ES2066615T3 - Metodo en varias etapas para la desulfuracion a fondo de combustibles fosiles. - Google Patents

Metodo en varias etapas para la desulfuracion a fondo de combustibles fosiles.

Info

Publication number
ES2066615T3
ES2066615T3 ES92908483T ES92908483T ES2066615T3 ES 2066615 T3 ES2066615 T3 ES 2066615T3 ES 92908483 T ES92908483 T ES 92908483T ES 92908483 T ES92908483 T ES 92908483T ES 2066615 T3 ES2066615 T3 ES 2066615T3
Authority
ES
Spain
Prior art keywords
hds
fossil fuel
desulfurization
sulfur
biocatalizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92908483T
Other languages
English (en)
Inventor
Daniel J Monticello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Energy Biosystems Corp
Original Assignee
Energy Biosystems Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Biosystems Corp filed Critical Energy Biosystems Corp
Application granted granted Critical
Publication of ES2066615T3 publication Critical patent/ES2066615T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Treating Waste Gases (AREA)

Abstract

UN METODO PARA DESULFURIZAR DE MANERA PROFUNDA UN COMBUSTIBLE FOSIL QUE CONTIENE UNA VARIEDAD DE COMPUESTOS ORGANICOS DE AZUFRE, ALGUNOS DE LOS CUALES SON LABILES A LA HIDRODESULFURIZACION (HDS) Y ALGUNOS SON REFRACTARIOS A LA HDS, QUE CONSISTE EN (A) SOMETER EL COMBUSTIBLE FOSIL A UNA HDS O METODO SIMILAR DE DESULFURIZACION DE COMPUESTOS DE AZUFRE ORGANICOS, LABILES Y (B) SOMETER EL COMBUSTIBLE FOSIL A UNA DESULFURIZACION BIOCATALITICA (BDS) UTILIZANDO UN BIOCATALIZADOR QUE SE CAPAZ DE LIBERAR AZUFRE SELECTIVAMENTE DE LOS COMPUESTOS DE AZUFRE ORGANICOS, REFRACTARIOS AL A HDS. DE ESTE MODO SE PRODUCE UN COMBUSTIBLE FOSIL QUE NO GENERA NIVELES SUFICIENTES DE PRODUCTOS DE COMBUSTION QUE CONTENGA AZUFRE, PELIGROSOS QUE REQUIERE UNA DESULFURIZACION DESPUES DE LA COMBUSTION CUANDO SE QUEMA. ADEMAS, SE PUEDE PRODUCIR EL COMBUSTIBLE FOSIL PROFUNDAMENTE DESULFURIZADO UTILIZANDO UNICAMENTE UN TRATAMIENTO DE HDS SUAVE, EN LUGAR DE QUE SEAN NECESARIAS CONDICIONES QUE PUEDAN SER LO SUFICIENTEMENTE SEVERAS COMO PARA RESULTAR PERJUDICIALES PARA EL VALOR COMBUSTIBLE DEL PRODUCTO DESEADO. EL BIOCATALIZADOR UTILIZADO EN LA ETAPA BDS EN EL MOMENTO DE LA INVENCION ES CAPAZ DE CATALIZAR LA EXFOLIACION OXIDATIVA, ESPECIFICA DEL AZUFRE DE ENLACES ORGANICOS DE CARBONO Y AZUFRE EN MOLECULAS HETEROCICLICAS AROMATICAS QUE CONTIENEN AZUFRE TALES COMO EL DIBENZOTIOFENO. UN BIOCATALIZADOR PARTICULARMENTE PREFERENTE ES UN CULTIVO DE LA BACTERIA RHODOCOCCUS RHODOCROUS, ATCC N
ES92908483T 1991-03-15 1992-03-09 Metodo en varias etapas para la desulfuracion a fondo de combustibles fosiles. Expired - Lifetime ES2066615T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/669,914 US5232854A (en) 1991-03-15 1991-03-15 Multistage system for deep desulfurization of fossil fuels

Publications (1)

Publication Number Publication Date
ES2066615T3 true ES2066615T3 (es) 1995-03-01

Family

ID=24688242

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92908483T Expired - Lifetime ES2066615T3 (es) 1991-03-15 1992-03-09 Metodo en varias etapas para la desulfuracion a fondo de combustibles fosiles.

Country Status (13)

Country Link
US (2) US5232854A (es)
EP (1) EP0576557B1 (es)
JP (1) JPH06506016A (es)
KR (1) KR100188615B1 (es)
CN (1) CN1032483C (es)
AT (1) ATE116679T1 (es)
AU (1) AU656962B2 (es)
BR (1) BR9205746A (es)
CA (1) CA2105779A1 (es)
DE (1) DE69201131T2 (es)
ES (1) ES2066615T3 (es)
HK (1) HK68997A (es)
WO (1) WO1992016602A2 (es)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5002888A (en) * 1990-01-05 1991-03-26 Institute Of Gas Technology Mutant microorganisms useful for cleavage of organic C-S bonds
US5344778A (en) * 1990-02-28 1994-09-06 Institute Of Gas Technology Process for enzymatic cleavage of C-S bonds and process for reducing the sulfur content of sulfur-containing organic carbonaceous material
US5358870A (en) * 1990-02-28 1994-10-25 Institute Of Gas Technology Microemulsion process for direct biocatalytic desulfurization of organosulfur molecules
US5593889A (en) * 1990-11-21 1997-01-14 Valentine; James M. Biodesulfurization of bitumen fuels
EP0563142B1 (en) * 1990-12-21 1995-12-13 Energy Biosystems Corporation Use of a biocatalyst for the reduction of petroleum viscosity
US5232854A (en) * 1991-03-15 1993-08-03 Energy Biosystems Corporation Multistage system for deep desulfurization of fossil fuels
US5510265A (en) * 1991-03-15 1996-04-23 Energy Biosystems Corporation Multistage process for deep desulfurization of a fossil fuel
ATE120239T1 (de) * 1991-05-01 1995-04-15 Energy Biosystems Corp System und kontinuierliches verfahren zur biokatalytischen entschwefelung von schwefelhaltigen heterozyklischen molekülen.
EP0562313A1 (en) * 1992-03-12 1993-09-29 Institute of Gas Technology Biochemical cleavage of organic C-S bonds
US5356813A (en) * 1992-04-30 1994-10-18 Energy Biosystems Corporation Process for the desulfurization and the desalting of a fossil fuel
AU715700B2 (en) * 1992-07-10 2000-02-10 Energy Biosystems Corporation Recombinant DNA encoding a desulfurization biocatalyst
AU684253B2 (en) * 1992-07-10 1997-12-11 Energy Biosystems Corporation Recombinant dna encoding a desulfurization biocatalyst
US5458752A (en) * 1993-09-03 1995-10-17 Martin Marietta Energy Systems, Inc. Apparatus and method for the desulfurization of petroleum by bacteria
US5468626A (en) * 1993-12-17 1995-11-21 Energy Biosystems Corporation Method for separating a sulfur compound from carbonaceous materials
NZ272544A (en) * 1994-08-24 1996-03-26 Mitsubishi Heavy Ind Ltd Removal of sulphur from hydrogen sulphide-containing gas at geothermal power plants using a cell breeding culture tank independent of the biochemical treatment tank
IT1283233B1 (it) * 1996-03-12 1998-04-16 Eniricerche Spa Arthrobacter sp. e suo impiego per la desolforazione di combustibili fossili
US5973195A (en) * 1998-03-19 1999-10-26 Energy Biosystems Corporation Surfactants derived from 2-(2-hydroxyphenyl)benzenesulfinate and alkyl-substituted derivatives
US6124130A (en) * 1998-08-10 2000-09-26 Clean Diesel Technologies, Inc. Microbial catalyst for desulfurization of fossil fuels
WO2000042005A1 (en) 1999-01-14 2000-07-20 Energy Biosystems Corporation Compositions comprising 2-(2-hydroxyphenyl) benzenesulfinate and alkyl-substituted derivatives thereof
FR2793256B1 (fr) * 1999-05-05 2001-07-27 Total Raffinage Distrib Procede d'obtention de produits petroliers a faible taux de soufre par desulfuration d'extraits
US6461859B1 (en) 1999-09-09 2002-10-08 Instituto Mexicano Del Petroleo Enzymatic oxidation process for desulfurization of fossil fuels
IT1317849B1 (it) 2000-02-24 2003-07-15 Enitecnologie Spa Mezzi e metodi per l'espressione di proteine omologhe ed eterologhe inceppi di rhodococcus.
US6420457B1 (en) 2000-04-04 2002-07-16 Westinghouse Savannah River Company, Llc Microwave treatment of vulcanized rubber
US6407144B1 (en) 2000-04-04 2002-06-18 Westinghouse Savannah River Company, Llc Combination biological and microwave treatments of used rubber products
US6479558B1 (en) 2000-04-04 2002-11-12 Westinghouse Savannah River Company Microbial processing of used rubber
US6402939B1 (en) 2000-09-28 2002-06-11 Sulphco, Inc. Oxidative desulfurization of fossil fuels with ultrasound
US6896796B2 (en) * 2001-02-16 2005-05-24 W. R. Grace & Co.-Conn. Membrane separation for sulfur reduction
US6841062B2 (en) * 2001-06-28 2005-01-11 Chevron U.S.A. Inc. Crude oil desulfurization
US9920253B2 (en) 2008-12-30 2018-03-20 Somerset Coal International Microorganism mediated liquid fuels
WO2010077459A2 (en) * 2008-12-30 2010-07-08 Jrst, Llc Microorganism mediated liquid fuels
US20110220550A1 (en) * 2010-03-15 2011-09-15 Abdennour Bourane Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US9296960B2 (en) 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US8741127B2 (en) 2010-12-14 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating and oxidation of aromatic-rich hydrotreated products
US8741128B2 (en) 2010-12-15 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction
ES2652032T3 (es) 2011-07-29 2018-01-31 Saudi Arabian Oil Company Procedimiento de hidrotratamiento selectivo de destilados medios
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
KR101346306B1 (ko) * 2013-06-11 2014-01-02 이종두 광물성 소마티드 추출방법 및 이를 이용한 다기능 첨단 소재 제조방법
CN111613019B (zh) * 2020-06-18 2022-07-22 大唐环境产业集团股份有限公司 防止脱硫烟气so2超标排放的预警方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE147365C (es) *
US2521761A (en) * 1947-07-23 1950-09-12 Texaco Development Corp Method of desulfurizing crude oil
US2641564A (en) * 1948-03-31 1953-06-09 Texaco Development Corp Process of removing sulfur from petroleum hydrocarbons and apparatus
US2574070A (en) * 1948-07-01 1951-11-06 Texaco Development Corp Purification of substances by microbial action
US2975103A (en) * 1956-04-06 1961-03-14 Exxon Research Engineering Co Bacteriological desulfurization of petroleum
US3069325A (en) * 1959-12-21 1962-12-18 Phillips Petroleum Co Treatment of hydrocarbons
US3305353A (en) * 1964-03-30 1967-02-21 British Columbia Res Council Accelerated microbiological ore extraction process
DD146753A3 (de) * 1978-02-08 1981-03-04 Petrolchemisches Kombinat Verfahren zur hydrokatalytischen reinigung von biologisch behandelten erdoeldestillaten
US4206288A (en) * 1978-05-05 1980-06-03 Union Carbide Corporation Microbial desulfurization of coal
US4283270A (en) * 1980-06-25 1981-08-11 Mobil Oil Corporation Process for removing sulfur from petroleum oils
US4659670A (en) * 1983-05-18 1987-04-21 The Standard Oil Company Biological desulfurization of coal
US4562156A (en) * 1983-07-11 1985-12-31 Atlantic Research Corporation Mutant microorganism and its use in removing organic sulfur compounds
US4618348A (en) * 1983-11-02 1986-10-21 Petroleum Fermentations N.V. Combustion of viscous hydrocarbons
US4632906A (en) * 1984-11-29 1986-12-30 Atlantic Richfield Company Biodesulfurization of carbonaceous materials
US4703010A (en) * 1986-05-02 1987-10-27 The Board Of Regents For The University Of Oklahoma Electrolytic bioreactor assembly and method
US4808535A (en) * 1986-08-05 1989-02-28 Atlantic Research Corporation Acinetobacter species and its use in removing organic sulfur compounds
US4861723A (en) * 1986-12-15 1989-08-29 Shell Oil Company Microbiological desulfurization of coal and coal water admixture to provide a desulfurized fuel
US4851350A (en) * 1987-03-04 1989-07-25 The Standard Oil Company Microbial desulfurization of coal
KR900004936B1 (ko) * 1987-12-31 1990-07-12 한국과학기술원 황산염 환원세균을 이용한 전기화학적 석유의 탈황방법
US5094668A (en) * 1988-03-31 1992-03-10 Houston Industries Incorporated Enzymatic coal desulfurization
US5002888A (en) * 1990-01-05 1991-03-26 Institute Of Gas Technology Mutant microorganisms useful for cleavage of organic C-S bonds
US5104801A (en) * 1990-01-05 1992-04-14 Institute Of Gas Technology Mutant microorganisms useful for cleavage of organic c-s bonds
US5198341A (en) * 1990-01-05 1993-03-30 Institute Of Gas Technology Useful for cleavage of organic C-S bonds Bacillus sphaericus microorganism
US5132219A (en) * 1990-02-28 1992-07-21 Institute Of Gas Technology Enzymes from Rhodococcus rhodochrous strain ATCC No. 53968, Bacillus sphaericus strain ATCC No. 53969 and mixtures thereof for cleavage of organic C--S bonds of carbonaceous material
EP0558682B1 (en) * 1990-11-21 1998-06-10 VALENTINE, James, M. Biodesulfurization of bitumen fuels
US5232854A (en) * 1991-03-15 1993-08-03 Energy Biosystems Corporation Multistage system for deep desulfurization of fossil fuels

Also Published As

Publication number Publication date
US5387523A (en) 1995-02-07
BR9205746A (pt) 1994-09-27
DE69201131D1 (de) 1995-02-16
DE69201131T2 (de) 1995-08-03
WO1992016602A3 (en) 1992-12-23
EP0576557B1 (en) 1995-01-04
CN1064880A (zh) 1992-09-30
ATE116679T1 (de) 1995-01-15
WO1992016602A2 (en) 1992-10-01
EP0576557A1 (en) 1994-01-05
CN1032483C (zh) 1996-08-07
JPH06506016A (ja) 1994-07-07
US5232854A (en) 1993-08-03
HK68997A (en) 1997-05-30
AU1643992A (en) 1992-10-21
KR100188615B1 (ko) 1999-06-01
CA2105779A1 (en) 1992-09-16
AU656962B2 (en) 1995-02-23

Similar Documents

Publication Publication Date Title
ES2066615T3 (es) Metodo en varias etapas para la desulfuracion a fondo de combustibles fosiles.
ES2057593T3 (es) Una preparacion de microperoxidasa que contiene un hemopeptido como componente activo.
ES462770A1 (es) Metodo y aparato para la combustion de gases residuales in- dustriales de bajo valor calorifico.
AR027472A1 (es) Proceso para eliminar el mercurio de los hidrocarburos.
MX9403256A (es) Metodo para el tratamiento de un catalizador de combustion espontanea.
BR0314741A (pt) Método e aparelho para tratamento térmico
MX167771B (es) Procedimiento para la reduccion de oxidos de nitroeno con reduccion al minimo de la produccion de otos contaminantes
BR9205954A (pt) Processo contínuo para dessulfurar um líquido de petróleo e sistema para dessulfurar continuamente um líquido de petróleo
DE60213085D1 (de) Reaktor zur zersetzung von flüssigen monergolen treibstoffen auf ammoniumdinitiridbasis und zersetzungsverfahren
BR0315111A (pt) Processo para a remoção de oxigênio de uma mistura de gás e processo para a remoção de oxigêxio e alcino de uma mistura de gás
CL2009001474A1 (es) Procedimiento para tratar mineral sulfurado que comprende biolixiviar en solucion de iones cl- con un consorcio de cultivos mixtos de leptosprillium ferriphilum y microorganismo oxidante de azufre, halofilico o halotolerante, donde la solucion contiene 1500-30000 ppm de cl- y ademas contiene al, mg o na, a t>10 grados y ph 1-3.
TR200001920T2 (tr) Ateşlenme özelliği geliştirilmiş yakıtlar.
BR0113486A (pt) Processo de tratar um aço inoxidável
ATE254149T1 (de) Verfahren zur herstellung von einem kohlenstoffhaltigen feststoff und wasserstoffreichen gasen
BR112019000237A2 (pt) processo para o tratamento de águas residuais que contêm material orgânico e amônia
AR046397A1 (es) Reduccion simultanea de nox y carbono en las cenizas utilizando manganeso en quemadores de carbon
ES2142969T3 (es) Metodo de funcionamiento de un horno.
HK1047015B (zh) 用於擴散而對抗含於空氣中的細菌的抗菌組合物，擴散這種組合物的方法
AR031311A1 (es) Metodo para operar un horno
KR910006155A (ko) 유출액이 함유하는 유기물질 및 설페이트를 제거하기 위해 혐기성 발효를 이용하여 유출액을 처리하는 방법
DK250489D0 (da) Fremgangsmaade til reduktion af nitrogenoxider samt minimering af dannelsen af andre forurenende bestanddele
BR0304813A (pt) Método para reduzir a emissão de gás de óxido residual de um processo industrial
PL1888226T3 (pl) Sposób usuwania ciał barwnych z paliw na bazie węglowodorów z użyciem węgla aktywnego
AR007876A1 (es) Un metodo para modificar un combustible liquido de hidrocarburo
JPS5390672A (en) Sluge incinerating method by controlling atmosphere and the system therefor

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 576557

Country of ref document: ES