Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K7/00—Use of ingredients characterised by shape
  • C08K7/02—Fibres or whiskers
  • C08K7/04—Fibres or whiskers inorganic
  • C08K7/06—Elements
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/16—Antifouling paints; Underwater paints
  • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
  • C09D5/1612—Non-macromolecular compounds
  • C09D5/1618—Non-macromolecular compounds inorganic
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/16—Antifouling paints; Underwater paints
  • C09D5/1687—Use of special additives
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/20—Diluents or solvents
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/60—Additives non-macromolecular
  • C09D7/61—Additives non-macromolecular inorganic
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/66—Additives characterised by particle size
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/66—Additives characterised by particle size
  • C09D7/69—Particle size larger than 1000 nm
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/02—Elements
  • C08K3/08—Metals
  • C08K2003/085—Copper
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/32—Phosphorus-containing compounds
  • C08K2003/321—Phosphates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K2201/00—Specific properties of additives
  • C08K2201/011—Nanostructured additives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
  • C08K3/015—Biocides
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/34—Silicon-containing compounds
  • C08K3/36—Silica
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/40—Glass
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
  • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
  • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

• BIOCIDAL BIOCIDAL
• ANTISEPTIC ECOLOGICAL NON-SOLVENT COATING
• PARTICLE BIOCIDAL, ANTISEPTIC, ECOLOGICAL NON-SOLVENT COATING, WITH PARTICLE
• the present invention relates to a biocidal coating composition of a surface comprising flat lamellar metal nanoparticles and / or microparticles of diameter less than 45 microns which overlap, suspended in a binder comprising an epoxy resin, a thixotropic agent and a natural diluent chosen from water, preferably demineralized, and / or ethylene glycol and / or denatured alcohol.
• a coating process comprising a step of applying said composition, and G using the coating composition according to the invention to coat a surface.
• Copper has antibacterial properties which have been recognized for centuries. Humans have harnessed the naturally antibacterial properties of copper since the earliest ages. It has been clearly shown by numerous scientific studies carried out for decades that copper is able to eradicate the most resistant bacteria, molds and viruses. It is also known that these virtues are used for the prevention of nosocomial infections.
• paints It is well known to provide this protection by means of so-called "antifouling" paints.
• the major drawback of effective paints is that they contain toxic particles which diffuse into the environment, and new international standards relating to environmental protection are increasingly restrictive from this point of view. Paints meeting these international standards, especially paints intended for pleasure boats, have the disadvantage of being significantly less effective than previous paints, involving more frequent fairings of boats and therefore prolonged periods of immobilization of the latter as well as increased user costs.
• Document FR2894974 discloses a product for protecting a surface intended to be submerged, such as a ship's hull, comprising particles spaced apart from each other, a binder and a diluent.
• Document WO2016 / 081476 discloses a composition comprising non-metallic particles, an epoxy resin and a natural solvent. The absence of a dispersing agent is problematic because said particles are not kept in suspension.
• cylindrical type powders preferably spherical, have a "round" structure, deforming the structure initially treated, forcing a surfacing of said protection, following their application, which generates a significant reduction in the thickness of the coating .
• the biocidal properties generated by the copper find direct application in a large number of technical fields, such as agribusiness, the pharmaceutical industry, the field of health, water sports, sports structures, school complexes, building constructions, establishments open to the public, airports, stations, roof protection among others.
• the copper and / or cupronickel powders used to date have a spherical, disorganized structure, which cannot provide a standard and regular thickness, therefore, not allowing optimal biocidal protection.
• the object of the present invention is therefore to solve the aforementioned technical problems by providing a composition containing nanoparticles and / or microparticles of copper and / or cupro-nickel with flat lamellar structures which overlap, dispersed in a binder comprising in particular an agent. thixotropic allowing regular, controlled application by film of different thicknesses thus creating a “placoid scale” type coating, and also making it possible to preserve the antiseptic properties of copper by eradicating molds, bacteria and viruses, while minimizing costs production by reducing the amount of epoxy binder used to obtain said composition.
• the invention relates to a biocidal coating composition with a surface comprising flat lamellar metallic nanoparticles and / or microparticles with a diameter of less than 45 microns which overlap, suspended in a binder comprising:
• diluent chosen from water, preferably demineralized, and / or ethylene glycol and / or denatured alcohol.
• composition is understood to mean a combination of two or more materials of different types.
• it is the combination of a binder with metallic nanoparticles and / or microparticles, preferably copper and / or cupronickel and / or metallic.
• the composition according to the invention makes it possible not to trap air molecules (oxygen) in the and / or protected supports.
• flat, overlapping lamellar particles By flat, overlapping lamellar particles is understood according to the present invention thin plates, each being of the order of a few nanometers or a few microns, said plate being by their shape, thin, flat, juxtaposed and nested , with respect to each other, forming a smooth mesh without surface defect making it possible to avoid the dispersion of said nanoparticles and / or microparticles in the environment while retaining the antiseptic properties of copper.
• These particles are elongated in shape, resembling a flat ovoid shape, as shown schematically in Figure 3, and shown by microscopic photograph in Figure 4, allowing juxtaposition and nesting between them.
• the coating is referred to in the text as a "placoid scale” type.
• Said “placoid scales” are similar to the subcutaneous denticles of cartilaginous fish such as the scales of Selachians, namely sharks and rays, forming small flattened teeth, overlapping in order to play a hydrodynamic role by making the skin of said fish raincoat.
• said flat lamellar nanoparticles and / or microparticles overlap to allow the coating on which the composition is applied to be made impermeable to external agents such as viruses, bacteria or the various molds that may form.
• the lamellar nanoparticles of the "placoid scale” type ensure homogeneity and a guarantee of continuity of protection between each nanoparticles and / or microparticles, without any air bubbles being trapped.
• nanoparticles and / or microparticles is understood within the meaning of the invention, particles of small sizes, of the order of a few nanometers or a few microns, preferably the size of said nanoparticles is between 5 nm to 9 nm and the size of the microparticles is between 1 ⁇ m to 20 ⁇ m.
• the diameter of said particles used according to the invention is less than 45 microns in size.
• the present invention makes it possible to retain the powerful naturally biocidal and antibacterial properties of copper and / or cupronickel in its raw state once the support has been covered.
• binder is understood to mean a substance which binds the flat lamellar nanoparticles and / or microparticles according to the invention to one another.
• the binder ensures the cohesion of the nanoparticles and / or microparticles for the formation of a "placoid scale” type protection.
• thermosetting resins having good mechanical and chemical properties. These resins include a base and a hardener. They are manufactured by polymerization of epoxy monomers with a hardener (crosslinking agent) which can be based on acid anhydride, phenol or most often amine (polyamine, aminoamide): they are three-dimensional polymers. .
• the epoxy resin being an expensive element, the reduction in its use makes it possible to reduce the costs incurred and that of the coating composition according to the invention.
• the present invention allows, because of its overlapping configuration of the particles to use a less important quantity of epoxy resin, and therefore to achieve significant savings of the main materials of said invention while increasing the initial protection of the nanoparticles and / or microparticles used in the invention. said composition.
• epoxy resin is also meant the polymerization agent thereof.
• An example of a polymerization agent may be that available commercially under the reference RESOLCOAT 1014.
• This epoxy resin and the polymerization agent can also be those commercially available under the references CLEAR COAT / A and CLEAR CO AT / B, respectively, with dilution with trichlorethylene ethylene ketone or methyl ethylene ketone.
• the composition comprises between 1 and 50%, preferably between 5 and 45%, even more preferably between 5 and 35%, by total weight of the composition of said epoxy resin.
• epoxy resins are commercially available under the reference RESOLCOAT 1014, or other brands.
• thixotropic agent is understood according to the invention a dispersing agent, making it possible to maintain the nanoparticles and / or microparticles used in the formulation in the binder in suspension, and to provide them with thixotropic properties, namely to be able to change from a liquid state to a solid state under the effect of constant stress.
• This will allow the composition according to the invention once affixed to the surface to be coated to achieve its biocidal power.
• the thixotropic fluid Left to stand for a long time, the thixotropic fluid will restructure itself and allow it to transform into a more or less viscous product, thus making it possible to keep the metal particles in suspension, Its viscosity increases and can tend to infinity, depending on the type of mixture research
• said composition comprises between 10 and 45%, preferably between 15 and 45%, even more preferably between 28 and 45%, by weight of said thixotropic agent.
• said thixotropic agent is colloidal clay consisting of a mixture of sodium, magnesium and lithium silicates.
• said thixotropic agent consists of a mixture of sodium silicates, magnesium and lithium is the product Laponite ® RD.
• the term “natural diluent” is understood to mean a substance allowing the dilution of the various elements making up the coating composition according to the invention.
• Said diluent will completely evaporate after application of the coating composition to the surface to be coated.
• said natural diluent is chosen from water, preferably demineralized, and / or ethylene glycol and / or denatured alcohol,
• the composition comprises between 10 and 45%, preferably between 15 and 45%, even more preferably between 28 and 45%, by total weight of the composition of natural diluent.
• said copper and / or cupronickel nanoparticles have a diameter of between 5 nm to 9 nm.
• said copper and / or cupronickel microparticles have a diameter of between 1 ⁇ m to 20 ⁇ m.
• said composition comprises between 10 and 95%, preferably between 40 and 95%, even more preferably between 55 and 95%, by total weight of the composition of said nanoparticles and / or microparticles.
• biocide is understood within the meaning of the invention, the definition of the term “biocide” of the European Parliament and of the council n ° 98/8 / EC of February 16, 1998 concerning the placing on the market of biocidal products (JO / CE n ° L 123 of April 24, 1998) which define them as "Active substances and preparations containing one or more active substances which are presented in the form in which they are delivered to the user, which are intended to destroy , repel or render harmless organisms, to prevent their action or to combat in any other way, by chemical or biological action. "
• said metallic nanoparticles and / or microparticles are nanoparticles and / or microparticles of copper and / or cupronickel.
• the composition comprises:
• a thixotropic agent preferably Laponite® RD
• the composition comprises:
• a thixotropic agent preferably Laponite® RD
• the composition comprises:
• a thixotropic agent preferably Laponite ® RD
• the composition comprises:
• a thixotropic agent preferably Laponite ® RD
• the invention provides a composition applicable to a surface intended to be immersed or to remain in the open air.
• the application of this composition makes it possible to provide improved protection efficiency of said surface, whether or not it is submerged.
• the composition After application to the surface, the composition forms a layer of particles and binder having a thickness of approximately five to ten times greater than that of a layer of conventional antifouling paint, comparable to a "lining" of the shell .
• the very high proportion of overlapping particles makes it possible to obtain an attachment of the particles to each other, and therefore to avoid the dispersion of these particles in the environment.
• the coating composition After application to the surface intended to be treated, the coating composition forms a layer of nanoparticles and / or microparticles having a thickness of at least 600 microns, depending on the nature of the support (s) to be covered.
• the resistance of the coating according to the invention is high over time, the latter not fearing an alteration in the air during drying of the treated surface, or immersion for several consecutive years.
• the intrinsic strength of this layer is also high, so that it is not damaged by any handling of the surface, for example a ship's hull, or other structure comprising the treated surface.
• the lifespan of such a layer can reasonably be compared to that of a boat itself.
• the coating is easy to repair, by local reapplication of the product.
• This layer can be revived, if necessary, by simple rubbing using a weakly abrasive household sponge, without drying the treated surface, and while respecting the environment.
• the invention relates to a method for coating a surface comprising at least one step of applying to said surface a coating composition according to the invention.
• said method of coating a surface further comprises at least one step of drying said coating after said at least one step of applying to said surface.
• said at least one application step is carried out by cold metallization.
• the cold metallization technique makes it possible, by associating nanoparticles and / or microparticles of metal with a binder, to cover any rigid or semi-rigid support, including porous ones.
• Said invention makes it possible to cover any substrate in order to obtain a result which is smooth to the touch while providing long-lasting antiseptic protection.
• the high content of nanoparticles and / or microparticles of copper and / or flat lamellar nickel, which overlap, allows perfect homogeneity between them and form a so-called “placoid” covering protection.
• said at least one cold metallization application step is carried out by means of a spray and / or a paint roller and / or a brush and / or by electrodeposition.
• said at least one application step is repeated until a coating with a thickness of at least 600 microns is obtained on the surface to be coated.
• said method can comprise the application of a specific interface on the surface to be coated before the step of applying the coating composition according to the invention, allowing a more durable maintenance of this. last.
• the coating composed of nanoparticles and or laminated microparticles goes thanks to the binder ensuring a surface called “placoid scales" preventing any installation of viruses, microbes or air entrapment while releasing the antiseptic properties of the nanoparticles and / or microparticles of copper and / or nickel and / or metal in flat lamellar shapes.
• the polymerization of the epoxy resin causes evaporation of the order of 15% of this resin, ie 5.63 grams, and the demineralized water undergoes 100% evaporation, ie 600 grams; the net weight of the product applied and polymerized is therefore 116 g per m 2 .
• composition of the dry product per m 2 is therefore as follows:
• the invention relates to the use of the composition for the biocidal coating of a surface according to the invention for coating a surface, porous or non-porous, chosen from: wood, composite, steel, aluminum , stainless steel, ferrocement, concrete, polyester, epoxy, pvc, carbon rigid or semi-rigid.
• the invention relates to the use of the biocidal surface coating composition according to the invention for coating a boat hull.
• Figure 1 shows a schematic example of application of a coating with metal balls, comprising the substrate, copper balls, and air bubbles, as found in the prior art, for example in document FR2894974.
• Figure 2 is a microscopic view of spherical shaped copper balls.
• Figure 3 is a schematic example of a lamellar coating according to the invention, the particles of which are flat, ovoid, and forms a "placoid scale" type coating.
• Figure 4 is a microscopic view of flat lamellar nanoparticles of the "placoid scale” type, without binder. The flat, lamellar particles of the "placoid scale” type overlap.
• the coating composition according to the invention is prepared.
• composition according to the invention is then applied by means of the method according to the invention, comprising a cold metallization step, on the surface of a boat hull.
• This boat hull coated with the coating composition according to the invention is then immersed for one month in sea water.
• a second boat hull made of material identical to the coated one is also left for a month in sea water, near the first hull. At the end of this month, the boat hulls are compared, and it appears that the hull not coated with the composition according to the invention is in worse condition than that coated with the composition according to the invention. Indeed, there are marks reflecting the attack of living organisms (bacteria, algae, etc.) on the untreated hull, while the boat hull coated with the composition according to the invention is intact.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Wood Science & Technology (AREA)
• Inorganic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Plant Pathology (AREA)
• Nanotechnology (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)
• Paints Or Removers (AREA)

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• 2020
  • 2020-05-11 FR FR2004636A patent/FR3109943B1/fr active Active
• 2021
  • 2021-05-11 WO PCT/EP2021/062556 patent/WO2021228902A1/fr unknown
  • 2021-05-11 EP EP21725501.7A patent/EP4150013A1/de active Pending
  • 2021-05-11 CA CA3177956A patent/CA3177956A1/fr active Pending
  • 2021-05-11 AU AU2021272305A patent/AU2021272305A1/en active Pending
  • 2021-05-11 KR KR1020227041947A patent/KR20230010211A/ko unknown
  • 2021-05-11 US US17/998,290 patent/US20230227667A1/en active Pending
  • 2021-05-11 JP JP2022568719A patent/JP2023526042A/ja active Pending

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