ES2002724A6 - Procedimiento para la fabricacion de 2-etilhexanol - Google Patents

Procedimiento para la fabricacion de 2-etilhexanol

Info

Publication number
ES2002724A6
ES2002724A6 ES8601306A ES8601306A ES2002724A6 ES 2002724 A6 ES2002724 A6 ES 2002724A6 ES 8601306 A ES8601306 A ES 8601306A ES 8601306 A ES8601306 A ES 8601306A ES 2002724 A6 ES2002724 A6 ES 2002724A6
Authority
ES
Spain
Prior art keywords
ethyl
butanal
hexenal
substances
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8601306A
Other languages
English (en)
Inventor
Gunther Kesse
Boy Cornils
Josef Hibbel
Hanswilhelm Bach
Wilhel Gick
Ernst Wiebus
Wolfgang Zgorzeski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruhrchemie AG
Original Assignee
Ruhrchemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruhrchemie AG filed Critical Ruhrchemie AG
Publication of ES2002724A6 publication Critical patent/ES2002724A6/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation

Abstract

PROCEDIMIENTO PARA LA FABRICACION DE 2©ETILHEXANOL. EN ESTE CASO, EL PROPENO ES SOMETIDO A LA HIDROFORMILACION -EN PRESENCIA DE UN CATALIZADOR QUE, DISUELTO EN AGUA, CONTIENE RODIO Y UNAS TRIARILFOSFINAS SULFONADAS- Y DE LA MEZCLA DE REACCION SE SEPARAN, MEDIANTE DESTILACION, AQUELLAS PARTES CUYO PUNTO DE EBULLICION ES MAS BAJO QUE EL PUNTO DE EBULLICION DEL N©BUTANAL; LOS RESIDUOS DE LA DESTILACION, QUE SE COMPONEN ESENCIALMENTE DEL N©BUTANAL, SON SOMETIDOS, EN PRESENCIA DE UN ALCALI ACUOSO, A LA ALDOLIZACION, Y EL 2©ETILHEXENAL RESULTANTE ES TRANSFORMADO EN EL 2©ETIL©HEXANOL, EN PRIMER LUGAR DENTRO DE LA FASE GASEOSA Y LUEGO, EN LA FASE LIQUIDA, EN UN CATALIZADOR DE HIDROGENACION QUE ESTA FIRMEMENTE ESTABLECIDO.
ES8601306A 1985-08-29 1986-08-22 Procedimiento para la fabricacion de 2-etilhexanol Expired ES2002724A6 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19853530839 DE3530839A1 (de) 1985-08-29 1985-08-29 Verfahren zur herstellung von 2-ethylhexanol

Publications (1)

Publication Number Publication Date
ES2002724A6 true ES2002724A6 (es) 1988-10-01

Family

ID=6279640

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8601306A Expired ES2002724A6 (es) 1985-08-29 1986-08-22 Procedimiento para la fabricacion de 2-etilhexanol

Country Status (15)

Country Link
US (1) US4684750A (es)
EP (1) EP0216151B1 (es)
JP (1) JPS6251632A (es)
KR (1) KR890003749B1 (es)
AT (1) ATE61328T1 (es)
AU (1) AU587748B2 (es)
BR (1) BR8604095A (es)
CA (1) CA1258873A (es)
CS (1) CS265222B2 (es)
DE (2) DE3530839A1 (es)
ES (1) ES2002724A6 (es)
HU (1) HU202465B (es)
RO (1) RO94395B (es)
YU (1) YU45357B (es)
ZA (1) ZA866387B (es)

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US4874900A (en) * 1987-06-16 1989-10-17 Union Camp Corporation Preparation of pseudoionones
US5043510A (en) * 1989-03-27 1991-08-27 E. I. Du Pont De Nemours And Company Aqueous alkylation process
DE3932331A1 (de) * 1989-09-28 1991-04-11 Hoechst Ag Verfahren zur herstellung von alkoholen (zweistufig)
US5102505A (en) * 1990-11-09 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Mixed aldehyde product separation by distillation
US5227544A (en) * 1991-02-15 1993-07-13 Basf Corporation Process for the production of 2-ethylhexanol
US5215667A (en) * 1991-08-20 1993-06-01 Exxon Chemical Patents Inc. Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
US5288818A (en) * 1991-08-20 1994-02-22 Exxon Chemical Patents Inc. Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction
GB9118603D0 (en) * 1991-08-30 1991-10-16 Shell Int Research Process for the preparation of alcohols
DE4210026A1 (de) * 1992-03-27 1993-09-30 Hoechst Ag Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
DE4243524A1 (de) * 1992-12-22 1994-06-23 Hoechst Ag Gemische isomerer Nonanole und Decanole, ihre Herstellung, aus ihnen erhältliche Phthalsäureester und deren Verwendung als Weichmacher
DE4333324A1 (de) * 1993-09-30 1995-04-06 Hoechst Ag Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
US5399793A (en) * 1993-11-29 1995-03-21 Exxon Chemical Patents Inc. Hydrogenation catalyst for oxo alcohol process
JP4122526B2 (ja) * 1994-07-29 2008-07-23 三菱化学株式会社 高純度イソアルデヒドの製造方法
SG75173A1 (en) 1998-05-21 2000-09-19 Mitsubishi Chem Corp Process for producing alcohols
JP3864617B2 (ja) * 1998-05-21 2007-01-10 三菱化学株式会社 アルコールの製造方法
DE19842371A1 (de) * 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen
DE19914259A1 (de) 1999-03-29 2000-10-05 Basf Ag Verfahren zur destillativen Auftrennung eines flüssigen Rohaldehydgemisches
DE19956410A1 (de) 1999-11-24 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur Durchführung von Aldolkondensationen
DE10252173B3 (de) * 2002-11-09 2004-06-03 Celanese Chemicals Europe Gmbh Verfahren zur Gewinnung von aliphatischen C3-C10-Alkoholen aus Hochsiedern
US7586017B2 (en) * 2003-12-18 2009-09-08 Exxonmobil Chemical Patents Inc. Hydrogenation
EP1697289B1 (en) * 2003-12-18 2014-06-11 ExxonMobil Chemical Patents Inc. Improvements in or relating to hydroformylation
EP1694617B1 (en) * 2003-12-18 2011-07-20 ExxonMobil Chemical Patents Inc. Improvements in or relating to catalysed reactions
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
DE102008044783B4 (de) * 2008-08-28 2012-05-16 Oxea Gmbh Verfahren zur Gewinnung von aliphatischen C3- bis C10- Aldehyden aus Hochsiedern durch thermische Behandlung
KR101089488B1 (ko) 2010-07-14 2011-12-02 주식회사 엘지화학 올레핀으로부터 이소타입의 알데히드와 알콜의 병산 장치 및 이를 이용한 병산 방법
WO2012008717A2 (en) * 2010-07-14 2012-01-19 Lg Chem, Ltd. Apparatus for coproducting iso type reaction products and alcohols from olefins, and method for coproducting them using the apparatus
DE102012014395B3 (de) * 2012-07-13 2013-08-22 Oxea Gmbh Isononylamine ausgehend von 2-Ethylhexanol, Verfahren zu ihrer Herstellung sowie ihre Verwendung
CN103864587B (zh) * 2012-12-10 2016-05-11 中国石油天然气股份有限公司 一种合成2-乙基-2-己烯醛的方法
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
JP6269026B2 (ja) * 2013-12-18 2018-01-31 三菱瓦斯化学株式会社 ジイソブチルケトンの水素化によるジイソブチルカルビノールの製造法
EP2891698B1 (en) 2014-01-03 2019-12-04 Arkema France Use of an alcohol component to improve electrical conductivity of an aviation fuel composition
GB201617463D0 (en) 2016-10-14 2016-11-30 Johnson Matthey Davy Technologies Limited Process
WO2019097403A1 (en) 2017-11-20 2019-05-23 Sabic Global Technologies B.V. Recovery of ethyl hexanol from recycle streams in 2-ethyl hexanol process
US10562833B2 (en) * 2017-12-01 2020-02-18 Evonik Degussa Gmbh Method for obtaining alcohols from aldehydes III
US10377690B1 (en) 2018-08-22 2019-08-13 Eastman Chemical Company Method for catalytic production of refined enal products from an aldehyde feed stream using a single enclosed unit

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US3288866A (en) * 1966-11-29 Plural stage hydrogenation of alke- nals to alcohols using copper catalyst and then palladium catalyst
US3127451A (en) * 1960-01-25 1964-03-31 Exxon Research Engineering Co Conversion of aldox aldehydes to alcohols
US3118954A (en) * 1960-01-25 1964-01-21 Exxon Research Engineering Co Graduated hydrogenation of aldox aldehydes to alcohols
US3272873A (en) * 1961-10-18 1966-09-13 Exxon Research Engineering Co Hydrogenation of alpha, betaunsaturated aldehydes
US3248428A (en) * 1961-12-22 1966-04-26 Exxon Research Engineering Co Aldolization process
DE1276618B (de) * 1965-11-26 1968-09-05 Huels Chemische Werke Ag Verfahren zur Herstellung von gesaettigten aliphatischen Alkoholen
FR1563043A (es) * 1968-02-15 1969-04-11
AT277949B (de) * 1968-03-18 1970-01-12 Orlicek A Verfahren zur herstellung von 2-aethylhexanol
SU406823A1 (ru) * 1970-05-25 1973-11-21 Способ получения 2-этилгексанола
SU478830A1 (ru) * 1973-04-27 1975-07-30 Предприятие П/Я Р-6913 Способ получени 2-этилгексанола
DE2437957B2 (de) * 1974-08-07 1976-06-16 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur kontinuierlichen herstellung von 2-aethylhexanol
FR2314910A1 (fr) * 1975-06-20 1977-01-14 Rhone Poulenc Ind Procede d'hydroformylation des olefines
SU692824A1 (ru) * 1976-03-26 1979-10-25 Предприятие П/Я А-7466 Способ получени 2-этилгексанола
DE2713434C3 (de) * 1977-03-26 1980-10-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur Herstellung von 2-Äthylhexanol
US4374278A (en) * 1980-02-28 1983-02-15 Union Carbide Corporation Hydroformylation catalyst reactivation
DE3168398D1 (en) * 1980-11-20 1985-02-28 Monsanto Co Preparation of plasticizer alcohols from propylene-butene mixtures
US4426542A (en) * 1981-04-22 1984-01-17 Monsanto Company Synthesis of plasticizer and detergent alcohols
US4426541A (en) * 1982-03-16 1984-01-17 Exxon Research & Engineering Co. Process for production of aliphatic alcohols

Also Published As

Publication number Publication date
RO94395B (ro) 1988-07-01
HUT42045A (en) 1987-06-29
EP0216151A3 (en) 1989-03-29
HU202465B (en) 1991-03-28
YU45357B (en) 1992-05-28
DE3677864D1 (de) 1991-04-11
RO94395A (ro) 1988-06-30
AU587748B2 (en) 1989-08-24
CS265222B2 (en) 1989-10-13
KR890003749B1 (ko) 1989-10-04
BR8604095A (pt) 1987-04-14
ATE61328T1 (de) 1991-03-15
CS614086A2 (en) 1989-01-12
EP0216151B1 (de) 1991-03-06
DE3530839A1 (de) 1987-03-05
CA1258873A (en) 1989-08-29
AU6203486A (en) 1987-03-05
US4684750A (en) 1987-08-04
EP0216151A2 (de) 1987-04-01
ZA866387B (en) 1987-04-29
YU147686A (en) 1988-02-29
JPS6357411B2 (es) 1988-11-11
JPS6251632A (ja) 1987-03-06
KR870002042A (ko) 1987-03-28

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20010201