ES2064783T3 - Sales de 3-hidroxi-2-ciclobuten-1-ona, su preparacion y utilizacion. - Google Patents

Sales de 3-hidroxi-2-ciclobuten-1-ona, su preparacion y utilizacion.

Info

Publication number
ES2064783T3
ES2064783T3 ES91102714T ES91102714T ES2064783T3 ES 2064783 T3 ES2064783 T3 ES 2064783T3 ES 91102714 T ES91102714 T ES 91102714T ES 91102714 T ES91102714 T ES 91102714T ES 2064783 T3 ES2064783 T3 ES 2064783T3
Authority
ES
Spain
Prior art keywords
salts
cyclobuten
image
alkali metal
general formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91102714T
Other languages
English (en)
Inventor
Barry Dr Jackson
Thomas Dr Scholl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lonza AG
Original Assignee
Lonza AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lonza AG filed Critical Lonza AG
Application granted granted Critical
Publication of ES2064783T3 publication Critical patent/ES2064783T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
    • C07C211/35—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton containing only non-condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/03—Monoamines
    • C07C211/05—Mono-, di- or tri-ethylamine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/42—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrolysis
    • C07C45/43—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrolysis of >CX2 groups, X being halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/516—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of nitrogen-containing compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/527—Unsaturated compounds containing keto groups bound to rings other than six-membered aromatic rings
    • C07C49/573—Unsaturated compounds containing keto groups bound to rings other than six-membered aromatic rings containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/707—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups a keto group being part of a three- to five-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

SE DESCRIBEN SALES 3-HIDROXI-2-CICLOBUTENO-1-ONA DE LA FORMULA GENERAL DONDE R ES UN GRUPO AMONIO DE LA FORMULA GENERAL EN LA QUE R1, R2 Y R3 TIENEN VALOR IDENTICO O DISTINTO Y SON UN ATOMO DE HIDROGENO, O GRUPO CICLOALQUIL O GRUPO BAJO EN ALQUIL O R ES UN ATOMO DE METAL ALCALINO. ESTAS SALES SEGUN LA FORMULA I CONTIENEN UNA BASE A TRAVES DE UNA TRANSFORMACION DE 3-ACETOXI-2-CICLOBUTENO-1-ONA, DE 1,3-CICLOBUTANDION O DE UN 3-ACETOXI-2-CICLOBUTENO-1-ONA CONTENIENDO RESIDUOS DE DESTILACION DE LA PRODUCCION DE DICETENO. COMO BASE PUEDE UTILIZAR UNA AMINA DE LA FORMULA GENERAL DONDE R1, R2 Y R3 TIENEN EL CONOCIDO SIGNIFICADO O SON UN ALCOHOLATO DE METAL ALCALINO O UN HIDROXIDO DE METAL ALCALINO. LAS SALES SEGUN LA FORMULA I SON APROPIADAS PARA LA FABRICACION DE ACIDO CUADRATICO, DONDE EN UNA PRIMERA ETAPA ES HIDROGENADO Y EN UNA SEGUNDA ETAPA ES HIDROLIZADO.
ES91102714T 1990-02-26 1991-02-25 Sales de 3-hidroxi-2-ciclobuten-1-ona, su preparacion y utilizacion. Expired - Lifetime ES2064783T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH59890 1990-02-26

Publications (1)

Publication Number Publication Date
ES2064783T3 true ES2064783T3 (es) 1995-02-01

Family

ID=4190702

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91102714T Expired - Lifetime ES2064783T3 (es) 1990-02-26 1991-02-25 Sales de 3-hidroxi-2-ciclobuten-1-ona, su preparacion y utilizacion.

Country Status (10)

Country Link
US (3) US5087756A (es)
EP (1) EP0444563B1 (es)
JP (1) JP2890860B2 (es)
AT (1) ATE114297T1 (es)
CA (1) CA2036808C (es)
DE (1) DE59103554D1 (es)
DK (1) DK0444563T3 (es)
ES (1) ES2064783T3 (es)
IE (1) IE65907B1 (es)
RU (2) RU2017719C1 (es)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5360937A (en) * 1992-03-24 1994-11-01 Lonza Ltd. 1,3-cyclobutanedione-bisketals, process for their production and their use
US5278031A (en) * 1992-10-23 1994-01-11 Polaroid Corporation Process for thermochemical generation of squaric acid and for thermal imaging, and imaging medium for use therein
EP1314910A1 (de) * 2001-11-21 2003-05-28 Honeywell International, Inc. Einrichtung zur Erzeugung einer Drehbewegung
US7902320B2 (en) 2005-06-17 2011-03-08 Eastman Chemical Company Graphic art films comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US20060270773A1 (en) * 2005-05-26 2006-11-30 Hale Wesley R Polyester-polycarbonate blends for diffuser sheets with improved luminance
US20100298523A1 (en) * 2005-06-17 2010-11-25 Eastman Chemical Company Polyester Compositions Which Comprise Cyclobutanediol and at Least One Phosphorus Compound
US7704605B2 (en) 2006-03-28 2010-04-27 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US20100087574A1 (en) * 2005-10-28 2010-04-08 Emmett Dudley Crawford Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
CA2625846A1 (en) * 2005-10-28 2007-05-10 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound
US20070100125A1 (en) * 2005-10-28 2007-05-03 Crawford Emmett D Polyester compositions comprising minimal amounts of cyclobutanediol
US8193302B2 (en) * 2005-10-28 2012-06-05 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US20070100122A1 (en) * 2005-10-28 2007-05-03 Crawford Emmett D Polyester compositions containing cyclobutanediol and articles made therefrom
US20100096589A1 (en) * 2005-10-28 2010-04-22 Emmett Dudley Crawford Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom
US9598533B2 (en) 2005-11-22 2017-03-21 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7737246B2 (en) * 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
US9169388B2 (en) 2006-03-28 2015-10-27 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
US20070232779A1 (en) * 2006-03-28 2007-10-04 Leslie Shane Moody Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid
US20070232778A1 (en) * 2006-03-28 2007-10-04 Leslie Shane Moody Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid
JP4761211B2 (ja) * 2006-11-14 2011-08-31 富士フイルム株式会社 テレビレンズ装置
US7560600B2 (en) * 2006-12-02 2009-07-14 Eastman Chemical Company Process for the preparation of a tetraalkylcyclobutane-1,3-diol using a promoted nickel-based catalyst
US7582804B2 (en) * 2006-12-02 2009-09-01 Eastman Chemical Company Process for the preparation of a tetraalkycyclobutane-1,3-diol using a promoted-copper catalyst
US7723551B2 (en) 2006-12-02 2010-05-25 Eastman Chemical Company Process for the simultaneous co-production of 2,2,4,4-tetramethylcyclobutane-1,3-diol and 1,4-cyclohexanedimethanol
US7838707B2 (en) * 2006-12-02 2010-11-23 Eastman Chemical Company Process for the preparation of a tetraalkylcyclobutane-1,3-diol using an ruthenium-promoted cobalt-based catalyst
US7524994B2 (en) * 2006-12-02 2009-04-28 Eastman Chemical Company Process for the preparation of a tetraalkylcyclobutane-1,3-diol using an iridium-promoted cobalt-based catalyst
US7521583B2 (en) * 2006-12-02 2009-04-21 Eastman Chemical Company Process for the preparation of tetraalkylcyclobutane-1,3-diol in the presence of a cobalt-based catalyst
DE102008013784B4 (de) 2007-03-15 2017-03-23 Denso Corporation Kompressor
US8501287B2 (en) 2007-11-21 2013-08-06 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
KR101895184B1 (ko) 2007-11-21 2018-09-04 이스트만 케미칼 컴파니 플라스틱 젖병, 다른 취입 성형된 제품, 및 이들의 제조 방법
US8198371B2 (en) 2008-06-27 2012-06-12 Eastman Chemical Company Blends of polyesters and ABS copolymers
US8895654B2 (en) 2008-12-18 2014-11-25 Eastman Chemical Company Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420868B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US20130217830A1 (en) 2012-02-16 2013-08-22 Eastman Chemical Company Clear Semi-Crystalline Articles with Improved Heat Resistance
US9145346B1 (en) 2014-12-10 2015-09-29 Eastman Chemical Company Process for 2,2,4,4-tetramethylcyclobutane-1,3-diol crystallization
WO2024094637A1 (en) * 2022-10-31 2024-05-10 Arxada Ag Process for the preparation of cyclic ketones

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US3244749A (en) * 1961-10-30 1966-04-05 Hooker Chemical Corp Ammonium salts of 3-hydroxypentahalo-2-cyclopentenone
US3379746A (en) * 1965-09-07 1968-04-23 Hooker Chemical Corp Metal salts of 3-hydroxy-pentahalo-2-cyclopentenone
BE786650A (fr) * 1971-07-24 1973-01-24 Ercoli Raffaele Procede de preparation de l'acide squarique
NL7603598A (nl) * 1975-04-18 1976-10-20 Ciba Geigy Werkwijze voor het bereiden van preparaten voor het beinvloeden van de plantegroei alsmede de toepassing daarvan.
DE2618557C3 (de) * 1976-04-28 1980-07-31 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von Hexachlorcyclobuten
DE2623836C3 (de) * 1976-05-28 1978-12-21 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von Quadratsäure
US4104308A (en) * 1976-06-21 1978-08-01 International Business Machines Corporation Synthesis of squaric acid
DE2824558C3 (de) * 1978-06-05 1981-07-09 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Quadratsäure
DE3314431A1 (de) * 1983-04-21 1984-10-25 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von quadratsaeure
US4461681A (en) * 1983-05-31 1984-07-24 The Halcon Sd Group, Inc. Process for the preparation of squaric acid by the electrolysis of carbon monoxide in anhydrous aliphatic nitrile solvent media
US4523980A (en) * 1984-08-31 1985-06-18 The Halcon Sd Group, Inc. Process for the recovery of high purity squaric acid
JPH01299245A (ja) * 1988-05-24 1989-12-04 Kyowa Hakko Kogyo Co Ltd スクアリン酸の製造方法

Also Published As

Publication number Publication date
IE65907B1 (en) 1995-11-29
JPH05993A (ja) 1993-01-08
US5118847A (en) 1992-06-02
RU2078757C1 (ru) 1997-05-10
JP2890860B2 (ja) 1999-05-17
DK0444563T3 (da) 1994-12-12
ATE114297T1 (de) 1994-12-15
DE59103554D1 (de) 1995-01-05
US5118861A (en) 1992-06-02
EP0444563B1 (de) 1994-11-23
EP0444563A3 (en) 1992-04-15
IE910538A1 (en) 1991-08-28
EP0444563A2 (de) 1991-09-04
RU2017719C1 (ru) 1994-08-15
US5087756A (en) 1992-02-11
CA2036808C (en) 2000-05-23
CA2036808A1 (en) 1991-08-27

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