ES2115780T3 - Composicion de revestimiento termoendurecible, exenta de emulsionante, su preparacion y utilizacion. - Google Patents

Composicion de revestimiento termoendurecible, exenta de emulsionante, su preparacion y utilizacion.

Info

Publication number
ES2115780T3
ES2115780T3 ES94100079T ES94100079T ES2115780T3 ES 2115780 T3 ES2115780 T3 ES 2115780T3 ES 94100079 T ES94100079 T ES 94100079T ES 94100079 T ES94100079 T ES 94100079T ES 2115780 T3 ES2115780 T3 ES 2115780T3
Authority
ES
Spain
Prior art keywords
groups
weight
unsaturated carboxylic
components
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94100079T
Other languages
English (en)
Inventor
Klaus Dr Bederke
Volker Duecoffre
Carmen Dr Flosbach
Wolfgang Dr Goldner
Walter Dr Schubert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Axalta Coating Systems Germany GmbH and Co KG
Original Assignee
Herberts GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19934300616 external-priority patent/DE4300616A1/de
Priority claimed from DE19934317864 external-priority patent/DE4317864A1/de
Priority claimed from DE19934332067 external-priority patent/DE4332067A1/de
Application filed by Herberts GmbH filed Critical Herberts GmbH
Application granted granted Critical
Publication of ES2115780T3 publication Critical patent/ES2115780T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/631—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyesters and/or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/638—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the use of compounds having carbon-to-carbon double bonds other than styrene and/or olefinic nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8093—Compounds containing active methylene groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/31794—Of cross-linked polyester

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Paints Or Removers (AREA)

Abstract

MEDIO DE RECUBRIMIENTO CALENTABLE, LIBRE DE EMULSIONANTES, EN FORMA DE UNA EMULSION ACUOSA, PROCESO PARA SU ELABORACION Y SU UTILIZACION. EL MEDIO DE RECUBRIMIENTO CONTIENE: A) 30 HASTA 80 % EN PESO DE UNO O MULTIPLES POLIACRILATOS POLIESTER OLIGOMEROS DILUIBLES CON AGUA DESPUES DE LA NEUTRALIZACION CON BASES, OBTENIBLES MEDIANTE POLIMERIZACION RADICAL DE 50 HASTA 95 % EN PESO DE UNO O MULTIPLES ESTERES DE ACIDOS CARBOXILICOS NO SATURADOS CON PORCIONES HIDROFOBAS E HIDROFILAS, DONDE A) LA PORCION HIDROFOBA ESTA BASADA EN ESTERES MONOMEROS DE ACIDOS CARBOXILICOS NO SATURADOS CON GRUPOS OH SECUNDARIOS, QUE PUEDEN ESTAR PRESENTES EN UNA MEZCLA CON COMONOMEROS LIBRES DE GRUPOS OH, Y B) LA PORCION HIDROFILA ESTA BASADA EN ESTERES MONOMEROS DE ACIDOS CARBOXILICOS NO SATURADOS CON GRUPOS OH PRIMARIOS Y ESTERES MONOMEROS DE ACIDOS CARBOXILICOS NO SATURADOS CON GRUPOS COOH, QUE PUEDEN ESTAR PRESENTES EN UNA MEZCLA DE COMONOMEROS LIBRES DE GRUPOS OH, DONDE LA RELACION EN CIFRAS DE LOS COMPONENTES B)Y A) QUE PROVIENEN DE GRUPOS OH PRIMARIOS A SECUNDARIOS EN COPOLIMEROS ALCANZA DESDE 1 : 1,5 HASTA 1 : 2,5, EN 5 HASTA 50 % EN PESO DE UNO O MULTIPLES OLIGOMEROS POLIESTER DE FUNCION HIDROXI, OBTENIBLES A TRAVES DE POLICODENSACION DE UNO O MULTIPLES DIOLES Y/O POLIOLES Y UNO O MULTIPLES ACIDOS DICARBOXILICOS Y/O SUS DERIVADOS, CON UN PESO MOLECULAR CALCULADO DESDE 200 HASTA 1000, DE UN INDICE HIDROXI DESDE 100 HASTA 600 Y UN INDICE DE ACIDEZ DESDE 0 HASTA 15. LOS MONOMEROS A) Y B) SON UTILIZADOS EN CANTIDADES DE ESTE TIPO, DE FORMA QUE EL POLIACRILATO POLIESTER OLIGOMERO MUESTRA UN INDICE HIDROXI DESDE 100 HASTA 390 Y UN INDICE ACIDO DESDE 16 HASTA 50, CON LO CUAL SE AÑADE EL TANTO % EN PESO RESPECTIVO DE CONTENIDO EN CUERPOS SOLIDOS CON RESPECTO AL 100 % EN PESO; Y B) 70 HASTA 20 % EN PESO DE UNO O MULTIPLES POLIISOCIANATOS Y/O DE UNO O MULTIPLES RESINAS DE MELANINA, DONDE AL MENOS UNA RESINA DE MELAMINA ES UNA RESINA HEXAMETOXIMETILMELAMINA
ES94100079T 1993-01-13 1994-01-05 Composicion de revestimiento termoendurecible, exenta de emulsionante, su preparacion y utilizacion. Expired - Lifetime ES2115780T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19934300616 DE4300616A1 (de) 1993-01-13 1993-01-13 Emulgatorfreies, hitzehärtbares Überzugsmittel, dessen Herstellung und Verwendung
DE19934317864 DE4317864A1 (de) 1993-05-28 1993-05-28 Emulgatorfreies, hitzehärtbares Überzugsmittel, dessen Herstellung und Verwendung
DE19934332067 DE4332067A1 (de) 1993-09-21 1993-09-21 Emulgatorfreies, hitzehärtbares Überzugsmittel, dessen Herstellung und Verwendung

Publications (1)

Publication Number Publication Date
ES2115780T3 true ES2115780T3 (es) 1998-07-01

Family

ID=27204651

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94100079T Expired - Lifetime ES2115780T3 (es) 1993-01-13 1994-01-05 Composicion de revestimiento termoendurecible, exenta de emulsionante, su preparacion y utilizacion.

Country Status (7)

Country Link
US (1) US5460892A (es)
EP (1) EP0607792B1 (es)
JP (1) JPH06234952A (es)
KR (1) KR940018441A (es)
AT (1) ATE164617T1 (es)
DE (1) DE59405549D1 (es)
ES (1) ES2115780T3 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3223413B2 (ja) * 1995-03-08 2001-10-29 日新製鋼株式会社 接着性に優れた塗装鋼板
DE19525375A1 (de) * 1995-07-12 1997-01-16 Herberts Gmbh Überzugsmittel, deren Verwendung und Verfahren zur Herstellung von Mehrschichtüberzügen
DE19535603A1 (de) * 1995-09-25 1997-03-27 Basf Lacke & Farben 3-Komponenten-Beschichtungsmittel mit hoher Lösemittelbeständigkeit und hoher Abklebfestigkeit
AT405518B (de) * 1997-08-07 1999-09-27 Vianova Kunstharz Ag Neue acrylatpolymerisate, deren grundlage polyesterharze oder polyester-oligomere sind, deren herstellung und verwendung in beschichtungsmitteln
WO1999042531A1 (en) 1998-02-18 1999-08-26 Ppg Industries Ohio, Inc. Multi-component composite coating composition and coated substrate
PT980880E (pt) * 1998-08-17 2005-03-31 Bayer Materialscience Ag Utilizacao de uma combinacao aquosa de aglutinantes para a preparacao de revestimentos de secagem fisica
US6066692A (en) * 1998-10-30 2000-05-23 Air Products And Chemicals, Inc. Two component waterborne urethane/vinyl polymer composite for coating applications
US6270905B1 (en) 1999-02-16 2001-08-07 Ppg Industries Ohio, Inc. Multi-component composite coating composition and coated substrate
US6503975B1 (en) * 2000-03-29 2003-01-07 E. I Du Pont De Nemours And Company Surfactant free aqueous emulsions
JP2002105396A (ja) * 2000-10-03 2002-04-10 Kansai Paint Co Ltd 水性塗料組成物
JP2003003115A (ja) 2001-06-22 2003-01-08 Nippon Paint Co Ltd 中塗り塗料組成物、複層塗膜形成方法および複層塗膜
US20030050388A1 (en) * 2001-09-06 2003-03-13 Strickland Debra S. Aqueous coating composition
US6881786B2 (en) * 2002-05-20 2005-04-19 Ppg Industries Ohio, Inc. One-component, waterborne film-forming composition
US6884845B2 (en) * 2002-05-20 2005-04-26 Ppg Industries Ohio, Inc. Low temperature curable, two-component, waterborne film-forming composition
US20070218301A1 (en) * 2006-03-15 2007-09-20 Pachuta Justin A Tinted anti-fingerprint coating on 430 stainless steel for appliances
JP5511675B2 (ja) * 2008-10-21 2014-06-04 関西ペイント株式会社 複層塗膜形成方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3993849A (en) * 1974-12-24 1976-11-23 E. I. Du Pont De Nemours And Company Metal substrate coated with a thermosetting powder coating composition of an acrylic polymer, a hydroxy functional plasticizer and a blocked polyisocyanate cross-linking agent
DE3132937A1 (de) * 1981-08-20 1983-03-03 Henkel KGaA, 4000 Düsseldorf Wasserverduennbare harzzubereitung auf basis von alkydharzen und polyacrylatharzen sowie deren verwendung als wasserverduennbare lackharze
DE3319013A1 (de) * 1983-05-26 1984-11-29 Bayer Ag, 5090 Leverkusen (meth)-acryloylgruppen enthaltende di- und polyester, verfahren zu ihrer herstellung und ihre verwendung
JPS6028463A (ja) * 1983-07-26 1985-02-13 Nippon Paint Co Ltd 水性塗料組成物
JPH0730285B2 (ja) * 1987-11-13 1995-04-05 ハニー化成株式会社 被覆用組成物
DE3910829A1 (de) * 1989-04-04 1990-10-11 Herberts Gmbh Waessriges hitzehaertbares ueberzugsmittel auf polyester- und acrylbasis, verfahren zu dessen herstellung und dessen verwendung
JPH04130168A (ja) * 1990-09-20 1992-05-01 Nippon Paint Co Ltd クリヤー塗料及び塗膜の形成方法

Also Published As

Publication number Publication date
ATE164617T1 (de) 1998-04-15
EP0607792A1 (de) 1994-07-27
JPH06234952A (ja) 1994-08-23
DE59405549D1 (de) 1998-05-07
US5460892A (en) 1995-10-24
KR940018441A (ko) 1994-08-18
EP0607792B1 (de) 1998-04-01

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