ES2044347T3 - Desazuframiento de gases de combustion. - Google Patents
Desazuframiento de gases de combustion.Info
- Publication number
- ES2044347T3 ES2044347T3 ES90115531T ES90115531T ES2044347T3 ES 2044347 T3 ES2044347 T3 ES 2044347T3 ES 90115531 T ES90115531 T ES 90115531T ES 90115531 T ES90115531 T ES 90115531T ES 2044347 T3 ES2044347 T3 ES 2044347T3
- Authority
- ES
- Spain
- Prior art keywords
- combustion gases
- sulphite
- overflow
- oxidation
- calcium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000567 combustion gas Substances 0.000 title abstract 2
- 238000010257 thawing Methods 0.000 title 1
- 239000012736 aqueous medium Substances 0.000 abstract 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 2
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 abstract 2
- 235000010261 calcium sulphite Nutrition 0.000 abstract 2
- 239000004295 calcium sulphite Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 239000011505 plaster Substances 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 235000011132 calcium sulphate Nutrition 0.000 abstract 1
- 239000001175 calcium sulphate Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 230000020477 pH reduction Effects 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/464—Sulfates of Ca from gases containing sulfur oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Geology (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
UN METODO PARA ELIMINAR BIOXIDO DE AZUFRE PROCEDENTE DE GASES DE LA COMBUSTION, CON OXIDACION DE SULFITO DE CALCIO EN LA DESCARGA PROCEDENTE DE UN SISTEMA DE DEPURACION DE LIQUIDOS, PARA OBTENER YESO, OXIDIZA EL SULFITO EN UN DESBORDAMIENTO ESPESADOR, A UN PH ENTRE 4''0 Y 6''5. EL SULFITO DE CALCIO SE OXIDIZA A UN SULFATO DE CALCIO QUE SE PRECIPITA DESDE UN MEDIO ACUOSO, Y SE SEPARA, EN TANTO QUE EL MEDIO ACUOSO ACIDICO SE RECICLA A UNA FASE DE ACIDIFICACION ANTERIOR A LA OXIDACION. PUEDE DESCARGARSE UNA PORCION POSTERIOR MENOR DE MEZCLA LAVADORA, DESDE LA UNIDAD LAVADORA DE LIQUIDO, A UN PH DE 4''5 A 6''0 Y TAMBIEN TRATADA CON ACIDO OXIDIZADO Y EL YESO RESULTANTE SEPARADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/395,667 US4976936A (en) | 1989-08-18 | 1989-08-18 | Flue gas desulfurization with oxidation of calcium sulfite in FGD discharges |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2044347T3 true ES2044347T3 (es) | 1994-01-01 |
Family
ID=23563985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES90115531T Expired - Lifetime ES2044347T3 (es) | 1989-08-18 | 1990-08-13 | Desazuframiento de gases de combustion. |
Country Status (6)
Country | Link |
---|---|
US (1) | US4976936A (es) |
EP (1) | EP0414094B1 (es) |
AT (1) | ATE89764T1 (es) |
CA (1) | CA2023434C (es) |
DE (1) | DE69001729T2 (es) |
ES (1) | ES2044347T3 (es) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991018131A1 (en) * | 1990-05-14 | 1991-11-28 | Materials-Concepts-Research Limited | Process to produce hydrogen and/or hemihydrate calcium sulphate from calcium sulphite |
DE4034497C1 (es) * | 1990-10-30 | 1992-02-13 | Metallgesellschaft Ag, 6000 Frankfurt, De | |
US5082639A (en) * | 1990-11-06 | 1992-01-21 | Dravo Lime Company | Sulfur dioxide removal from gases using a modified lime |
US5433925A (en) * | 1991-05-24 | 1995-07-18 | Freeport-Mcmoran Inc. | Method and apparatus for removing sulfur dioxide from gas streams |
FR2697846B1 (fr) * | 1992-11-10 | 1995-01-20 | Total Raffinage Distribution | Utilisation comme charge pour polymères de chaux sulfatée provenant de la désulfuration par voie sèche de fumées. |
US5270026A (en) * | 1992-12-11 | 1993-12-14 | Dravo Lime Company | Sulfur dioxide scrubbing process producing purified magnesium hydroxide |
US5312609A (en) * | 1992-12-31 | 1994-05-17 | Dravo Lime Company | Method of sulfur dioxide removal from gaseous streams with α-hemihydrate gypsum product formation |
US5308509A (en) * | 1993-03-08 | 1994-05-03 | The Babcock & Wilcox Company | FGD performance enhancement by hydroclone and recycling steps |
SE511987C2 (sv) * | 1993-03-09 | 2000-01-10 | Eka Chemicals Ab | Metod för avskiljning av sulfat från en vattenhaltig elektrolyt i en alkalimetallkloratprocess |
CA2147059C (en) * | 1994-04-28 | 1999-08-10 | John W. College | Magnesium-enhanced sulfur dioxide scrubbing with gypsum formation |
US5486342A (en) * | 1994-06-13 | 1996-01-23 | Electric Power Research Institute | Clear liquor scrubbing of sulfur dioxide with forced oxidation in flue gas desulfurization system |
JP2923208B2 (ja) * | 1994-09-12 | 1999-07-26 | 三菱重工業株式会社 | 湿式排煙脱硫装置 |
US5562892A (en) * | 1995-01-26 | 1996-10-08 | Kirk; Donald W. | Process for the production of alpha hemihydrate calcium sulfate from flue gas sludge |
DE29517698U1 (de) * | 1995-07-29 | 1996-01-18 | Gottfried Bischoff Gmbh & Co | Rauchgasentschwefelungsanlage |
JP3015718B2 (ja) * | 1995-09-08 | 2000-03-06 | 三菱重工業株式会社 | 排煙処理システム |
US5614158A (en) * | 1995-10-20 | 1997-03-25 | Dravo Lime Company | Process for removing sulfur dioxide from gases and producing gypsum and purified magnesium hydroxide |
US5846286A (en) * | 1997-03-07 | 1998-12-08 | Dravo Lime Company | Method for removing NOx from a gas stream while producing an alkaline earth nitrate fertilizer composition |
FR2764206B1 (fr) * | 1997-06-10 | 1999-09-03 | Lab Sa | Perfectionnement aux procedes de desulfuration des fumees par voie humide |
FR2779663B1 (fr) * | 1998-06-10 | 2000-09-01 | Lab Sa | Procede et installation de desulfuration de fumees |
US6572832B2 (en) | 2001-03-27 | 2003-06-03 | Carmeuse North America Services, Inc. | Method of removing sulfur dioxide from a gaseous stream in a wet scrubbing unit |
US6695018B2 (en) * | 2002-06-10 | 2004-02-24 | The Babcock & Wilcox Company | Collection scoop for flue gas desulfurization systems with bleed streams or ex situ forced oxidation |
US6997119B2 (en) * | 2002-07-23 | 2006-02-14 | Radway Jerrold E | Combustion emissions control and utilization of byproducts |
US8226754B2 (en) * | 2008-10-15 | 2012-07-24 | Urs Corporation | Low cost wet lime/limestone/sodium FGD system |
CN109876759B (zh) * | 2019-04-09 | 2021-07-20 | 昆山宇顺环保科技有限公司 | 利用低温废气加速脱硫灰中亚硫酸钙氧化的方法及装置 |
CN114191929B (zh) * | 2021-12-24 | 2022-12-06 | 常州化工设计院有限公司 | 一种化工尾气处理工艺 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2080779A (en) * | 1937-05-18 | Purification of combustion gases | ||
US2090142A (en) * | 1933-12-28 | 1937-08-17 | Ici Ltd | Wet purification of gases |
CA950169A (en) * | 1970-10-26 | 1974-07-02 | Kureha Kagaku Kogyo Kabushiki Kaisha | Production of gypsum from combustion exhaust gas |
FR2173177B1 (es) * | 1972-02-23 | 1977-09-02 | Kureha Chemical Ind Co Ltd | |
US3919393A (en) * | 1973-03-08 | 1975-11-11 | Dravo Corp | Process for sulfur dioxide removal from combustion gases |
US3919394A (en) * | 1973-05-14 | 1975-11-11 | Dravo Corp | Process for the removal of oxides of sulfur from a gaseous stream |
US3961021A (en) * | 1973-09-25 | 1976-06-01 | Kureha Kagaku Kogyo Kabushiki Kaisha | Method for removing sulfur dioxide from combustion exhaust gas |
US4046856A (en) * | 1974-03-15 | 1977-09-06 | Kawasaki Jukogyo Kabushiki Kaisha | Method for removing sulfur oxide from stack gas |
JPS5820888B2 (ja) * | 1975-02-25 | 1983-04-26 | 株式会社三井三池製作所 | ハイガスチユウノ イオウサンカブツノ シヨリホウホウ |
US3985860A (en) * | 1975-09-22 | 1976-10-12 | Pullman Incorporated | Method for oxidation of SO2 scrubber sludge |
JPS5252871A (en) * | 1975-10-28 | 1977-04-28 | Mitsubishi Heavy Ind Ltd | Method of treating exhaust gas |
JPS53117683A (en) * | 1977-03-23 | 1978-10-14 | Kawasaki Heavy Ind Ltd | Removing method for sulfure oxides contained in exhayst gas |
DE2755252A1 (de) * | 1977-12-12 | 1979-07-05 | Babcock Bsh Ag | Verfahren zur entfernung von schwefeldioxid aus abgasen unter erzeugung von gips |
US4164549A (en) * | 1978-01-30 | 1979-08-14 | Dravo Corporation | Lime scrubbing process for sulfur dioxide removal from gases |
JPS5511045A (en) * | 1978-07-11 | 1980-01-25 | Mitsubishi Heavy Ind Ltd | Exhaust gas processing method |
JPS597493B2 (ja) * | 1980-10-28 | 1984-02-18 | 川崎重工業株式会社 | 排ガスの脱硫装置 |
JPS6058230A (ja) * | 1983-09-09 | 1985-04-04 | Babcock Hitachi Kk | 排煙脱硫方法および装置 |
US4696805A (en) * | 1985-02-05 | 1987-09-29 | Mitsubishi Jukogyo Kabushiki Kaisha | Method for desulfurizing exhaust gas |
-
1989
- 1989-08-18 US US07/395,667 patent/US4976936A/en not_active Expired - Lifetime
-
1990
- 1990-08-13 EP EP90115531A patent/EP0414094B1/en not_active Expired - Lifetime
- 1990-08-13 DE DE9090115531T patent/DE69001729T2/de not_active Expired - Fee Related
- 1990-08-13 ES ES90115531T patent/ES2044347T3/es not_active Expired - Lifetime
- 1990-08-13 AT AT90115531T patent/ATE89764T1/de not_active IP Right Cessation
- 1990-08-16 CA CA002023434A patent/CA2023434C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2023434C (en) | 1998-06-23 |
CA2023434A1 (en) | 1991-02-19 |
DE69001729D1 (de) | 1993-07-01 |
EP0414094B1 (en) | 1993-05-26 |
US4976936A (en) | 1990-12-11 |
DE69001729T2 (de) | 1993-09-02 |
EP0414094A2 (en) | 1991-02-27 |
ATE89764T1 (de) | 1993-06-15 |
EP0414094A3 (en) | 1991-06-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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