EP4015706B1 - Hydrolyzable sheet - Google Patents

Hydrolyzable sheet Download PDF

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Publication number
EP4015706B1
EP4015706B1 EP20872932.7A EP20872932A EP4015706B1 EP 4015706 B1 EP4015706 B1 EP 4015706B1 EP 20872932 A EP20872932 A EP 20872932A EP 4015706 B1 EP4015706 B1 EP 4015706B1
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EP
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Prior art keywords
sheet
mass
water
chemical solution
base paper
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EP20872932.7A
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German (de)
English (en)
French (fr)
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EP4015706A4 (en
EP4015706A1 (en
Inventor
Kaori KANAMARU
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Daio Paper Corp
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Daio Paper Corp
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • A47L13/17—Cloths; Pads; Sponges containing cleaning agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky

Definitions

  • the present invention relates to a water dispersible sheet.
  • a toilet cleaning sheet which is a water dispersible sheet, has surface strength so as not to tear when a toilet bowl is scrubbed with it, and a water dispersing property so as to be discarded as it is in water collected in the toilet bowl and to be flushed after completion of cleaning (see, for example, Patent Document 1) .
  • EP 0 357 496 A2 discloses a wiping cloth for cleaning non-abrasive surfaces comprising a nonwoven substrate impregnated with a synthetic surfactant, said substrate being a mixture of 90 to 10% by weight of polymeric microfibers wherein said fibers have a diameter of less than 10 microns and 10 to 90% by weight woodpulp or cellulosic fibers.
  • EP 3 521 511 A1 discloses a water-disintegrable sheet in which a base paper sheet is impregnated with an aqueous agent, wherein the base paper sheet has a weight per unit area of 30 to 150 gsm and includes a water-soluble binder and cellulose nanofibers.
  • the aqueous agent includes a cross-linking agent, which cross-links with a water-soluble binder.
  • content of the water-soluble binder and content of the cellulose nanofibers gradually increase from inside toward outside of the base paper sheet in a thickness direction.
  • the conventional toilet cleaning sheet whose strength is prioritized has low water dispersing property
  • the sheet whose water dispersing property is prioritized has less strength and is torn easily during scrubbing of the toilet bowl.
  • the user may suffer from hand roughness.
  • the present invention has been made in consideration of the above problems, and aims to provide a water-dispersible sheet having improved surface strength while the water dispersing property was maintained and hand roughness was suppressed.
  • a water dispersible sheet that is a base paper sheet impregnated with a chemical solution, the base paper sheet being made of a water dispersible fiber aggregate, that is a single layer or multiple layers of paper or nonwoven fabric, including natural fibers and/or synthetic fibers impregnated with a water-soluble binder having a carboxyl group, including: diethylene glycol monobutyl ether and propylene glycol monomethyl ether in the chemical solution, wherein.
  • the chemical solution contains 11.50% by mass to 13.50% by mass of propylene glycol monomethyl ether and 3.00% by mass to 5.00 by mass of diethylene glycol monobutyl ether.
  • the base paper sheet is impregnated with the chemical solution of 100 to 500 % by mass relative to the mass of the base paper sheet.
  • the chemical solution further comprises a cross-linking agent that forms cross-links with the water-soluble binder.
  • a toilet cleaning sheet will be described as an example of the water dispersible sheet, but the water dispersible sheet also includes a wet tissue impregnated with a chemical solution for use in wiping.
  • X, Y, up and down, and left and right directions are defined as shown in FIG. 1 , FIG. 2A, and FIG. 2B .
  • the toilet cleaning sheet S of the present invention is a sheet in which base paper sheets are subjected to ply processing (stacked) and is preferably a toilet cleaning sheet of a wet type that is impregnated with a predetermined chemical solution.
  • the base paper sheet is preferably made by ply processing of two base paper sheets, because when it is made by ply processing of three or more base paper sheets, CMC described later is applied in a spotty manner.
  • the base paper sheet may also be composed of a single base paper sheet, without ply processing.
  • the surface of the toilet cleaning sheet S may be left as the original base paper sheet, but is preferably embossed.
  • embosses EM11 and EM12 are provided as shown in FIG. 1 .
  • the basis weight of the base paper sheet per sheet is about 30 to 150 g/m 2 .
  • the basis weight is based on JIS P 8124.
  • the base paper sheet of the toilet cleaning sheet S is configured with a water dispersible fiber aggregate so as to be discarded in the water collected in the toilet bowl as it is after cleaning the toilet bowl and the like.
  • the fiber aggregate is not particularly limited as long as it has a water dispersing property, but a single layer or multiple layers of paper or nonwoven fabric can be suitably used.
  • the fiber raw material may be a natural fiber or a synthetic fiber, and they may be mixed. Suitable fiber raw materials include cellulosic fibers such as wood pulp, non-wood pulp, rayon, and cotton, biodegradable fibers made of polylactic acid, and the like.
  • cellulosic fibers such as wood pulp, non-wood pulp, rayon, and cotton
  • biodegradable fibers made of polylactic acid, and the like.
  • polyethylene fibers, polypropylene fibers, polyvinyl alcohol fibers, polyester fibers, polyacrylonitrile fibers, synthetic pulp, glass wool, and the like may be used in combination.
  • a fiber aggregate containing at least pulp is preferable, and suitable pulp to be used as a raw material is leaf bleached kraft pulp (LBKP) and needle bleached kraft pulp (NBKP) blended in an appropriate ratio.
  • LKP leaf bleached kraft pulp
  • NKP needle bleached kraft pulp
  • the blended ratio of the leaf bleached kraft pulp more preferably exceeds 50% by mass, in other words, the blended ratio of the needle bleached kraft pulp to the leaf bleached kraft pulp is less than 1/1.
  • it may be configured of a sheet made of crushed pulp or a sheet of crushed pulp covered or sandwiched with a water dispersible sheet(s) .
  • a water-soluble binder for enhancing paper strength is applied to the base paper sheet of the toilet cleaning sheet S.
  • the water-soluble binder include a binder component such as carboxymethyl cellulose, polyvinyl alcohol, starch or a derivative thereof, hydroxypropyl cellulose, sodium alginate, trant gum, guar gum, xanthan gum, gum arabic, carrageenan, galactomannan, gelatin, casein, albumin, purplan, polyethylene oxide, Viscose, polyvinyl ethyl ether, sodium polyacrylate, sodium polymethacrylate, polyacrylamide, hydroxylated derivatives of polyacrylic acid, polyvinyl pyrrolidone / vinyl pyrrolidone vinyl acetate copolymer, and the like.
  • a water-soluble binder having a carboxyl group is preferably used.
  • the water-soluble binder having a carboxyl group is an anionic water-soluble binder which readily generates carboxylate in water.
  • examples thereof include polysaccharide derivatives, synthetic polymers, and natural products.
  • polysaccharide derivative examples include a salt of carboxymethyl cellulose, carboxyethyl cellulose or a salt thereof, and carboxymethylated starch or a salt thereof, and an alkali metal salt of carboxymethyl cellulose (CMC) is particularly preferable.
  • CMC carboxymethyl cellulose
  • CMC has an etherification degree of 0.6 to 2.0, particularly 0.9 to 1.8, more preferably 1.0 to 1.5. This is because the water dispersing property and the development of wet paper strength become extremely good.
  • water-swellable CMC This exerts a function of linking the fibers constituting the base paper sheet while remaining unswollen by forming cross-links with a specific metal ion as the cross-linking agent in the chemical solution, so that strength as a durable toilet wiping sheet in cleaning/wiping is exhibited.
  • CMC is applied to the toilet cleaning sheet S as the water-soluble binder.
  • the base paper sheet may be uniformly impregnated with CMC in the thickness direction, but is preferably impregnated with CMC such that the content of CMC in the base paper sheet gradually increases from the center in the thickness direction toward the front face and the back face.
  • Examples of the synthetic polymers include a salt of a polymer or a copolymer of an unsaturated carboxylic acid, a salt of a copolymer of an unsaturated carboxylic acid and a monomer copolymerizable with the unsaturated carboxylic acid, and the like.
  • Examples of the unsaturated carboxylic acid include acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic anhydride, maleic acid, fumaric acid, and the like.
  • Examples of the monomer copolymerizable with them include esters of these unsaturated carboxylic acids, vinyl acetate, ethylene, acrylamide, vinyl ether, and the like.
  • a particularly preferred synthetic polymer is one using acrylic acid or methacrylic acid as the unsaturated carboxylic acid, and specifically include salts of polyacrylic acid, polymethacrylic acid, or acrylic acid methacrylic acid copolymer, and salts of a copolymer of acrylic acid or methacrylic acid, an alkyl acrylate or alkyl methacrylate.
  • Examples of natural products include sodium alginate, xanthan gum, gellan gum, Tragacanth gum, pectin, and the like.
  • CNF Cellulose nanofibers
  • CNF can be added to the water-soluble binder (CMC in the present embodiment), and the specific surface area of the base paper sheet is larger than that with pulp-only composition.
  • CNF refers to fine cellulose fibers obtained by fibrillating pulp fibers.
  • CNF refers to cellulose fibers containing cellulose fine fibers having a fiber width of nano-order size (1 nm or more and 1000 nm or less).
  • An average fiber width is preferably 100 nm or less.
  • Number average, median, mode diameter (mode) and the like are calculated from a certain number of fibers as the average fiber width.
  • the base paper sheet may be uniformly impregnated with CNF in the thickness direction, but is preferably impregnated with CNF such that the content of CNF in the base paper sheet gradually increases from the center in the thickness direction toward the front face and the back face.
  • pulp fibers usable for the production of CNF include chemical pulp such as broad leaf tree pulp (LBKP) and needle leaf tree pulp (NBKP); mechanical pulp such as Bleaching thermomechanical pulp (BTMP), stone ground pulp (SGP), pressurized stone ground pulp (PGW), refiner ground pulp (RGP), chemi-ground pulp (CGP), thermogrand pulp (TGP), grand pulp (GP), thermomechanical pulp (TMP), chemi-Thermo Mechanical pulp (CTMP), and refiner mechanical pulp (RMP); used paper pulp manufactured from tea waste paper, craft envelope waste paper, magazine waste paper, newspaper waste paper, leaflets waste paper, office waste paper, cardboard waste paper, high quality white waste paper, Kent waste paper, simili waste paper, regional waste paper, and groundwood paper; and deinked pulp (DIP) made by deinking used paper pulp. As long as the effects of the present invention are not impaired, these may be used alone or in combination of multiple types.
  • BTMP Bleaching thermomechanical pulp
  • SGP stone ground pulp
  • PGW pressurized stone ground pulp
  • Fibrillation methods used for producing CNF are not limited to, but include, for example, mechanical methods such as a high pressure homogenizer method, a microfluidizer method, a grinder grinding method, a bead mill freeze pulverization method, and an ultrasonic fibrillating method.
  • CNF that has been only mechanically treated by the above fibrillation methods namely, CNF that has been subjected to no modification with functional groups
  • CNF that has been subjected to no modification with functional groups has higher thermal stability and therefore can be used in a wider range of applications than CNF that has been subjected to modification with functional groups such as phosphate groups and carboxymethyl groups.
  • CNF that has been subjected to modification with functional groups such as phosphate groups and carboxymethyl groups can also be used in the present invention.
  • the pulp fiber may be mechanically treated by the fibrillation methods, and then chemically treated by carboxymethylation, or enzymatically treated.
  • Chemically treated CNF include, for example, iCNF (individualized CNF) (single nanocellulose) having a diameter of 3 to 4 nm, such as TEMPO-oxidized CNF, phosphorylated CNF, and phosphite esterified CNF.
  • CNF treated only chemically or enzymatically, or CNF treated chemically or enzymatically and then treated mechanically by the fibrillation method may be used.
  • the fiber orientation ratio (length/width) in the length and width directions of the toilet cleaning sheet S is not particularly limited, but is preferably 0.8 to 2.0, more preferably 0.8 to 1.2.
  • the fiber orientation ratio in the length and width directions of the toilet cleaning sheet S is set to 0.8 to 2.0, preferably 0.8 to 1.2.
  • the fiber orientation ratio in the length and width directions can be obtained from the ratio of the wet strengths in the directions of MD (Machine Direction) to CD (Cross Direction).
  • the toilet cleaning sheet S of the present embodiment is impregnated with a predetermined chemical solution containing the cross-linking agent that forms cross-links with the water-soluble binder (CMC in the case of the toilet cleaning sheet S of the present embodiment).
  • the chemical solution contains an auxiliary agent such as glycol ethers, an aqueous detergent, an antiseptic, a disinfectant, an organic solvent, and the like.
  • the base paper sheet After impregnated with the water-soluble binder and then dried, the base paper sheet is impregnated with the chemical solution.
  • the toilet cleaning sheet S is impregnated with the chemical solution of 100 to 500 % by mass, preferably 150 to 300 % by mass, relative to the mass of the base paper sheet as the base material of the toilet cleaning sheet S.
  • boric acid various metal ions and the like can be used, but when CMC is used as the water-soluble binder, a polyvalent metal ion is preferably used.
  • polyvalent metal ions selected from a group consisting of alkaline earth metals, manganese, zinc, cobalt, and nickel, from the viewpoint of developing wet strength for durability in use by sufficiently bonding the fibers and from the viewpoint of improving the sufficient water dispersing property.
  • these metal ions ions of calcium, strontium, barium, zinc, cobalt, or nickel are used particularly preferably.
  • Glycol ethers have a structure in which a hydroxyl group at one or both ends of glycol, a divalent alcohol, is etherified, and have a hydrophobic alkyl group and a hydrophilic ether group and hydroxy group in the molecule. Glycol ethers have a lower molecular weight than surfactants and leads to a lower dynamic surface tension than conventional detergents containing only surfactants. Therefore, an interface between the chemical solution and stain can be formed more quickly. Glycol ethers also function as a coupling agent to compatibilize hydrophobic oil or stain with water, and can pull off stain and prevent it from reattaching. Therefore, the addition of glycol ethers to the chemical solution can improve the wiping performance of the toilet cleaning sheet S.
  • the chemical solution of the present invention includes glycol ethers such as: propylene glycol monomethyl ether (PGME), diethylene glycol monobutyl ether (DGME), ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, polyethylene glycol monomethyl ether, ethylene glycol isopropyl ether, diethylene glycol monoisopropyl ether, triethylene glycol monomethyl ether, polyethylene glycol monomethyl ether, ethylene glycol isopropyl ether, diethylene glycol monoisopropyl ether, and ethylene glycol monobutyl ether.
  • glycol ethers such as: propylene glycol monomethyl ether (PGME), diethylene glycol monobutyl ether (DGME), ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, polyethylene glycol monomethyl ether, ethylene glycol isopropyl ether, diethylene glycol monoisopropyl
  • PGME which is usually added as a detergent ingredient and is known to improve detergency, exhibits an effect of directly improving the sheet strength, and has an effect of enhancing the sheet strength improving effect due to the CMC and the polyvalent metal ion.
  • the amount of PGME to be added is preferably 20 to 60 g/m 2 , more preferably 26 to 40 g/m 2 .
  • the amount is less than 20 g/m 2 , the deodorant effect is not sufficiently obtained. Even when the amount is more than 60 g/m 2 , the obtained deodorant effect is not more than that when the amount is 60 g/m 2 .
  • DGME is an auxiliary agent similar to PGME in that it has an effect of improving sheet strength.
  • the amount of DGME to be added is preferably 5 to 30 g/m 2 , more preferably 10 to 20 g/m 2 .
  • glycol ethers such as PGME need to be formulated appropriately into the chemical solution in addition to DGME.
  • aqueous detergent for example, lower or higher (aliphatic) alcohol can be used in addition to a surfactant.
  • parabens such as methylparaben, ethylparaben, propylparaben, and the like can used.
  • the disinfectant for example, benzalkonium chloride, chlorhexidine gluconate, povidone iodine, ethanol, benzyl cetyl oxide, triclosan, chloroxylenol, isopropylmethylphenol, and the like can used.
  • organic solvent polyhydric alcohols such as glycol (divalent), glycerin (trivalent), sorbitol (tetravalent), and the like can used.
  • auxiliary agent of the above-mentioned components of the chemical solution can be selected appropriately, and a component which fulfills other functions may be contained in the chemical solution as necessary.
  • PG propylene glycol
  • the surface of the toilet cleaning sheet S may be the base paper sheet as it is, embossing is preferably applied.
  • embosses EM11 and EM12 are embossed on it.
  • the embosses EM11 are arranged so as to form a diamond lattice. As a result, uneven wiping can be reduced as compared with the case where the embosses EM11 are arranged to form a square lattice or a rectangular lattice.
  • the embosses EM12 are arranged between the embosses EM11.
  • the embosses EM11 each have, as shown in FIG. 3A , a protrusion PR21 having a curved shape.
  • the embosses EM12 each have, as shown in FIG. 3B , a protrusion PR22 having a plane shape.
  • the embosses EM12 are arranged between the embosses EM11, the protrusions PR21 of the embosses EM11 and the protrusions PR22 of the embosses EM12 are closely adhered to each other to form a continuous emboss EM21 as shown in FIG. 3C .
  • the protrusions PR21 of the embosses EM11 and the protrusions PR22 of the embosses EM12 may be only close to each other and do not have to be continuous.
  • the respective embosses are deformed and the contact areas increase for the first time when a force is applied to the toilet cleaning sheet S during the wiping operation. Therefore, as well as increasing the contact areas, flexibility is also improved due to deformation of the respective embosses.
  • the contact areas CN31 after deformation of the embosses EM11 due to the force applied to the toilet cleaning sheet S during the wiping operation are generated discretely in the vicinity of the respective embosses EM11.
  • the contact areas SN32 after deformation of the embosses EM11 and EM12 due to the force applied to the toilet cleaning sheet S during the wiping operation are increased as compared with the contact area CN31 of FIG. 4A .
  • the two types of the embosses EM11 and EM12 also exhibit the effect of normal embosses, and it is possible to improve the texture, absorbency, bulkiness, etc. of the toilet cleaning sheet S.
  • the continuous embosses EM21 also exhibit the effect of good appearance by embossing.
  • the toilet cleaning sheet S is folded in two at the center portion in the Y direction by a fold process. Then, it is stored in a plastic case for storage or in a packaging film in a folded state, and unfolded as necessary at the time of use.
  • the way of folding the toilet cleaning sheet S is not limited to folding in two, but may be folding in four or eight, for example.
  • a base paper sheet having a basis weight of 43 g/m 2 was prepared into two plies.
  • a water-soluble binder solution consisting of 96% water and 4% CMC was sprayed on the outer surface of the raw fabric using a water-soluble binder application facility.
  • the CMC contained in the binder solution is CMC1330 (Daicel).
  • the raw fabric was dried by being passed through a hot air dryer (temperature 180°C) until the moisture content was about 8%, and a base paper sheet was prepared.
  • the base paper sheet was impregnated with 200% by mass of the chemical solution to prepare a test sheet.
  • the chemical solution includes 4.050% by mass of cross-linking agent, 0.200% by mass of the aqueous detergent, 0.205% by mass of the antiseptic, 0.200% by mass of the disinfectant, 3.000% by mass of PG, 75.845% by mass of purified water, and 16.500% by mass of the glycol ether(s) of respective blended rate(s) according to in Examples 1 to 5 and Comparative Examples 1 to 2.
  • the DGME used here is a linear compound.
  • the blended rates of glycol ethers in the chemical solution were 1.000% by mass for DGME and 15.500% by mass for PGME.
  • the blended rates of glycol ethers in the chemical solution were 3.000% by mass for DGME and 13.500% by mass for PGME.
  • the blended rates of glycol ethers in the chemical solution were 5.000% by mass for DGME and 11.500% by mass for PGME.
  • the blended rates of glycol ethers in the chemical solution were 8.250% by mass for both DGME and PGME.
  • the blended rates of glycol ethers in the chemical solution were 10.000% by mass for DGME and 6.500% by mass for PGME.
  • the blended rate of a glycol ether in the chemical solution was 16.500% by mass for PGME.
  • the blended rate of a glycol ether in the chemical solution was 16.500% by mass for DGME.
  • Test pieces (toilet cleaning sheets) were each cut out to be 75 mm in width and 240 mm in length in the MD and CD directions without peeling off the ply, folded in three such that both ends in the width direction overlapped, and each rubbed with a Gakushin type fastness rubbing tester at a portion to be measured. The number of rubbings was measured at the time when a damage such as scuffing or tear was visually recognized on the sheet. This measurement was performed three times in each of the MD direction and CD direction, and an average of the three measured values was calculated.
  • the test conditions with the Gakushin type fastness rubbing tester were as follows.
  • one piece of PP band (Sekisui Jushi Corporation, Item Number 19K (width 15 mm ⁇ length 60 mm)) was fixed to the rubbing finger with screws such that there are no gaps or wrinkles.
  • Width 25 mm (the sheet with a width of 75 mm was folded in three without peeling off the ply) ⁇ length 240 mm (on the side of the sample holder)
  • test sheets of Examples and Comparative Examples were each cut into 114 mm ⁇ 114 mm and the water dispersing property of each of the test sheets was measured according to a method as in testing the ease of loosening based on JIS P 4501.
  • the evaluation result was set to AA when the rate of users who answered that "I do not feel hand roughness at all" was the highest among the ten users, BB when the rate of users who answered that "I feel a little hand roughness” was the highest, and CC when the rate of users who answered that "I feel hand roughness” was the highest.
  • Table I shows averaged values of results of the above tests 1 and 2 each conducted four times, and values of results of the above test 3 that was conducted once, for each of the test sheets of the above examples and comparative examples.
  • Example 1 to 5 and Comparative Examples 1 to 2 were each cut into 165 mm ⁇ 230 mm, placed on a tile on which nine dots having a diameter of 1 mm were drawn with an oil-based magic marker to simulate sebum stains. Further, a weight of 1 kg was placed on each of the test sheets, wiping was performed at a constant speed, and the tile after the wiping was checked.
  • a sheet was evaluated as "AA” (no stain on the tile) when more than 90% of the area of the stained portion could be wiped off.
  • a sheet was evaluated as "BB” (very little stain on the tile) when 60% or more and less than 90% of the area of the stained portion could be wiped off.
  • a sheet was evaluated as "CC” (a slight stain on the tile) when 20% or more and less than 60% of the area of the stained portion could be wiped off.
  • a sheet was evaluated as "DD” (a lot of stain on the tile) when less than 20% of the area of the stained portion could be wiped off.
  • the present invention can be used for a water-dispersible sheet having improved surface strength while the water dispersing property was maintained and hand roughness was suppressed.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Paper (AREA)
  • Non-Flushing Toilets (AREA)
  • Detergent Compositions (AREA)
EP20872932.7A 2019-09-30 2020-09-11 Hydrolyzable sheet Active EP4015706B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019180255A JP7105750B2 (ja) 2019-09-30 2019-09-30 水解性シート
PCT/JP2020/034534 WO2021065423A1 (ja) 2019-09-30 2020-09-11 水解性シート

Publications (3)

Publication Number Publication Date
EP4015706A1 EP4015706A1 (en) 2022-06-22
EP4015706A4 EP4015706A4 (en) 2022-10-12
EP4015706B1 true EP4015706B1 (en) 2023-12-20

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EP20872932.7A Active EP4015706B1 (en) 2019-09-30 2020-09-11 Hydrolyzable sheet

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US (1) US20220282427A1 (ja)
EP (1) EP4015706B1 (ja)
JP (1) JP7105750B2 (ja)
KR (1) KR20220068988A (ja)
CN (1) CN114423902B (ja)
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