EP4288576A1 - Utilisation d'un alliage nickel-chrome-fer-molybdène sans titane - Google Patents

Utilisation d'un alliage nickel-chrome-fer-molybdène sans titane

Info

Publication number
EP4288576A1
EP4288576A1 EP22708292.2A EP22708292A EP4288576A1 EP 4288576 A1 EP4288576 A1 EP 4288576A1 EP 22708292 A EP22708292 A EP 22708292A EP 4288576 A1 EP4288576 A1 EP 4288576A1
Authority
EP
European Patent Office
Prior art keywords
max
welding
use according
alloy
wire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22708292.2A
Other languages
German (de)
English (en)
Inventor
Helena Alves
Julia BOTINHA
Martin Wolf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VDM Metals International GmbH
Original Assignee
VDM Metals International GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102022101851.2A external-priority patent/DE102022101851A1/de
Application filed by VDM Metals International GmbH filed Critical VDM Metals International GmbH
Publication of EP4288576A1 publication Critical patent/EP4288576A1/fr
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/20Direct sintering or melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/105Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0255Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
    • B23K35/0261Rods, electrodes, wires
    • B23K35/0266Rods, electrodes, wires flux-cored
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/3066Fe as the principal constituent with Ni as next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/055Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0257Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K15/00Electron-beam welding or cutting
    • B23K15/0046Welding
    • B23K15/0086Welding welding for purposes other than joining, e.g. built-up welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/34Laser welding for purposes other than joining
    • B23K26/342Build-up welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/04Welding for other purposes than joining, e.g. built-up welding
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • the invention relates to the use of a titanium-free nickel-chromium-iron-molybdenum alloy with high resistance to pitting and crevice corrosion and high yield point and strength.
  • Alloy 825 is a material with high corrosion resistance used in the oil and gas and chemical industries.
  • the Alloy 825 alloy is sold under the material number 2.4858 and has the following chemical composition: C ⁇ 0.05%, S ⁇ 0.03%, Cr 19.5 - 23.5%, Ni 38 - 46%, Mn ⁇ 1 .0%, Si ⁇ 0.5%, Mo 2.5 - 3.5%, Ti 0.6 - 1.2%, Cu 1.5 - 3.0%, Al ⁇ 0.2%, Fe rest .
  • the PREN summarizes the alloying elements with a positive effect on pitting and crevice corrosion resistance in a material-specific index.
  • Alloy 825 (ISO 18274: Ni8065) has not yet established itself as a welding additive or filler metal (FM) and is rarely used. The reason for this is the difficult workability, which is reflected in the fact that the weld metal often shows hot cracks in the form of solidification and remelting cracks. These are particularly important in the critical applications of the oil and gas industry Processing problems that are inherent to the material represent an exclusion criterion, which means that an alternative welding filler material is often used instead of FM 825, namely the welding filler material FM 625 (ISO 18274: Ni6625). However, the FM 625 has the following disadvantages compared to the FM 825:
  • the weld metal made of FM 625 is less easy to rework mechanically, for example when overturning build-up welds or when leveling excessive weld seams, since it is significantly harder.
  • the hardness of FM 825 weld metal is no more than 250 HV10, while the hardness of FM 625 weld metal is usually 310 HV10.
  • the alloying element niobium poses the risk of undesired gamma" or delta phase formation, particularly during heat treatment after welding (so-called Post Weld Heat Treatment, PWHT) or during hot forming, for example through inductive bending of build-up welded pipes
  • PWHT Post Weld Heat Treatment
  • the formation of gamma" or delta phase is accompanied by a drastic loss of corrosion resistance and/or ductility.
  • the FM 825 has another disadvantage, namely titanium as an alloying element. Titanium can easily oxidize in an uncontrolled manner during fusion welding if the material is in the liquid phase a depletion of the interstitial titanium in the weld metal - and can thus lead to an undefined reduction in its stabilizing effect. In addition, the oxidation or nitration of titanium during welding can lead to a significant reduction in the quality of a welded joint, in that the titanium oxide or titanium nitride particles produced and distributed in the weld metal reduce the strength, ductility and/or corrosion resistance of the weld metal.
  • the alloy is openly melted in continuous or ingot casting, b) to eliminate the segregations caused by the increased molybdenum content, homogenization annealing of the slabs/billets produced at 1150 - 1300°C 15 h to 25 h is carried out, wherein c) the homogenization annealing is carried out in particular after a first hot forming.
  • Alloy 825 CTP has a higher PREN of approx. 42 than Alloy 825 and is not titanium alloyed. Alloy 825 CTP material was developed to overcome the following disadvantages of Alloy 825:
  • the aim of the invention is to bring the material described in DE 102014002401 A1 to a new area of application.
  • Fe residue as well as impurities resulting from the melting process, which is processed as an alloyed solid in the form of wire, strip, rod or powder via the molten phase and is used in wet corrosion applications in the oil and gas and chemical industries.
  • Alloy 825 CTP as a filler material for welding is not described in DE 102014 002 402 A1 and the product forms of welding wire, welding strip and powder (e.g. for additive manufacturing) are not mentioned.
  • the new area of application is characterized by the fact that the material is basically processed via the molten phase.
  • the element carbon is given in the alloy as follows:
  • carbon can be limited as follows:
  • the chromium content is between 20.0 and 23.0%.
  • Cr can preferably be set in the alloy within the spread range as follows:
  • the nickel content is between 39.0 and 44.0%, with preferred ranges being set as follows:
  • the molybdenum content is between > 4.0 - ⁇ 7.0%, whereby, depending on the area of application of the alloy, preferred molybdenum contents can be set as follows:
  • Figure 2 shows a macro cross-section of the welded joint. No hot cracks were found in the weld.
  • the Alloy 825 or FM 825 CTP has been melted in the following compositions:
  • the material FM 825 CTP has been melted on an industrial scale as a welding filler material and further processed into welding filler material, among other things as welding wire with a diameter of 1.00 mm.
  • Welding speed 55 cm/min and pure argon was used as the protective gas.
  • the build-up welding was partially carried out in 2 layers. Both the visual inspection and the dye penetrant inspection showed that neither macro nor micro hot cracks could be detected on the weld metal surface.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Plasma & Fusion (AREA)
  • Arc Welding In General (AREA)
  • Welding Or Cutting Using Electron Beams (AREA)
  • Laser Beam Processing (AREA)
  • Powder Metallurgy (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Conductive Materials (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

L'invention concerne l'utilisation d'un alliage ayant la composition suivante (en % en masse) : max. 0,02 % de C, max. 0,01 % de S, max. 0,03 % de N, de 20,0 à 23,0 % de Cr, de 39,0 à 44,0 % de Ni,de 0,4 à moins de 1,0 % de Mn, de 0,1 à moins de 0,5 % de Si, de plus de 4,0 à moins de 7,0 % de Mo, max. 0,15 % de Nb, de plus de 1,5 à moins de 2,5 % de Cu, de 0,05 à moins de 0,3 % d'Al, max. 0,5 % de Co, de 0,001 à moins de 0,005 % de B et de 0,005 à moins de 0,015% de Mg, le reste étant du Fe et des impuretés résultant de la fusion, lequel alliage est en outre transformé par l'intermédiaire de la phase fondue en tant que solide allié sous la forme d'un fil, d'une bande, d'un barreau ou d'une poudre et utilisé dans l'industrie pétrolière, gazière et chimique dans des applications de corrosion par voie humide.
EP22708292.2A 2021-02-04 2022-01-31 Utilisation d'un alliage nickel-chrome-fer-molybdène sans titane Pending EP4288576A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102021102590 2021-02-04
DE102022101851.2A DE102022101851A1 (de) 2021-02-04 2022-01-27 Verwendung einer titanfreien Nickel-Chrom-Eisen-Molybdän-Legierung
PCT/DE2022/100082 WO2022167042A1 (fr) 2021-02-04 2022-01-31 Utilisation d'un alliage nickel-chrome-fer-molybdène sans titane

Publications (1)

Publication Number Publication Date
EP4288576A1 true EP4288576A1 (fr) 2023-12-13

Family

ID=80682316

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22708292.2A Pending EP4288576A1 (fr) 2021-02-04 2022-01-31 Utilisation d'un alliage nickel-chrome-fer-molybdène sans titane

Country Status (6)

Country Link
US (1) US20240018635A1 (fr)
EP (1) EP4288576A1 (fr)
JP (1) JP2024505366A (fr)
KR (1) KR20230109165A (fr)
CA (1) CA3204358A1 (fr)
WO (1) WO2022167042A1 (fr)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105745345A (zh) * 2014-02-13 2016-07-06 Vdm金属有限公司 无钛合金
DE102014002402A1 (de) 2014-02-13 2015-08-13 VDM Metals GmbH Titanfreie Legierung

Also Published As

Publication number Publication date
WO2022167042A1 (fr) 2022-08-11
CA3204358A1 (fr) 2022-08-11
US20240018635A1 (en) 2024-01-18
JP2024505366A (ja) 2024-02-06
KR20230109165A (ko) 2023-07-19

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