ES2113063T3 - Sintesis del metilmercaptan a partir del dimetildisulfuro. - Google Patents
Sintesis del metilmercaptan a partir del dimetildisulfuro.Info
- Publication number
- ES2113063T3 ES2113063T3 ES94402265T ES94402265T ES2113063T3 ES 2113063 T3 ES2113063 T3 ES 2113063T3 ES 94402265 T ES94402265 T ES 94402265T ES 94402265 T ES94402265 T ES 94402265T ES 2113063 T3 ES2113063 T3 ES 2113063T3
- Authority
- ES
- Spain
- Prior art keywords
- dimetildisulfide
- methylmercaptan
- synthesis
- methylmercaptane
- selectivity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/06—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols from sulfides, hydropolysulfides or polysulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/02—Thiols having mercapto groups bound to acyclic carbon atoms
- C07C321/04—Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA INVENCION SE REFIERE A LA FABRICACION DEL MEITILMERCAPTANO POR HIDROGENACION CATALITICA DEL DIMETILDISULFURO SOBRE UN CATALIZADOR A BASE DE SULFURO(S) DE AL MENOS UN METAL DE TRANSICION. OPERANDO EN PRESENCIA DE AGUA Y/O DE HIDROGENO SULFURADO, SE MEJORA CONSIDERABLEMENTE LA SELECTIVIDAD EN METILMERCAPTANO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9312491A FR2711366B1 (fr) | 1993-10-20 | 1993-10-20 | Synthèse du méthylmercaptan à partir du diméthyldisulfure. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2113063T3 true ES2113063T3 (es) | 1998-04-16 |
Family
ID=9452030
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94402265T Expired - Lifetime ES2113063T3 (es) | 1993-10-20 | 1994-10-10 | Sintesis del metilmercaptan a partir del dimetildisulfuro. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5493058A (es) |
| EP (1) | EP0649837B1 (es) |
| JP (1) | JP2637373B2 (es) |
| KR (1) | KR0150828B1 (es) |
| CN (1) | CN1037435C (es) |
| AT (1) | ATE161829T1 (es) |
| AU (1) | AU669641B2 (es) |
| CA (1) | CA2133808C (es) |
| DE (1) | DE69407725T2 (es) |
| DK (1) | DK0649837T3 (es) |
| ES (1) | ES2113063T3 (es) |
| FR (1) | FR2711366B1 (es) |
| GR (1) | GR3026343T3 (es) |
| IL (1) | IL110927A (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5728887A (en) * | 1996-04-10 | 1998-03-17 | E. I. Du Pont De Nemours And Company | Catalytic hydrogenolysis of organic thiocyanates and disulfides to thiols |
| US6169210B1 (en) | 1999-04-20 | 2001-01-02 | Kaung-Far Lin | Method for producing dialkyl disulfides |
| US6433206B1 (en) * | 2001-11-05 | 2002-08-13 | Crompton Corporation | Process for preparing silylorganomercaptans |
| FR2844726B1 (fr) * | 2002-09-25 | 2004-12-03 | Atofina | Procede catalytique de fabricaton de mercaptans a partir de thioethers |
| CN100443165C (zh) * | 2004-03-12 | 2008-12-17 | 德古萨股份公司 | 一种用于一氧化碳与硫化氢反应合成甲硫醇的催化剂 |
| DE102005020536A1 (de) * | 2004-09-07 | 2006-03-23 | Degussa Ag | Verfahren zur Herstellung von Mercaptoorganyl(alkoxysilan) |
| DE102005020534B4 (de) * | 2004-09-07 | 2006-07-06 | Degussa Ag | Verfahren zur Herstellung von Mercaptoorganyl(alkoxysilanen) |
| CN101143329A (zh) | 2006-09-11 | 2008-03-19 | 德古萨股份公司 | Mo-O-K基催化剂、其制备方法及其在甲硫醇合成中的应用 |
| DE102007007458A1 (de) * | 2007-02-15 | 2008-08-21 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Methylmercaptan aus Dialkylsulfiden und Dialkylpolysulfiden |
| RU2402529C1 (ru) * | 2009-02-12 | 2010-10-27 | Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (статус государственного учреждения) | Способ получения диметилсульфида |
| TR201818880T4 (tr) * | 2010-12-16 | 2019-01-21 | Hoffmann La Roche | Disülfürlerin hidrojenasyonu yoluyla aromatik tiyol türevlerinin hazırlanması prosesi. |
| FR3041659B1 (fr) * | 2015-09-30 | 2017-10-20 | Arkema France | Procede de production de l-methionine |
| FR3041636B1 (fr) * | 2015-09-30 | 2018-11-16 | Arkema France | Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures a l'aide d'hydrogene |
| FR3041658B1 (fr) * | 2015-09-30 | 2017-10-20 | Arkema France | Procede de production de l-methionine |
| FR3041635B1 (fr) * | 2015-09-30 | 2019-01-25 | Arkema France | Procede de production de mercaptans par hydrogenolyse enzymatique de disulfures |
| CA3093203C (en) * | 2018-03-07 | 2021-03-16 | De Nora Permelec Ltd | Electrolysis electrode and method for manufacturing same |
| KR102404706B1 (ko) | 2018-07-06 | 2022-06-07 | 주식회사 엘지화학 | 전기분해용 환원 전극의 활성층 조성물 및 이로 유래된 환원 전극 |
| KR102679027B1 (ko) * | 2019-09-03 | 2024-07-01 | 주식회사 엘지화학 | 전기분해용 전극 |
| US11603499B2 (en) | 2021-06-30 | 2023-03-14 | Saudi Arabian Oil Company | Hydroprocess integrating oxidized disulfide oil compounds |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2402614A (en) * | 1940-09-19 | 1946-06-25 | Du Pont | Catalytic process |
| NL127232C (es) * | 1963-03-12 | 1900-01-01 | ||
| FR1386654A (fr) * | 1963-03-12 | 1965-01-22 | Us Rubber Co | Nouveaux catalyseurs pour hydrogénation non destructrice |
| US3326980A (en) * | 1964-12-11 | 1967-06-20 | Crown Zellerbach Corp | Preparation of methyl mercaptan from waste pulping liquors |
| US3488739A (en) * | 1967-02-27 | 1970-01-06 | Sun Oil Co | Preparation of methyl mercaptan and dimethyl sulfide |
| CH509993A (de) * | 1968-05-11 | 1971-07-15 | Bayer Ag | Verfahren zur Herstellung von Thiophenolen |
| US3880933A (en) * | 1973-05-02 | 1975-04-29 | Phillips Petroleum Co | Hydrogenation of carbon disulfide to methyl mercaptan in presence of hydrogen sulfide |
| US4313006A (en) * | 1980-09-03 | 1982-01-26 | Pennwalt Corporation | Process for converting dialkyl sulfides to alkyl mercaptans |
| EP0134200B1 (de) * | 1983-08-12 | 1987-03-04 | Ciba-Geigy Ag | Verfahren zur Herstellung von Merkaptanen |
-
1993
- 1993-10-20 FR FR9312491A patent/FR2711366B1/fr not_active Expired - Fee Related
-
1994
- 1994-09-12 IL IL110927A patent/IL110927A/en not_active IP Right Cessation
- 1994-10-06 CA CA002133808A patent/CA2133808C/fr not_active Expired - Fee Related
- 1994-10-10 AU AU75719/94A patent/AU669641B2/en not_active Ceased
- 1994-10-10 EP EP94402265A patent/EP0649837B1/fr not_active Expired - Lifetime
- 1994-10-10 ES ES94402265T patent/ES2113063T3/es not_active Expired - Lifetime
- 1994-10-10 DK DK94402265T patent/DK0649837T3/da active
- 1994-10-10 DE DE69407725T patent/DE69407725T2/de not_active Expired - Lifetime
- 1994-10-10 AT AT94402265T patent/ATE161829T1/de not_active IP Right Cessation
- 1994-10-12 US US08/321,701 patent/US5493058A/en not_active Expired - Lifetime
- 1994-10-19 JP JP6253988A patent/JP2637373B2/ja not_active Expired - Fee Related
- 1994-10-20 CN CN94117487A patent/CN1037435C/zh not_active Expired - Fee Related
- 1994-10-20 KR KR1019940026893A patent/KR0150828B1/ko not_active Expired - Fee Related
-
1998
- 1998-03-13 GR GR980400528T patent/GR3026343T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07304730A (ja) | 1995-11-21 |
| CA2133808C (fr) | 1998-06-23 |
| CA2133808A1 (fr) | 1995-04-21 |
| AU7571994A (en) | 1995-05-11 |
| GR3026343T3 (en) | 1998-06-30 |
| DE69407725T2 (de) | 1998-06-04 |
| AU669641B2 (en) | 1996-06-13 |
| DE69407725D1 (de) | 1998-02-12 |
| CN1106382A (zh) | 1995-08-09 |
| FR2711366A1 (fr) | 1995-04-28 |
| FR2711366B1 (fr) | 1995-12-15 |
| DK0649837T3 (da) | 1998-09-07 |
| EP0649837B1 (fr) | 1998-01-07 |
| IL110927A0 (en) | 1994-11-28 |
| ATE161829T1 (de) | 1998-01-15 |
| EP0649837A1 (fr) | 1995-04-26 |
| KR0150828B1 (ko) | 1998-10-15 |
| KR950011405A (ko) | 1995-05-15 |
| JP2637373B2 (ja) | 1997-08-06 |
| US5493058A (en) | 1996-02-20 |
| IL110927A (en) | 1998-06-15 |
| CN1037435C (zh) | 1998-02-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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