EP4619675A1 - Wand für einen dichten und wärmeisolierenden behälter - Google Patents

Wand für einen dichten und wärmeisolierenden behälter

Info

Publication number
EP4619675A1
EP4619675A1 EP23805030.6A EP23805030A EP4619675A1 EP 4619675 A1 EP4619675 A1 EP 4619675A1 EP 23805030 A EP23805030 A EP 23805030A EP 4619675 A1 EP4619675 A1 EP 4619675A1
Authority
EP
European Patent Office
Prior art keywords
plate
wall
thermally insulating
pillar
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP23805030.6A
Other languages
English (en)
French (fr)
Inventor
Guillaume SALMON LEGAGNEUR
Bruno Deletre
Guillaume De Combarieu
Benoît MOREL
Benjamin FAUBRY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gaztransport et Technigaz SA
Original Assignee
Gaztransport et Technigaz SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gaztransport et Technigaz SA filed Critical Gaztransport et Technigaz SA
Publication of EP4619675A1 publication Critical patent/EP4619675A1/de
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B63SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63BSHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B25/00Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
    • B63B25/02Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
    • B63B25/08Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
    • B63B25/12Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed
    • B63B25/16Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed heat-insulated
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/02Vessels not under pressure with provision for thermal insulation
    • F17C3/025Bulk storage in barges or on ships
    • F17C3/027Wallpanels for so-called membrane tanks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0147Shape complex
    • F17C2201/0157Polygonal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/052Size large (>1000 m3)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/03Thermal insulations
    • F17C2203/0304Thermal insulations by solid means
    • F17C2203/0358Thermal insulations by solid means in form of panels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0639Steels
    • F17C2203/0643Stainless steels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0646Aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0648Alloys or compositions of metals
    • F17C2203/0651Invar
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/23Manufacturing of particular parts or at special locations
    • F17C2209/232Manufacturing of particular parts or at special locations of walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/012Hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • F17C2223/0161Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/033Small pressure, e.g. for liquefied gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/06Controlling or regulating of parameters as output values
    • F17C2250/0605Parameters
    • F17C2250/0678Position or presence
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/01Improving mechanical properties or manufacturing
    • F17C2260/011Improving strength
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/01Improving mechanical properties or manufacturing
    • F17C2260/016Preventing slosh
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0102Applications for fluid transport or storage on or in the water
    • F17C2270/0105Ships
    • F17C2270/0107Wall panels

Definitions

  • the invention relates to the field of waterproof and thermally insulating membrane tank walls.
  • the invention relates to the field of sealed and thermally insulating tank walls for the storage, transport and/or use as fuel of liquefied gas at low temperature, such as tanks intended to include liquefied gas. liquid hydrogen which is at approximately -253°C at atmospheric pressure.
  • tanks intended to include liquefied gas. liquid hydrogen which is at approximately -253°C at atmospheric pressure.
  • these tanks can be installed on land or on a floating structure.
  • the tank may be intended for the transport of liquefied gas or for the use of liquefied gas as fuel for the propulsion of the floating structure.
  • the sealing membrane is subjected to strong thermomechanical stresses, for example during loading, unloading and during transport of the liquefied gas contained in the tank, for example in the event of sloshing during transport. at sea, also called “sloshing” phenomenon, which generates waves of liquefied gas that break against the waterproof membrane from inside the tank.
  • stresses are the cause of numerous damage problems to tank walls.
  • the sealing membrane is not stressed uniformly.
  • the thermally insulating barrier is discontinuous, that is to say that it is made up for example of heat-insulating elements juxtaposed with each other and each supporting a plurality of flat zones of the membrane.
  • waterproofing its behavior is not homogeneous when the waterproofing membrane deforms under the effect of thermal and mechanical stresses, indicated previously.
  • hydrodynamic pressures due to the “sloshing” phenomenon are exerted locally in certain flat areas of the waterproofing membrane and are only taken up by the heat-insulating element(s) which support said flat areas.
  • An idea behind the invention is to solve the aforementioned problems.
  • Another idea underlying the invention is to propose a wall for a waterproof and thermally insulating tank comprising supporting elements capable of resisting the forces exerted transversely to the direction of thickness of the wall.
  • the invention provides a wall for a sealed and thermally insulating tank for storing a liquefied gas, the wall comprising successively, in a direction of thickness of the wall, a thermally insulating barrier intended to be anchored , directly or indirectly, to a supporting structure and a waterproofing membrane which rests against the thermally insulating barrier, the thermally insulating barrier comprising: - at least one support element and - a modular structure located between the at least one support element and the sealing membrane, the modular structure being fixed against the at least one support element, the sealing membrane resting against the modular structure and being fixed to said modular structure, the modular structure comprising at least a first plate and a second plate, the sealing membrane comprises a first zone fixed to the first plate and a second zone fixed to the second plate, the first plate being linked to the second plate by a connection which has a degree of freedom in translation in a direction perpendicular to the direction of thickness of the wall in order to authorize contraction of the sealing membrane and a degree of connection according to
  • the first plate and the second plate of the modular structure on which the first zone and the second zone of the sealing membrane are fixed can carry out relative movements in the direction perpendicular to the direction of thickness of the wall.
  • the sealing membrane in particular, and particularly when it has undulations, to contract when the tank is cooled and to expand when the tank is heated, for example when the tank is emptied. More precisely, when the temperature drops in the tank, the material making up the waterproofing membrane contracts, and to compensate for the waves the waterproofing membrane deploys. This means that the waves are more open at a cold temperature, for example when the tank is cold, than at a warmer temperature. When the tank is heated, for example when the tank is emptied, it is the opposite.
  • connection of the first plate to the second plate in the direction of thickness of the wall allows the dynamic pressures exerted on one of the first and second plates to also be taken up by the other plate, which ensures better distribution of stresses exerted on the wall.
  • This connection also makes it possible to eliminate or at least limit the differences in height or walking phenomena between the support surfaces of the waterproofing membrane, which limits the fatigue stresses on the waterproofing membrane.
  • such a wall may include one or more of the following characteristics.
  • connection is formed by direct contact between a side portion of the first plate and a side portion of the second plate. That is to say that the first plate and the second plate touch each other without an intermediate piece to connect them.
  • the lateral portion of the first plate comprises at least a first rectilinear tongue and an external tongue respectively located on either side in the direction of thickness of the wall of a respective portion of the lateral portion of the second plate.
  • the lateral portion of the first plate comprises a second rectilinear tongue
  • the external tongue being positioned between the first and the second rectilinear tongues
  • the lateral portion of the second plate comprises a first external tongue, a second external tongue and a rectilinear tab positioned between the first outer tab and the second outer tab of the side portion of the second plate
  • the first and second rectilinear tabs of the side portion of the first plate extending in a rectilinear manner and the first and second second external tongues of the side portion of the second plate being offset in the direction of thickness of the wall and positioned respectively outside the rectilinear tongue of the side portion of the second plate
  • the rectilinear tongue of the side portion of the second plate extending in a rectilinear manner and the external tongue of the side portion of the first plate being offset in the direction of thickness of the wall and positioned outside the rectilinear tongue of the side portion of the second plate .
  • the first plate is linked directly by contact to the second plate while allowing movement in the direction perpendicular to the direction of thickness of the wall. Said movement in the direction perpendicular to the direction of thickness of the wall is carried out without the connection of the first plate with the second plate breaking.
  • connection by direct contact is a pinching of the lateral portion of the first plate with the lateral portion of the second plate. That is, the first plate clamps the second plate.
  • This pinching makes it possible in particular to maintain direct contact of the first plate with the second plate in the presence of thermodynamic stress while allowing a slide-type movement, in translation in the direction perpendicular to the direction of thickness of the wall.
  • the side portion of the first plate cooperates by interlocking in shape with the side portion of the second plate and forms a nesting zone.
  • the nesting zone has a through passage which passes through, in the direction perpendicular to the direction of thickness of the wall, the lateral portion of the first plate and the lateral portion of the second plate, the through passage being formed by at least one opening provided in the lateral portion of the first plate corresponding to at least one opening provided in the lateral portion of the second plate, a rod being housed in said through passage so that the first plate and the second plate have a degree of connection in the direction of thickness of the wall.
  • the rod is rectilinear.
  • the rod is metallic or made of rigid composite material.
  • the rod has a sufficient length to be housed in the at least one opening provided in the side portion of the first plate and in the at least one opening provided in the side portion of the second plate.
  • the rod has a length equal to or greater than the length of the through passage.
  • the rod has a height chosen so that there is no play depending on the direction of thickness of the wall between the rod and the through passage.
  • the rod has at one end a stop in the form of a base in order to maintain the rod in the through passage.
  • the through passage is formed by a plurality of oblong-shaped openings.
  • the width of the through passage is less than the width of the rod in order to allow freedom in translation in the direction perpendicular to the direction of thickness of the wall.
  • the lateral portion of the first plate comprises a tenon projecting towards the second plate, said tenon being received by a mortise arranged in the lateral portion of the second plate.
  • the lateral portion of the first plate comprises a second tenon projecting towards the second plate, said second tenon being received by a second mortise arranged in the lateral portion of the second plate.
  • the lateral portion of the first plate comprises a third tenon projecting towards the second plate, said third tenon being received by a third mortise arranged in the lateral portion of the second plate.
  • the first, second and third tenons each have identical or different dimensions and correspond respectively to the first, second and third mortises which each have identical or different dimensions in order to receive the corresponding tenon.
  • the modular structure comprises a third plate, a fourth plate and a fifth plate, the sealing membrane comprising a third zone fixed to the third plate, a fourth zone fixed to the fourth plate and a fifth zone fixed to the fifth plate, the first plate being linked to the third, fourth and fifth plates by connections which have a degree of freedom in translation in a direction perpendicular to the direction of thickness of the wall and a degree of connection in the direction d thickness of the wall.
  • the first plate is linked to the third, fourth and fifth plates via respectively a first side portion, a second side portion, a third side portion and a fourth side portion of said first plate.
  • the modular structure comprises a plurality of plates, for example sixteen plates, in which each of the plates of the plurality of plates is at least linked to another plate, and preferably each of the plates is linked to at least two other plates, for example three other plates or four other plates.
  • the modular structure increases the distribution of the different stresses in a homogeneous manner, on the wall support element(s). Thus, local damage to the wall is limited.
  • the modular structure comprises a third plate, a fourth plate and a fifth plate, the sealing membrane comprising a third zone fixed to the third plate, a fourth zone fixed to the fourth plate and a fifth zone fixed to the fifth plate, the first plate being connected to the second, third, fourth and fifth plates via respectively a first side portion, a second side portion, a third side portion and a fourth side portion of said first plate.
  • the first plate has the general shape of a polygon, for example a quadrilateral and preferably a square or rectangle.
  • each side of the polygon corresponds respectively to a lateral portion.
  • the first plate has the following dimensions: - a length between 20 and 300 centimeters (cm); - a width of between 20 and 300 cm; - a thickness of between 4 and 30 millimeters (mm).
  • the first plate is a metal plate, preferably comprising an alloy of iron and nickel.
  • the first plate is a plate made of composite material.
  • the composite material plate comprises a metal plate to allow welding of the sealing membrane on said metal plate.
  • the characteristics defining the first side portion of the first plate can also apply to the other side portions of the first plate, such as the second side portion, the third side portion and the fourth side portion.
  • the characteristics defining the side portion of the second plate can also apply to the other side portions of the second plate.
  • the first plate has an axis of symmetry.
  • the first side portion and the fourth side portion respectively have an axis of symmetry with the second side portion and the third side portion.
  • the axis of symmetry passes through a diagonal of the first plate.
  • the first side portion, the second side portion, the third side portion and the fourth side portion of the first plate each have identical or different characteristics.
  • the first plate is fixed against the at least one support element via a first fixing located in the center of the first plate
  • the second plate is fixed against the at least one support element via a second fixing located in the center of the second plate.
  • the central binding ensures better balancing of the binding.
  • the first fixing and the second fixing is a screw-nut system or riveting.
  • the aforementioned characteristics for the first plate also apply to the other plates of the modular structure, for example to the second plate, the third plate, the fourth plate and/or the fifth plate.
  • the aforementioned characteristics for the second plate also apply to the other plates of the modular structure, for example to the first plate, the third plate, the fourth plate and/or the fifth plate.
  • the at least one support element is a thermally insulating panel comprising a layer of self-supporting insulating foam sandwiched between an internal rigid plate and an external rigid plate, preferably the layer of insulating foam is a polymer foam.
  • the modular structure is fixed to the internal rigid plate.
  • the internal rigid plate is equipped with metal plates intended for anchoring the modular structure.
  • the at least one support element is an insulating box comprising a bottom plate, a cover plate and supporting sails extending, in the direction of thickness of the wall between the bottom plate and the cover plate and delimiting at least one compartment filled with a thermally insulating gasket.
  • an insulating box is for example described in document WO2012127141.
  • the thermally insulating lining is chosen from: perlite, glass wool and rock wool.
  • the at least one support element comprises a layer of flexible material in contact with the modular structure.
  • the flexible material has a Young's modulus in compression in the direction of thickness of the tank wall of between 0.25 and 25 MPa, for example in felt.
  • the flexible material has a Young's modulus in compression lower than the Young's modulus of the self-supporting insulating foam layer of the thermally insulating panel. That is to say that the flexible material is more flexible than said layer of self-supporting insulating foam of the thermally insulating panel.
  • the ratio between the Young's modulus in compression of the flexible material and the Young's modulus in compression of said layer of self-supporting insulating foam of the thermally insulating panel is less than or equal to 1/5, preferably included in 1/5 and 1/20.
  • the flexible material has a Young's modulus in compression lower than the Young's modulus of the material, such as plywood, in which at least one of the bottom plate, the cover plate and the sails carrying the insulating box.
  • the ratio between the Young's modulus in compression of the flexible material and the Young's modulus in compression of said material in which at least one of the bottom plate, the cover plate and the supporting sails is made is less than or equal to 1/5, preferably between 1/5 and 1/20.
  • the layer of flexible material extends in the direction perpendicular to the direction of thickness of the wall.
  • the thermally insulating barrier comprises a first support element and a second support element, the first support element being a first pillar and the second support element being a second pillar, the first pillar and the second pillar extending along the thickness direction of the wall, the first pillar being fixed to the first plate and the second pillar being fixed to the second plate.
  • the modular structure comprises: a first sleeve fixed between an internal end of the first pillar and the first plate, a second sleeve fixed between an internal end of the second pillar and the second plate, and a metal beam connecting the first sleeve and the second sleeve by a sliding junction in the direction perpendicular to the direction of thickness of the wall.
  • the metal beam has a rectilinear shape. According to one embodiment, the metal beam has the shape of a rectangular parallelepiped.
  • the sleeve has a cylindrical or cubic shape.
  • the thermally insulating barrier comprises a third support element, the third support element being a third pillar extending in the direction of thickness of the wall, in which the first pillar, the second pillar and the third pillar are aligned.
  • the modular structure comprises a third plate and a third sleeve fixed between an internal end of the third pillar and the third plate, the sealing membrane comprising a third zone fixed to the third plate, in which, the metal beam connects the third sleeve.
  • each sleeve is fixed by fitting inside the internal end of the pillar.
  • each sleeve is fixed by interlocking outside the internal end of the pillar.
  • the internal end of the pillar is the end of the pillar being closest to the waterproof membrane intended to be in contact with the liquefied gas contained in the tank.
  • the first sleeve and the second sleeve comprise a through opening in the direction perpendicular to the direction of thickness of the wall in order to receive the metal beam.
  • the third sleeve comprises a through opening in the direction perpendicular to the direction of thickness of the wall in order to receive the metal beam.
  • the modular structure comprises a metal beam connecting the first plate and the second plate by a sliding junction in the direction perpendicular to the direction of thickness of the wall.
  • the metal beam has an “I” shaped cross section.
  • the joist is a normal profile “I” profile, also called an “IPN” joist.
  • the beam with an "I" shaped cross section has a first and a second lateral grooves extending in the longitudinal direction of the beam, the first lateral groove receives a lateral portion of the first plate and the second lateral groove receives a lateral portion of the second plate.
  • the beam with an "I" shaped cross section blocks the rotation of the first plate and the second plate relative to axes parallel to the direction of thickness of the wall. Consequently, the surface of the modular structure at the first and second plates is flat and rigid.
  • the first lateral groove and the second lateral groove of the beam each receive a plurality of lateral portions of plates of the modular structure.
  • each pillar is made of a composite material comprising fibers and a matrix, which makes it possible to obtain satisfactory compressive strength for a limited conductive section.
  • each pillar has a tubular section.
  • each pillar has an internal space which is lined with an insulating lining of open-cell porous material, for example chosen from an open-cell insulating polymer foam, such as open-cell polyurethane foam, wool glass, rock wool, melamine foam, polyester wadding, polymer aerogels, such as polyurethane-based airgel, in particular marketed under the Slentite ® brand, and silica aerogels.
  • open-cell insulating polymer foam such as open-cell polyurethane foam, wool glass, rock wool, melamine foam, polyester wadding
  • polymer aerogels such as polyurethane-based airgel, in particular marketed under the Slentite ® brand
  • silica aerogels such as silica aerogels.
  • the first plate is linked to an internal end of the first pillar via a connecting device which retains the first plate to the first pillar in the thickness direction, the connecting device having: - a degree of freedom in rotation around a first axis which is perpendicular to the direction of thickness of the wall, and - a degree of freedom in rotation around a second axis which is perpendicular to the direction of thickness of the wall and orthogonal to the first axis.
  • connection of the connecting device between the sealing membrane and the pillar allows relative movement between them and thus forms a damping device which attenuates the forces which are likely to be transmitted to the pillar, particularly when the waterproofing membrane is subject to the sloshing phenomenon.
  • the bending moments acting on the pillar are thus reduced.
  • the lifespan of the support element and therefore of the tank wall is thus increased compared to a tank wall not having the aforementioned characteristics.
  • the second plate is linked to an internal end of the second pillar via a second connecting device which retains the second plate to the second pillar in the thickness direction, the second connecting device having: - a degree of freedom in rotation around a first axis which is perpendicular to the direction of thickness of the wall, and - a degree of freedom in rotation around a second axis which is perpendicular to the direction of thickness of the wall and orthogonal to the first axis.
  • connection device has: - a degree of connection in translation along the first axis, and - a degree of connection in translation along the second axis.
  • connection device has a degree of rotational connection in the direction of thickness of the wall.
  • the connecting device comprises a support fixed to the internal end of the first pillar.
  • the sleeve is fixed against a longitudinal surface of the pillar.
  • the sleeve extends beyond the internal end of the pillar.
  • the pillar is hollow.
  • the sealing membrane is welded to the first metal plate.
  • the support comprises a closing plate fixed to the internal end of the first pillar and covering the internal end of the first pillar.
  • the closure plate is metallic.
  • connection device comprises a ball joint cup and a ball joint head housed in said ball joint cup, one of the ball joint cup and the ball joint head being integral with the first plate and the other being integral with the support.
  • ball joint head and “ball joint bowl” are respectively defined within the meaning of this text as being the protuberance and the receiving cavity of a ball joint connection.
  • the connecting device is arranged so as to press the ball joint head and the ball joint cup against each other.
  • the connecting device comprises a rod passing through the ball joint head and the ball joint cup.
  • the rod of the connecting device has a first end fixed to an element among the support and the first plate.
  • said rod of the connecting device has a second end fixed to the other element among the support and the first plate.
  • said rod of the connecting device has a first end equipped with a stop.
  • said rod of the connecting device has a second end equipped with a stop.
  • the connecting device further comprises at least one elastic member or a spherical washer mounted on the rod and disposed between the stop and one of the ball joint cup and the ball joint head so as to press the ball joint ball head and the ball joint cup against each other.
  • the elastic member comprises a Belleville washer.
  • the rod is a screw comprising a screw head and the stop is the screw head.
  • the connecting device comprises a plurality of rods spaced from each other and a plurality of elastic members, each rod comprising a first end which is fixed to a first element among the first plate and the support and a second end comprising a stop, said rod passing through a second element among the first plate and the support, each elastic member mounted on one of the rods and positioned between the first plate and the support so as to press the second element against the surface of stop.
  • the plurality of rods comprises three rods distributed so that the three segments of the straight lines connecting the rods in pairs form an equilateral triangle.
  • the stop is positioned in a recess provided in the ball joint head or the ball joint cup, the elastic member or the spherical washer being located in the recess between the screw head and a bottom of the recess.
  • the support element comprises: - an external plate which is linked to an external end of the first pillar via an external connection device which retains the external plate to the first pillar in the direction of thickness, the secondary sealing membrane being fixed to the external plate, the external connection device having: - a degree of freedom in rotation around a first axis which is perpendicular to the direction of thickness of the wall, and - a degree of freedom in rotation around a second axis which is perpendicular to the direction of thickness of the wall and orthogonal to the first axis.
  • the external connection device is similar to the connection device, that is to say it may include one or more of the characteristics of the connection device which is arranged at the external end of the first pillar.
  • the external connection device comprises a support fixed to the external end of the first pillar and comprises a ball joint cup and a ball joint housed in said ball joint cup, one of the ball joint cup and the ball head being secured to the external plate and the other being secured to the support.
  • the external plate is metallic.
  • the secondary sealing membrane is welded to the external metal plate.
  • the secondary thermally insulating barrier comprises the support element.
  • the secondary thermally insulating barrier comprises a plurality of support elements.
  • the primary thermally insulating barrier comprises the aforementioned support element.
  • the primary thermally insulating barrier comprises a plurality of support elements.
  • the secondary thermally insulating barrier and the primary thermally insulating barrier each comprise the support element.
  • the primary thermally insulating barrier and the secondary thermally insulating barrier comprise a plurality of support elements.
  • the primary sealing membrane comprises a first series of corrugations having first corrugations parallel to each other and a second series of corrugations having second corrugations parallel to each other and perpendicular to the first corrugations
  • the primary waterproofing membrane comprises a plurality of flat zones which are each defined between two first adjacent corrugations and between two second adjacent corrugations, the plurality of flat zones of the primary sealing membrane comprising a first flat zone which is welded against the first plate of the support element.
  • the first wall and the second wall form a corner of the tank, and the first wall and the second wall each comprise a row of support elements supporting the sealing membrane which extends parallel at the edge, in which the row includes the support element.
  • the primary thermally insulating barrier comprises at least a second row of pillars comprising a fourth, a fifth and a sixth pillars which are fixed to the secondary thermally insulating barrier and which rise in the direction of thickness of the wall, the fourth, the fifth and the sixth pillars being aligned in a direction parallel to the second undulations and being respectively fixed to a fourth, a fifth and a sixth plates, in which the fourth, the fifth and the sixth pillars are respectively located at the level of a flat area.
  • the primary thermally insulating barrier comprises both support elements which are aligned parallel to the first undulations of the primary sealing membrane and support elements which are aligned parallel to the second undulations of the primary sealing membrane.
  • the waterproofing membrane is fixed to the modular structure by welding.
  • the thermally insulating barrier is a primary thermally insulating barrier and the sealing membrane is a primary sealing membrane which is intended to be in contact with the liquefied gas contained in the tank, the wall comprising a barrier secondary thermally insulating barrier intended to rest against the supporting structure, a secondary waterproofing membrane which rests against the secondary thermally insulating barrier, the primary thermally insulating barrier resting against the secondary waterproofing membrane and the primary waterproofing membrane resting against the barrier primary thermally insulating.
  • the secondary thermally insulating barrier rests against the supporting structure.
  • the first series of corrugations and the second series of corrugations of the secondary waterproofing membrane project inwards, in the opposite direction to the supporting structure.
  • the primary thermally insulating barrier has a gas phase placed at negative pressure relative to atmospheric pressure.
  • the thermal insulation properties of the primary thermally insulating barrier are increased.
  • the gas phase is placed at an absolute pressure less than 1 Pa, advantageously less than 10 -1 Pa, preferably less than 10 –2 Pa and for example of the order of 10 –3 Pa. This makes it possible to increase the thermal insulation performance of the primary thermally insulating barrier.
  • the secondary thermally insulating barrier has a gas phase under vacuum, preferably at an absolute pressure less than 1 Pa.
  • the primary sealing membrane comprises a plurality of corrugated metal sheets, each corrugated metal sheet having edges which are each lap welded to an edge of an adjacent corrugated metal sheet.
  • the secondary thermally insulating barrier comprises insulating panels anchored to the supporting structure.
  • the insulating panels are made from: glass wool, rock wool, polyester wadding, open-cell polymer foams, such as open-cell polyurethane foam or melamine foams.
  • each insulating panel comprises a layer of insulating polymer foam sandwiched between an internal plate and an external plate, for example made of plywood or made in a polymer matrix reinforced by fibers, such as glass fibers. .
  • the internal plate of the insulating panels is equipped with metal plates intended for anchoring the modular structure on the insulating panels and/or for anchoring the waterproof membrane on the insulating panels.
  • the internal plate of the insulating panels is equipped with metal plates intended for anchoring the edges of the corrugated metal sheets of the secondary waterproofing membrane on the insulating panels.
  • the liquefied gas is hydrogen
  • the invention also provides a waterproof and thermally insulating tank comprising a plurality of aforementioned walls.
  • the sealed and thermally insulating tank contains liquefied hydrogen.
  • the tank can be made using different techniques, notably in the form of an integrated membrane tank.
  • the tank is a polyhedral tank.
  • Such a tank can be part of a land storage installation or be installed in a floating, coastal or deep water structure, in particular a liquid hydrogen transport vessel, that is to say a hydrogen tanker, a floating unit storage and regasification unit (FSRU), a floating production and remote storage unit (FPSO) and others.
  • a tank can also be used as a fuel tank in any type of ship.
  • a ship for transporting liquefied gas comprises a double hull and a aforementioned tank placed in the double hull.
  • the invention also provides a transfer system for a liquefied gas, the system comprising the aforementioned ship, insulated pipes arranged so as to connect the sealed and thermally insulating tank installed in the hull of the ship to an installation floating or land storage and a pump to drive a flow of liquefied gas through insulated pipelines from or to the floating or land-based storage facility to or from the vessel's watertight and thermally insulating tank.
  • the invention also provides a method of loading or unloading such a vessel, in which a liquefied gas is conveyed through insulated pipes from or to a floating or terrestrial storage installation to or from the tank waterproof and thermally insulating the vessel.
  • FIG. 1 There is a cutaway and schematic perspective view of a supporting structure intended to support a waterproof and thermally insulating tank for storing a liquefied gas.
  • FIG. 1 There is a partial perspective view of a wall of a waterproof and thermally insulating tank according to a first embodiment.
  • FIG. 1 There is a perspective view of a plate of a modular structure according to one embodiment.
  • FIG. 1 There is a perspective view of a modular structure formed by four plates linked together according to the embodiment of the .
  • FIG. 1 There is a perspective view of a wall according to another embodiment, comprising a modular structure.
  • FIG. 1 There is a perspective view of a plate of the modular structure of the .
  • FIG. 1 There is a perspective view of a connection of a first plate with a second plate, of the modular structure of the .
  • FIG. 1 There is a schematic, partial and perspective view of a wall comprising a modular structure according to another embodiment.
  • FIG. 1 There is a schematic, partial and perspective view of a wall comprising a modular structure according to another embodiment.
  • FIG. 1 There is a schematic, partial and sectional view of a wall comprising a modular structure according to another embodiment.
  • FIG. 1 There is a schematic, partial and perspective view of a wall comprising the modular structure according to the embodiment of the , in which the waterproofing membrane has been deliberately omitted.
  • the liquefied gas intended to be stored in the tank may in particular be liquid hydrogen which has the particularity of being stored at approximately -253°C at atmospheric pressure.
  • the invention applies to any other liquefied gas, for example liquefied natural gas.
  • a tank 1 intended to receive a liquefied gas.
  • the tank 1 comprises a supporting structure formed by the internal hull (not shown) of a double-hulled ship (not shown).
  • the tank 1 has a general polyhedral or prismatic shape.
  • the tank 1 has a first transverse wall 2 and a second transverse wall 3, here of octagonal shape.
  • the first transverse wall 2 is only partially shown in order to allow visualization of the internal space of the tank 1.
  • the tank 1 also includes a ceiling wall 4, a bottom wall 5, lower chamfer walls 6 , side walls 7 and upper chamfer walls 8.
  • the ceiling wall 4, the bottom wall 5, the lower chamfer walls 6, the side walls 7, and the upper chamfer walls 8 extend in the direction longitudinal of the ship, connect the first and second transverse walls 2, 3 at the level of transverse edges 9, and meet at the level of longitudinal edges 10.
  • Each wall of the tank successively presents, in a direction of thickness of the wall, a thermally insulating barrier intended to rest against a supporting structure and a sealing membrane which rests against the thermally insulating barrier.
  • each wall of the tank has a multi-layer structure comprising, from the outside towards the inside of the tank, a secondary thermally insulating barrier comprising a plurality of secondary insulating panels, intended to be anchored, directly or indirectly , to a supporting structure, a secondary waterproof membrane resting against the secondary thermally insulating barrier, a primary thermally insulating barrier comprising a plurality of primary insulating panels or a plurality of primary pillars, resting against the secondary waterproof membrane and a primary waterproof membrane intended to be in contact with the liquefied gas contained in the tank.
  • the primary sealed membrane defines an internal space intended to receive liquefied gas, such as hydrogen.
  • the wall 11 for a sealed and thermally insulating tank for storing a liquefied gas has a multilayer structure comprising, in the direction of thickness of the wall 11, from the outside towards the inside, a secondary thermally insulating barrier 12 intended to rest against a supporting structure 23, a secondary sealing membrane 13, a primary thermally insulating barrier 14 and a primary sealing membrane 15 intended to be in contact with the liquefied gas contained in the tank.
  • the secondary thermally insulating barrier 12 comprises a plurality of insulating panels 16 anchored to the supporting structure 23.
  • the insulating panels 16 each comprise a layer of insulating polymer foam 17 sandwiched between an internal plate 18 and an external plate 19.
  • the internal plates 18 and external 19 are, for example, plywood plates glued to said layer of insulating polymer foam 17.
  • the internal 18 and external 19 plates are made in a polymer matrix reinforced by fibers, such as fibers of glass.
  • the insulating polymer foam may in particular be a polyurethane-based foam.
  • the polymer foam is advantageously reinforced with fibers, such as glass fibers, helping to reduce its thermal contraction.
  • the insulating panels 16 are anchored to the supporting structure 23 by means of secondary anchoring devices, not shown.
  • Each insulating panel 16 is, for example, fixed to at least each of its four corners.
  • Each secondary anchoring device comprises a stud welded to the supporting structure 23 as well as a support member which is fixed on the stud and which bears against a support zone of the insulating panels 16.
  • the external plate 19 of the insulating panels 16 projects beyond the layer of insulating polymer foam 17, at least at the corners of the insulating panel 16, so as to form the support zones of the insulating panels 16 cooperating with the members of the insulating panels 16.
  • Elastic members such as Belleville washers, are advantageously threaded onto the stud, between a nut mounted on the stud and the support member, which ensures elastic anchoring of the insulating panels 16 on the supporting structure 23 .
  • portions of putty 20 are interposed between the external plate 19 of the insulating panels 16 and the supporting structure 23.
  • the portions of putty 20 thus contribute to compensating for the surface irregularities of the supporting structure 23.
  • the portions of mastic 20 adhere to the external plate 19 of the insulating panels 16 and to the supporting structure 23.
  • the portions of mastic 20 thus participate in the anchoring of the insulating panels 16 on the supporting structure 23.
  • secondary anchoring devices are optional.
  • the insulating panels 16 have substantially the shape of a rectangular parallelepiped and are juxtaposed in parallel rows and separated from each other by gaps 21 guaranteeing functional assembly clearance.
  • the gaps 21 are filled with a heat-insulating filling, not shown, such as glass wool, rock wool or flexible open-cell polymer foam, for example.
  • the gaps can also be filled with insulating plugs, as described in applications WO2019155157 or WO2021028624, for example.
  • the internal face of the insulating panels 16 has two series of grooves 22 perpendicular to each other and intended to receive undulations, projecting towards the outside of the tank, formed on the corrugated metal sheets of the secondary sealing membrane 13.
  • Each of the series of grooves 22 is parallel to two opposite sides of the insulating panels 16.
  • the grooves 22 pass entirely through the thickness of the internal plate 18 as well than an internal portion of the layer of insulating polymer foam 17.
  • the grooves 22 have a shape complementary to those of the undulations of the secondary sealing membrane 13.
  • the internal plate 18 of the insulating panels 16 is equipped with metal plates intended for anchoring the edges of the corrugated metal sheets of the secondary waterproofing membrane 13 on the insulating panels 16.
  • the metal plates extend in two directions perpendiculars which are each parallel to two opposite sides of the insulating panels 16.
  • the metal plates are fixed on the internal plate 18 of the insulating panels 16, by screws, rivets or staples, for example.
  • the metal plates are placed in recesses made in the internal plate 18 such that the internal surface of the metal plates is flush with the internal surface of the internal plate 18.
  • the insulating panels 16 have relaxation slots 27 which make it possible to reduce their stiffness so that the secondary thermally insulating barrier 12 deforms in the most homogeneous manner possible. This makes it possible to obtain the most uniform deformations possible of the undulations of the secondary sealing membrane 13.
  • the insulating panels 16 have relaxation slots 27 at least opposite each of the undulations 24 of the membrane. secondary sealing 13.
  • a relaxation slot 27 extends from the bottom of each of the grooves 22 towards the external plate 19 of the insulating panels 16.
  • the insulating blocks 16 also include relaxation slots which open onto the external face of the insulating panels 16. Such relaxation slots are then not arranged facing an undulation of the secondary sealing membrane 13 but halfway between two parallel undulations of the sealing membrane secondary 13.
  • the secondary sealing membrane 13 comprises a plurality of corrugated metal sheets each having a substantially rectangular shape.
  • Corrugated metal sheets are, for example, made of Invar®: that is to say an alloy of iron and nickel whose expansion coefficient is typically between 1.2.10 -6 and 2.10 -6 K -1 , or in an iron alloy with a high manganese content whose expansion coefficient is typically of the order of 7.10 -6 K -1 .
  • corrugated metal sheets can also be made from stainless steel or aluminum.
  • corrugated metal sheets are overlap welded along their edges in order to ensure the tightness of the secondary sealing membrane 13. Furthermore, the corrugated metal sheets are arranged offset relative to the insulating panels 16 of the barrier secondary thermally insulating material 12 such that each of said corrugated metal sheets extends jointly over several adjacent insulating panels 16. In order to ensure the anchoring of the secondary waterproofing membrane 13 on the secondary thermally insulating barrier 12, the edges of the corrugated metal sheets are welded to the metal plates, for example by spot welds.
  • the secondary sealing membrane 13 has undulations and more particularly a first series of undulations extending parallel to a first direction and a second series of undulations extending parallel to a second direction.
  • the directions of the series of undulations are perpendicular to each other.
  • Each of the series of corrugations is parallel to two opposite edges of the corrugated metal sheet.
  • the undulations here project towards the outside of the tank, that is to say in the direction of the supporting structure 23.
  • the secondary sealing membrane 13 comprises, between the undulations, a plurality of flat zones.
  • the undulations of the secondary waterproofing membrane 13 are housed in the grooves 22 provided in the internal face of the insulating panels 16 and in the gaps 21 provided between the adjacent insulating panels 16.
  • each primary anchoring device aimed at ensuring the anchoring of the support elements of the primary thermally insulating barrier 14 on the insulating panels 16 of the thermally insulating barrier.
  • Each primary anchoring device comprises a stud, not shown, which passes through the secondary sealing membrane in a watertight manner.
  • the primary thermally insulating barrier 14 comprises a plurality of pillars 30 which extend in the direction of thickness of the wall 11.
  • the pillars 30 make it possible to support the primary sealing membrane 15 and, consequently, to take up the forces due to the hydrostatic and dynamic pressures exerted, on the primary sealing membrane 15, by the liquefied gas contained inside the tank.
  • the pillars 30 are aligned in rows which are parallel to the direction of the undulations of the first series of undulations 45a and in rows parallel to the direction of the undulations of the second series of undulations 45b.
  • the primary waterproof membrane 15 for its part is obtained in a manner similar to the secondary waterproof membrane by assembling a plurality of corrugated metal sheets 44.
  • the corrugated metal sheets 44 each have a substantially rectangular shape.
  • the corrugated metal sheets 44 are, for example, made of Invar®: that is to say an alloy of iron and nickel whose expansion coefficient is typically between 1.2.10 -6 and 2.10 -6 K -1 , or in an iron alloy with a high manganese content whose expansion coefficient is typically of the order of 7.10 -6 K -1 .
  • the corrugated metal sheets 44 can also be made of stainless steel or aluminum.
  • the corrugated metal sheets 44 are overlap welded along their edges in order to ensure the tightness of the primary sealing membrane 15.
  • the primary sealing membrane 15 comprises undulations 45. More particularly, it comprises a first series of corrugations 45a extending parallel to a first direction and a second series of corrugations 45b extending parallel to a second direction.
  • the directions of the series of corrugations 45a, 45b are perpendicular and are parallel or perpendicular to the rows of pillars 30.
  • Each of the series of corrugations 45a, 45b is parallel to two opposite edges of the corrugated metal sheets 44.
  • the corrugations 45 project towards inside the tank, that is to say in the opposite direction to the supporting structure 23.
  • Each corrugated metal sheet 44 has between the corrugations 45, a plurality of flat zones 46.
  • the wall 11 comprises a modular structure 50 located between a plurality of pillars 30 and the primary sealing membrane 15.
  • the primary sealing membrane 15 is fixed on the modular structure 50 by welding at the level of the flat zones 46. According to one embodiment, each of the flat zones 46 of the primary sealing membrane 15 is fixed on a respective plate of the modular structure 50. According to another embodiment, the primary sealing membrane 15 is only welded to the modular structure along the edges of the corrugated metal sheets 44.
  • the modular structure 50 comprises a first plate 51, a second plate 52 and a third plate 53.
  • the second plate 52 is linked to the first plate 51 via a first connection 54 located at a lateral portion of the first plate 51 and a side portion of the second plate 52.
  • the second plate is also connected via a second connection 55 to the third plate 53 via another side portion of the second plate and a side portion of the third plate.
  • the first connection 54 and the second connection 55 are such that they allow a degree of freedom in translation in a direction X which is perpendicular to the direction of thickness of the wall and is parallel to the direction of one of the series of undulation 45a, 45b of the primary sealing membrane 15.
  • the modular structure 50 is fixed to the pillars 30 by bolts. That is to say that each plate is respectively fixed to a pillar 30 for example via a screw and nut system 82.
  • a plate according to the embodiment of the is illustrated in more detail on the .
  • the plate of the is named first plate 51.
  • the second plate 52 and the third plate 53 of the have identical characteristics.
  • the first plate 51 has the general shape of a square presenting a first side portion 101, a second side portion 102, a third side portion 103 which is opposite the first side portion 101 and a fourth side portion 104.
  • the first lateral portion 101 and the second lateral portion 102 each have a first rectilinear tongue 105, a second rectilinear tongue 105 and an external tongue 107 located between the first rectilinear tongue 105 and the second rectilinear tongue 105.
  • the third lateral portion 103 and the fourth lateral portion 104 each have a rectilinear tongue 105 located between a first external tongue 107 and a second external tongue 107.
  • the external tongues 107 are each offset in a direction of thickness Y of the wall, towards the outside of the tank, relative to the rectilinear tongues 105.
  • the first side portion 101 and the second side portion 102 are complementary to the third side portion 103 and the fourth side portion 104.
  • first side portion 101 and the second side portion 102 can each be linked with any of the third side portions 103 and fourth side portions 104 of a neighboring plate.
  • Such a first plate 51 is manufactured for example by stamping or folding a metal sheet.
  • the modular structure 50 allows the uniform distribution of the forces exerted on the pillars 30 but also allows, in the event of damage to a pillar 30, to maintain the support of the primary waterproofing membrane 15.
  • Such a modular structure 50 comprising a plurality of plates identical to the first plate 51 is illustrated in particular in Figures 5 and 6.
  • the modular structure 50 includes: - a first plate 51 linked to a second plate 52 by contact of the fourth lateral portion 104 of the first plate 51 with the second lateral portion 102 of the second plate 52.
  • the first plate 51 being further linked to a third plate 56 by contact of the first lateral portion 101 of the first plate 51 with the third lateral portion 103 of the third plate 56.
  • the fourth plate 57 being further linked to a third plate 56 by contact of the second lateral portion 102 of the fourth plate 57 with the fourth lateral portion 104 of the third plate 56.
  • This hole 60 aims to avoid a superposition of material causing difficulties in assembling the modular structure.
  • the wall 111 for a sealed and thermally insulating tank for storing a liquefied gas comprises a support element 130 which can be: - a thermally insulating panel comprising a layer of self-supporting insulating polymer foam sandwiched between an internal plywood plate and an external plywood plate; Or - an insulating box filled with a thermally insulating gasket.
  • the support element further comprises a layer of flexible material 31 positioned against the panel or the insulating box 130, the modular structure 50 being positioned and fixed against the layer of flexible material 31.
  • each plate has in its center a circular recess 83 comprising a through hole 84 intended to receive a fixing.
  • the fixing to freeze each plate in the direction of thickness Y of the wall 111 is carried out at a single point, for example in the center of the plate, for example by bolts.
  • the plates of the modular structure 50 collaborate with each other via connections at the level of the lateral portions which allow movement in the direction perpendicular X to the direction of thickness of the wall 111. That is to say, when the waterproof membrane (not shown on the ) contracts or expands in response to thermal constraints, the plates of the modular structure 50 are each free to slide in translation in the direction X.
  • the layer of flexible material 31 makes it possible to increase the load distribution effect.
  • the modular structure 150 comprises a plurality of plates linked together via a mortise-tenon system illustrated in more detail in Figures 8 and 9.
  • Plate 58 of the present similarly to plate 51 of the , a general shape of a square having a first side portion 201, a second side portion 202, a third side portion 203 which is opposite the first side portion 201 and a fourth side portion 204.
  • the plate 58 has a symmetry along the axis S passing through a diagonal of said plate 58.
  • the first side portion 201 and the second side portion 202 each have a first and a second rectangular tenon 205 and a cylindrical tenon 206 projecting respectively from the first side portion 201 of the plate 58 and from the second side portion 202 of the plate 58 .
  • the third lateral portion 203 and the fourth lateral portion 204 each have a first and a second rectangular mortise 207 and a cylindrical mortise 208 hollowed out respectively in the third lateral portion 203 of the plate 58 and in the fourth lateral portion 204 of the plate 58.
  • the dimensions of the mortises are adapted to allow the reception of the corresponding tenons.
  • each plate of the modular structure 150 has the characteristics of the plate 58.
  • first side portion 201 and the second side portion 202 can each be linked with any of the third side portions 203 and fourth side portions 204 of a neighboring plate.
  • the first and second rectangular tenons 205 and the cylindrical tenon 206 of the first lateral portion 201 are respectively linked to the first and second rectangular mortises 207 and to the cylindrical mortise 208 of the third lateral portion 203 of the adjacent plate.
  • the second side portion 202 is linked to the fourth side portion 204 of the adjacent plate via the first and second rectangular tenons 205 and the cylindrical tenon 206 of the second side portion 201 which fit into the first and second mortises rectangular 207 and the cylindrical mortise 208 of the fourth lateral portion 203 of the adjacent plate.
  • the width dimensions of the first tenon 205 are less than the width dimensions of the first mortise 207 in order to allow movement of the first tenon 205 in the first mortise 207, in directions X1 and X2 perpendicular to the direction of thickness of the wall.
  • This difference in dimensions makes it possible in particular to authorize a slide movement in response to contraction or thermal expansion without completely breaking the connection. That is to say that the dimensions are also chosen with regard to the estimated thermal contraction and expansion so that the tenon does not come completely out of the mortise.
  • the modular structure 450 comprises a plurality of plates 451 linked together via an interlocking system as illustrated in Figures 13 and 14.
  • the modular structure 450 comprises a plurality of plates 451, four of which are illustrated on the which are fitted together by complementarity of shape between a side portion of a plate 451 and a side portion of another adjacent plate 451.
  • the complementary shapes of the two nested plates 451 each have openings 452 which extend in a direction perpendicular for example have an oblong shape.
  • a rectilinear rod 453 is housed in the consecutive through openings 452 and passes through said consecutive through openings 452 in order to maintain a degree of connection in the thickness direction Y of the wall of the interlocking plates.
  • the transverse dimension of the rectilinear rod 453, measured perpendicular to the thickness direction, is less than the corresponding transverse dimension of said through openings 452.
  • the rectilinear rod 453 is mounted with clearance in a transverse direction perpendicular to the longitudinal direction of the rectilinear rod 453 and the thickness direction Y of the wall, which makes it possible to authorize the relative movements of the plates with respect to each other in the plane orthogonal to the thickness direction of the wall .
  • the rectilinear rod 453 has, at one end, a stop in the form of a base 454 in order to maintain the rectilinear rod 453 housed in the through passage.
  • the pillars 30 of the are organized in rows, similar to the pillars 30 presented on the .
  • the modular structure 250 comprises a plurality of plates 251 linked together via metal beams capable of sliding in one of the directions X1, X2 perpendicular to the direction thickness of the wall parallel to one of the series of corrugations of the corrugation series 45a, 45b of the primary sealing membrane 15.
  • the modular structure 250 further comprises a plurality of sleeves 252 which are each positioned on an internal end of a pillar 30.
  • Each sleeve 252 has two through openings forming a cross-shaped notch.
  • a plurality of continuous metal beams 253 each pass through a series of sleeves 252 aligned via their respective notch, in a first direction X1, perpendicular to the direction of thickness of the wall.
  • first direction X1 perpendicular to the direction of thickness of the wall.
  • the continuous metal beams 253 are capable of carrying out a sliding movement in the first direction X1.
  • a plurality of discontinuous metal beams 254 each connect, in a second direction X2 which is perpendicular to the direction of thickness of the wall and which is perpendicular to the first direction X1, a first sleeve 252 of a first pillar 30 with a second sleeve 252 of a second pillar 30 adjacent to the first pillar 30 via their respective notch.
  • the discontinuous metal beams 254 are able to perform a sliding movement in the second direction X2.
  • Each plate 251 is fixed, for example by means of rivets 85, to a pillar 30 via a sleeve 252.
  • the modular structure 250 also allows a uniform distribution of the forces exerted on the pillars 30 but also allows, in the event of damage to a pillar 30, to maintain the support of the primary waterproof membrane.
  • the supporting element is an insulating panel in place of the pillars 30 and the sleeves 252 are distributed on an internal surface of the insulating panel and the continuous and discontinuous metal beams are distributed in a manner similar to the .
  • the 350 modular structure differs from the 250 modular structure of the in that it comprises sleeves 352 of cubic shape and in that it comprises a plurality of discontinuous metal beams 254, in a first direction X1 and in the second direction X2, connecting two adjacent sleeves 352.
  • the supporting element is an insulating panel in place of the pillars 30 and the sleeves 352 are distributed on an internal surface of the insulating panel and the discontinuous metal beams are distributed in a manner similar to the .
  • Figures 25 and 26 show another alternative embodiment of a wall for a waterproof and thermally insulating tank for storing a liquefied gas.
  • the 550 modular structure differs from the 250 modular structure of the in that the metal beams 153, 154 are positioned at the level of the gap between two adjacent plates 151, for example in a gap along two plates on either side of the gap as is illustrated in the . There illustrates in particular a sectional view of a metal beam 153 located opposite an undulation of the sealing membrane 15.
  • the metal beams 153, 154 have an "I" shape comprising two grooves which each receive at least one lateral portion of a plate 151.
  • the metal beams 153 extend in the first direction X1 perpendicular to the thickness direction of Wall.
  • the metal beams 154 extend in a second direction X2 which is perpendicular to the direction of thickness of the wall and which is perpendicular to the first direction X1.
  • the metal beams 153 and 154 form a network of metal beams making it possible to block the adjacent plates from rotating and therefore make it possible to maintain the flatness and rigidity of the modular structure 550.
  • Figures 15 to 24 represent embodiments of the connecting device linking the modular structure to the pillar.
  • the connection of the first plate to the second plate is deliberately omitted in order to facilitate understanding of the illustrations.
  • the identical or similar elements of Figures 15 to 24 bear the same reference numbers incremented by a multiple of 100. Note that if these figures represent a connecting device for connecting the modular structure to a single pillar, a connecting device identical is advantageously used for several or all of the other pillars.
  • the support element 120 comprises a pillar 121 which is hollow, a first plate 122 and a connecting device 130 which allows the connection of the first plate 122 to the internal end of the pillar 121.
  • the connecting device 130 comprises a support 131 which is a metal sleeve fitted into the internal end of the pillar 121 and glued via a layer of glue 191 against an internal longitudinal surface of the pillar 121.
  • the sleeve extends beyond the the internal end of the pillar 121 by forming a receiving collar 132 which has a diameter greater than the external diameter of the pillar 121.
  • the connecting device 130 comprises three threaded rods 133, designated screws in the remainder of the description, and only one of which is present in the cutting plane of the .
  • the three screws 133 are regularly positioned on a geometric circle concentric with the longitudinal axis of the pillar 121. In other words, the three screws 133 are distributed in such a way that the three segments of the straight lines connecting the rods two by two form an equilateral triangle.
  • the screws 133 pass through the first plate 122 and each have an internal end 134 screwed into a tapped hole 135 which is positioned in the receiving flange 132.
  • the screws 133 further comprise, at the level of the internal end 136, a head screw which is positioned in a countersink 123 made in the internal surface 124 of the first plate 122.
  • the connecting device 130 further comprises an elastic member 137 which is a spring washer, also called an elastic washer or Belleville washer.
  • the elastic member 137 is mounted on the screw 133, between the first plate 122 and the receiving flange 132 so as to press the first plate 122 against the screw head 136.
  • the elastic crushing properties of the elastic member 137 allow a rotational movement of the first plate 122 along a first axis X3 which is perpendicular to the direction of thickness of the wall and along a second axis X4 which is perpendicular to the direction of thickness Y of the wall and orthogonal to the first axis X3.
  • the elastic member 137 returns to its initial shape and the first plate 122 returns to its initial positioning.
  • the elastic properties of the elastic member 137 allow a translation movement of the first plate 122, in the thickness direction Y of the wall. Such a movement brings the first plate 122 closer to the fixing flange 132, reducing the distance between the first plate 122 and the fixing flange 132 by a distance less than or equal to the distance represented by the elastic crushing capacity of the elastic member 137.
  • the elastic member 137 returns to its initial shape and the first plate 122 to its initial position.
  • the support element 520 differs from that of the in that the support 531 is a closing plate, for example made of metal, which covers the opening of the hollow pillar 521.
  • the closing plate has a diameter similar or identical to the diameter of the pillar 521.
  • the support element 520 comprises three rods 533, only one of which is visible in the cutting plane of the , the rods 533 each pass through the first plate 522 and each have an external end 534 fixed in a hole 535 which is provided in the closing plate and an internal end 536 fixed in a recess 525 having a bottom 526. Fixing the rods 533 to the support 531 is for example carried out via a threading and tapping system. The screws 533 can be adjusted by screwing into the tapped hole 535 in order to adjust the height of the first plate 522.
  • the connecting device 530 comprises four Belleville washers 537 superimposed and mounted on each rod 533, between the first plate 522 and the closing plate.
  • the three rods 533 are distributed around the periphery of the closing plate 531 so that the three segments of the straight lines connecting the rods two by two form an equilateral triangle.
  • the support element 820 differs from the in that it comprises a first metal part 840 positioned against the external surface 827 of the first plate 822 and fixed against the external surface 827 via fixing screws 841.
  • the support element 820 further comprises a second metal part 860 located opposite the first metal part 840.
  • the second metal part 860 is positioned against the internal surface of the receiving flange 832 and fixed against the receiving flange 832 via fixing screws 844.
  • the support element comprises a central threaded rod 833 which passes through the hole 835 which is provided in the second metal part 860.
  • the threaded rod 833 has an external end 834 which is fixed via an abutment against an external surface of the second metal part 860 at the level of the hole 835.
  • the threaded rod further comprises an internal end 836 fixed via a stop in a recess 825 comprising a bottom 826 located in the first metal part 840.
  • the fixing of the rod 833 to the first metal part 840 and to the second metal part 860 is for example produced via a screw and nut system.
  • the Belleville 837 washers can be adjusted, for example constrained via tightening or loosening the nuts mounted on the 833 rod.
  • the support element 220 differs from that of the in that the connecting device 230 comprises a ball head 238 housed in a ball joint cup 239.
  • the ball joint cup 239 is formed in the receiving flange 232, at the center of the diameter of the receiving flange 232.
  • ball head 238 is formed by a protuberance projecting from the first plate 222 and has a shape complementary to that of the ball joint cup 239.
  • the connecting device 230 comprises a screw 233 which passes through the first plate 222, the ball head 238 and the ball joint cup 239.
  • the external end 234 of the screw 233 is fixed in a hole 235 made in the ball joint cup 239 and the internal end of the screw 233 comprises a screw head 236 which is positioned in a recess 225 formed in the internal surface 224 of the first plate 222, the recess 225 comprising a bottom 226.
  • the elastic member 237 is located in the recess 225 between the screw head 233 and the bottom 226 of the recess 225 so as to press the first plate 222 against the receiving flange 232, while allowing a degree of freedom in rotation around the first axis X3 and a degree of freedom rotating around the second axis X4.
  • the support element 320 differs from that of the in that the metal sleeve 331 does not have a receiving collar, and in that the ball head 338 projects from a metal part 340 positioned against the external surface 327 of the first plate 322.
  • the metal part 340 has a diameter greater than the external diameter of pillar 321.
  • the metal part 340 is fixed to the first plate 322 via fixing screws 341 located on the periphery of the metal part 340.
  • the fixing screws 341 pass through the first plate 322 and the metal part 340.
  • the fixing screws 341 each comprise a external end 342 which is fixed to the metal part 340, for example by riveting, and an internal end 343 which includes a screw head which is housed in a countersink 323 formed in the internal surface 324 of the first plate 322.
  • the support element 420 differs from that of the in that it comprises a first metal part 440 positioned against the external surface 427 of the first plate 422 and fixed against the external surface 427 via fixing screws 441.
  • the support element 420 further comprises a second metal part 460 located opposite the first metal part 440.
  • the second metal part 460 is positioned against the internal surface of the receiving flange 432 and fixed against the receiving flange 432 via fixing screws 444.
  • the first metal part 440 comprises a ball head 438 forming a protuberance from the external surface 445 and the second metal part 460 comprises a base 462 projecting from the internal surface 461 of the second metal part 460, the base comprising the cup of ball joint 439.
  • the ball joint head 438 is housed in the ball joint cup 439.
  • the first metal part 440, the second metal part 460 and the receiving flange 432 have for example an identical or similar diameter.
  • the screw 433 passes through the first plate 422, the first metal part 440, the ball head 438, the ball joint cup 439 and the second metal part 460.
  • the screw 433 has an external end which is fixed in the second metal part 460.
  • the elastic member 437 is replaced by a spherical washer located in the recess 425 between the screw head 436 and the bottom 426 of the recess 425.
  • the spherical washer has two parts which cooperate with each other via spherical surfaces , which allows mobility of the screw head 436 relative to the first plate 422.
  • the support element 620 differs from that in that the support is a closing plate 631.
  • the ball joint cup 639 is formed in the closing plate 632, at the level of the center of the diameter of the closing plate 632.
  • the fixing rod 633 passes through the first plate 622, the metal part 640 and the closing plate 632.
  • the rod 633 has an outer end 634 fixed in a hole 635 which is provided at the level of the center of the diameter of the closing plate 632 and an inner end fixed via a rod head 636 in the recess 625 made in the first plate 622.
  • the support element 920 differs from that in that it does not include the ball head 438 and the base 452 illustrated on the and in that the elastic member 837 is positioned between the first metal part 940 and the second metal part 960.
  • the fixing of the threaded rod 933 to the first metal part 940 and to the second metal part 960 is for example carried out in a manner similar to the embodiment illustrated via the , that is to say via screw-nut systems.
  • connection device as illustrated with Figures 15 to 23 can be applied to the tank walls of Figures 2 to 11.
  • the bolts comprising the nuts 82 illustrated on the can be replaced by a connecting device of the embodiments illustrated with Figures 15 to 23.
  • the aforementioned wall 11, comprising one or more aforementioned supporting elements, is intended to be integrated into a sealed and thermally insulating tank for storing a liquefied gas.
  • the liquefied gas intended to be stored in the tank may in particular be liquid hydrogen which has the particularity of being stored at approximately -253°C at atmospheric pressure.
  • Such a tank is fixed against a supporting structure 1 as illustrated with the .
  • the secondary sealing membrane 113 of the first tank wall 111 is connected to the secondary sealing membrane of the second tank wall 211 in the connection zone 92.
  • the primary sealing membrane 115 of the first tank wall 111 is connected to the primary sealing membrane of the second tank wall 211 in the connection zone 92.
  • the first tank wall 111 and the second tank wall 211 each comprise, at the level of the primary thermally insulating barrier, a first row 95 of support elements supporting the primary sealing membrane which extends parallel to the edge formed at the intersection between the first and the second walls and whose support elements extend in the direction of thickness of their respective wall, between the secondary sealing membrane 113 and the primary sealing membrane 115.
  • the first tank wall 111 and the second tank wall 211 each further comprise, at the level of the primary thermally insulating barrier, a second row 96 of support elements, parallel to the first row, the support elements of which also extend according to the direction of thickness of their respective wall.
  • the support elements of each second row 96 comprise carrying elements 720 comprising for example the characteristics of a support element as illustrated in one of Figures 1 to 23.
  • a cutaway view of a ship 70 for transporting liquefied gas shows a waterproof and thermally insulating tank 71 of generally prismatic shape mounted in the double hull 72 of the ship.
  • the wall of the tank 71 comprises a primary sealing membrane intended to be in contact with the liquefied gas, for example LNG, contained in the tank, a secondary sealing membrane arranged between the primary sealing membrane and the double hull 72 of the ship, and two thermally insulating barriers arranged respectively between the primary sealing membrane and the secondary sealing membrane and between the secondary sealing membrane and the double hull 72.
  • loading/unloading pipes 73 arranged on the upper deck of the ship can be connected, by means of appropriate connectors, to a maritime or port terminal to transfer a cargo of LNG from or to the tank 71.
  • the loading and unloading station 75 is a fixed off-shore installation comprising a movable arm 74 and a tower 78 which supports the movable arm 74.
  • the movable arm 74 carries a bundle of insulated flexible pipes 79 which can connect to the loading/unloading pipes 73.
  • the adjustable movable arm 74 adapts to all ship templates 70.
  • a connection pipe not shown extends inside the tower 78.
  • the loading and unloading station 75 allows the loading and unloading of the ship 70 from or to the onshore installation 77.
  • the underwater pipe 76 allows the transfer of the liquefied gas between the loading or unloading station 75 and the installation on land 77 over a long distance, for example 5 km, which makes it possible to keep the ship 70 at a long distance from the coast during loading and unloading operations.
  • pumps on board the ship 70 and/or pumps fitted to the on-shore installation 77 and/or pumps fitted to the loading and unloading station 75 are used.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Ocean & Marine Engineering (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
EP23805030.6A 2022-11-15 2023-11-10 Wand für einen dichten und wärmeisolierenden behälter Pending EP4619675A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2211854A FR3141983B1 (fr) 2022-11-15 2022-11-15 Paroi pour une cuve étanche et thermiquement isolante
PCT/EP2023/081477 WO2024104916A1 (fr) 2022-11-15 2023-11-10 Paroi pour une cuve étanche et thermiquement isolante

Publications (1)

Publication Number Publication Date
EP4619675A1 true EP4619675A1 (de) 2025-09-24

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EP (1) EP4619675A1 (de)
JP (1) JP2025537791A (de)
KR (1) KR20250110255A (de)
CN (1) CN120359377A (de)
AU (1) AU2023381732A1 (de)
CL (1) CL2025001433A1 (de)
FR (1) FR3141983B1 (de)
TW (1) TW202434830A (de)
WO (1) WO2024104916A1 (de)

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Publication number Priority date Publication date Assignee Title
FR3154164A1 (fr) * 2023-10-13 2025-04-18 Gaztransport Et Technigaz Paroi pour cuve étanche et thermiquement isolante
CN118881952B (zh) * 2024-09-14 2025-11-07 中国长江三峡集团有限公司 一种低温工质用缓冲储存罐的晃荡效应缓解控制方法

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
FR2739675B1 (fr) * 1995-10-05 1997-11-07 Gaztransport Et Technigaz Cuve terrestre pour le stockage du liquide a basse temperature
FR2973097B1 (fr) 2011-03-23 2013-04-12 Gaztransp Et Technigaz Element calorifuge pour paroi de cuve etanche et thermiquement isolante
KR101435381B1 (ko) * 2011-12-16 2014-08-29 삼성중공업 주식회사 단열 보드와 그 설치 방법, 상기 단열 보드를 구비한 액화 천연 가스 저장 탱크
WO2013169076A1 (ko) * 2012-05-11 2013-11-14 대우조선해양 주식회사 이중구조의 액화천연가스 저장용기
FR3004234B1 (fr) * 2013-04-09 2016-07-29 Gaztransport Et Technigaz Cuve etanche et isolante ayant une barriere d'etancheite susceptible localement d'un glissement par rapport a la barriere isolante
FR3077865B1 (fr) 2018-02-09 2020-02-28 Gaztranport Et Technigaz Cuve etanche et thermiquement isolante comportant des bouchons isolants inter-panneaux
FR3085199B1 (fr) * 2018-08-24 2020-07-17 Gaztransport Et Technigaz Paroi de cuve etanche et thermiquement isolante
WO2021028624A1 (fr) 2019-08-09 2021-02-18 Gaztransport Et Technigaz Procédé de fabrication d'une paroi de cuve étanche et thermiquement isolante comportant des bouchons isolants inter-panneaux
FR3115093B1 (fr) * 2020-10-09 2023-04-28 Gaztransport Et Technigaz Cuve étanche et thermiquement isolante

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FR3141983B1 (fr) 2025-01-31
JP2025537791A (ja) 2025-11-20
TW202434830A (zh) 2024-09-01
CL2025001433A1 (es) 2025-08-22
CN120359377A (zh) 2025-07-22
AU2023381732A1 (en) 2025-05-29
FR3141983A1 (fr) 2024-05-17
KR20250110255A (ko) 2025-07-18
WO2024104916A1 (fr) 2024-05-23

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