ES2093003T3 - Polimero en forma de sindio-iso-bloques y procedimiento para su preparacion. - Google Patents
Polimero en forma de sindio-iso-bloques y procedimiento para su preparacion.Info
- Publication number
- ES2093003T3 ES2093003T3 ES90109206T ES90109206T ES2093003T3 ES 2093003 T3 ES2093003 T3 ES 2093003T3 ES 90109206 T ES90109206 T ES 90109206T ES 90109206 T ES90109206 T ES 90109206T ES 2093003 T3 ES2093003 T3 ES 2093003T3
- Authority
- ES
- Spain
- Prior art keywords
- polymer
- iso
- blocks
- syndium
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
EL INVENTO SE REFIERE A UN POLIMERO EN BLOQUES SINDIO-ISO, QUE SE OBTIENEN A PARTIR DE OLEFINAS-1 CON CADENAS DE MOLECULAS QUE TIENEN SECUENCIAS ISOSTATICAS Y SINDIOESTATICAS; PRESENTAN PROPIEDADES SIMILARES A LOS CAUCHOS Y SE PRODUCEN MEDIANTE LA POLIMERIZACION DE 1-OLEFINAS, EN PRESENCIA DE UN CATALIZADOR FORMADO POR UN ALUMINOXANO Y UN COMPLEJO METALICO QUIRAL DE FORMULA (I) CON UN ENLACE PUENTEADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3916553A DE3916553A1 (de) | 1989-05-20 | 1989-05-20 | Syndio- isoblockpolymer und verfahren zu seiner herstellung |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2093003T3 true ES2093003T3 (es) | 1996-12-16 |
Family
ID=6381116
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90109206T Expired - Lifetime ES2093003T3 (es) | 1989-05-20 | 1990-05-16 | Polimero en forma de sindio-iso-bloques y procedimiento para su preparacion. |
Country Status (8)
Country | Link |
---|---|
US (2) | US6225425B1 (es) |
EP (1) | EP0399347B1 (es) |
JP (1) | JP2988962B2 (es) |
AU (1) | AU624953B2 (es) |
CA (1) | CA2017192A1 (es) |
DE (2) | DE3916553A1 (es) |
ES (1) | ES2093003T3 (es) |
ZA (1) | ZA903829B (es) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5420217A (en) * | 1989-09-13 | 1995-05-30 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
ES2116301T3 (es) * | 1991-03-09 | 1998-07-16 | Targor Gmbh | Procedimiento para la obtencion de copolimeros de cicloolefina homogeneos quimicamente. |
US5191132A (en) * | 1991-05-09 | 1993-03-02 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
CA2067525C (en) | 1991-05-09 | 1998-09-15 | Helmut G. Alt | Organometallic fluorenyl compounds, preparation and use |
US5436305A (en) * | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5416228A (en) * | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
US6245870B1 (en) * | 1992-03-20 | 2001-06-12 | Fina Technology, Inc. | Process for producing syndiotactic/isotactic block polyolefins |
EP0578838A1 (en) * | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
EP0567952B1 (en) * | 1992-04-29 | 1997-12-03 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
US5710222A (en) * | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
US5594080A (en) * | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
IT1273662B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
TW440567B (en) * | 1996-04-04 | 2001-06-16 | Toho Titanium Co Ltd | Propylene homopolymer |
DE19637669A1 (de) | 1996-09-16 | 1998-03-19 | Hoechst Ag | Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung |
AT405284B (de) * | 1996-10-31 | 1999-06-25 | Danubia Petrochem Polymere | Verfahren zur kontinuierlichen herstellung von elastischen polypropylenen |
EP0965603A1 (en) * | 1998-06-19 | 1999-12-22 | Fina Research S.A. | Polyolefin production |
SG85238A1 (en) | 1998-07-02 | 2001-12-19 | Montell Technology Company Bv | Compositions containing substantially amorphous alpha-olefin polymers |
EP1196464B9 (en) * | 1998-10-23 | 2005-03-23 | ExxonMobil Chemical Patents Inc. | Bridged metallocenes for olefin copolymerization |
FR2813079B1 (fr) * | 2000-08-18 | 2003-07-25 | Atofina | Ligands avec au moins un substituant fluorosilicone pour la preparation de metallocenes |
JP2002275282A (ja) * | 2001-03-15 | 2002-09-25 | Grand Polymer Co Ltd | ポリプロピレン二軸延伸フィルム |
DE60328582D1 (de) * | 2002-01-31 | 2009-09-10 | Mitsubishi Chem Corp | Nichtsteife propylenharzzusammensetzung |
CA2464518A1 (en) | 2002-08-29 | 2004-03-11 | Lg Chem, Ltd. | Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same |
EP2465878B1 (en) * | 2002-09-27 | 2020-04-01 | Mitsui Chemicals, Inc. | Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same |
JP4205402B2 (ja) * | 2002-11-15 | 2009-01-07 | 三井化学株式会社 | プロピレン系共重合体の製造方法 |
EP1650236A1 (en) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Activating agents for hafnium based metallocene components |
US7795194B2 (en) | 2004-11-26 | 2010-09-14 | Mitsui Chemicals, Inc. | Synthetic lubricating oil and lubricating oil composition |
US7517939B2 (en) * | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
US7619047B2 (en) * | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
US7470759B2 (en) * | 2006-07-31 | 2008-12-30 | Fina Technology, Inc. | Isotactic-atactic polypropylene and methods of making same |
US8119553B2 (en) * | 2007-09-28 | 2012-02-21 | Chevron Phillips Chemical Company Lp | Polymerization catalysts for producing polymers with low melt elasticity |
CN102405240B (zh) | 2009-04-21 | 2014-05-21 | 三井化学株式会社 | 烯烃聚合物的制造方法 |
US20120135903A1 (en) | 2010-05-11 | 2012-05-31 | Mitsui Chemicals, Inc. | Lubricating oil composition |
US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
WO2014123212A1 (ja) | 2013-02-08 | 2014-08-14 | 三井化学株式会社 | 固体状ポリアルミノキサン組成物、オレフィン重合用触媒、オレフィン重合体の製造方法、および固体状ポリアルミノキサン組成物の製造方法 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NZ126521A (es) * | 1959-06-06 | |||
US3305538A (en) | 1961-11-22 | 1967-02-21 | Montedison Spa | Polymerization process |
US3268627A (en) | 1963-05-16 | 1966-08-23 | Standard Oil Co | Blends of isotactic and syndiotactic polypropylene |
US3364190A (en) | 1964-04-27 | 1968-01-16 | Standard Oil Co | Process for polymerizing propylene to syndiotactic polypropylene |
US3547870A (en) * | 1967-08-01 | 1970-12-15 | Johnson & Johnson | Printing ink from randiopropylene |
WO1987000299A1 (en) | 1985-06-24 | 1987-01-15 | Leonard Bronstein | Contact lens |
JPS5473842A (en) | 1977-11-25 | 1979-06-13 | Mitsubishi Petrochem Co Ltd | Polyolefin resin composition |
US4411821A (en) | 1981-02-23 | 1983-10-25 | E. I. Du Pont De Nemours And Company | 1-Olefin polymerization catalyst |
DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
US4497906A (en) | 1982-02-16 | 1985-02-05 | Sumitomo Chemical Company, Limited | Solid catalyst component for olefin polymerization |
US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US4522982A (en) | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
EP0128046B1 (en) | 1983-06-06 | 1987-10-21 | Exxon Research And Engineering Company | Process and catalyst for producing reactor blend polyolefins |
DE3443087A1 (de) | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
DE3524535A1 (de) | 1985-07-10 | 1987-01-22 | Hoechst Ag | Verfahren zur herstellung von perylen-3,4,9,10-tetracarbonsaeure-n,n'- dimethylimid in hochdeckender pigmentform |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
IL80888A (en) | 1985-12-12 | 1991-12-12 | Exxon Chemical Patents Inc | Olefin polymerization catalysts,their preparation and use thereof |
US4658078A (en) | 1986-08-15 | 1987-04-14 | Shell Oil Company | Vinylidene olefin process |
DE3640948A1 (de) | 1986-11-29 | 1988-06-01 | Hoechst Ag | Verfahren zur herstellung eines 1-olefin-stereoblockpolymers |
DE3640924A1 (de) * | 1986-11-29 | 1988-06-01 | Hoechst Ag | 1-olefin-stereoblockpolymer und verfahren zu seiner herstellung |
US4794096A (en) | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
DE3718180A1 (de) | 1987-05-29 | 1988-12-15 | Hoechst Ag | Wasserloesliche monoazo-naphtholcarbonsaeure-verbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
US5176941A (en) | 1987-11-07 | 1993-01-05 | Hoechst Aktiengesellschaft | Process of producing a ceramic/fiber composite using a molten polysilazone |
US4931417A (en) | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US5162278A (en) | 1988-07-15 | 1992-11-10 | Fina Technology, Inc. | Non-bridged syndiospecific metallocene catalysts and polymerization process |
DE3826074A1 (de) * | 1988-07-30 | 1990-02-01 | Hoechst Ag | Propylen-isoblockpolymer und verfahren zu seiner herstellung |
DE3826075A1 (de) * | 1988-07-30 | 1990-02-01 | Hoechst Ag | 1-olefin-isoblockpolymer und verfahren zu seiner herstellung |
DE3907964A1 (de) * | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
-
1989
- 1989-05-20 DE DE3916553A patent/DE3916553A1/de not_active Withdrawn
-
1990
- 1990-05-16 DE DE59010446T patent/DE59010446D1/de not_active Expired - Fee Related
- 1990-05-16 ES ES90109206T patent/ES2093003T3/es not_active Expired - Lifetime
- 1990-05-16 EP EP90109206A patent/EP0399347B1/de not_active Expired - Lifetime
- 1990-05-17 JP JP2125626A patent/JP2988962B2/ja not_active Expired - Fee Related
- 1990-05-18 CA CA002017192A patent/CA2017192A1/en not_active Abandoned
- 1990-05-18 ZA ZA903829A patent/ZA903829B/xx unknown
- 1990-05-23 AU AU55772/90A patent/AU624953B2/en not_active Ceased
-
1993
- 1993-11-01 US US08/147,006 patent/US6225425B1/en not_active Expired - Fee Related
-
1995
- 1995-06-06 US US08/466,456 patent/US6197902B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2017192A1 (en) | 1990-11-20 |
EP0399347A3 (de) | 1991-03-13 |
EP0399347A2 (de) | 1990-11-28 |
JP2988962B2 (ja) | 1999-12-13 |
DE59010446D1 (de) | 1996-09-19 |
AU5577290A (en) | 1991-01-10 |
JPH039913A (ja) | 1991-01-17 |
ZA903829B (en) | 1991-02-27 |
US6197902B1 (en) | 2001-03-06 |
AU624953B2 (en) | 1992-06-25 |
US6225425B1 (en) | 2001-05-01 |
EP0399347B1 (de) | 1996-08-14 |
DE3916553A1 (de) | 1990-11-22 |
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