ES2026836T1 - Oxidacion de compuestos aromaticos sustituidos con alquilo terciario. - Google Patents

Oxidacion de compuestos aromaticos sustituidos con alquilo terciario.

Info

Publication number
ES2026836T1
ES2026836T1 ES199191870017T ES91870017T ES2026836T1 ES 2026836 T1 ES2026836 T1 ES 2026836T1 ES 199191870017 T ES199191870017 T ES 199191870017T ES 91870017 T ES91870017 T ES 91870017T ES 2026836 T1 ES2026836 T1 ES 2026836T1
Authority
ES
Spain
Prior art keywords
oxidation
aromatic compounds
tertiary alkyl
compounds replaced
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES199191870017T
Other languages
English (en)
Other versions
ES2026836T3 (es
Inventor
Roy Anthony Periana
George Francis Schaefer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES2026836T1 publication Critical patent/ES2026836T1/es
Application granted granted Critical
Publication of ES2026836T3 publication Critical patent/ES2026836T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

SE EXPONE UN PROCESO PARA LA PRODUCCION DE ACIDOS AROMATICOS DICARBOXILICOS PARA-ORIENTADOS EN LA QUE UN COMPUESTO AROMATICO PROVISTO DE UN GRUPO ALCALINO TERCIARIO SE OXIDA CON OXIGENO MOLECULAR EN LA PRESENCIA DE UN COMPUESTO CATALIZADOR QUE COMPRENDE UNA SAL DE COBALTO, UNA PEQUEÑA CANTIDAD DE UNA SAL DE MANGANESO Y UNA FUENTE DE CLORURO EN PRESENCIA DE UN DISOLVENTE.
ES91870017T 1990-01-31 1991-01-30 Oxidacion de compuestos aromaticos sustituidos con alquilo terciario y catalizador empleado para la misma. Expired - Lifetime ES2026836T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/473,031 US5068407A (en) 1990-01-31 1990-01-31 Oxidation of tertiary-alkyl substituted aromatics

Publications (2)

Publication Number Publication Date
ES2026836T1 true ES2026836T1 (es) 1992-05-16
ES2026836T3 ES2026836T3 (es) 1995-11-16

Family

ID=23877906

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91870017T Expired - Lifetime ES2026836T3 (es) 1990-01-31 1991-01-30 Oxidacion de compuestos aromaticos sustituidos con alquilo terciario y catalizador empleado para la misma.

Country Status (10)

Country Link
US (1) US5068407A (es)
EP (1) EP0440593B1 (es)
JP (1) JP2918703B2 (es)
AT (1) ATE125246T1 (es)
AU (1) AU626106B2 (es)
CA (1) CA2035323C (es)
DE (1) DE69111254T2 (es)
DK (1) DK0440593T3 (es)
ES (1) ES2026836T3 (es)
GR (1) GR3017403T3 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2711517B2 (ja) * 1994-11-15 1998-02-10 ナショナル サイエンス カウンシル ６−アルキル−２−ナフタレンカルボン酸及び６−イソプロピル−２−ナフタレンカルボン酸の製造方法
DE4441881A1 (de) * 1994-11-24 1996-05-30 Hoechst Ag Verfahren zur Herstellung bromierter oder chlorierter aromatischer Carbonsäuren
US6657068B2 (en) 2002-03-22 2003-12-02 General Electric Company Liquid phase oxidation of halogenated ortho-xylenes
US6649773B2 (en) 2002-03-22 2003-11-18 General Electric Company Method for the manufacture of halophthalic acids and anhydrides
US6657067B2 (en) 2002-03-22 2003-12-02 General Electric Company Method for the manufacture of chlorophthalic anhydride
US7541489B2 (en) 2004-06-30 2009-06-02 Sabic Innovative Plastics Ip B.V. Method of making halophthalic acids and halophthalic anhydrides

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2833816A (en) * 1954-05-03 1958-05-06 Mid Century Corp Preparation of aromatic polycarboxylic acids
US2833817A (en) * 1956-06-27 1958-05-06 Mid Century Corp Process for the preparation of terephthalic acid
US2833818A (en) * 1956-07-30 1958-05-06 Mid Century Corp Process for the preparation of terephthalic acid
US2833819A (en) * 1957-06-14 1958-05-06 Mid Century Corp Process for the preparation of isophthalic and terephthalic acids
US2833820A (en) * 1957-06-14 1958-05-06 Mid Century Corp Process for the preparation of isophthalic and terephthalic acids
US3089907A (en) * 1958-04-21 1963-05-14 Mid Century Corp Pressure controlled liquid phase oxidation process for aromatic acid production
US3296280A (en) * 1963-07-18 1967-01-03 Sun Oil Co The oxidation of tertiary-butyl groups attached to an aromatic ring to form the corresponding aromatic carboxylic acid
US3383402A (en) * 1965-04-13 1968-05-14 Schenectady Chemical Synthesis of dimethyl bibenzoate
US3631097A (en) * 1968-06-19 1971-12-28 Carbogen Corp Oxidation of alkylated diphenyl compounds
US3636082A (en) * 1969-01-03 1972-01-18 Du Pont Carbonylation of organic halides with metallic alcoholates
JPS5846494B2 (ja) * 1981-03-09 1983-10-17 工業技術院長 ジフェニル−４，４′−ジカルボン酸二カリウム塩の製造方法
JPS60174745A (ja) * 1984-02-20 1985-09-09 Mitsubishi Gas Chem Co Inc ４，４’−ビフェニルジカルボン酸の製造法
GB8515063D0 (en) * 1985-06-14 1985-07-17 Ici Plc Polyaromatic compounds
JPS63122645A (ja) * 1986-11-11 1988-05-26 Kureha Chem Ind Co Ltd ビフエニル−４，４’−ジカルボン酸の製造方法
JPH0768247B2 (ja) * 1987-06-11 1995-07-26 新日本理化株式会社 ジアリ−ルジカルボン酸の製造方法

Also Published As

Publication number Publication date
EP0440593A3 (en) 1992-09-09
AU7007891A (en) 1991-08-01
DE69111254T2 (de) 1996-04-04
US5068407A (en) 1991-11-26
EP0440593B1 (en) 1995-07-19
ES2026836T3 (es) 1995-11-16
EP0440593A2 (en) 1991-08-07
JP2918703B2 (ja) 1999-07-12
ATE125246T1 (de) 1995-08-15
DE69111254D1 (de) 1995-08-24
JPH04211036A (ja) 1992-08-03
CA2035323C (en) 1998-12-22
CA2035323A1 (en) 1991-08-01
DK0440593T3 (da) 1995-10-02
AU626106B2 (en) 1992-07-23
GR3017403T3 (en) 1995-12-31

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