EP4296339A1 - Metallbearbeitungsflüssigkeitskonzentrat - Google Patents
Metallbearbeitungsflüssigkeitskonzentrat Download PDFInfo
- Publication number
- EP4296339A1 EP4296339A1 EP23178960.3A EP23178960A EP4296339A1 EP 4296339 A1 EP4296339 A1 EP 4296339A1 EP 23178960 A EP23178960 A EP 23178960A EP 4296339 A1 EP4296339 A1 EP 4296339A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- metalworking fluid
- water
- fluid concentrate
- ethylene oxide
- additives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005555 metalworking Methods 0.000 title claims abstract description 47
- 239000012530 fluid Substances 0.000 title claims abstract description 44
- 239000012141 concentrate Substances 0.000 title claims abstract description 32
- -1 fatty acid ester Chemical class 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000203 mixture Substances 0.000 claims abstract description 36
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002253 acid Substances 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 239000000194 fatty acid Substances 0.000 claims abstract description 20
- 229930195729 fatty acid Natural products 0.000 claims abstract description 20
- 230000007797 corrosion Effects 0.000 claims abstract description 19
- 238000005260 corrosion Methods 0.000 claims abstract description 19
- 239000003112 inhibitor Substances 0.000 claims abstract description 18
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000003139 biocide Substances 0.000 claims abstract description 14
- 239000005069 Extreme pressure additive Substances 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- 239000006260 foam Substances 0.000 claims abstract description 12
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 10
- 239000006174 pH buffer Substances 0.000 claims abstract description 10
- 239000003349 gelling agent Substances 0.000 claims abstract description 9
- 229920001400 block copolymer Polymers 0.000 claims abstract description 6
- 229920005604 random copolymer Polymers 0.000 claims abstract description 5
- 239000005076 polymer ester Substances 0.000 claims abstract description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 28
- 150000003839 salts Chemical class 0.000 claims description 17
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 claims description 16
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 15
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 claims description 12
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 230000002209 hydrophobic effect Effects 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 125000000129 anionic group Chemical group 0.000 claims description 9
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 8
- 150000002334 glycols Chemical class 0.000 claims description 8
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 8
- 229940073769 methyl oleate Drugs 0.000 claims description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
- 239000012964 benzotriazole Substances 0.000 claims description 7
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 6
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 claims description 6
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 6
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 3
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 claims description 3
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 claims description 3
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 claims description 3
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 claims description 3
- AHZILZSKKSPIKM-UHFFFAOYSA-N 3-aminooctan-4-ol Chemical compound CCCCC(O)C(N)CC AHZILZSKKSPIKM-UHFFFAOYSA-N 0.000 claims description 3
- 101000962041 Homo sapiens Neurobeachin Proteins 0.000 claims description 3
- 102100039234 Neurobeachin Human genes 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 125000005608 naphthenic acid group Chemical class 0.000 claims description 3
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 claims description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 2
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 2
- 150000002826 nitrites Chemical class 0.000 claims description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 239000005077 polysulfide Substances 0.000 claims description 2
- 229920001021 polysulfide Polymers 0.000 claims description 2
- 150000008117 polysulfides Polymers 0.000 claims description 2
- 239000011684 sodium molybdate Substances 0.000 claims description 2
- 235000015393 sodium molybdate Nutrition 0.000 claims description 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 27
- 229910052751 metal Inorganic materials 0.000 description 18
- 239000002184 metal Substances 0.000 description 18
- 238000009472 formulation Methods 0.000 description 17
- 238000005461 lubrication Methods 0.000 description 15
- 239000012071 phase Substances 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 8
- 239000002173 cutting fluid Substances 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 238000005491 wire drawing Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 244000188595 Brassica sinapistrum Species 0.000 description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 2
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229960002303 citric acid monohydrate Drugs 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 239000010730 cutting oil Substances 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 150000002462 imidazolines Chemical class 0.000 description 2
- 229920005610 lignin Chemical class 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical class CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- BCFOOQRXUXKJCL-UHFFFAOYSA-N 4-amino-4-oxo-2-sulfobutanoic acid Chemical class NC(=O)CC(C(O)=O)S(O)(=O)=O BCFOOQRXUXKJCL-UHFFFAOYSA-N 0.000 description 1
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 150000002303 glucose derivatives Chemical class 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- NJGCRMAPOWGWMW-UHFFFAOYSA-N octylphosphonic acid Chemical compound CCCCCCCCP(O)(O)=O NJGCRMAPOWGWMW-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical class CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
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- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
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- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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- C10M2229/04—Siloxanes with specific structure
- C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
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- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/011—Cloud point
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
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- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
- C10N2050/011—Oil-in-water
Definitions
- the present invention relates to a metalworking fluid, and more particularly a metalworking fluid comprising a blend of synthetic (water-based) and semi-synthetic (oil-based) components.
- Metalworking fluids have many applications within industry, such as destructive metalworking (chips of metal are produced, such as in milling or grinding) and deformation metalworking (chips of metal are not produced, such as in rolling), as well as more specific applications such as wire drawing.
- the metalworking fluids are used to cool and lubricate during metalworking operations.
- Such fluids typically comprise an oil-based (oleaginous) component, an aqueous component and emulsifier.
- the products are typically supplied as concentrates which are diluted with water by the user. In use the continuous water phase provides cooling, whilst the oil droplets plate out on metal surfaces to form a lubricating film between the metal being worked and the tool.
- emulsifiers to create an emulsion.
- Surfactants are typically used as emulsifiers, with sufficient surfactant included to ensure that the emulsion forms completely.
- metalworking fluids were soluble oils, typically comprising a majority of mineral oil together with other components such as emulsifiers, corrosion inhibitors and other additives.
- the oil was mixed with water to form an emulsion.
- additives such as sodium emulsifiers, sodium EDTA, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfit
- metalworking fluid is known as a "fully synthetic" fluid, all components of which are soluble in water.
- the lubrication is provided by compounds whose solubility in water is inversely proportional to temperature, such that at room temperature they are soluble in water, whereas as the temperatures typically encountered at the metalworking surface due to friction (80°C or more) they plate out to form a lubricating film on the metal surface.
- examples of such compounds are polyelkylene glycols (PAGs), which are copolymers of ethylene oxide and propylene oxide.
- the present invention provides a metalworking fluid concentrate comprising
- composition of the invention provides excellent lubrication in a wide range of applications including wire drawing, gives low deposits during use and also has excellent long-term stability.
- water-soluble means that no more than 0.5wt% of a compound is left undissolved in the aqueous phase when the compound is either dissolved in water or reacts in water to form a salt which itself dissolves.
- Component (A) is a blend of a C 8 -C 30 alcohol with a fatty acid ester R 1 CO 2 R 2 where R 1 is a C 8 -C 30 acid residue and R 2 is a C 1 -C 12 alcohol residue.
- the alcohol is preferably a C 12 -C 24 , more preferably a C 14 -C 20 alcohol, with C 16 being particularly preferred.
- the acid residue R 1 is preferably a C 12 -C 24 hydrocarbyl group, more preferably C 14 -C 20 , with C 16 -C 18 being particularly preferred.
- the alcohol residue R 2 is preferably a C 1 -C 8 hydrocarbyl group. Examples of the alcohol of which R 2 is the residue are methanol, 2-ethylhexanol, ethanol, butanol and isotridecanol.
- Amounts of component (A1) range from 1.5 to 3.7wt%, preferably from 1.8 to 3.5wt% and more preferably from 2 to 3wt%.
- Component (A2) is a surfactant, which means anything capable of acting as an emulsifier.
- the surfactant is preferably nonionic, and may have a hydrophobic portion of C 10 -C 28 , preferably C 14 -C 24 , and more preferably C 16 -C 20 chain length, optionally modified with 1-20, preferably 4-16 and more preferably 6-12 units of a hydrophobic polyalkoxylate chain, plus a hydrophilic portion comprising a polyalkoxylate.
- the nonionic surfactant may comprise a C 10 -C 28 , preferably C 14 -C 24 and more preferably C 16 -C 20 fatty acid esterified with a polyfunctional alcohol.
- the surfactant may alternatively be anionic, in which case it may have a hydrophobic portion of C 10 -C 28 , preferably C 14 -C 24 , and more preferably C 16 -C 20 chain length, optionally modified with 1-20, preferably 4-16 and more preferably 8-10 units of a hydrophobic polyalkoxylate chain, and capped with an anionic group such as carboxylate, sulfate, sulfonate, sulfosuccinate or phosphate, with carboxylate, sulfonate and phosphate being preferred, of which carboxylate and phosphate are most preferred.
- a further list of possible surfactants includes C 16 -C 18 fatty alcohol ethoxylates - with an ethoxylation range of 0-9 moles (fatty alcohol polyglycol ethers); C 16 -C 18 fatty alcohol ethoxylate and propoxylate; C 6 /C 8 /C 16 -C 18 alkyl polyoxyethylene ether carboxylic acids with a 2 to 9 mole ethoxylation range; alkyl ether ethoxylate mono phosphate esters - alkyl chain C18 , with a 2 to 5 mole ethoxylation range; ethoxylated oleine with a 6/9 mole ethoxylation range; and polyethylene glycol esters of C 16 -C 18 fatty acids. Combinations of various surfactants may be particularly advantageous.
- surfactants include alkanolamides, alkylaryl sulfonates, alkylaryl sulfonic acids, amine oxides, amide and amine soaps, block copolymers, carboxylated alcohols, carboxylic acids/fatty acids, ethoxylated alcohols, ethoxylated amines/amides, ethoxylated fatty acids, ethoxylated fatty esters and oils, ethoxylated phenols, fatty amines and esters, glycerol esters, glycol esters, imidazolines and imidazoline derivatives, lignin and lignin derivatives, maleic or succinic anhydrides, methyl esters, monoglycerides and derivatives, naphthenic acids, olefin sulfonates, phosphate esters, polyalkylene glycols, polyols, polymeric (polysaccharides, acrylic acid, acrylamide), propoxylated &
- nonionic surfactants are fatty alcohol alkoxylates, polyethylene glycol esters, sorbitan esters and sorbitan ester alkoxylates.
- anionic surfactants are alkyl ether carboxylates, sulfosuccinates, sulphonates, alkyl phosphate esters and alkyl ether phosphate esters.
- Combinations of surfactants may also be particularly advantageous.
- Amounts of component (A2) range from 1.5 to 3.7wt%, preferably from 1.8 to 3.5wt% and more preferably from 2 to 3wt%.
- Types of additives include glycols and glycol ethers to prevent gelling, foam control agents, anti-wear additives, extreme pressure additives, pH buffers and biocides.
- Biocides include, but are not limited to, formaldehyde releasing agents including ortho-formal, hexahydratriazine and derivatives, methylene bis morpholene, oxazoladine and derivatives, isothiazolinones and derivatives and iodo propyl butyl carbamate-fungicide.
- formaldehyde releasing agents including ortho-formal, hexahydratriazine and derivatives, methylene bis morpholene, oxazoladine and derivatives, isothiazolinones and derivatives and iodo propyl butyl carbamate-fungicide.
- Extreme pressure additives include, but are not limited to, chlorinated and sulfurized fatty acids and esters, polysulfides, organophosphates, and neutralized phosphate esters.
- foam control agents include, but are not limited to, methyl silicone oil, fluorosilicone oil, polyacrylate and the like.
- the total amount of all components (A3) ranges from 0.5 to 1.8wt%, preferably from 0.6 to 1.5wt% and more preferably from 0.7 to 1.4wt%.
- Component (B1) is an amine which is soluble in water at room temperature.
- Examples include aminomethylpropanol (AMP-95), 3-amino-4-octanol, diglycolamine (DGA), monoethanolamine (MEA), monoisopropanolamine (MIPA), butylethanolamine (NBEA), dicylclohexylamine (DCHA), diethanolamine (DEA), butyldiethanolamine (NBDEA), triethanolamine (TEA), and methylpentamethylenediamine.
- Amounts of component (B1) range from 6 to 15wt%, preferably from 6.5 to 10wt% and more preferably from 7 to 8wt%. Alternative preferred ranges are from 9 to 12wt%, preferably from 10 to 12wt%.
- Corrosion inhibitors are chemical compounds which, when added at low concentrations, inhibit the corrosion of metals and alloys. They generally function by either forming a passivation layer on the metal, or by inhibiting either the oxidation or reduction part of the redox corrosion system (anodic and cathodic inhibitors), or by scavenging dissolved oxygen. Different metals typically require different corrosion inhibitors.
- corrosion inhibitors examples include alkylphosphonic acids, alkali and alkanolamine salts of carboxylic acids, undecandioic/dodecandioic acid and its salts, C 4 -C 22 carboxylic acids and their salts, tolytriazole and its salts, benzotriazole and its salts, imidazoline and its salts, alkanolamines and amides, sulfonates, alkali and alkanolamine salts of naphthenic acids, phosphate ester amine salts, alkali nitrites, alkali carbonates, carboxylic acid derivatives, alkylsulfonamide carboxylic acids, arylsulfonamide carboxylic acids, fatty sarkosides, phenoxy derivatives and sodium molybdate.
- a further list of possible corrosion inhibitors which can be used includes polycarboxylic acid compounds, polymeric phosphoric acid compounds and benzotriazole. but are not limited to amine/alkali salts of short chain carboxylic mono acids, di acids and tri acids, short chain acidic phosphate esters, including alkoxylated esters, semi-succinate half esters, amide-carboxylic acid salts, fatty amides, and amine and alkali sulphonates or their derivatives.
- Inhibitors for yellow metals include benzotriazole or its derivatives and tolutriazole or its derivatives.
- Suitable esters include, but are not limited to TMP (trimethylol propane) mono, di and tri esters of C 8 - C 18 fatty acids, glycol esters of predominantly olely fatty acids, methyl or isopropyl esters of predominantly olely fatty acids or triglycerides, natural triglycerides, such as rapeseed, and modified natural oils such as blown rapeseed.
- TMP trimethylol propane
- di and tri esters of C 8 - C 18 fatty acids glycol esters of predominantly olely fatty acids, methyl or isopropyl esters of predominantly olely fatty acids or triglycerides
- natural triglycerides such as rapeseed
- modified natural oils such as blown rapeseed.
- Preferred cast iron corrosion inhibitors include undecandioic/dodecandioic acid and its salts.
- Preferred yellow metal corrosion inhibitors include tolytriazole sodium salts.
- Preferred aluminum corrosion inhibitors include octanephosphonic acid and citric acid monohydrate.
- Amounts of component (B2) range from 2 to 5wt%, preferably from 2.1 to 4.5wt% including ranges from 2.2 to 2.8wt% and from 4.0 to 4.5wt%, with the higher range being for applications involving copper.
- the amounts and types of corrosion inhibitor required for different metals are well understood by those skilled in the art.
- Component (B3) is a compound having a solubility in water which varies inversely with temperature. As stated above it is selected from ethylene oxide or propylene oxide block copolymers, ethylene oxide or propylene oxide random copolymers, ethylene oxide or propylene oxide polymer esters and ethylene oxide ethers. Examples of such compounds are the reaction products of alcohols and alkylene oxides commonly known as polyalkylene glycols (PAGs). Polyalkylene glycols are well known as lubricants in many applications including metalworking fluids due to their high thermal and oxidative stability, excellent lubricity and high film strength/load capacity, as well as good anti-wear properties and shear stability.
- PAGs polyalkylene glycols
- PAGs are random or block copolymers containing ethylene oxide (EO) and propylene oxide (PO) units.
- the cloud point defined as the temperature at which the PAG in a 1% aqueous solution comes out of solution, is dependent primarily on the EO content, which can range from 10% to 80%, and is typically between 20% and 75%.
- the cloud point may vary from 20°C to 90°C, with values in the range 40°C to 90°C being preferred.
- the exact PAG used may depend on the cloud point required, which in turn depends on the intended final application of the concentrate.
- Amounts of component (B3) range from 5 to 15wt%, preferably from 6 to 14wt% and more preferably from 7 to 13wt%.
- Component (B4) is water, and is present in an amount of 60-80wt%, preferably 69-78wt%, more preferably 70-77wt%. Alternative prefered ranges are 60-72wt%, preferably 62-70wt%.
- Each of the above components of the concentrate (A1)-(A3) and (B 1)-(B3) may comprise either a single compound or more than one compound.
- a preferred metalworking fluid concentrate formulation comprises
- Formulations which are particularly suited for metalworking operations at relatively high temperatures, such as those involving ferrous metals, preferably contain amounts of the various components listed above as follows:
- a particularly preferred formulation suited for metalworking operations at relatively high temperatures is a metalworking fluid concentrate comprising
- Formulations which are particularly suited for metalworking operations at lower temperatures typically contain lower amounts of water, because the lower operating temperature means that the PAG reaches its cloud point more slowly and hence additional lubricant components are required. If the worked metal is copper, such as in some wire drawing, such formulations also require higher amounts of corrosion inhibitors due to the presence of corrosive copper ions.
- Preferred formulations for such operations contain amounts of the various components listed above as follows:
- a particularly preferred formulation for lower temperature operation is a metalworking fluid concentrate comprising
- the metalworking fluid concentrate is preferably formulated by mixing components (A1)-(A3) and (B1-B4) as two separate formulations or phases (A) and (B), which are then combined to form the final formulation.
- components (B1) and (B2) may be dissolved in water (B4), and the PAG (B3) dissolved in the resulting solution.
- Pre-blended components (A1)-(A3) may then be added.
- Components (A1)-(A3) may be regarded as oleaginous components, and (B1)-(B4) as aqueous components similar to a fully synthetic metalworking fluid.
- a key feature of the present invention is that the oleaginous phase (A) and the aqueous phase (B) are capable of forming a stable emulsion when mixed together.
- the precise amounts of component (A2) can be adjusted in order to optimise the long-term stability.
- the metalworking fluid concentrate is diluted with water in a known manner, either prior to or during use. Accordingly a further aspect of the invention provides a metalworking fluid comprising 3-20wt% of the above metalworking fluid concentrate and 80-97wt% of water. Preferably the concentrate comprises 10-15wt% of the metalworking fluid.
- a drawing oil concentrate was formulated by forming an oleaginous phase (A) comprising components (A1)-(A3) and an aqueous phase (B) comprising components (B1)-(B4).
- the two phases were then mixed together to form an emulsion having the composition shown in Table 1: TABLE 1 Component Compound wt% A1 G16 Guerbet alcohol 1.8 A1 CE-1875 (methyl oleate/methyl palmitate) 0.9 A2 Oleth-9-carboxyate 0.9 A2 Oxirane, 2-methyl, polymer with oxirane, hexadecyl ether (CAS 9087-53-0) 1.8 A3 Foamban ® 1840 0.1 A3 Ethyl diglycol ether 0.75 B1 Triethanolamine 90% 14.44 B2 Polycarboxylic acid 50% 4.0 B2 Benzotriazole 0.4 B3 PAG W270 (75% EO, cloud point 85°C) 9.0 B4 Water 65.91
- the emulsion was diluted in both deionized water and also water containing 500ppm Ca salts to a concentration of 10%. In both cases the result was a bright, semi-translucent and stable emulsion.
- Example 1 provides lubrication slightly more rapidly than the fully synthetic oil, and much more rapidly than a soluble oil. Overall lubrication was also significantly better than both commercial oils.
- Example 2 is a general purpose metal-cutting fluid designed for use with both ferrous and non-ferrous metals. It was formulated in the same way as Example 1, and has the composition shown in Table 3: TABLE 3 Component Compound wt% A1 G16 Guerbet alcohol 1.8 A1 CE-1875 (methyl oleate/methyl palmitate) 0.9 A2 Oleth-9-carboxyate 0.1 A2 C 16 -C 18 phosphate ester 2.7 A3 Foamban ® 1840 0.3 A3 20% bisisothiazolinone in glycol (biocide) 1.2 A3 Ethyl diglycol ether 0.75 B1 Triethanolamine 90% 7.8 B2 Polycarboxylic acid 50% 2.5 B3 Pluronic PE6400 (PO/EO block, -40% PEG) 9.0 B4 Water 72.95
- Example 2 The stability of this formulation was found to be similar to that of Example 1.
- the performance of this formulation was compared with two commercially available metalworking fluid concentrates, one a soluble oil and the other a semi-synthetic cutting fluid, using a Reichert wear tester as in Example 1. All formulations were used as a 10% dilution in water. The results are shown in Table 4 below: TABLE 4 Noise drop-off time (secs) % weight loss of bearing pin Example 2 21.5 14.9 Commercial soluble cutting oil 100 81.7 Commercial semi-synthetic cutting oil 100 77.4
- Example 2 provides lubrication much more rapidly than both commercial oils, and overall lubrication was also significantly better than both commercial oils.
- Example 3 is a metal-cutting fluid designed for use with non-ferrous metals, which are typically softer and therefore generate less heat. As a result the temperature of the working surface rises to the cloud point of component B3 more slowly, thereby requiring a higher degree of lubrication from the oleaginous phase. Consequently the amount of oleaginous phase is higher and the amount of water lower in this Example. Such formulations may also require a higher level of corrosion inhibitor due to the presence of corrosive copper ions from the worked metal.
- Example 3 was formulated in the same way as Example 1, and has the composition shown in Table 5: TABLE 5 Component Compound wt% A1 G16 Guerbet alcohol 2.42 A1 CE-1875 (methyl oleate/methyl palmitate) 1.21 A2 Oleth-9-carboxyate 1.21 A2 Oxirane, 2-methyl, polymer with oxirane, hexadecyl ether (CAS 9087-53-0) 2.42 A3 Foamban ® 1840 0.13 A3 20% bisisothiazolinone in glycol (biocide) 1.2 A3 Ethyl diglycol ether 1.01 B1 Triethanolamine 90% 11.9 B2 Citric acid monohydrate 0.5 B2 Polycarboxylic acid 50% 2.5 B3 Pluronic RPE1740 (EO/PO block. -40% PEG) 9.0 B4 Water 66.5
- Example 2 The stability of this formulation was found to be similar to that of Example 1.
- the performance of this formulation was compared with two commercially available metalworking fluid concentrates, one a non-ferrous cutting fluid and the other a semi-synthetic cutting fluid, using a Reichert wear tester as in Example 1. All formulations were used as a 10% dilution in water. The results are shown in Table 6 below: TABLE 6 Noise drop-off time (secs) % weight loss of bearing pin Example 3 11 9.0 Commercial soluble cutting fluid 100 98.3 Commercial semi-synthetic cutting fluid 100 77.4
- Example 3 provides lubrication much more rapidly than both commercial oils, and overall lubrication was also significantly better than both commercial oils.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000053701A1 (en) * | 1999-03-05 | 2000-09-14 | Castrol Limited | Lubricant composition comprising a carboxy-terminated reaction product |
| EP2075319A1 (de) * | 2007-12-10 | 2009-07-01 | Nalco Company | Formulierung einer Metallverarbeitungsflüssigkeit |
| CN109777584A (zh) * | 2017-11-13 | 2019-05-21 | 杨轲宇 | 一种含有氧化石墨烯切削液及其制备方法 |
| WO2022099300A1 (en) * | 2020-11-05 | 2022-05-12 | Ardagh Metal Beverage USA Inc. | Metalworking formulations with corrosion inhibitor formulations |
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| GB846839A (en) * | 1959-01-30 | 1960-08-31 | Shell Res Ltd | Method and lubricating composition for metal rolling, cutting and drilling |
| CN107312605A (zh) * | 2016-04-27 | 2017-11-03 | 上海金艺检测技术有限公司 | 高性能全合成切削液及其制备方法 |
| CN110684585B (zh) * | 2018-07-05 | 2021-10-29 | 厦门油典集团有限公司 | 一种微乳型切削液及其制备方法 |
| CN113652290A (zh) * | 2021-08-09 | 2021-11-16 | 安美科技股份有限公司 | 一种长寿命镁合金切削液的制备及其使用方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000053701A1 (en) * | 1999-03-05 | 2000-09-14 | Castrol Limited | Lubricant composition comprising a carboxy-terminated reaction product |
| EP2075319A1 (de) * | 2007-12-10 | 2009-07-01 | Nalco Company | Formulierung einer Metallverarbeitungsflüssigkeit |
| CN109777584A (zh) * | 2017-11-13 | 2019-05-21 | 杨轲宇 | 一种含有氧化石墨烯切削液及其制备方法 |
| WO2022099300A1 (en) * | 2020-11-05 | 2022-05-12 | Ardagh Metal Beverage USA Inc. | Metalworking formulations with corrosion inhibitor formulations |
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| GB202209118D0 (en) | 2022-08-10 |
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