EP4294901A1 - Composition de matériau combustible pour une bougie - Google Patents
Composition de matériau combustible pour une bougieInfo
- Publication number
- EP4294901A1 EP4294901A1 EP21707926.8A EP21707926A EP4294901A1 EP 4294901 A1 EP4294901 A1 EP 4294901A1 EP 21707926 A EP21707926 A EP 21707926A EP 4294901 A1 EP4294901 A1 EP 4294901A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- oil
- fuel composition
- candle
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 239000000463 material Substances 0.000 title abstract description 12
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 23
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 23
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000008117 stearic acid Substances 0.000 claims abstract description 23
- 239000004204 candelilla wax Substances 0.000 claims abstract description 19
- 235000013868 candelilla wax Nutrition 0.000 claims abstract description 19
- 229940073532 candelilla wax Drugs 0.000 claims abstract description 19
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 8
- 235000019198 oils Nutrition 0.000 claims abstract description 8
- 239000000446 fuel Substances 0.000 claims description 39
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 27
- 239000008158 vegetable oil Substances 0.000 claims description 27
- 239000002285 corn oil Substances 0.000 claims description 9
- 235000005687 corn oil Nutrition 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 8
- 239000000341 volatile oil Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 239000003205 fragrance Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 235000019486 Sunflower oil Nutrition 0.000 claims description 3
- 239000002600 sunflower oil Substances 0.000 claims description 3
- 235000016401 Camelina Nutrition 0.000 claims description 2
- 244000197813 Camelina sativa Species 0.000 claims description 2
- 239000000944 linseed oil Substances 0.000 claims description 2
- 235000021388 linseed oil Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 235000005713 safflower oil Nutrition 0.000 claims description 2
- 239000003813 safflower oil Substances 0.000 claims description 2
- 230000007928 solubilization Effects 0.000 claims description 2
- 238000005063 solubilization Methods 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000010497 wheat germ oil Substances 0.000 claims description 2
- 239000008171 pumpkin seed oil Substances 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 description 14
- 239000001993 wax Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 6
- 239000004071 soot Substances 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 244000178289 Verbascum thapsus Species 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 241000241413 Propolis Species 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229920000704 biodegradable plastic Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000005800 cardiovascular problem Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000004130 lipolysis Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 229940069949 propolis Drugs 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C5/00—Candles
- C11C5/002—Ingredients
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C5/00—Candles
- C11C5/002—Ingredients
- C11C5/004—Ingredients dyes, pigments; products giving a coloured flame
Definitions
- the invention relates to a fuel composition for a candle, comprising vegetable oil, candelilla wax and stearic acid, and a process for producing the same.
- the main candle raw materials used are paraffins (saturated hydrocarbons), stearins (fatty acids), beeswax and triglycerides (hardened or partially hydrogenated fats), alone or in a mixture.
- n-paraffins is used as a collective term for saturated aliphatic hydrocarbons, where straight-chain or branched chains (isoparaffins) can be present.
- the n-paraffins are solid and waxy from Cn onwards.
- Waxes a distinction is made between natural waxes of plant or animal origin, chemically modified and synthetic waxes. Waxes can normally be kneaded at 20°C, especially waxes with a softening point such as paraffin or beeswax, above 40°C they melt without decomposition and they are solid to brittle and hard and coarse to fine crystalline.
- Step is generally understood to mean a mixture of stearic acid and palmitic acid which results from the fatty acid mixture formed during lipolysis after the liquid oleic acid has been separated off and cleaned.
- a candle In most cases, a candle consists of a wick embedded in a block of wax, with the wax providing the fuel for the candle to burn.
- Paraffin has many properties that make it suitable for use in a candle. Paraffin, as used in candles, is typically highly refined and is in a crystalline state at room temperature. Paraffin-based candles are typically solid in consistency and may be formed into a free-standing columnar structure called a pillar candle, which is then placed on candlesticks and the like.
- paraffin is an inexpensive raw material and meets most of the burning needs of a candle, making it an economically attractive choice candle material makes.
- paraffin-based candles have the disadvantage that they are based on a non-renewable material.
- burning paraffin candles releases soot and other pollutants that can be harmful to health and the environment. Soot can cause respiratory problems and aggravate diseases such as cardiovascular problems.
- the products of combustion can damage works of art, such as those where candles are lit during religious worship, and their preservation can be impaired.
- paraffin since paraffin is not a biodegradable product, the unburned residue of such candles pollutes and harms the environment.
- US Pat. No. 6,645,261 relates to candle waxes consisting of palmitic acid and hardened vegetable oil.
- KR 101976807 Bl discloses a liquid candle composition of the gel type, which consists of 78% by weight of vegetable oil, 15% by weight of fragrant plant parts (e.g. lavender), 2% by weight of candelilla wax and 1-2% by weight of each color pigment, propolis and essential oil.
- This composition is placed in any ornamental container fitted with a fixed wick and serves as a home decor in addition to its function as a scented candle.
- a solid candle composition is known from US Pat.
- vegetable oil e.g. corn oil, palm oil or sunflower oil
- fragrance 0-1 parts by weight of at least one antioxidant
- the object of the invention is to provide an inexpensive fuel composition for a candle which consists of renewable, biodegradable and readily available raw materials.
- This ecological composition should also be suitable both for indoor use and for outdoor use, eg for cemetery candles, should burn almost soot-free and have a burning time and performance that is at least equivalent to that of a paraffin candle. Furthermore, compared to the state of Technique in the industrial production of the fuel composition time and cost savings can be achieved.
- the fuel composition for a candle comprising vegetable oil, candelilla wax and stearic acid is creamy in consistency.
- the creamy consistency of the fuel composition makes it possible to provide a candle which is not based on paraffin or petroleum products, but which nevertheless has physical and chemical stability and which also allows outdoor use at temperatures between -20°C and 40°C.
- the fuel composition of vegetable oil, candelilla wax and stearic acid according to the invention is also odorless and non-toxic, burns without soot and pollutants and, in particular, unlike most conventional candle materials, is biodegradable.
- the candelilla wax contained in the fuel composition according to the invention acts as a structuring or lipid thickening agent.
- the formation of crystals in the form of platelets creates a network that can "hold back" oil. This results in a soft, homogeneous and creamy consistency.
- the fuel composition also includes stearic acid, which acts as a consistency agent that contributes to compaction.
- the stearic acid contributes to the hardness of the fuel composition and also increases the burn time.
- the stearic acid can provide better distribution of colorants and fixation of essences if such additional materials are desired in the fuel composition.
- the fuel composition comprises 78-94% by weight vegetable oil, 3-12% by weight candelilla wax and 3-15% by weight stearic acid.
- the proportion of vegetable oil is 85-92% by weight, preferably 88-91% by weight, in particular 90% by weight
- the proportion of candelilla wax is 4-10% by weight, preferably 5- 7% by weight, in particular 5% by weight
- the proportion of stearic acid is 4-12% by weight, preferably 5-8% by weight, in particular 5% by weight.
- the vegetable oil is selected from corn oil, sunflower oil, linseed oil, soybean oil, palm oil, wheat germ oil, safflower oil, camelina oil and mixtures thereof.
- Corn germ oil is particularly preferably used as the vegetable oil for the fuel composition. Unlike the quantitatively limited petroleum products, corn oil is an abundant and renewable resource because corn can be grown in a wide variety of climatic conditions. In contrast to paraffin, it is regenerative, biodegradable, neutral in terms of CO2 emissions and free of sulfur and heavy metals. It is also non-volatile and has a flash point of around 200°C, meaning it is neither flammable nor explosive and can be stored for long periods without risk.
- the stearic acid is preferably a vegetable stearic acid.
- the fuel material for the candle is made entirely of plant-based components.
- Fuel composition also pigments, fragrances and/or essential oils, the total proportion of pigments, fragrances and/or essential oils being ⁇ 2.5% by weight.
- these additional ingredients of the fuel composition are preferably of plant or animal origin.
- the additional ingredients are preferably selected in such a way that soot and pollutant-free combustion of the fuel composition remains guaranteed.
- Another aspect of the invention relates to a method for producing a fuel composition according to the invention, which comprises the following steps:
- the addition of the candelilla wax to the vegetable oil triggers an aggregation process which, by forming a three-dimensional network, causes the oil to be retained or collected.
- This structuring is further reinforced by the addition of stearic acid, so that the oil is immobilized or oil migration is prevented and thus a creamy consistency is achieved.
- the stearic acid can also optimally integrate into the oleogel mixture and unfold its effect.
- a fuel composition of creamy consistency is obtained. Cooling down and putting the candle to rest can expediently already take place in candle containers equipped with a wick, which are preferably made of a biodegradable material. If final filling is planned for a later date, the fuel composition can be made soft or processable for compression or press molding by heating to a temperature of about 35-40° C Piston filling system, candle cups or other suitable containers, where it regains its physically stable consistency after cooling.
- a further aspect of the invention relates to a candle, in particular a cemetery candle, which comprises a fuel composition according to the invention, as described above.
- the candle also includes a biodegradable wick and a biodegradable wrapper, such as a biodegradable bioplastic candle cup.
- the fuel composition has solidified in the candle jar and has a creamy consistency.
- the candle material is physically stable and the "cream” does not run out of the container even if it is turned upside down (turned upside down) and the container is slightly knocked.
- the candle is physically stable to temperature variations from -20°C to 40°C.
- the candle produced according to the invention burns odorless and does not emit soot or other chemical pollutants. Their burning power corresponds to that of a paraffin candle of the same volume.
- the burning time of the candle made from the fuel composition according to the invention is 12 min/g and is therefore longer than that of a paraffin candle (10 min/g on average).
- the residues of the fuel composition remaining after the candle has burned down are completely biodegradable.
- 88 g of corn oil are heated to 80° C. in a container equipped with a stirrer and heater. After reaching this temperature, 5 g of candelilla wax are added and the mixture is stirred while maintaining the temperature of 80°C in order to dissolve any solid particles of the structuring agent in the corn oil. After about 5 minutes the wax is completely dissolved in the vegetable oil. Thereafter, 5 g of stearic acid are added to the mixture while stirring and the temperature is further maintained at 80°C.
- a colored pigment is added and mixed into the composition.
- 1 g essential oil e.g. lavender oil
- the finished mixture is then poured into a jar with a candle wick and left to stand for 24 hours.
- the colored fuel composition has solidified in the candle vessel and has a creamy consistency and a pleasant scent.
- the candle material is physically stable and burns without releasing soot and pollutants.
Abstract
Une composition de matériau combustible pour une bougie, comprenant de l'huile, de la cire de candellila et de l'acide stéarique, a une texture crémeuse. La composition de matériau combustible fournit un matériau de bougie, qui est physiquement stable et complètement biodégradable.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2021/054289 WO2022174929A1 (fr) | 2021-02-22 | 2021-02-22 | Composition de matériau combustible pour une bougie |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4294901A1 true EP4294901A1 (fr) | 2023-12-27 |
Family
ID=74732889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21707926.8A Pending EP4294901A1 (fr) | 2021-02-22 | 2021-02-22 | Composition de matériau combustible pour une bougie |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP4294901A1 (fr) |
WO (1) | WO2022174929A1 (fr) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030061760A1 (en) * | 2001-03-08 | 2003-04-03 | Bernard Tao | Vegetable lipid-based composition and candle |
US6063144A (en) | 1999-02-23 | 2000-05-16 | Calzada; Jose Francisco | Non-paraffin candle composition |
US6645261B2 (en) | 2000-03-06 | 2003-11-11 | Cargill, Inc. | Triacylglycerol-based alternative to paraffin wax |
US6503285B1 (en) | 2001-05-11 | 2003-01-07 | Cargill, Inc. | Triacylglycerol based candle wax |
CA2449562A1 (fr) | 2001-08-02 | 2003-02-13 | Archer Daniels Midland Company | Bougies a base d'huiles vegetales |
EP2724620B1 (fr) * | 2012-10-26 | 2018-01-10 | Walter RAU Neusser Öl und Fett AG | Composition oleochimique |
KR101976807B1 (ko) * | 2017-06-30 | 2019-05-09 | 김해주 | 젤 타입 액상 향초 조성물 |
-
2021
- 2021-02-22 WO PCT/EP2021/054289 patent/WO2022174929A1/fr active Application Filing
- 2021-02-22 EP EP21707926.8A patent/EP4294901A1/fr active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2022174929A1 (fr) | 2022-08-25 |
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