ES2110532T3 - Procedimiento para la preparacion de copolimeros elastomericos de etileno. - Google Patents
Procedimiento para la preparacion de copolimeros elastomericos de etileno.Info
- Publication number
- ES2110532T3 ES2110532T3 ES93102661T ES93102661T ES2110532T3 ES 2110532 T3 ES2110532 T3 ES 2110532T3 ES 93102661 T ES93102661 T ES 93102661T ES 93102661 T ES93102661 T ES 93102661T ES 2110532 T3 ES2110532 T3 ES 2110532T3
- Authority
- ES
- Spain
- Prior art keywords
- procedure
- preparation
- dialide
- vcl3
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
- 239000005977 Ethylene Substances 0.000 title 1
- 229920001198 elastomeric copolymer Polymers 0.000 title 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
SE PRESENTA UN PROCESO PARA PREPARAR COPOLIMEROS ELASTOMERICOS DE ETILENO CON (ALFA)-OLEFINAS CH2 = CHR, QUE CONTIENEN OPCIONALMENTE PROPORCIONES DE DIENO, EL PROCESO SE CARACTERIZA POR EL USO, DURANTE LA POLIMERIZACION, DE UN CATALIZADOR QUE COMPRENDE EL PRODUCTO DE LA REACCION DE: I) UN COMPONENTE SOLIDO QUE COMPRENDE VCL3 SOPORTADO SOBRE UN DIALURO DE MANGANESO EN UNA CONFIGURACION ESFERICA O ESFEROIDAL, EN FORMA ACTIVA; II) UN COMPUESTO DE ALQUILAMONIO; III) OPCIONALMENTE UN HALOHIDROCARBONO. EL VCL3 SE PRECIPITA SOBRE DICHO DIALURO DE MANGANESO MEDIANTE EL CALENTAMIENTO DE LAS SOLUCIONES DE VCL4 EN SOLVENTES INERTES DE HIDROCARBONO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI920441A IT1254474B (it) | 1992-02-28 | 1992-02-28 | Processo per la preparazione di copolimeri elastomerici dell'etilene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2110532T3 true ES2110532T3 (es) | 1998-02-16 |
Family
ID=11362177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93102661T Expired - Lifetime ES2110532T3 (es) | 1992-02-28 | 1993-02-19 | Procedimiento para la preparacion de copolimeros elastomericos de etileno. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5532326A (es) |
| EP (1) | EP0557904B1 (es) |
| JP (1) | JPH0641237A (es) |
| CN (1) | CN1044710C (es) |
| AT (1) | ATE159735T1 (es) |
| CA (1) | CA2090447A1 (es) |
| DE (1) | DE69314823T2 (es) |
| DK (1) | DK0557904T3 (es) |
| ES (1) | ES2110532T3 (es) |
| IT (1) | IT1254474B (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1256403B (it) * | 1992-08-18 | 1995-12-05 | Montecatini Tecnologie Srl | Componenti e catalizzatori a base di vanadio per la polimerizzazione di olefine,e processi di polimerizzazione impieganti gli stessi |
| JPH08208734A (ja) * | 1994-11-02 | 1996-08-13 | Union Carbide Chem & Plast Technol Corp | 塩化マグネシウムに担持されたバナジウム触媒を使用する均質エチレンプロピレンゴムの製造法 |
| CN1101826C (zh) * | 1995-11-23 | 2003-02-19 | 韩华综合化学株式会社 | 乙烯聚合物的制备方法 |
| AR012645A1 (es) * | 1997-05-01 | 2000-11-08 | Dow Global Technologies Inc | Polimeros de alfa-olefinas preparados por polimerizacion en presencia de complejos de metales que contienen grupos indenilo |
| US6391816B1 (en) * | 1999-10-27 | 2002-05-21 | Phillips Petroleum | Organometal compound catalyst |
| EP1697433A1 (en) * | 2003-12-23 | 2006-09-06 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom |
| CN103374088B (zh) * | 2012-04-20 | 2015-09-16 | 中国石油化工股份有限公司 | 一种乙烯-α烯烃共聚物及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| US4071672A (en) * | 1972-11-10 | 1978-01-31 | Mitsui Petrochemical Industries Ltd. | Process for polymerizing or copolymerizing olefins |
| IT1096661B (it) * | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| IT1154555B (it) * | 1982-11-11 | 1987-01-21 | Anic Spa | Procedimento per la preparazione di polimeri dell'etilene e catalizzatore relativo |
| FR2560200B1 (fr) * | 1984-02-23 | 1986-06-27 | Bp Chimie Sa | Procede de preparation de catalyseurs supportes a base de composes de vanadium pour la polymerisation et la copolymerisation de l'ethylene |
| IT1197320B (it) * | 1986-10-02 | 1988-11-30 | Ausimont Spa | Catalizzatori per la preparazione di copolimeri olefinici elastomerici,saturi ed insaturi,e vopolimeri con essi ottenuti |
| GB2235926B (en) * | 1989-07-26 | 1993-04-14 | James C W Chien | Vanadium catalyst systems for olefin polymerization |
| FR2650827B1 (fr) * | 1989-08-08 | 1993-03-05 | Bp Chem Int Ltd | Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium |
| US5030605A (en) * | 1989-12-29 | 1991-07-09 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst for regulating the molecular weight distribution of ethylene polymers |
| FR2656614B1 (fr) * | 1990-01-03 | 1993-05-07 | Bp Chemicals Snc | Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium, supporte sur un chlorure de magnesium. |
| FR2658498B1 (fr) * | 1990-02-19 | 1992-05-15 | Atochem | Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits. |
| IT1252129B (it) * | 1991-11-22 | 1995-06-05 | Himont Inc | Componenti a catalizzatori sferici per la polimerizzazione di olefine |
-
1992
- 1992-02-28 IT ITMI920441A patent/IT1254474B/it active IP Right Grant
-
1993
- 1993-02-19 EP EP93102661A patent/EP0557904B1/en not_active Expired - Lifetime
- 1993-02-19 ES ES93102661T patent/ES2110532T3/es not_active Expired - Lifetime
- 1993-02-19 DE DE69314823T patent/DE69314823T2/de not_active Expired - Fee Related
- 1993-02-19 DK DK93102661.1T patent/DK0557904T3/da active
- 1993-02-19 AT AT93102661T patent/ATE159735T1/de not_active IP Right Cessation
- 1993-02-26 CA CA002090447A patent/CA2090447A1/en not_active Abandoned
- 1993-02-26 JP JP5039081A patent/JPH0641237A/ja active Pending
- 1993-02-27 CN CN93103484A patent/CN1044710C/zh not_active Expired - Fee Related
-
1994
- 1994-11-14 US US08/341,441 patent/US5532326A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69314823D1 (de) | 1997-12-04 |
| EP0557904A2 (en) | 1993-09-01 |
| JPH0641237A (ja) | 1994-02-15 |
| DE69314823T2 (de) | 1998-03-12 |
| CN1044710C (zh) | 1999-08-18 |
| US5532326A (en) | 1996-07-02 |
| CN1076457A (zh) | 1993-09-22 |
| DK0557904T3 (da) | 1997-12-01 |
| ATE159735T1 (de) | 1997-11-15 |
| IT1254474B (it) | 1995-09-25 |
| EP0557904A3 (en) | 1994-07-06 |
| ITMI920441A1 (it) | 1993-08-28 |
| EP0557904B1 (en) | 1997-10-29 |
| ITMI920441A0 (it) | 1992-02-28 |
| CA2090447A1 (en) | 1993-08-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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