Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/26—Organic compounds containing nitrogen
  • C11D3/33—Amino carboxylic acids
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/001—Softening compositions
  • C11D3/0015—Softening compositions liquid
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/2075—Carboxylic acids-salts thereof
  • C11D3/2086—Hydroxy carboxylic acids-salts thereof
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
  • C11D7/22—Organic compounds
  • C11D7/26—Organic compounds containing oxygen
  • C11D7/265—Carboxylic acids or salts thereof
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
  • C11D7/22—Organic compounds
  • C11D7/32—Organic compounds containing nitrogen
  • C11D7/3245—Aminoacids
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
  • C11D2111/10—Objects to be cleaned
  • C11D2111/12—Soft surfaces, e.g. textile

Definitions

• the invention refers to household chemicals and is a vegetal - amino acid composition and its application for preparation of liquid care products for delicate fabrics (silk, wool, cashmere), such as environment-friendly liquid detergent and fabric softener.
• the invention relates to the vegetal - amino acid composition and is composed of components A and B, where:
• Shikimic acid of vegetable origin is one of such substances. It represents small molecule, which can be produced in the result of chemical synthesis, microbial fermentation and extraction from specific plant species, in particular, from star anise seeds (Latin: Illicium verum ) . Despite the fact that it is present is a large number of microorganisms and fungi, it is an intermediate metabolite of biosynthetic reactions, and in these reactions, it is presented in very low concentrations. Shikimic acid in significant amount can be found in star anise and its allies only [ Ghosh S. et al., Production of shikimic acid //Biotechnology advances, 2012 ] . The use of shikimic acid in household chemicals has not been disclosed.
• arginine amino acid Another component, which is widely presented in nature and which at the same time can be potentially used in garment care products, is arginine amino acid. It represents small molecule with weak alkaline properties, the use of which, in combination with other amino acids, is widely spread in hair care products, but not in household chemicals. Arginine is widely used in such areas as protein refolding, solubilization of proteins and small molecules, column chromatography and viral inactivation [ Arakawa T., Kita Y. Multi-faceted arginine: mechanism of the effects of arginine on protein, 2014 ] . In conjunction of household chemicals, arginine-based surface-active agents (SAAs) are known.
• SAAs surface-active agents
• arginine-based SAAs single-chain, dimeric and arginine-based glycerolipidic conjugates. All these classes represent substances, different from monocomponent arginine in their chemical properties [ Singh A., Tyagi V. K. Arginine based novel cationic surfactants: a review, 2014 ] .
• human hair and animal hair from which woolen fabric are made (mainly, sheep hair), they have a number of differences.
• merino wool made of wool-producing merino sheep, has hair cuticle one cell layer wide, while human hair cuticle is made of 10-30 layers [ Jones L. N. Hair structure anatomy and comparative anatomy //Clinics in dermatology, 2001 ] .
• wool has less regular cuticle structure and looks less smooth than human hair.
• Medulla the central part of hair, is merely present in wool, but is expressly evident in human hair. In particular, this is related to differences in hair diameter: human hair is "thicker" than wool.
• wool has significant advantages over human hair in relation to the parameters, critical in fabric manufacturing; it is softer, more elastic, holds water, moisture and colorants better, has larger gloss and is less prone to ignition [ Structure of wool and its differentiation from hair fibre, https://sites.google.com/site/viveklpm/wool/structure-of-wool-and-its-differentiation-from-hair-fibre ] .
• arginine being the basic amino acid
• Arginine has positive effective charge, i.e. it is in charged state and is able to bind with negatively charged molecules at pH ⁇ 9, which corresponds to most garment care products [ Lewis C. et al. Effect of pH on the binding of sodium, lysine, and arginine Counterions to l-Undecyl Leucinate micelles //Journal of Surfactants and Detergents. - 2016. - T. 19. - No. . 6. - C. 1175-1188 ] .
• arginine forms a special stoichiometric complex with shikimic acid and operates under the "anchor" principle, i.e. it binds negatively charged molecules on wool surface with shikimic acid. Apart from the fact that arginine is able to bind with negatively charged groups on protein surface, it also contributes to protein refolding [ Arakawa T., Kita Y. Multi-faceted arginine: mechanism of the effects of arginine on protein, 2014 ] .
• the authors of the present invention propose the following hypothesis: a complex of arginine and shikimic acid exhibit synergic activity in relation to woolen fabric restoration at the ultrastructural level by restoring protein molecule structure.
• shikimic acid being highly hydrophilic, is hygroscopic, i.e. is able to absorb moisture.
• the substances used to color fabrics are water soluble, this refers to additional effect of the complex, which is retaining fabric color, which preserves the initial appearance of fabrics and increases wear period.
• such or similar properties for garment care products in relation to the complex of arginine and shikimic acid have not been shown, which emphasizes its uniqueness and innovation.
• Shikimic acid and arginine are declared as one of Michael acceptor junction and linker, correspondingly, in Patent Application US20190240126 (KEMON SPA [IT] ).
• This patent application covers cosmetic composition for topical application, containing 30-95% w/w of active component, to restructure and protect hair and scalp by restoring disulfide bonds, which are broken in damaged hair and scalp, while the specified active agent contains mixture of at least one acyclic terpene and at least two Michael acceptor junctions and 5-30% w/w of at least one linker per the weight of the specified active component and at least one specified linker.
• composition of the active complex in addition to shikimic acid and arginine (as one of the linkers), one more acceptor junction (sorbic acid) and one acyclic terpene must be present.
• This composition is designed especially for hair, which, as it was described earlier, has a significant number of differences from wool.
• the patent application specified the range of working pH from 2 to 10
• pH is not specified in the section with the embodiments of the invention. Due to this, it is impossible to certainly decide on the range of working pH values.
• most shampoos and conditioners have pH ⁇ 5, which can be the base of interpretation of the use of the given composition in hair care products.
• Arginine is used not only in hair care products, but also in compositions designed for garment care.
• the use of arginine in the composition for stain removal from fabrics with surface active agent is described in Patent Application WO2014095617 (UNILEVER PLC [GB] ). Nonetheless, this patent application does not disclose arginine composition to restore fabrics, in particular, delicate fabrics.
• the effect of the composition is limited to removal of stains of lipid rii, as the embodiments in the patent application included samples of fabrics with beef fat stains as test samples.
• arginine is also described in Patent Application WO2004038084 (international patent application, CLOROX CO [US], ADAIR MARTHA J [US]7) in the composition, where arginine acts as chlorine and/or active oxygen absorbent or neutralizer.
• the composition is presented in liquid, liquid gel or gel form and is designed for use in fabric care, in particular, to protect fabrics from color damage.
• the formulation of the declared composition is as follows: (a) from about 0.001% to about 5% by weight of one or more enzymes for fabric care, which are effective in prevention of pilly garneting, stain formation and other damages to fibers during laundry; (b) from about 0.001% to about 20% by weight of one or more UV-screening agents, where one or several UV-screening agents are for bleaching and prevention of photo-discoloration and other damage to fabrics by light; (c) from approximately 0.001% to approximately 60% by weight of one or more surface-active dispersing, emulsifying and/or solubilizing agents; (d) from about 0% to about 20% be weight of one or more dye transfer inhibitors, agents, preventing reprecipitation, or colorant sequestrants; (e) from about 0% to about 20% by weight of one or more colorants, color pigments and fabric color fixer or protector for fabric finish; (f) from about 0% to about 5% by weight of one or more textile lubricants and/or fabric softeners.
• Arginine in its turn, is declared as chlorine and/or active oxygen absorbent or neutralizer, which act as agents, contributing to fabric discoloration.
• the embodiments include the studies of tensile strength, but not fabric discoloration inhibition or fiber restoration of delicate fibers at the microscopic level.
• arginine is also declared in garment care conditioning products ( US6750189 (PROCTER & GAMBLE [US] ) and WO2016106362 (international patent application, INTERNATIONAL FLAVORS & FRAGRANCES INC. [US] )).
• arginine is declared not as a separate component, but in the composition of homo-/cocondensate, copolymer of amino acids or cross-linked polymer, the properties of which can be different from unbound arginine due to their physical and chemical nature, in particular, dimension and composition of molecules.
• arginine is declared as a stabilizing agent in the formulation of the composition: from 1 to 30% of conditioning agent for fabrics, from 0.1% to 30% of the capsule, having oil kernel and wall of the capsule, where the oil kernel contains active material and the capsule wall, incapsulating oil kernel, and 20 ppm or more of the stabilizing agent.
• the active material is flavoring agent, designed to eliminate odor, or a combination of them.
• Kitchen spray (Kitchen Cleaner, Happy Elephant, SARAYA) is available in the market. Its formulation includes surfactants (1% sophorolipids), arginine (additive), ethanol (stabilizer), citric acid (pH adjustor). In the manufacturer's website this product is promoted as an effective and safe product, composed of food ingredients, to remove stains of lipid nature, streak-free. Despite the presence of garment care products in the Happy Elephant product line (https://happyelephant.info/products/kitchencleaner.html), the formulation of them does not include arginine and shikimic acid, which shows that the manufacturer does not use arginine and shikimic acid as functional additive to restore fabrics. At the same time, the function of arginine in the kitchen spray is not clarified.
• the acquired effect is more probably explained by the formation of stoichiometric complex, composed of arginine and shikimic acid, which is bound with wool surface under the "anchor" principle, fixing these components on hair. Being attached and integrated into wool fibers at the ultrastructural level, the complex contributes to the restoration of woolen fabrics, as well as sustaining colorant molecules on the surface of woolen and other fabrics.
• the complex Due to the fact that the complex includes shikimic acid and arginine - the substances, which are normally contained in living organisms, the complex is environmentally friendly and safe for skin in stated concentrations. Moreover, arginine and shikimic acid have positive impact on skin; in particular, products, containing these components, contribute to the reduction of atopic dermatitis symptoms [ Batory M., Rotsztejn H. Shikimic acid in the light of current knowledge, 2022 ; Zhang Y. et al. Skin care product rich in antioxidants and antiinflammatory natural compounds reduces itching and inflammation in the skin of atopic dermatitis patients, 2022 ] .
• the invention as whole relates to the complex of shikimic acid and arginine and its application in the composition of various household chemicals, allowing such technical results as restoration of delicate fabrics and preservation of fabric color, which are not achieved or achieved insufficiently with modern commercially available products in the art.
• the invention relates to the vegetal - amino acid composition based on shikimic acid and arginine as a synergist for the use in household chemicals and laundry detergents, active at pH 2.5-9.5.
• the invention relates to the composition and is comprised of components A and B, where:
• the composition is different in that shikimic acid is a substance or a commercially available component with registration number CAS 138-59-0 .
• the invention can be different in that the specified shikimic acid is in water-glyceric or water-sorbitol, or water-glyceric-sorbitol, or water-propylene glycol or other solutions, as well as in powdery or granulated condition with various fillers.
• Dry shikimic acid present commercially available products or standardized extracts of vegetable origin.
• the composition is different in that L-arginine present a substance or a commercially available component with registration number CAS 74-79-3 .
• the invention can be different in that the specified arginine is in water-glyceric or water-sorbitol, or water-glyceric-sorbitol, or water-propylene glycol or other solutions, as well as in powdery or granulated, or crystalline condition with various fillers. Dry arginine present commercially available products or standardized amino acid additives for various application.
• composition under the invention can contain, %wt: Shikimic acid or its salts, shikimates 0.001-0.5%, L-arginine 0.001-0.5%.
• the invention relates to the use of vegetal - amino acid composition of shikimic acid and arginine as a synergist under the invention for manufacturing of laundry detergent for delicate fabrics under the invention.
• the invention relates to the laundry detergent for delicate fabrics and fabric softener, containing the vegetal - amino acid composition of shikimic acid and arginine as a synergist under the invention.
• composition can be different in that it additionally contains any auxiliary ingredients in the base of household chemicals: anionic surface-active agents (SAAs), amphoteric SAAs, cationic SAAs, solvents, solubilizers, emulsifiers, stabilizers, thickeners, bleachers, preservatives, pH adjustors, flavorings, essential oils.
• SAAs anionic surface-active agents
• the invention relates to the laundry detergent for white and colored fabrics, containing 0.001-1% wt of the composition under the invention.
• the invention relates to the laundry detergent for delicate fabrics, containing 0.001-1%wt of the composition under the invention.
• the laundry detergent can be different in that the specified detergent is selected from laundry detergents for children clothes.
• the laundry detergent can be different in that the specified detergent is selected from powdered laundry detergents.
• the laundry detergent can be different in that the specified detergent is a stain remover or bleach in liquid, dry, concentrated form.
• the laundry detergent can be different in that the specified detergent is a laundry and freshener conditioner, containing 0.001-1%wt of the composition under the invention.
• the invention relates to the use of vegetal - amino acid composition under the invention for microregeneration of delicate fibers, fabric smoothening and static charge decrease, color preservation and prevention of color discoloration, increase of longevity during daily wear of garments made of delicate fabrics, with maintenance of long-time cleanliness and hygienic wash of fabrics.
• the invention relates to the vegetal - amino acid composition based on shikimic acid and arginine as a synergist for the use in household chemicals and laundry detergents, active at pH 2.5-9.5.
• the invention relates to the composition and is comprised of components A and B, where:
• the invention relates to the use of vegetal - amino acid composition of shikimic acid and arginine as a synergist under the invention for manufacturing of laundry detergent for delicate fabrics under the invention.
• shikimic acid in the means under the invention can be in the range of 0.001-0.5 %wt depending on the type and intensity of the desired properties.
• shikimic acid can be contained in the amount from 0.001, 0.005, 0.01, 0.025, 0.05, 0.1, 0.25, 0.3, 0.4 or 0.5, or in any amounts between the specified values.
• the invention can be different in that the specified shikimic acid is in water-glyceric or water-sorbitol, or water-glyceric-sorbitol, or water-propylene glycol or other solutions, as well as in powdery or granulated condition with various fillers.
• Dry shikimic acid present a substance or a commercially available product under registration number CAS 138-59-0.
• L-arginine in the means under the invention can be in the range 0.001-0.5 %wt depending on the type and intensity of the desired properties.
• L-arginine can be contained in the amount from 0.001, 0.005, 0.01, 0.025, 0.05, 0.1, 0.25, 0.3, 0.4 or 0.5, or in any amounts between the specified values.
• the invention can be different in that the specified L-arginine is in water-glyceric or water-sorbitol, or water-glyceric-sorbitol, or water-propylene glycol or other solutions, as well as in powdery or granulated, or crystalline condition with various fillers.
• Dry L-arginine presents / can present a substance or a commercially available products under registration number CAS 74-79-3 .
• the present invention also relates to the use of the composition under the invention in a household chemical product.
• a household chemical product for washing delicate fibers under the invention can contain 0.001-0.5 %wt of the composition under the invention.
• household chemical product under the invention can contain 0.001, 0.0025, 0.005, 0.01, 0.015, 0.02, 0.025, 0.03, 0.035, 0.04, 0.045, 0.05, 0.1, 0.15, 0.2, 0.25, 0.3, 0.4 or 0.5 %wt, or any amounts between the specified values of the composition under the invention.
• the present invention also relates to laundry detergent for white and colored fabrics, laundry detergent for delicate fabrics or laundry detergent for children clothes, containing 0.001-0.5%wt of the composition under the invention.
• the present invention also relates to laundry conditioner for white and colored fabrics, containing 0.001-0.5%wt of the composition under the invention.
• the present invention also relates to stain remover or bleacher, containing 0.001-0.5%wt of the composition under the invention.
• the present invention also relates to the use of vegetal - amino acid composition under the invention for microregeneration of delicate fibers, fabric smoothening and static charge decrease, color preservation and prevention of color discoloration, increase of longevity during daily wear of garments made of delicate fabrics, with maintenance of long-time cleanliness and hygienic wash of fabrics.
• composition preferably does not contain other active and/or additional substances, such as washing active agents and/or acceptable excipient agents, but can also contain them.
• additional substances can present or present agents traditionally used in the art, well known to those skilled in the art. Addition of the specified agents to the formulation of the complex under the invention does not replace the achievement of the claimed technical results, but can improve them.
• the scope of the invention also includes household chemicals, such as laundry detergents, sports laundry detergents, laundry detergents for children clothes, powered laundry detergents.
• acceptable excipient agents can be selected from the following categories of components.
• Non-ionic SAAs are non-ionic SAAs:
• Disperse medium for polysaccharide/solvent Disperse medium for polysaccharide/solvent:
• Fungicides sodium pyrithione, climbazole.
• Enzymes Protease (ficin, bacillolysin, subtilisin), alpha-amylase, pectate lyase, mannanase, mannosidase, cellulase, amine oxidase, feruloyl esterase, beta-glucanase, tannase, alpha-glucosidase, beta-glucosidase, alpha-galactosidase, beta-galactosidase, laccase, manganese peroxidase, licheninase, xylanase and other commercially available enzymes, used in laundry detergents, dishwashing chemicals, floor washing products, glass washing products, multi-surface cleansers.
• Oxygen-based bleaches hydrogen peroxide, calcium peroxide, urea peroxide, ⁇ -phthalimidoperoxycaproic acid and other commercially available components.
• Essential oil fragrances or essential oils in pure form or as mixtures in various ratios orange, bergamot, lemon, lime, mandarin, grapefruit, neroli, rosewood, yuzu, lemongrass, lavender, sage, thyme, melissa, peppermint, tea tree, eucalyptus, cedar, sandalwood, black pepper, pink pepper, cinnamon, cardamom, coriander, jasmine, rose, peony, blue chamomile or others.
• the prepared liquid detergents and stain removers provide high efficiency of cleaning and elimination of odor for delicate fabrics with any tap water hardness 0-5 mg-equ/L and at any washing temperature from +15°C to +60°C.
• the product does not cause discoloration of fabric and dye bleeding, maintains the initial appearance of garment, streak-free, completely washes off fabric surface, suitable for children's laundry and people with sensitive hand skin.
• Prepared laundry conditioner provides softening and easier ironing of various fabrics, in particular delicate fabrics, with any hardness of tap water 0-5 mg-eq/l and at any washing temperature from +15°C to +60°C. It does not cause discoloration of fabrics and dye washout, streak-free, is suitable for washing children's laundry and for people with sensitive hand skin.
• the fabric was damaged by washing in the "Wool Fabric” mode for 39 minutes with a base wash gel from Table No. 1 (without shikimic acid and arginine) containing protease (EC 3.4.21.14, CAS 9014-01-1 , Novozymes) in concentration of 0.25 %wt.
• a base wash gel from Table No. 1 (without shikimic acid and arginine) containing protease (EC 3.4.21.14, CAS 9014-01-1 , Novozymes) in concentration of 0.25 %wt.
• the samples were resubmitted for imaging to record the condition of the wool after fiber damage ( Figure 4 ).
• the average striation ratio was 2.23 + 0.63 c.u. (Table 9).
• Laundry conditioner without shikimic acid and arginine Laundry conditioner with shikimic acid and arginine in concentrations of 0.001 %wt and 0.001 %wt.
• 8 Liquid laundry detergent Laundry conditioner with shikimic acid and arginine in concentrations of 0.001 %wt and 0.001 %wt.
• the composition with the concentration of arginine and shikimic acid 0.001 %wt and 0.001 %wt reduces striation by 30.9%, with concentrations of 0.01 %wt and 0.01 %wt - by 26.15%, with concentrations of 0.25 %wt and 0.25 %wt - by 19.4%.
• the working range of the components of the composition is in the range from 0.001 %wt to 0.25 %wt of arginine and from 0.001 %wt to 0.25 %wt of shikimic acid, and the composition can be used in both laundry gels and conditioners.
• Delicate fabric of blue color, size 50 mm x 100 mm, water hardness 5.35 mg*eq/dm3 was used as test samples; the solution of the test means was prepared according to the method of application for hard water.
• the essence of the method to determine color retention when using laundry and care products is photometric determination of the changes in the reflection power of the surface of the fabric treated with the test product in comparison with a control sample treated with water.
• the authors of the invention have shown an unexpected technical result: the innovation composition based on shikimic acid and arginine not only restores the fibers of wool fabric with reduced strength characteristics, but also contributes to the preservation of fabric color. These effects make it possible to preserve the original appearance of the garment and restore the damaged fabric.
• This technical result has not been previously described in the literature and has practical value for increasing the life of garments made of delicate fabrics, reducing the stress for the environment and allowing the competent use of available resources.

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Emergency Medicine (AREA)
• Detergent Compositions (AREA)

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Citations (5)

• 2024
  • 2024-05-28 EP EP24178408.1A patent/EP4656709A1/de active Pending
• 2025
  • 2025-05-21 WO PCT/EP2025/063928 patent/WO2025247718A1/en active Pending

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