOLIMERO DE BLOQUE PRECURSOR CON UN NUMERO SUFICIENTE DE UNIDADES D EN LOS BLOQUES DE POLIMERO D QUE RETIENEN SU INSATURACION EN LA HIDROGENACION SELECTIVA PARA PERMITIR LA VULCANIZACION DEL COPOLIMERO DE BLOQUE.
ES94920820T 1993-06-24 1994-06-24 Copolimeros de bloques elastomericos solidos. Expired - Lifetime ES2127932T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/080,638 US5438102A (en) 1993-06-24 1993-06-24 Solid elastomeric block copolymers

Publications (1)

Publication Number Publication Date
ES2127932T3 true ES2127932T3 (es) 1999-05-01

Family

ID=22158644

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94920820T Expired - Lifetime ES2127932T3 (es) 1993-06-24 1994-06-24 Copolimeros de bloques elastomericos solidos.

Country Status (11)

Country Link
US (2) US5438102A (es)
EP (1) EP0705286B1 (es)
JP (1) JPH08512067A (es)
KR (1) KR960703140A (es)
AU (1) AU686193B2 (es)
CA (1) CA2162283A1 (es)
DE (1) DE69415980T2 (es)
ES (1) ES2127932T3 (es)
FI (1) FI956224A0 (es)
NO (1) NO309149B1 (es)
WO (1) WO1995000566A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6248702B1 (en) 1990-01-16 2001-06-19 Mobil Oil Corporation Dispersant and dispersant viscosity index improvers from selectively hydrogenated aryl-substituted olefin containing diene copolymers
US6162768A (en) * 1990-01-16 2000-12-19 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: free radically initiated direct grafting reaction products
US6054539A (en) * 1998-07-31 2000-04-25 Mobil Oil Corporation Selectively hydrogenated polymer compositions: polybutadiene-isoprene-polybutadiene
US6228817B1 (en) 1990-01-16 2001-05-08 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US6103676A (en) * 1998-06-23 2000-08-15 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: hydroformylation/reductive amination reaction products
US6034184A (en) * 1998-06-23 2000-03-07 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: Mannich reaction products
US5780540A (en) * 1990-01-16 1998-07-14 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers
US5310814A (en) * 1991-03-15 1994-05-10 Exxon Chemical Patents Inc. Viscosity modifier polybutadiene polymers
TW337532B (en) * 1994-11-16 1998-08-01 Shell Int Research A chemical resistant composition and its use
JP3469384B2 (ja) * 1995-12-14 2003-11-25 株式会社クラレ 接着剤組成物
AT408229B (de) * 1997-02-11 2001-09-25 Borealis Ag Verwendung von thermoplastischen elastomeren zur verbesserung der stabilität von polyolefinen gegenüber ionisierender strahlung
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
US6215033B1 (en) 1998-12-11 2001-04-10 Mobil Oil Corporation Dispersants and dispersant viscosity index improvers from selectively hydrogenated polymers: blends with lower molecular weight components
US6319881B1 (en) 1998-06-23 2001-11-20 Exxonmobil Oil Corporation Haze free oil additive compositions containing dispersants from selectively hydrogenated diene copolymers
AU7582400A (en) 1999-09-17 2001-04-17 University Of Akron, The A self-reinforced rubber matrix having high glass transition temperature thermoset domains
US6579940B1 (en) 1999-10-28 2003-06-17 Edwards Lifesciences Corporation Thermoplastic elastomeric material as a replacement for natural rubber latex
US7288590B2 (en) * 2000-06-27 2007-10-30 Exxon Chemical Patents, Inc. Adhesives with improved die-cutting performance
US6613838B1 (en) 2000-08-30 2003-09-02 Edwards Lifesciences Corporation Synthetic rubber elastomers as replacements for natural rubber latex
US7074855B2 (en) 2001-05-01 2006-07-11 Kuraray Co., Ltd. Thermoplastic elastomer composition
US8580874B2 (en) 2007-04-20 2013-11-12 Firestone Polymers, Llc Polymer-modified asphalt compositions
KR101183733B1 (ko) * 2008-02-08 2012-09-17 아사히 가세이 케미칼즈 가부시키가이샤 열가소성 엘라스토머 조성물 및 그의 제조 방법
CN106749910B (zh) * 2016-11-29 2019-06-04 中国科学院长春应用化学研究所 一种2,3-二甲基-1,3-丁二烯基嵌段共聚物及其制备方法
CN111053945B (zh) * 2019-12-30 2021-12-10 安徽雄亚塑胶科技有限公司 一种环保高强度高回弹tpe止血带材料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4107236A (en) * 1976-02-09 1978-08-15 Phillips Petroleum Company Hydrogenated block copolymers containing a block derived from low vinyl polybutadiene and a block derived from medium vinyl polybutadiene
JPS5575441A (en) * 1978-12-04 1980-06-06 Asahi Chem Ind Co Ltd Styrene resin composition having excellent impact resistance
US4294942A (en) * 1979-01-16 1981-10-13 The Goodyear Tire & Rubber Company Rubbery copolymers of 2,3-dimethyl 1,3-butadiene
US4879349A (en) * 1987-11-05 1989-11-07 Shell Oil Company Selective hydrogenation process
JP2593900B2 (ja) * 1987-12-24 1997-03-26 株式会社クラレ 樹脂組成物
JP2725354B2 (ja) * 1989-03-16 1998-03-11 日本合成ゴム株式会社 ブロック共重合体およびその組成物
US5187236A (en) * 1990-01-16 1993-02-16 Mobil Oil Corporation Solid block and random elastomeric copolymers

Also Published As

Publication number Publication date
US5552492A (en) 1996-09-03
NO955190D0 (no) 1995-12-20
NO955190L (no) 1995-12-20
WO1995000566A1 (en) 1995-01-05
NO309149B1 (no) 2000-12-18
US5438102A (en) 1995-08-01
AU7179194A (en) 1995-01-17
KR960703140A (ko) 1996-06-19
FI956224A (fi) 1995-12-22
FI956224A0 (fi) 1995-12-22
DE69415980D1 (de) 1999-02-25
EP0705286A1 (en) 1996-04-10
CA2162283A1 (en) 1995-01-05
AU686193B2 (en) 1998-02-05
DE69415980T2 (de) 1999-05-27
JPH08512067A (ja) 1996-12-17
EP0705286A4 (en) 1996-06-12
EP0705286B1 (en) 1999-01-13

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