ES2127438T3 - Elastomeros de poliuretano cicloalifaticos termoplasticos. - Google Patents

Elastomeros de poliuretano cicloalifaticos termoplasticos.

Info

Publication number
ES2127438T3
ES2127438T3 ES95111995T ES95111995T ES2127438T3 ES 2127438 T3 ES2127438 T3 ES 2127438T3 ES 95111995 T ES95111995 T ES 95111995T ES 95111995 T ES95111995 T ES 95111995T ES 2127438 T3 ES2127438 T3 ES 2127438T3
Authority
ES
Spain
Prior art keywords
isocianato
molar relation
prepolimero
hexandiol
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95111995T
Other languages
English (en)
Inventor
Heinz Dr Pudleiner
Rolf Dr Dhein
Herbert Dr Hugl
Hanns-Peter Dr Muller
Herbert Heidingsfeld
Hans-Georg Hoppe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of ES2127438T3 publication Critical patent/ES2127438T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4854Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L29/00Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
    • A61L29/04Macromolecular materials
    • A61L29/06Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • C08G18/3234Polyamines cycloaliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Materials For Medical Uses (AREA)

Abstract

LA INVENCION SE REFIERE A ELASTOMEROS DE POLIURETANO OBTENIBLES A PARTIR DE A) 5 - ISOCIANATO - 1 - (ISOCIANATO METILO) - 1.1.3 - TRIMETILO CICLOHEXANO (DIISOCIANATO ISOFORONA) Y/O BIS - (4 - ISOCIANATO CICLOHEXILO) - METANO Y B) POLITETRAHIDROFURANO Y/O HEXANDIOL POLICARBONATO CON PESO MOLECULAR DESDE 1.500 HASTA 3.000 EN RELACION MOLAR A) : B) = 1,2 : 1 HASTA 30 : 1, C) UNA MEZCLA PROLONGADORA DE CADENA A BASE DE C.1) 5 - AMINO - 3 - AMINOMETILO - 1,3,3 - TRIMETILO CICLOHEXANO (DIAMINA ISOFORONA) Y/O BIS - (4 - AMINO CICLOHEXILO) - METANO Y C.2) 1,6 - HEXANDIOL, 1,4 - BUTANDIOL, DIETILENO GLICOL, DI Y TRIPROPILENO GLICOL Y/O HIDROQUINONA - DI - {BE} - ETER HIDROXIETILO, EN RELACION MOLAR C.1) : C.2) = 60 : 40 HASTA 20 : 80 Y D) 0,01 HASTA 7 EQUIVALENTES % CON REFERENCIA A LOS GRUPOS NCO EN A) DE UN MONOISOCIANATO, MONOALCOHOL O MONOAMINA (COMO REGULAR DE PESO MOLECULAR) DONDE A), B) Y C.2) SE TRANSFORMAN EN UNA PRIMERA ETAPA PARA LA OBTENCION DE PREPOLIMERO NCO Y ESTE PREPOLIMERO SE TRANSFORMA CON C.1 Y D) EN UNA SEGUNDA ETAPA PARA LA OBTENCION DE UREA POLIURETANO, Y DONDE LA RELACION MOLAR DE LOS GRUPOS NCO CON RESPECTO A TODOS LOS ATOMOS DE HIDROGENO ACTIVOS SE ENCUENTRA DESDE 0,9 : 1 HASTA 1,2 : 1 Y LOS CUERPOS MOLDEADOS ELABORADOS CON ELLO, EN PARTICULAR LAMINAS, TUBOS FLEXIBLES DE APLICACION EN MEDICINA Y CATETER.
ES95111995T 1994-08-11 1995-07-31 Elastomeros de poliuretano cicloalifaticos termoplasticos. Expired - Lifetime ES2127438T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4428458A DE4428458A1 (de) 1994-08-11 1994-08-11 Cycloaliphatische thermoplastische Polyurethanelastomere

Publications (1)

Publication Number Publication Date
ES2127438T3 true ES2127438T3 (es) 1999-04-16

Family

ID=6525451

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95111995T Expired - Lifetime ES2127438T3 (es) 1994-08-11 1995-07-31 Elastomeros de poliuretano cicloalifaticos termoplasticos.

Country Status (9)

Country Link
US (1) US5942593A (es)
EP (1) EP0696604B1 (es)
JP (1) JPH0859787A (es)
KR (1) KR100347502B1 (es)
CA (1) CA2155564A1 (es)
DE (2) DE4428458A1 (es)
DK (1) DK0696604T3 (es)
ES (1) ES2127438T3 (es)
TW (1) TW300238B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19812160C1 (de) * 1998-03-20 1999-07-08 Bayer Ag Formkörper aus wirkstoffhaltigen thermoplastischen Polyurethanen
DE19921412A1 (de) 1999-05-08 2000-11-09 Basf Ag Lineare Oligo- und Polyurethane mit definierter Struktur, ihre Herstellung und ihre Verwendung
DE10243966A1 (de) * 2002-09-20 2004-04-01 Adiam Life Science Ag Verfahren zur Herstellung von biokompatiblen Polyurethanen
US20050033237A1 (en) * 2003-08-08 2005-02-10 James Fentress Catheter assemblies and injection molding processes and equipment for making the same
DE102004054040A1 (de) * 2004-11-05 2006-05-11 Bayer Innovation Gmbh Wirkstoffhaltige Silikonelastomere
GB0500764D0 (en) * 2005-01-14 2005-02-23 Baxenden Chem Low swell, water vapour permeable poly(urethane-urea)s
DE102006009096B4 (de) * 2006-02-28 2009-06-10 Bayer Materialscience Ag Thermoplastisch verarbeitbare Polyurethane, Verfahren zu ihrer Herstellung und ihre Verwendung
DE102006020644A1 (de) 2006-04-28 2007-10-31 Bayer Innovation Gmbh Antiseptikahaltige Silikonelastomere
DE102008018967A1 (de) 2008-04-16 2009-10-22 Ticona Gmbh Oxymethylenpolymere, Verfahren zu deren Herstellung und deren Verwendung
US8026318B2 (en) * 2008-08-22 2011-09-27 Air Products And Chemicals, Inc. Mixed polycycloaliphatic amines (MPCA) and MPCA alkylates
US8840976B2 (en) 2010-10-14 2014-09-23 Ticona Llc VOC or compressed gas containment device made from a polyoxymethylene polymer
EP2505609B1 (en) 2011-04-01 2015-01-21 Ticona GmbH High impact resistant polyoxymethylene for extrusion blow molding
WO2013101624A1 (en) 2011-12-30 2013-07-04 Ticona Llc Printable molded articles made from a polyoxymethylene polymer composition
WO2014105670A1 (en) 2012-12-27 2014-07-03 Ticona Llc Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849360A (en) * 1970-09-03 1974-11-19 Textron Inc Polyurea-urethanes produced from a mixture of two polyamines
AT307951B (de) 1971-02-18 1973-06-12 Deutsch Friedrich Verfahren zur Herstellung eines Stahlbeschlagteiles für Schier, insbesondere einer Stahlkante und nach diesem Verfahren hergestellter Stahlbeschlagteil
US4041208A (en) * 1971-06-21 1977-08-09 Ppg Industries, Inc. Transparent, impact-resistant polyesterurethane laminates
GB1339813A (en) * 1971-11-05 1973-12-05 Monsanto Co Urethane elastomers
IN141398B (es) 1973-05-16 1977-02-26 Ethicon Inc
DE2423764C3 (de) * 1974-05-16 1979-10-18 Bayer Ag, 5090 Leverkusen Verfahren zur kontinuierlichen Herstellung von elastomeren Polyurethanharnstoffen
DE2854409A1 (de) 1978-12-16 1980-06-26 Bayer Ag Verfahren zur herstellung von thermoplastischen chemiewerkstoffen
DE2854408A1 (de) 1978-12-16 1980-07-03 Bayer Ag Thermoplastische polyaetherpolyurethane mit verbesserter thermostabilitaet
DE2920501A1 (de) * 1979-05-21 1980-11-27 Bayer Ag Verfahren zur herstellung von polyurethanharnstoffelastomeren
JPS59108021A (ja) * 1982-12-10 1984-06-22 Sanyo Chem Ind Ltd ポリウレタン溶液の製造法
DE3329775A1 (de) * 1983-08-18 1985-02-28 Bayer Ag, 5090 Leverkusen Thermoplastische polyurethane hoher waermestandfestigkeit auf basis von naphthylendiisocyanat, verfahren zu ihrer herstellung und ihre verwendung
DE3401753A1 (de) * 1984-01-19 1985-08-01 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von polyurethanen, polyurethane mit aromatischen aminoendgruppen und ihre verwendung
DE3870681D1 (de) * 1987-02-24 1992-06-11 Mitsubishi Chem Ind Nichtporoeser film aus polyurethanharz.
US4849458A (en) 1988-06-17 1989-07-18 Matrix Medica, Inc. Segmented polyether polyurethane
US4948860A (en) 1989-05-01 1990-08-14 Becton, Dickinson And Company Melt processable polyurethaneurea copolymers and method for their preparation
DE4211454C2 (de) * 1992-04-06 1995-11-02 Degussa Verfahren zum Verlängern der Topfzeit bei der Härtung von Epoxidharzen mit Isophorondiamin-Isomerengemischen
WO1994007934A1 (en) * 1992-09-29 1994-04-14 Asahi Kasei Kogyo Kabushiki Kaisha Thermoplastic polyurethane derived from polytetramethylene carbonate diol
JP3471055B2 (ja) * 1992-12-28 2003-11-25 サカタインクス株式会社 ポリウレタン樹脂、その製造方法およびそれを用いたラミネート用印刷インキ組成物

Also Published As

Publication number Publication date
TW300238B (es) 1997-03-11
DK0696604T3 (da) 1999-09-13
JPH0859787A (ja) 1996-03-05
DE59504962D1 (de) 1999-03-11
EP0696604A1 (de) 1996-02-14
KR100347502B1 (ko) 2002-10-31
US5942593A (en) 1999-08-24
KR960007635A (ko) 1996-03-22
DE4428458A1 (de) 1996-02-15
CA2155564A1 (en) 1996-02-12
EP0696604B1 (de) 1999-01-27

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