ES2055669A1 - Regeneracion in situ de suelos y aguas subterraneas contaminados empleando cloruro calcico. - Google Patents

Regeneracion in situ de suelos y aguas subterraneas contaminados empleando cloruro calcico.

Info

Publication number
ES2055669A1
ES2055669A1 ES09300784A ES9300784A ES2055669A1 ES 2055669 A1 ES2055669 A1 ES 2055669A1 ES 09300784 A ES09300784 A ES 09300784A ES 9300784 A ES9300784 A ES 9300784A ES 2055669 A1 ES2055669 A1 ES 2055669A1
Authority
ES
Spain
Prior art keywords
carbonate
formations
groundwater
calcium chloride
land
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES09300784A
Other languages
English (en)
Other versions
ES2055669B1 (es
Inventor
David Charles Grant
Carmine M Mancuso
Herbert Andrew Burgman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CBS Corp
Original Assignee
Westinghouse Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Westinghouse Electric Corp filed Critical Westinghouse Electric Corp
Publication of ES2055669A1 publication Critical patent/ES2055669A1/es
Application granted granted Critical
Publication of ES2055669B1 publication Critical patent/ES2055669B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • A62D3/33—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by chemical fixing the harmful substance, e.g. by chelation or complexation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09C—RECLAMATION OF CONTAMINATED SOIL
    • B09C1/00—Reclamation of contaminated soil
    • B09C1/08—Reclamation of contaminated soil chemically
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH OR ROCK DRILLING; MINING
    • E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/28—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/20—Organic substances
    • A62D2101/24—Organic substances containing heavy metals
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/40—Inorganic substances
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/40—Inorganic substances
    • A62D2101/43—Inorganic substances containing heavy metals, in the bonded or free state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09C—RECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00—In situ

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Toxicology (AREA)
  • Fluid Mechanics (AREA)
  • Health & Medical Sciences (AREA)
  • Soil Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Processing Of Solid Wastes (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

REGENERACION IN SITU DE SUELOS Y AGUAS SUBTERRANEAS CONTAMINADOS EMPLEANDO CLORURO CALCICO. UN METODO PARA ESTABILIZAR IN SITU CONTAMINANTES METALICOS PESADOS SOLUBLES EN FORMACIONES TERRESTRES O SUBMARINAS QUE CONTIENEN CARBONATO, QUE CONSISTE EN INTRODUCIR EN LA FORMACION QUE CONTIENE CARBONATO UNA SOLUCION ACUOSA DE CLORURO CALCICO, CUYA SOLUCION CONTIENE UNA CANTIDAD ESTABILIZANTE DE IONES CALCIO. LOS CONTAMINANTES Y EL CARBONATO FORMAN CON LOS IONES CALCIO COPRECIPITADOS QUE SON INSOLUBLES EN LOS FLUIDOS DE LA FORMACION, INHIBIENDO CON ELLO SUSTANCIALMENTE LA MOVILIZACION POSTERIOR DE LOS METALES PESADOS POR LAS AGUAS SUBTERRANEAS. EL METODO ES EFICAZ CON LOS METALES PESADOS QUE SE ENCUENTRAN TANTO EN FORMA CATIONICA COMO ANIONICA EN LAS FORMACIONES TERRESTRES O SUBMARINAS QUE CONTIENEN CARBONATO. EL METODO PUEDE SER UTILIZADO PARA TRATAR FORMACIONES TERRESTRES A CENTENARES DE METROS POR DEBAJO DE LA SUPERFICIE, VERTEDEROS O FORMACIONES SUBMARINAS PARA REDUCIR LOS CONTAMINANTES METALICOS PESADOS SOLUBLES A ALGUNAS PARTES POR MILLON.
ES09300784A 1992-04-16 1993-04-16 Regeneracion in situ de suelos y aguas subterraneas contaminados empleando cloruro calcico. Expired - Fee Related ES2055669B1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/870,439 US5275739A (en) 1992-04-16 1992-04-16 In-situ restoration of contaminated soils and groundwater using calcium chloride

Publications (2)

Publication Number Publication Date
ES2055669A1 true ES2055669A1 (es) 1994-08-16
ES2055669B1 ES2055669B1 (es) 1995-03-01

Family

ID=25355373

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09300784A Expired - Fee Related ES2055669B1 (es) 1992-04-16 1993-04-16 Regeneracion in situ de suelos y aguas subterraneas contaminados empleando cloruro calcico.

Country Status (6)

Country Link
US (1) US5275739A (es)
JP (1) JPH0639055A (es)
CA (1) CA2094091A1 (es)
DE (1) DE4312341A1 (es)
ES (1) ES2055669B1 (es)
IT (1) IT1263349B (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19547271A1 (de) * 1995-12-19 1997-06-26 Environ Ingenieurgesellschaft Verfahren und Vorrichtung zur Immobilisierung von Schadstoffen, insbesondere Schwermetallen und dabei insbesondere Quecksilber in entsprechend belasteten Böden oder anderen bodenähnlichen Materialien
US5779464A (en) * 1996-01-10 1998-07-14 The Ohio State University Research Foundation Calcium carbonate sorbent and methods of making and using same
US5846434A (en) * 1996-03-01 1998-12-08 University Of Georgia Research Foundation In-situ groundwater remediation by selective colloid mobilization
US6309996B1 (en) 1998-05-07 2001-10-30 The Ohio State University Suspension carbonation process for reactivation of partially utilized sorbent
US6379083B1 (en) * 1998-07-10 2002-04-30 Hazama Corporation Method for the remediation of soil contaminated with organic halide compounds
US7067456B2 (en) * 2003-02-06 2006-06-27 The Ohio State University Sorbent for separation of carbon dioxide (CO2) from gas mixtures
US7618606B2 (en) * 2003-02-06 2009-11-17 The Ohio State University Separation of carbon dioxide (CO2) from gas mixtures
AU2004314102B2 (en) * 2003-12-19 2009-12-24 Craig M. Bethke In situ treatment process to remove metal contamination from groundwater
US10335757B2 (en) 2004-03-05 2019-07-02 Specialty Earth Sciences Process for making environmental reactant(s)
US7431849B1 (en) * 2004-03-05 2008-10-07 Specialty Earth Sciences Llc Encapsulated reactant and process
US7678351B2 (en) * 2005-03-17 2010-03-16 The Ohio State University High temperature CO2 capture using engineered eggshells: a route to carbon management
JP4621634B2 (ja) * 2006-06-29 2011-01-26 国立大学法人北海道大学 微生物を用いたカルシウムを含む地盤の固結方法
EP2073914B1 (en) * 2006-09-25 2020-05-06 The Ohio State University Calcium looping process for high purity hydrogen production
US20120003135A1 (en) * 2009-01-02 2012-01-05 Nicholas Vollendorf Water treatment
US8512572B1 (en) * 2010-04-20 2013-08-20 U.S. Department Of Energy Method of precipitating uranium from an aqueous solution and/or sediment
JP6220114B2 (ja) 2011-11-30 2017-10-25 荏原工業洗浄株式会社 放射性セシウム固体状被汚染物の除染方法及び装置
WO2014144718A1 (en) 2013-03-15 2014-09-18 Carus Corporation Sustained release reactant blends
CN103920705B (zh) * 2014-04-24 2015-06-24 华北电力大学 一种全方位联合技术修复铀污染土壤的装置和方法
JP7299075B2 (ja) * 2019-06-10 2023-06-27 大成建設株式会社 酸性地下水の浄化方法
US11447685B2 (en) * 2019-08-28 2022-09-20 Halliburton Energy Services, Inc. Methods of stabilizing carbonate-bearing formations
CN110681692B (zh) * 2019-11-15 2021-08-27 斯蒂芬·Y·周 一种修复重金属污染土壤的方法
CN111069260B (zh) * 2020-01-13 2022-04-08 曜昂环境技术(江苏)有限公司 土壤和地下水中的非水相污染物的原位处理方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4418961A (en) * 1980-12-31 1983-12-06 Mobil Oil Corporation Method for restoring contaminants to base levels in previously leached formations
EP0128689A1 (en) * 1983-05-26 1984-12-19 E.I. Du Pont De Nemours And Company Iron chloride waste treatment in molten salt
US4950409A (en) * 1988-06-10 1990-08-21 Stanforth Robert R Method for treating hazardous wastes
US4981394A (en) * 1988-06-06 1991-01-01 Terran Research, Inc. Method of sealing permeable unconsolidated materials

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3950179A (en) * 1974-05-17 1976-04-13 Schneider Gordon L Stabilization composition
US4156658A (en) * 1974-06-28 1979-05-29 The United States Of America As Represented By The United States Department Of Energy Fixation of radioactive ions in porous media with ion exchange gels
JPS5452862A (en) * 1977-08-25 1979-04-25 Blue Circle Ind Ltd Method of removing heavy metal by silicate
US4354942A (en) * 1980-11-26 1982-10-19 Olin Corporation Stabilization of mercury in mercury-containing materials
DE3484652D1 (de) * 1983-03-21 1991-07-04 Union Oil Co Verfahren zum abtrennen schwerer metalle aus waessrigen loesungen durch kopraezipitation.
FR2568244B1 (fr) * 1984-07-26 1992-01-10 Soletanche Coulis special d'etancheite et son utilisation pour le stockage de dechets contenant des cations metalliques
US4909849A (en) * 1987-04-23 1990-03-20 Funderburk Raymond E Method and mixture for solidifying and immobilizing various hazardous waste contaminants in an organic matrix
US4888053A (en) * 1988-07-07 1989-12-19 Union Oil Co. Of California Chloride leaching of iron-based, heavy metal-containing sludges
US4997313A (en) * 1990-05-14 1991-03-05 General Motors Corporation Process for in-situ surfactant washing of contaminated soil

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4418961A (en) * 1980-12-31 1983-12-06 Mobil Oil Corporation Method for restoring contaminants to base levels in previously leached formations
EP0128689A1 (en) * 1983-05-26 1984-12-19 E.I. Du Pont De Nemours And Company Iron chloride waste treatment in molten salt
US4981394A (en) * 1988-06-06 1991-01-01 Terran Research, Inc. Method of sealing permeable unconsolidated materials
US4950409A (en) * 1988-06-10 1990-08-21 Stanforth Robert R Method for treating hazardous wastes

Also Published As

Publication number Publication date
JPH0639055A (ja) 1994-02-15
DE4312341A1 (de) 1993-10-21
ES2055669B1 (es) 1995-03-01
IT1263349B (it) 1996-08-05
CA2094091A1 (en) 1993-10-17
ITPD930083A0 (it) 1993-04-14
US5275739A (en) 1994-01-04
ITPD930083A1 (it) 1994-10-14

Similar Documents

Publication Publication Date Title
ES2055669A1 (es) Regeneracion in situ de suelos y aguas subterraneas contaminados empleando cloruro calcico.
EP1212149A4 (en) METHOD FOR SOIL AND / OR GROUNDWATER REMEDIATION
EP2707154B1 (en) In-situ subsurface decontamination
CA2182668A1 (en) Process for soil decontamination by oxidation and vacuum extraction
NO854434L (no) Fremgangsmaate for dekontaminering av en undergrunnsformasjon.
CA2094092A1 (en) In-situ restoration of contaminated soils and groundwater
CA2030382A1 (en) Process for in-situ surfactant washing of contaminated soil
NO20005691L (no) Fremgangsmåte for behandling av vann, jord, sedimenter og/eller slam
US6869535B2 (en) Co-oxidation method and co-oxidation reagent for decontaminating ground water and soil
EP0184411A3 (en) Method and apparatus for treating wellbore drilling cuttings
CN103736723A (zh) 重金属污染土壤与地下水一体化修复方法
MY120014A (en) Oil and gas field chemicals
JP3753644B2 (ja) 汚染された土壌および地下水を浄化するための鉄粉注入を伴うニューマチック・フラクチャリングによる可溶性および不溶性重金属および有機ハロゲン化合物の原位置還元法
BG98630A (en) Method for the decontamination of combustion wastes by removing the soluble toxic compounds from the treated solutions and their binding and concentration
JPS5413466A (en) Treating method for contaminated soil or sludge
Jacobs et al. Design considerations for in situ chemical oxidation using high pressure jetting technology
ATE131752T1 (de) Verfahren zum dekontaminieren von mit schwermetallen verunreinigten böden
IT1251428B (it) Procedimento per la decontaminazione di suoli inquinanti da sostanze idrocarburiche
Josef et al. Hydraulic in-situ remediation techniques with surfactants: optimization of hydraulic systems
DOBSON Geology and geochemical evolution of the Lost River, Alaska, tin deposit[Ph. D. Thesis]
RU1778305C (ru) Способ складировани и хранени горной породы
董东林 et al. Research on Water-Filling Patterns and Countermeasures── A case study of Xiaotun Coal Mine
Kirilenko et al. Hydrogeological Conditions of the Slaviansky Deposits of Rock Salt and Possibility of Industrial Use of Groundwater Brines(Gidrogeologicheskiye usloviya Slavianskogo mestorozhdeniya kamennoy soli i perspektivy promyshlennoy expluatatsii podzemnykh rassolov)
Turner et al. Contaminant Assessment and Remedial Action of a Low pH Leachate Plume in a Surficial Aquifer
Reed et al. Rapid Infiltration

Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20000401