EP3930660A1 - Reinigungstücher getränkt mit tränkungsmitteln enthaltend biotenside - Google Patents
Reinigungstücher getränkt mit tränkungsmitteln enthaltend biotensideInfo
- Publication number
- EP3930660A1 EP3930660A1 EP20702444.9A EP20702444A EP3930660A1 EP 3930660 A1 EP3930660 A1 EP 3930660A1 EP 20702444 A EP20702444 A EP 20702444A EP 3930660 A1 EP3930660 A1 EP 3930660A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- cleaning agent
- agent according
- impregnating agent
- impregnating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 238000002791 soaking Methods 0.000 title abstract 3
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- 239000004094 surface-active agent Substances 0.000 claims description 61
- 239000003995 emulsifying agent Substances 0.000 claims description 32
- 239000004744 fabric Substances 0.000 claims description 31
- 239000012459 cleaning agent Substances 0.000 claims description 28
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 claims description 27
- 238000005470 impregnation Methods 0.000 claims description 26
- 239000002537 cosmetic Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000003755 preservative agent Substances 0.000 claims description 16
- 239000006260 foam Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 239000002280 amphoteric surfactant Substances 0.000 claims description 10
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- 229920000642 polymer Polymers 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
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- HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical compound O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 claims description 7
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- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 4
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 claims description 3
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- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 claims description 2
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- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 2
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 2
- 229960001950 benzethonium chloride Drugs 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- 229940100524 ethylhexylglycerin Drugs 0.000 claims description 2
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- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 2
- 229940100573 methylpropanediol Drugs 0.000 claims description 2
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 2
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- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 claims description 2
- 229940081510 piroctone olamine Drugs 0.000 claims description 2
- 229940093424 polyaminopropyl biguanide Drugs 0.000 claims description 2
- 239000004302 potassium sorbate Substances 0.000 claims description 2
- 235000010241 potassium sorbate Nutrition 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 claims description 2
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 claims description 2
- 229960004063 propylene glycol Drugs 0.000 claims description 2
- 229960003415 propylparaben Drugs 0.000 claims description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 claims description 2
- 229960003885 sodium benzoate Drugs 0.000 claims description 2
- 229960004025 sodium salicylate Drugs 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000693 micelle Substances 0.000 abstract description 16
- 238000004140 cleaning Methods 0.000 description 41
- -1 alkyl ether sulfates Chemical class 0.000 description 33
- 238000002360 preparation method Methods 0.000 description 21
- 239000000126 substance Substances 0.000 description 17
- 239000003921 oil Substances 0.000 description 14
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- 125000004432 carbon atom Chemical group C* 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
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- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 description 1
- 229960002079 calcium pantothenate Drugs 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 229960004203 carnitine Drugs 0.000 description 1
- 229940044199 carnosine Drugs 0.000 description 1
- CQOVPNPJLQNMDC-ZETCQYMHSA-N carnosine Chemical compound [NH3+]CCC(=O)N[C@H](C([O-])=O)CC1=CNC=N1 CQOVPNPJLQNMDC-ZETCQYMHSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000019522 cellular metabolic process Effects 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
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- 235000005607 chanvre indien Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 229940031728 cocamidopropylamine oxide Drugs 0.000 description 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 description 1
- 235000017471 coenzyme Q10 Nutrition 0.000 description 1
- 229940110767 coenzyme Q10 Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229960003624 creatine Drugs 0.000 description 1
- 239000006046 creatine Substances 0.000 description 1
- 229940109239 creatinine Drugs 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229960003949 dexpanthenol Drugs 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 229940047642 disodium cocoamphodiacetate Drugs 0.000 description 1
- ZPRZNBBBOYYGJI-UHFFFAOYSA-L disodium;2-[1-[2-(carboxylatomethoxy)ethyl]-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate;hydroxide Chemical compound [OH-].[Na+].[Na+].CCCCCCCCCCCC1=NCC[N+]1(CCOCC([O-])=O)CC([O-])=O ZPRZNBBBOYYGJI-UHFFFAOYSA-L 0.000 description 1
- GLSRFBDXBWZNLH-UHFFFAOYSA-L disodium;2-chloroacetate;2-(4,5-dihydroimidazol-1-yl)ethanol;hydroxide Chemical compound [OH-].[Na+].[Na+].[O-]C(=O)CCl.OCCN1CCN=C1 GLSRFBDXBWZNLH-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 229940095139 ethylhexyl laurate Drugs 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 229940102465 ginger root Drugs 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 239000008169 grapeseed oil Substances 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- PMMXXYHTOMKOAZ-UHFFFAOYSA-N hexadecyl 7-methyloctanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCC(C)C PMMXXYHTOMKOAZ-UHFFFAOYSA-N 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 235000010181 horse chestnut Nutrition 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 150000002454 idoses Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229930013032 isoflavonoid Natural products 0.000 description 1
- 150000003817 isoflavonoid derivatives Chemical class 0.000 description 1
- 235000012891 isoflavonoids Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 235000019136 lipoic acid Nutrition 0.000 description 1
- 239000010469 macadamia oil Substances 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000001035 marshmallow Nutrition 0.000 description 1
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- 239000002609 medium Substances 0.000 description 1
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- 150000004706 metal oxides Chemical class 0.000 description 1
- 235000021239 milk protein Nutrition 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- SBLKVIQSIHEQOF-UHFFFAOYSA-N octadec-9-enedioic acid Chemical compound OC(=O)CCCCCCCC=CCCCCCCCC(O)=O SBLKVIQSIHEQOF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- PIUVNPNBPWVVKZ-UHFFFAOYSA-N octadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC PIUVNPNBPWVVKZ-UHFFFAOYSA-N 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- SERHXTVXHNVDKA-UHFFFAOYSA-N pantolactone Chemical compound CC1(C)COC(=O)C1O SERHXTVXHNVDKA-UHFFFAOYSA-N 0.000 description 1
- 229940115458 pantolactone Drugs 0.000 description 1
- SIEVQTNTRMBCHO-UHFFFAOYSA-N pantolactone Natural products CC1(C)OC(=O)CC1O SIEVQTNTRMBCHO-UHFFFAOYSA-N 0.000 description 1
- 229940055726 pantothenic acid Drugs 0.000 description 1
- 235000019161 pantothenic acid Nutrition 0.000 description 1
- 239000011713 pantothenic acid Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 235000011765 phytoene Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229940093448 poloxamer 124 Drugs 0.000 description 1
- 229940116406 poloxamer 184 Drugs 0.000 description 1
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000903 polyhydroxyalkanoate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- PZQSQRCNMZGWFT-QXMHVHEDSA-N propan-2-yl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC(C)C PZQSQRCNMZGWFT-QXMHVHEDSA-N 0.000 description 1
- 229960003581 pyridoxal Drugs 0.000 description 1
- 235000008164 pyridoxal Nutrition 0.000 description 1
- 239000011674 pyridoxal Substances 0.000 description 1
- 235000008160 pyridoxine Nutrition 0.000 description 1
- 239000011677 pyridoxine Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- ABTZKZVAJTXGNN-UHFFFAOYSA-N stearyl heptanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCC ABTZKZVAJTXGNN-UHFFFAOYSA-N 0.000 description 1
- 229940098758 stearyl heptanoate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 235000021092 sugar substitutes Nutrition 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 description 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
- 235000019157 thiamine Nutrition 0.000 description 1
- 239000011721 thiamine Substances 0.000 description 1
- 229960002663 thioctic acid Drugs 0.000 description 1
- 239000001585 thymus vulgaris Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 150000003625 trehaloses Chemical class 0.000 description 1
- GKAVWWCJCPVMNR-UHFFFAOYSA-N tridecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCC GKAVWWCJCPVMNR-UHFFFAOYSA-N 0.000 description 1
- SMYKBXMWXCZOLU-UHFFFAOYSA-N tris-decyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCCC)C(C(=O)OCCCCCCCCCC)=C1 SMYKBXMWXCZOLU-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000010374 vitamin B1 Nutrition 0.000 description 1
- 239000011691 vitamin B1 Substances 0.000 description 1
- 235000019160 vitamin B3 Nutrition 0.000 description 1
- 239000011708 vitamin B3 Substances 0.000 description 1
- 235000009492 vitamin B5 Nutrition 0.000 description 1
- 239000011675 vitamin B5 Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 229940118846 witch hazel Drugs 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
- 239000001841 zingiber officinale Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
- A61K2800/524—Preservatives
Definitions
- the present invention relates to a cleaning cloth impregnated with an impregnating agent, the impregnating agent containing biosurfactants, in particular glycolipids, further in particular rhamnolipids, in such an amount that micelles are formed.
- biosurfactants in particular glycolipids, further in particular rhamnolipids, in such an amount that micelles are formed.
- Cleaning cloths are a special form of cleaning agent, because the cleaning performance is based on the interaction of cloth and impregnating agent.
- Cleaning wipes are characterized by the fact that they are cleaning agents that are ready for immediate use. There is no additional solvent, especially water, he required to develop the effect. Also, no solvent, especially water, is required to wash off dirt. Cleaning cloths can be used comfortably on the go and when traveling, or simply once in between.
- cleaning wipes are used in a variety of ways, for example in leather and floor care, in hygiene, in intimate and body care.
- cleaning wipes are also used advantageously for baby care, for face and body cleaning, for cleaning the skin in the diaper area and as toilet paper to promote toilet training in small children.
- facial cleansing One area in which the use of cleaning wipes is particularly popular is facial cleansing. When cleansing the face, dirt that has got onto the skin from outside, dead cells and excess sebum must be removed. Make-up that has to be removed is one of the dirt that has got onto the skin from the outside.
- organic color pigments are also used as dyes.
- a binder are used, among other things, stearic acid esters, lanolin alcohol and acetate.
- waxes such as beeswax or carnauba wax and oils such as paraffin oils, silicone oils or castor oil.
- Decorative cosmetics can also contain preservatives, antioxidants, thickeners and other additives.
- DE 10157543 discloses emulsion-impregnated wipes, the emulsion containing chitosan and / or lecithin. This allows the content of emulsifiers and preservatives to be reduced.
- EP 1405632 discloses the incorporation of zinc oxide particles of a certain size into the impregnating agents and the possibility of applying these impregnating agents to the wipes.
- WO 2005/044220 A1 discloses. These impregnating agents have the effect that cleaning articles impregnated with these agents not only have a high cleaning power but also a high refatting power.
- Classic cleaning wipes can therefore be soaked with impregnating agents that do not need to incorporate "classic” surfactants, such as alkyl ether sulfates, which are usually used in liquid cleaning preparations. This can lead to the cleaning performance being reduced.
- Oil-containing cleaning wipes are often used to remove waterproof make-up preparations. These oil-containing cleaning wipes have the disadvantage that oils can get into the eyes due to their different levels of spreadability. This leads to a reduced compatibility of these products. Furthermore, when cleaning cloths containing oil are used, an oily residue often remains on the flaut, which many users find unpleasant.
- the impregnating agent has micelles.
- DE 102015212822 A1 is characterized in that it contains a mixture of different surfactants, anionic surfactants in the form of sodium acyl glutamates, non-ionic surfactants in the form of block polymers and alkyl polyglycosides.
- micelles in facial cleansing preparations has proven advantageous.
- the surfactants contained must be present in a certain amount so that the micelles can form.
- the surfactants contained in the micelles are usually arranged in such a way that the hydrophilic part of the surfactants points into the aqueous environment, while the lipophilic part of the surfactants points into the interior of the micelle.
- the micelles now interact with the various soiling of the flaut. In this way, solubilization occurs, so that the various types of dirt can be effectively removed from the dullness by wiping the cleaning cloth.
- the following parameters are important:
- the cleaning wipes should be gentle on the skin; the following parameters have an influence on the compatibility of the product:
- a cleaning agent consisting of a cloth and an impregnating agent, the impregnating agent comprising at least one biosurfactant, in particular at least one glycolipid, further in particular at least one rhamnolipid and at least one preservative.
- This cleaning agent is preferably used on the human body; it is preferably a cosmetic cleaning agent.
- the impregnating agent contains water; the impregnation agent is therefore an aqueous impregnation agent.
- the water content is advantageously 80 to 99% by weight, particularly advantageously 95 to 98.9% by weight, based on the total weight of the impregnating agent.
- the impregnating agent advantageously contains only one or more biosurfactants as surface-active substances, particularly advantageously only one or more glycolipids, further particularly advantageously only one or more rhamnolipid (s).
- one or more further surface-active substance (s) selected from further surfactants and / or emulsifiers are included.
- At least one biosurfactant in addition to at least one biosurfactant, in particular to the at least one glycolipid, further in particular to the at least one rhamnolipid and the one or more further surface-active substance (s), selected from surfactants and / or Emulsifiers, at least one humectant, at least one film-forming agent, at least one lipophilic component and / or at least one cosmetic active ingredient selected from the group of vitamins, plant extracts and / or individual active ingredients.
- s further surface-active substance selected from surfactants and / or Emulsifiers
- the impregnating agent according to the invention contains biosurfactants.
- Surfactants are amphiphilic substances that can dissolve organic, non-polar substances in water. They are characterized by an ambivalent behavior towards water and lipids.
- the surfactant molecule contains at least one hydrophilic and one lipophilic group, which enable the attachment to the interface between these two substance classes. In this way, surfactants ensure a reduction in the surface tension of the water, wetting of the flood, and facilitating dirt removal and loosening easy rinsing and - if desired - also for foam regulation. This provides the basis for removing dirt containing lipids.
- Biosurfactants are surfactants that are obtained from renewable raw materials and that are biodegradable. The manufacturing process for these surfactants is also sustainable, ideally through a fermentation process. Glycolipids, lipopeptides, fatty acids, phospholipids and others should be mentioned as biosurfactants. Preferred according to the invention are glycolipids, a group comprising rhamnolipids, sophorolipids, mannosylerythrollipids and trehalose lipids. Rhamnolipids are particularly preferred.
- Rhamnolipids can be described by the following structural formula:
- n 1 or 0,
- R 1 and R 2 independently of one another, are the same or different organic radicals with 2 to 24, preferably 5 to 13 carbon atoms, in particular a substituted or unsubstituted, branched or unbranched alkyl radical, which can also be unsaturated, the alkyl radical preferably being a linear saturated one Is an alkyl radical having 6 to 12 carbon atoms. Salts of these compounds are also included according to the invention.
- Rhamnolipids can be obtained, for example, when bacteria of the genus Pseudomonas, in particular Pseudomonas aeruginosa, grow on vegetable oils and n-alkanes.
- biosurfactants especially rhamnolipids
- DE 102015217503 A1 discloses the use of biosurfactants in cosmetic cleaning agents, with anionic surfactants being included as further surfactants.
- WO 2014/173659 A1 describes the use of glycolipids in cleaning preparations. These cleaning preparations must also contain a further surfactant, namely a synthetic surfactant.
- DE 102015217504 A1 discloses peeling compositions which, in addition to the peeling agent, must contain biosurfactants and a thickener.
- the document WO 2013/098066 A2 describes hair and skin cleaning compositions that contain biosurfactants. Furthermore, at least one fatty acid is always included.
- EP 2786742 A1 describes the use of rhamnolipids in cosmetics be. All exemplary embodiments contain at least one further surfactant or an emulsifier.
- the corresponding embodiments contain only one or more biosurfactants as surface-active substances in the impregnating agent according to the invention, more preferably only one or more glycolipids, even more preferably only one or more rhamnolipids.
- no additional emulsifiers and / or further surfactants are therefore incorporated into the impregnating agent according to the invention.
- emulsifiers are understood to mean compounds which stabilize emulsions.
- Emulsions are compositions which are characterized by the presence of at least 2 phases, usually a lipophilic phase and a hydrophilic phase.
- Emulsifiers stabilize the emulsions formed by interfacial films and by the formation of steric or electrical barriers, which prevents the emulsified particles from flowing together (coalescence).
- Emulsifiers are amphiphilic molecules, one part of the molecule having an affinity for polar molecules and another part having an affinity for unpolar molecules.
- emulsifiers can be used as solubilizers. Particularly suitable for this purpose are the emulsifiers which have a large hydrophilic content.
- surface-active substance is used for the substance classes surfactants and emulsifiers, because both substance classes can be identified by the term “surface-active”.
- the at least one rhamnolipid can be obtained under the trade name Rheance One from Evonik.
- the at least one biosurfactant preferably the at least one glycolipid, more preferably the at least one rhamnolipid, with a total content of 0.1 to 5.0 wt.%, Preferably 0.25 to 2.5 wt .-%, based on the total weight of the impregnating agent and based on the active content.
- Preservatives are those preserving substances that are approved for use in cosmetic products for Europe in accordance with the Cosmetics Ordinance for Germany and in accordance with Regulation (EC) No. 1223/2009 on cosmetic products.
- Phenoxyethanol, methyl-, ethyl-, propylparaben, polyaminopropyl biguanide, piroctone olamine, potassium sorbate, benzethonium chloride, sodium benzoate, sodium salicylate, alcohol denat can advantageously be used as preservatives. and / or benzyl alcohol can be used.
- stabilizers are those substances that are not included in the list of permitted preservatives (Cosmetics Ordinance Annex 6; Ordinance (EC) No. 1223/2009, Annex V), but nevertheless have a stabilizing effect and / or promote the stability of the preparation when used together with preservatives.
- the following compounds are advantageous as stabilizers: propylene glycol, ethylhexylglycerine, 1,2-hexanediol, methylpropanediol, butylene glycol, caprylyl glycol, glyceryl caprylate, hydroxyacetophenone and / or pentylene glycol.
- the compounds sodium benzoate as a preservative and ethylhexylglycerol as a stabilizer are preferably contained.
- only sodium benzoate and ethylhexylglycerin are contained as preservatives or stabilizers.
- the at least one preservative and / or the at least one stabilizer are in the impregnating agent according to the invention with a total content of 0.0001 to 10% by weight, preferably from 0.0005 to 8% by weight, particularly preferably from 0.001 to 7% by weight before, based on the total weight of the impregnating agent.
- the impregnating agent according to the invention can contain perfume.
- the perfume used is advantageously a mixture of perfume raw materials.
- the perfume is mainly contained in order to give the impregnation agent and, after the impregnation process, also the entire product, a pleasant smell.
- it is also known of selected perfume raw materials that they can develop an antimicrobial effect or can also support the effect of conventional preservatives.
- the perfume in the impregnating agent according to the invention is present in a content of 0.05 to 1.0% by weight, in particular 0.14 to 0.4% by weight, based on the total weight of the impregnating agent.
- the preparation according to the invention additionally contains one or more other surfactants.
- surfactants can be selected from various classes of surfactants.
- amphoteric surfactants have both anionic and cationic groups and accordingly behave like anionic or cationic surfactants in aqueous solution, depending on the pH. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment. In the neutral pH range, however, they are zwitterionic, as the following example should clarify:
- Suitable amphoteric surfactants can be selected, for example, from:
- Acyl- / dialkylethylenediamine for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, disodium cocoamphodiacetate, disodium cocoamphomonoacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphodampiacetate and sodium,
- N-alkylamino acids for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.
- Betaines for example Coco Betaine, Cocoamidopropyl Betaine,
- Sultaines for example lauryl hydroxy sultaine.
- amphoteric surfactant or surfactants are selected from acyl / dialkylethylenediamine, in particular from acylamphoacetates, which can be described by the following formula:
- acylamphoacetates are synthesized in two steps. First, a fatty acid or a mixture of fatty acids derived from a natural oil, preferably a vegetable oil such as coconut oil, soybean oil or palm oil, is admixed with N- (2-hydroxyethyljethylenediamines. The 2-alkyl-1-hydroxyethylimidazolines formed are hydrolyzed with NaOH to linear amidoamines, which in turn are mixed with monochloroacetic acid to form acyl monoamphoacetates, and if larger molar amounts of monochloroacetic acid are used, acylamphodiacetates are formed.
- Acylamphacetates are amphoteric surfactants which, depending on the pH value, are available as anionic, zwitterioni cal or cationic surfactants.
- the sodium salts of acylamphoacetates are known to have little imitative effect.
- the acyl radical is derived from fatty acids of vegetable origin, preferably from fatty acids obtained from coconut oil.
- the sodium salts of the acylamphoacetates are selected.
- the total content of the at least one amphoteric surfactant is in the range from 0.01 to 1.5% by weight, preferably 0.05 to 0.5% by weight, particularly preferred 0.1 to 0.25% by weight, based on the total weight of the preparation and the respective active content.
- Nonionic surfactants are characterized by the fact that they do not form any ions in the aqueous medium.
- Suitable nonionic surfactants can be selected, for example, from:
- Alkanolamides such as cocamides MEA / DEA / MIPA
- amine oxides such as cocamidopropylamine oxide
- Ethers for example alkyl polyglycosides such as lauryl glucoside, decyl glucoside and
- Methyl glucose esters esters of hydroxy acids.
- the preparation according to the invention contains at least one nonionic surfactant selected from alkyl polyglycosides.
- Alkyl polyglycosides can be represented by the general structural formula RO- (Z) x , where R is an alkyl radical with 6 to 30 carbon atoms, Z is a sugar radical and x is the number of sugar radicals.
- the alkyl radical can be a radical with a specific number of carbon atoms or can be a mixture of alkyl radicals. Mixtures of this kind are obtained when natural oils such as palm oil, soya oil or coconut oil are used as the starting material for the production of the alkyl polyglucosides. It is preferred if the alkyl groups have essentially 12 to 18 carbon atoms.
- the sugar residues can be monosaccharides or oligosaccharides, which preferably have sugar residues with 5 or 6 carbon atoms. Suitable sugar residues are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, allose, mannose, gulose, idose, talose and sucrose. Sugar substitutes, such as palatinose, can also be present as sugar residues. Glucose and sucrose are particularly preferred, glucose being particularly preferred.
- Alkyl polyglycosides contain on average 1.1 to 5, preferably 1.1 to 2.0, sugar residues per molecule.
- Alkyl polyglycosides with the name Decyl Glucoside for example available with the trade name Plantacare 2000 UP from the company BASF Personal Care & Nutrition or with the name Coco-Glucoside, for example available with the trade name Plantacare 818 UP from the company BASF Personal Care, are very particularly preferred & Nutri tion.
- the total content of the at least one nonionic surfactant is in the range from 0.01 to 1.5% by weight, preferably 0.05 to 0.5% by weight, particularly preferably 0 , 1 to 0.25% by weight, based on the total weight of the preparation and the respective active content.
- block polymers can also be counted among the nonionic surfactants. Block polymers are copolymers of ethylene oxide and propylene oxide units with the designation poloxamer. You will be through the formula
- the proportion of a units can make up from 20 to 90% of the poloxamer.
- block polymers are contained in the impregnating agent according to the invention, they can preferably be selected from the group of liquid or solid block polymers with a relative molecular weight of 9840 to 14600, particularly preferably selected from the group of poloxamer 101, poloxamer 124 and / or poloxamer 184.
- the at least one block polymer is contained in the impregnating agent according to the invention, the at least one block polymer with a total content of 0.05 to
- surfactants are selected which are based on amino acids, preferably N-acylamino acids.
- Suitable acylamino acids can, for example, be selected from:
- Acyl glutamates for example sodium acyl glutamate, sodium cocoyl glutamate and sodium caprylic / capric glutamate; Acylasparate, such as Di-TEA-palmitolylaspartate,
- Acyl peptides for example palmitoyl-hydrolyzed milk protein, sodium cocoyl-hydrolyzed soy protein and sodium / potassium-cocoyl-hydrolyzed collagen,
- Sarcosinates for example myristoyl sarcosine, TEA-lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,
- alaninates such as acyl alaninates
- Glycinates such as acyl glycinates.
- acyl glutamate s
- acyl glycinate s
- a particularly advantageous acyl glutamate is Disodium Cocoyl Glutamate, which is available, for example, with the trade name Hostapon - CCG from Clariant.
- the preparation according to the invention contains one or more surfactants based on amino acids
- the total content of the one or more surfactants mentioned is in the range from 0.01 to 2.0% by weight, preferably 0.05 to 1.5% by weight, particularly preferably 0.1 to 1.0% by weight, based on the total weight of the preparation and the respective active content.
- the impregnating agent according to the invention contains at least one additional surfactant, in particular selected from the advantageous surfactant classes, then this at least one additional surfactant makes a contribution to increasing the cleaning performance.
- the impregnating agent according to the invention additionally contains one or more surface-active substances in the form of emulsifiers.
- these emulsifiers serve primarily as solubilizers and not to stabilize an emulsion.
- Preferred solubilizers in the form of emulsifiers are O / W emulsifiers. These emulsifiers are characterized by HLB values of> 8 to 15. According to the invention, O / W emulsifiers with an HLB value> 10 are preferred.
- HLB values can be determined using the following formula:
- HLB 20 x (1 - Miip ophii / M),
- M stands for the molar mass of the entire emulsifier.
- emulsifiers with an HLB value of up to approx. 8 are considered to be W / O emulsifiers.
- O / W emulsifiers have HLB values of greater than 8 to 15.
- Substances with HLB values greater than 15 are often referred to as solvents.
- O / W emulsifiers In principle, a large number of known O / W emulsifiers can be used, but it has proven advantageous to use ethoxylated O / W emulsifiers, it is particularly advantageous if the impregnating agent according to the invention contains PEG-40 Hydrogenated Cas- tor Oil. Ethoxylated emulsifiers are characterized by the fact that they contain polyethylene glycol units. Polyethylene glycol can be abbreviated to PEG. The ethoxylated O / W emulsifiers or solvents mentioned have proven to be advantageous if lipophilic components, such as oils or perfume ingredients, are to be incorporated into the impregnation agent according to the invention.
- the impregnating agent contains at least one O / W emulsifier, in particular at least one ethoxylated O / W emulsifier, then the at least one O / W emulsifier has a total content of 0.05 to 1.5% by weight, preferably 0.1 to 1.0% by weight, based on the total weight of the impregnating agent.
- the impregnating agent according to the invention additionally contains at least one humectant.
- Humectants are substances or mixtures of substances that give cosmetic preparations the property of positively influencing and / or regulating the moisture content of the flake, in particular the epidermis, after application or distribution on the flake.
- Advantageous humectants for the purposes of the present invention are, for example, glycerol, lactic acid, sodium chloride and / o sorbitol.
- the total content of the at least one humectant is 0.1 to 10% by weight, preferably 0.2 to 5.0% by weight, based on the total weight of the impregnation agent before.
- the impregnating agent according to the invention additionally contains at least one film former.
- Film formers can, for example, be selected from the group of mucopolysaccharides, such as, for example, hyaluronic acid, and / or from the group of biosaccharides, such as, for example, gum-1. If at least one film former selected from the groups mentioned is contained in the impregnating agent according to the invention, it has a total content of 0.01 to 1.5% by weight, preferably 0.05 to 1.0% by weight, based on the total weight of the impregnating agent.
- Film formers can also be chosen advantageously from the group of biopolymers, such as xanthan gum and / or cellulose derivatives. If at least one film former selected from this group is contained in the impregnating agent according to the invention, it is present with a total content of 0.01 to 1.5% by weight, in particular 0.05 to 1% by weight, based on the total weight of the impregnating agent.
- the impregnating agent according to the invention additionally contains at least one lipophilic component selected from the polar oils.
- Polar Oils are, for example, fatty acid triglycerides, ie triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids with a chain length of 8 to 24, in particular 12 to 18 carbon atoms.
- the fatty acid triglycerides can, for example, advantageously be chosen from the group of synthetic, semi-synthetic and natural oils such as. B.
- cocoglyceride olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil and the like.
- lipophilic components can furthermore be selected in the context of the present invention from the group of monoesters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols get a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 carbon atoms.
- ester oils can then advantageously be selected from the group of octyl palmitate, octyl cocoate, octyl isostearate, octyl dodecyl myristate, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-isopropyl oleate, n-isopropyl stearate, isopropyl stearate, isopropyl stearate, isopropyl isonate, 2-iso-isonate iso-isonate, butyl stearate, ethyl 2-ethylhexyl laurate, 2-ethylhexyl stearate, 2-hexyl decyl stearate, 2-octyl dodecyl palmitate, stearyl heptanoate
- the lipophilic component can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates.
- Oils such as sunflower oil, castor oil, soybean oil, jojoba oil, almond oil and macadamia oil are particularly preferred.
- the at least one lipophilic component is advantageously present with a total content of 0.05 to 5.0% by weight, preferably 0.1 to 2.0% by weight, based on the total weight of the impregnating agent. It is also also advantageous if the impregnating agent according to the invention additionally contains at least one cosmetic active ingredient selected from the group of vitamins, plant extracts and / or individual active ingredients.
- the vitamins selected from the vitamins of the B group and / or the vitamin B complex can particularly advantageously be incorporated into the impregnating agent according to the invention.
- Substances of the vitamin B group and / or the vitamin B complex are usually water-soluble and play a special role in the cell metabolism of plants and animals in particular.
- vitamins of the B group and / or of the vitamin B complex examples include thiamine (vitamin B1), riboflavin (vitamin B2), nicotinic acid (vitamin B3), nicotinic acid amide (niacinamide), pantothenic acid (vitamin B5), panthenol ( Pro vitamin B5), panthenol triacetate, panthenol monoethyl ether, pantolactone, pyridoxine and pyridoxal.
- panthenol as a substance of the vitamins of the B group and / or that of the vitamin B complex into the impregnating agent according to the invention.
- Panthenol can, for example, be obtained from BASF under the trade name D-Panthenol 75 W as a 77% solution in water.
- niacinamide can be obtained from Lonza.
- Vitamin E and its derivatives can also be selected particularly advantageously.
- Plant extracts can also be contained particularly advantageously. These extracts can be produced by extracting the entire plant or parts by extracting certain plant parts, for example flowers and / or leaves. The extraction is carried out by known, customary methods of extraction. A selection from the multitude of possible plant extracts is listed here, namely extracts from green tea, oak bark, nettle, witch hazel, hops, henna, chamomile, burdock root, horsetail, hawthorn, linden blossom, almond, aloe vera, spruce needle, horse chestnut, sandalwood , Wa cholder, coconut, mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, Sage, rosemary, birch, mallow, cuckoo herb, quendel, yarrow, thyme, me lisse, restraint, coltsfoot, marshmallow, meristem, ginseng, ginger root and others.
- an extract from chamomile can preferably be used.
- the impregnating agent according to the invention can also contain individual active ingredients in a particularly advantageous manner.
- An exemplary selection from the multitude of possible single active ingredients and their derivatives is listed here, namely alpha-lipoic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosyl rutin, carnitine, carnosine, natural and / or synthetic isoflavonoids, creatine, creatinine , Taurine, bisabolol and / or b-alanine and 8-hexadecen-1, 16-dicarboxylic acid (dioic acid).
- Bisabolol for example, can preferably be contained.
- At least one cosmetic active ingredient selected from the group of vitamins, plant extracts and / or individual active ingredients is contained in the impregnating agent according to the invention, this is at least one cosmetic active ingredient with a total content of 0.01 to 1.5%, preferably 0.05 to 1% by weight, based on the total weight of the impregnating agent.
- the impregnating agent can additionally contain cosmetic auxiliaries such as are customarily used in such agents, e.g. Complexing agents and dyes, antioxidants and substances to adjust the pH value.
- the impregnating agent according to the invention is free from oleic acid, in particular free from unsaturated free fatty acids and further in particular free from free fatty acids.
- fatty acids are understood to mean saturated and unsaturated carboxylic acids which have 8 or more carbon atoms.
- the term “free from” means that less than 0.2% by weight, preferably less than 0.075% by weight and particularly preferably less than 0.05% by weight of the respective substance in contained in the impregnating agent according to the invention, based on the total weight of the impregnating agent.
- Cosmetic or dermatological wipes can consist of both water-soluble (e.g. such as toilet paper) and water-insoluble materials. Furthermore, the cloths can be smooth or have a surface structure. According to the invention, surface-structured cloths are preferred. According to the invention, in combination with the impregnating agents according to the invention, use is made of “dry” wipes which consist of fleece, in particular of water jet-bonded and / or water jet embossed fleece.
- Such nonwovens can have macro-embossing of any desired pattern.
- the selection to be made is based on the one hand on the impregnation to be applied and on the other hand on the field of application on which the later cloth is to be used.
- embossed nonwovens are used, large cavities on the surface of the nonwoven and in the nonwoven facilitate the absorption of dirt and impurities when the soaked cloth is passed over the skin.
- the cleaning effect can be increased many times over compared to unembossed cloths.
- the cloth has a weight of 30 to 120 g / m 2 , preferably 35 to 80 g / m 2 , particularly preferably 40 to 65 g / m 2 (measured at 20 C ⁇ 2 ° C and with a humidity of the room air of 65% ⁇ 5% for 24 hours).
- all organic and inorganic fiber materials on a natural and synthetic basis can be used as starting materials for the non-woven fabric of the cloth.
- examples include viscose, cotton, cellulose, jute, hemp, sisal, silk, wool, polypropylene, polyester, polyethylene terephthalate (PET), aramid, nylon, polyvinyl derivatives, polyurethanes, polylactide, polyhydroxyalkanoate, cellulose esters and / or polyethylene as well as mineral fibers such as glass fibers or carbon fibers.
- PET polyethylene terephthalate
- aramid nylon
- polyvinyl derivatives polyurethanes
- polylactide polyhydroxyalkanoate
- cellulose esters polyhydroxyalkanoate
- / or polyethylene as well as mineral fibers such as glass fibers or carbon fibers.
- the present invention is not limited to the materials mentioned, but rather a large number of fibers can be used for web formation, and combinations of the materials mentioned are also possible.
- the fibers consist of a mixture of 70% PET and 30% Tencel / Lyocell.
- Lyocell is an industrially manufactured regenerated fiber made from cellulose and has a high dry and wet strength. Such wipes are available, for example, from Spuntech under the designation 1T3P45P70L300B.
- the fibers consist of 100% viscose.
- Such wipes are available, for example, from Spuntech under the designation 13P46V100. Fibers made from high-strength polymers such as polyamide, polyester and / or high-stretched polyethylene are also advantageous.
- Fibers made of viscose, polyester, polypropylene, lyocel, polylactid acid and cotton in different compositions are also advantageous. are offered by the company Suominen under the name Biolace and Fibrella.
- Biodegradable fibers which are dispersed in the water and can therefore be disposed of with the water rinse, are particularly advantageous. offered by the company Suominen under the name HYDFtASPUN® WL0791065.
- the fibers can also be colored in order to emphasize and / or increase the visual attractiveness of the fleece.
- the fibers can additionally contain UV stabilizers and / or preservatives.
- the fibers used to form the cloth preferably have a water absorption rate of more than 4 mm / [10 sec] (measured according to ERT 10.4-02, WSP 10.1), in particular more than 6 mm / [10 sec].
- the weight ratio of the unimpregnated cloth to the impregnating agent is advantageously 1: 1 to 1: 5, particularly advantageously 1: 1.5: to 1: 4.5, particularly advantageously 2.0: 3.5.
- composition of the impregnating agents can be found in the table below.
- the numerical values relate to percent by weight and the active content.
- the degree of impregnation (given in grams of impregnating agent per gram of cloth) was able to be reduced to ⁇ 2.5 while maintaining good product performance.
- the degree of impregnation is usually between 2.8-3.1 (market standard).
- Foaming impregnation media are also disadvantageous for the consumer, since this causes the wipes to stick to one another in the packaging and consequently the removal of the individual wipes is worsened.
- impregnating agents Two impregnating agents were compared with one another as an example, one impregnating agent contained the surfactant rhamnolipid (1% by weight, active content; example according to the invention) and the other impregnating agent contained the surfactant sodium methyl cocoyl taurate (0.8% by weight, active content; comparative example ). In both approaches, the pH was adjusted to 4.6.
- the impregnating agent with the surfactant sodium methyl cocoyl taurate even with the low surfactant content of 0.8% (active), was not suitable for impregnation due to the high foam development, while the impregnating agent containing rhamnolipid could be distributed excellently on the cloth.
- the numerical values relate to percent by weight and the active content.
- the numerical values refer to the active content.
- micelles were demonstrated using a reverse CMC.
- the impregnating agent III (sample) was poured into a glass vessel.
- the sample was diluted by adding demineralized water, while the same amount was sucked off again in order to keep the volume in the vessel the same.
- the surface tension was measured after each dilution step. The measurement was carried out using a tensiometer (tensiometer K100, Krüss) at 20 ° C.
- the compatibility of cleaning products is of fundamental importance, especially if these products are intended for use on skin areas that are classified as sensitive, such as the facial skin, especially the eye area (removal of face and eye make-up) or the baby skin.
- the tolerance of the raw material rhamnolipid was tested in two different concentrations. A very high concentration of rhamnolipid was chosen with the sample containing 5% by weight. The investigation was carried out using the RBC assay.
- a defined aliquot of isolated calf erythrocytes is incubated with a series of increasing concentrations of the sample to be examined (stock solution for formulations 1: 100 w / v or 0.1% active content in PBS for raw materials) for 10 minutes with shaking at room temperature (RT). After centrifugation, the supernatants obtained are analyzed photometrically for their content of released hemoglobin (Hb0 2 ) at 530 nm. From this, the relative degree of hemolysis is calculated and the concentration-response curve with the H 50 value [mI / ml] as the parameter is determined. This indicates the concentration of the sample at which 50% of the hemoglobin is released.
- a defined aliquot of isolated calf erythrocytes is incubated with a fixed concentration of the sample (1% w / v or 0.1% active content) for 10 minutes while shaking at room temperature and then centrifuged. The change in the spectral absorption at 575 nm and 540 nm is measured in comparison to the native HbOp.
- the denaturation index Dl [%] is calculated from the ratio of the absorption values to one another. Na lauryl sulfate (0.1% active content) is used as the 100% standard.
- the quotient represents the ratio of the parameters of hemolysis (H 5 o) and denaturation (Dl) and is used to characterize and classify the examined sample.
Abstract
Description
Claims
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DE102019202723.7A DE102019202723A1 (de) | 2019-02-28 | 2019-02-28 | Reinigungstücher getränkt mit Tränkungsmitteln enthaltend Biotenside |
PCT/EP2020/051963 WO2020173639A1 (de) | 2019-02-28 | 2020-01-28 | Reinigungstücher getränkt mit tränkungsmitteln enthaltend biotenside |
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DE (1) | DE102019202723A1 (de) |
WO (1) | WO2020173639A1 (de) |
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EP3871652A1 (de) | 2020-02-25 | 2021-09-01 | Dr. Schumacher GmbH | Wasserbasiertes tränkungsmittel für feuchttücher |
WO2021236927A1 (en) * | 2020-05-20 | 2021-11-25 | Manhattan College | Silicone-free conditioning cleansing composition |
DE102020212221B3 (de) | 2020-09-29 | 2022-01-27 | Beiersdorf Aktiengesellschaft | Verbesserte Reinigungstücher getränkt mit Tränkungsmitteln basierend auf Hydrodispersionen |
CN115678687A (zh) * | 2022-09-15 | 2023-02-03 | 河南海利未来科技集团有限公司 | 一种低泡杀菌的洗碗机清洗剂及其制备方法 |
WO2024073333A1 (en) * | 2022-09-26 | 2024-04-04 | Stepan Company | Hard surface cleaning compositions comprising rhamnolipids and glutamate co-surfactant |
WO2024073335A1 (en) * | 2022-09-26 | 2024-04-04 | Stepan Company | Hard surface cleaning compositions comprising rhamnolipids and sultaine co-surfactant |
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DE19600743A1 (de) | 1996-01-11 | 1997-07-24 | Henkel Kgaa | Verwendung von Mischungen aus Glycolipiden und Tensiden |
DE10157543A1 (de) | 2001-11-23 | 2003-06-12 | Beiersdorf Ag | Emulsionsgetränkte Tücher |
DE10216511A1 (de) | 2002-04-11 | 2003-10-23 | Beiersdorf Ag | Stärkehaltige kosmetische Tücher |
DE10219638B4 (de) | 2002-05-02 | 2005-05-04 | Beiersdorf Ag | Hautreinigungstuch |
DE10246160A1 (de) | 2002-10-02 | 2004-04-15 | Beiersdorf Ag | Mit Befeuchtungsmitteln getränkte Tücher, welche Zinkoxid einer Partikelgröße von 20 bis 100 mm enthalten |
DE10352370A1 (de) | 2003-11-10 | 2005-06-23 | Beiersdorf Ag | Lipidhaltiges Substrat |
DE202004007851U1 (de) | 2004-05-13 | 2004-08-05 | Beiersdorf Ag | Kosmetisch oder dermatologisch getränktes Tuch |
DE102011090030A1 (de) * | 2011-12-28 | 2013-07-04 | Evonik Industries Ag | Wässrige Haar- und Hautreinigungszusammensetzungen, enthaltend Biotenside |
DE102012200383A1 (de) | 2012-01-12 | 2013-07-18 | Beiersdorf Ag | Hautreinigungstuch mit einstellbaren Peelingeigenschaften |
EP2786742A1 (de) | 2013-04-02 | 2014-10-08 | Evonik Industries AG | Kosmetika enthaltend Rhamnolipide |
MX348924B (es) | 2013-04-25 | 2017-07-04 | Unilever Nv | Composiciones de limpieza con propiedades de dispensado y suspensión mejoradas. |
US20160000661A1 (en) * | 2014-07-02 | 2016-01-07 | Essential Effects LLC | No-rinse hair cleansing formulation and wipes |
DE102015212822A1 (de) * | 2015-07-09 | 2017-01-12 | Beiersdorf Ag | Reinigungstücher getränkt mit Tränkungsmitteln basierend auf einer Mizellentechnologie |
DE102015217503A1 (de) * | 2015-09-14 | 2017-03-16 | Henkel Ag & Co. Kgaa | PEG-freie kosmetische Reinigungsmittel mit Biotensiden |
DE102015217504A1 (de) | 2015-09-14 | 2017-03-16 | Henkel Ag & Co. Kgaa | Peeling mit Biotensiden |
CH712858A2 (de) * | 2016-08-29 | 2018-03-15 | Remo Richli | Milde Zubereitungen mit alkoxylierten Fettsäureamiden und Glycolipid-Biotensiden. |
US11606963B2 (en) * | 2016-10-07 | 2023-03-21 | Evonik Operations Gmbh | Composition containing glycolipids and preservatives |
DE102018210175A1 (de) * | 2018-06-22 | 2019-12-24 | Beiersdorf Ag | Milde kosmetische Reinigungszubereitung |
CN109350593B (zh) * | 2018-11-01 | 2021-05-04 | 江南大学 | 一种远红外防冻免洗湿巾的制备及其应用 |
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2020
- 2020-01-28 EP EP20702444.9A patent/EP3930660A1/de not_active Withdrawn
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WO2020173639A1 (de) | 2020-09-03 |
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