EP3902773A1 - Procede et dispositif d'amelioration de la biodegradabilite d'une boue - Google Patents
Procede et dispositif d'amelioration de la biodegradabilite d'une boueInfo
- Publication number
- EP3902773A1 EP3902773A1 EP19829228.6A EP19829228A EP3902773A1 EP 3902773 A1 EP3902773 A1 EP 3902773A1 EP 19829228 A EP19829228 A EP 19829228A EP 3902773 A1 EP3902773 A1 EP 3902773A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- emulsion
- zone
- mud
- sludge
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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Classifications
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
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- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/232—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles
- B01F23/2323—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using flow-mixing means for introducing the gases, e.g. baffles by circulating the flow in guiding constructions or conduits
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- B01F25/31241—Injector mixers in conduits or tubes through which the main component flows with Venturi elements; Details thereof characterised by the place of introduction of the main flow the main flow being injected in the circumferential area of the venturi, creating an aspiration in the central part of the conduit
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- B01F25/51—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is circulated through a set of tubes, e.g. with gradual introduction of a component into the circulating flow
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- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
- B01F25/53—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is discharged from and reintroduced into a receptacle through a recirculation tube, into which an additional component is introduced
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F1/00—Treatment of water, waste water, or sewage
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/123—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using belt or band filters
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01F2215/0413—Numerical information
- B01F2215/0436—Operational information
- B01F2215/0468—Numerical pressure values
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/02—Biological treatment
- C02F11/04—Anaerobic treatment; Production of methane by such processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/38—Gas flow rate
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/40—Liquid flow rate
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/04—Flow arrangements
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/06—Pressure conditions
- C02F2301/066—Overpressure, high pressure
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/06—Sludge reduction, e.g. by lysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Definitions
- the present invention relates to a method for improving the biodegradability of an organic liquid sludge.
- organic mud a mud comprising at least 10% organic matter.
- Sludge disintegration processes are already known, for example used as pretreatment before anaerobic digestion.
- the objective of these techniques is to dissolve the particulate organic matter and to reduce the size of the bacterial flocs.
- preparation techniques are known by the action of ultrasound on the mud. However, these will generate cavitation phenomena at the molecular level, and therefore very high pressures / temperatures causing oxidation by the production of free radicals.
- the maximum recommended load is 6 to 8 g per liter of DM, which necessarily leads to a design of a large preparation installation.
- the present invention aims to overcome these drawbacks by improving in particular the possibilities reconditioning and / or reuse of sludge thanks to a treatment that better meets those previously known to the requirements of the practice, in particular in that it surprisingly allows a
- the present invention proposes in particular a method for improving the biodegradability of an organic sludge comprising at least two successive treatment cycles, each cycle being of total duration between around 8 s and from order
- each cycle comprising a first step of creating a first emulsion of hydrolysed sludge in a first zone called the reduced zone, by injecting a gas into said reduced zone, a second stage of expansion
- expansion zone 25 abrupt emulsion in a second zone, called expansion zone, and a third step of recovery of the emulsion via a third zone called restriction zone.
- the invention also provides a method for improving the biodegradability of an organic liquid sludge comprising a first step of creating a
- the method according to the invention therefore makes it possible in particular to
- the first zone, called reduced is a first zone
- the particularly small size of the injection area (for example 0.001 m 3 ) will allow an excellent mud / air mixture.
- the gas used is air.
- the presence of oxygen in the air further improves the constitution of an air / bacterial flock emulsion by bringing a level of dissolved oxygen and in the form of air bubbles allowing even better support for bacterial proliferation.
- the initial step is repeated on the hydrolyzed emulsion obtained successively at least N times with N> 2, for example N> 3 and / or N> 7 or 8.
- the invention on the one hand by increasing the density of MS, and on the other hand by preserving a
- the pressure / depression actions described above improve the nature and structure of the organic material which is better dispersed and better lysed with regard to bacteria, which generates better accessibility and biodegradability of the organic material by increasing the possibilities of exchanges, and therefore for example in the case of a next methanization step 10, the yield of the digestion reaction and therefore of methane production.
- one and / or moreover has recourse to one and / or the other of the following provisions:
- the first zone being the central part of a venturi elongated around an axis parallel to the direction of supply of the mud, the air is injected into said venturi obliquely with respect to the axis of the venturi;
- the second average pressure P2 in the second zone is P2> 3.5 bars and the third pressure P3 downstream of the restriction zone is atmospheric pressure.
- the emulsion is degassed strongly after the third zone before reiteration
- the air is injected in the direction of flow or against the flow of mud and / or injected at an angle between 20 ° and 90 °, for example between 20 ° and 50 °, for example 30 ° with the direction of the mud flow;
- Excess gas is extracted by soft impact of the emulsion on itself or on an energy absorbing flap, braking the emulsion.
- energy absorbent is meant to arrange for
- soft shock is meant a shock or progressive contact without percussion either on the emulsion itself
- flap or flexible wall means an elastic or semi-rigid element, for example made of rubber or equivalent, capable of absorbing and / or creating a loss
- the energy used is provided by the kinetic energy of two flows, air and mud, which are therefore subjected to several sequences:
- the method according to the invention leads to an improvement in the lysis of a few tens of percent of the bacteria in the medium, ie 10%, 20% or even more.
- the biodegradability of sludge is measured in particular by analyzing and comparing the capacity of bacterial proliferation in culture on agar, for example in a petri dish.
- the invention also provides a device implementing the methods as described above.
- It also proposes a device for improving the biodegradability of an organic sludge comprising a container, or reactor, in a pressurized line,
- 10 means for continuously supplying the container with mud, comprising a venturi for passing the mud, elongated around an axis, at least one nozzle for injecting air into the narrowing of said venturi, for injection at a angle to the axis
- the device has two air injection nozzles into the venturi at an angle with an angle of between 20 ° and 90 ° relative to the axis of said venturi.
- the invention also provides an organic mud soup or emulsion obtained after N passages by recirculation in the reactor described above, with N 3 2, advantageously 3 3, or even greater than 7.
- the organic mud soup includes
- lysed bacteria By lysed bacteria is meant a bacterium whose cell membrane has been destroyed,
- FIG. 1 is a block diagram showing the
- FIG. 2 is a diagram illustrating an embodiment of a device implementing the
- FIG. 2A shows in section an embodiment of an ejector usable with the invention.
- FIGS. 2B to 2F show other modes of
- FIG. 3 schematically illustrates in section the degasser of the device according to an embodiment of the invention.
- FIGS. 3A and 3B are front views and in
- Figures 4 and 4A are views from above and in section along IVA - IVA of another embodiment of the degasser with braking wall.
- Figure 4B is a schematic sectional view of another embodiment of the degasser with brake wall.
- FIG. 5 illustrates the dispersion of the organic material, the analysis of which (dispersion, distribution,
- FIG. 6 illustrates the porosity, the size and the geometry of the bacterial structures (aggregates) and the lysis obtained after none, one and eight repetitions of the cycle according to the embodiment of the invention more particularly described here on a liquid mud.
- FIGS. 7 and 8 respectively illustrate a group of bacteria in the process of destruction magnified to 0.5 micron, and bacteria completely lysed to 0.2 micron, respectively after eight reiterations.
- Figure 1 schematically illustrates a device
- a first emulsion of hydrolysed sludge is created in a first zone 3 (called the reduced zone) of the pipeline, by injection of a gas 4 into the reduced zone, by imparting to the emulsified sludge in said great area
- the reduced zone 3 is therefore a zone of low pressure Pi (for example Pi £ 0.5 bar relative) and of high speed allowing excellent mixing
- the first emulsion is then introduced into a second zone 5, called expansion zone or reactor, of larger volume, giving the first emulsion a low speed V2 (£ 1 m / s) but under a strong
- Zone 5 (or reactor) then continuously leads to a third zone 6 called restriction, for example formed by a valve 7 for regulation, evacuation of the first emulsion, of low
- This recirculation located upstream of the first reduced zone 3. This recirculation can be done via a nozzle 12 located upstream of a degasser 13 of the second emulsion, or downstream 14 of said degasser, in a manner controlled by an automaton 15 as a function of the number N
- Each emulsion circulation cycle between the reduced zone 3 and the restriction zone 6 is equivalent to a passage time (and therefore of gas bubble / sludge contact), in particular in the reactor, of
- the emulsion, enriched in gas / air at each passage, is thus passed through successive decompression / pressure / decompression or even acceleration / deceleration / acceleration phases.
- the method according to the invention allows thickening of the sludge obtained in fine after decantation (when leaving
- Figure 2 shows an embodiment of a device 16 according to the invention.
- the liquid organic sludges 17 are introduced via a feed pump 18 and a pipe 19 10 to a restriction 20 for example formed by a venturi in a tubular enclosure 21, for example 1 m high and 50 cm in diameter.
- a compressor 22 supplies compressed air 23 to the interior of the venturi 20, at an angle, for example with
- the tubular enclosure is for example maintained at a pressure of the order of 3 bars to 5 bars relative.
- This valve 25 constitutes a restriction.
- the emulsion feeds the degasser 26 according to the embodiment of the invention more particularly described here.
- the emulsion degasser is open at atmospheric pressure at 27 and comprises a vertical tube 28 for supplying the emulsion to a fountain allowing a soft impact of the emulsion on itself, which allows a gentle degassing and non-destructive of the emulsion, such as
- the gas obtained may or may not be reused (circuit 29) to be recycled via the compressor 22, in the restriction zone 20.
- the sludge remains for a determined time inside the degasser, for example of the order of 1 to 5 minutes, then is evacuated by gravity via a pipe 30 to a further treatment 31.
- FIG. 2A shows a mode of
- venturi 36 comprising a hollow body 37 comprising a mud inlet (flow F) formed by a frustoconical bore 38
- the mud / gas emulsion is carried out in this portion of cylindrical bore for example of volume 1 liter, for a mud flow rate of 50 m3 / h and of gas injected, advantageously air, of 250 Nm 3 / h.
- the cylindrical bore portion opens onto a reverse frustoconical portion 42 for discharging the emulsion towards the enclosure / reactor 21.
- FIGS. 2B to 2F show embodiments of a venturi with gas injection in the center of the venturi, with a nozzle against the flow of mud for example with an angle of 45 ° (FIG. 2B), a nozzle
- Figure 3 shows schematically in section the degasser 26 according to an embodiment of the invention.
- the degasser comprises a container 43, for example cylindrical, of height substantially equal to 1 m.
- the diameter of the container is for example between 200 and 300 millimeters.
- the mud is supplied at 44 by a pipe, for example with a diameter of 80 mm, which penetrates into the lower part 45 of the container and then has a 90 ° bend U and a
- the vertical cylindrical part 46 ends with a neck 47 for leaving the mud fountain.
- the container defines an internal volume V in which
- the volume has a bottom 48 provided with an outlet pipe 49 of diameter identical to the inlet pipe of the emulsion.
- the height of the upper part 51 is arranged to be equal to or slightly less than that of the neck 47, relative to the bottom of volume V, to allow a residence time in the degasser, determined, for example 20 s.
- Volume V ends at the top with a
- the mud emulsion that is to say between the bottom of the container and the periphery of the neck of the vertical cylindrical part 46, is for example between 400 and 600 mm for example 500 mm.
- FIGS. 3A and 3B show another embodiment of degasser according to the invention allowing degassing of the emulsion by soft shocks of
- FIGS. 4 and 4A show in top view and in section according to IVA - IVA, an example of degasser 60 according to another embodiment of the invention, comprising an enclosure E, for example of rectangular shape with cut corners C, willing horizontally with respect to the arrival of the mud flow F, for example of dimension LX 1 XH: 300 X 400 X 300 for a treatment flow rate of 10-13 M 3 / h, an MS of 8 to 10 g / l and a Veff of 30 liters.
- the Veff (Effective volume) is a volume of mud / water at the inlet of the degasser allowing the energy necessary for good degassing of the emulsion to be absorbed.
- This volume varies according to the different sizes.
- the enclosure E comprises a flow inlet which opens into a passage chamber 61, for example cylindrical, having a portion of cylinder 62 open at the bottom, over the entire length of the
- the enclosure has upwards a tube T, for evacuating the air from the degasser, and an outlet orifice S at the other end.
- the enclosure E may or may not have, for example 2/3 of its length, a
- Such a wall either directly brakes the emulsion, or further reinforces the homogeneity of
- FIG. 4B shows a variant of the degasser 60 ′ according to another embodiment of the invention, longitudinally.
- the internal wall intended to absorb the shock of the mixture can advantageously be made of rubber or other soft material. However, it is also possible to use, for example, a more rigid wall, for example of a more or less convex shape.
- FIG. 4B shows an inlet A for the emulsion and the excess gas in a zone B of the enclosure 60 ′ filled with mud X at the bottom and gas at the top.
- Zone B is closed by a wall L damping the energy of the flow, flexible or hard wall
- the excess gas is extracted from the gaseous sky by an air vent / vent D.
- the extraction of the liquid flow under poured by the wall L is carried out by the zone G which offers a calm, laminar flow.
- the destruction rate (lysis) is greater than or equal to 80%.
- FIGS. 7 and 8 show respectively at the scale of 0.5 micron and 0.2 25 micron, the destruction of the membranes 79 of the bacteria 80, giving access to their content, and thus showing their biodegradability, after 8 passages.
- the sludge 17 is supplied with a continuous flow by pumping at a flow Q, for example of 20 m 3 / h, in a pipe for example of diameter DN50 and of length L equal to a few meters.
- a flow Q for example of 20 m 3 / h
- a pipe for example of diameter DN50 and of length L equal to a few meters.
- the emulsion is recycled upstream of the degasser N times (Circuit 32).
- the emulsion then leads to rain in degasser 26.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Molecular Biology (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Treatment Of Sludge (AREA)
- Degasification And Air Bubble Elimination (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1874159A FR3091277B1 (fr) | 2018-12-26 | 2018-12-26 | Procédé et dispositif d’amélioration de la biodégradabilité d’une boue |
PCT/EP2019/087032 WO2020136212A1 (fr) | 2018-12-26 | 2019-12-24 | Procede et dispositif d'amelioration de la biodegradabilite d'une boue |
Publications (1)
Publication Number | Publication Date |
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EP3902773A1 true EP3902773A1 (fr) | 2021-11-03 |
Family
ID=66867320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19829228.6A Pending EP3902773A1 (fr) | 2018-12-26 | 2019-12-24 | Procede et dispositif d'amelioration de la biodegradabilite d'une boue |
Country Status (11)
Country | Link |
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US (1) | US20220112113A1 (ko) |
EP (1) | EP3902773A1 (ko) |
JP (1) | JP2022515281A (ko) |
KR (1) | KR20210107013A (ko) |
CN (1) | CN113226993A (ko) |
AU (1) | AU2019414856A1 (ko) |
BR (1) | BR112021009605A2 (ko) |
CA (1) | CA3120168A1 (ko) |
FR (1) | FR3091277B1 (ko) |
IL (1) | IL284252A (ko) |
WO (1) | WO2020136212A1 (ko) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113816575A (zh) * | 2021-10-29 | 2021-12-21 | 辽宁大学 | 一种利用水力空化装置降解剩余污泥的方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU4625089A (en) * | 1988-11-22 | 1990-06-12 | Stephen Terence Dunne | Liquid-gas mixing device |
FR2914919B1 (fr) * | 2007-04-13 | 2011-09-16 | Orege | Procede et dispositif d'epuration d'effluents liquides. |
PE20141388A1 (es) * | 2011-12-09 | 2014-10-22 | Outotec Oyj | Aparato y metodo de desaireacion |
GB2500663B (en) * | 2012-03-29 | 2017-04-12 | Hydro Ind Ltd | Method and apparatus for treatment of fluids by media assisted electro-based treatment |
FR3013702A1 (fr) * | 2013-11-27 | 2015-05-29 | Orege | Procede et dispositif de traitement de boues liquides, et galettes de boues obtenues avec un tel procede. |
CN106102857B (zh) * | 2013-11-27 | 2018-05-04 | 奥里格公司 | 处理液体污泥的方法和设备以及利用这种方法获得的污泥饼 |
FR3036698B1 (fr) * | 2015-05-29 | 2021-04-09 | Orege | Procede et dispositif d'epuration d'eaux domestiques ou industrielles. |
CN105836834B (zh) * | 2016-05-23 | 2019-06-04 | 武汉保尔富科技有限公司 | 一种溶气释放器 |
-
2018
- 2018-12-26 FR FR1874159A patent/FR3091277B1/fr active Active
-
2019
- 2019-12-24 AU AU2019414856A patent/AU2019414856A1/en active Pending
- 2019-12-24 BR BR112021009605-1A patent/BR112021009605A2/pt unknown
- 2019-12-24 KR KR1020217019604A patent/KR20210107013A/ko unknown
- 2019-12-24 CA CA3120168A patent/CA3120168A1/fr active Pending
- 2019-12-24 JP JP2021537820A patent/JP2022515281A/ja active Pending
- 2019-12-24 WO PCT/EP2019/087032 patent/WO2020136212A1/fr unknown
- 2019-12-24 EP EP19829228.6A patent/EP3902773A1/fr active Pending
- 2019-12-24 US US17/418,196 patent/US20220112113A1/en not_active Abandoned
- 2019-12-24 CN CN201980085565.5A patent/CN113226993A/zh active Pending
-
2021
- 2021-06-21 IL IL284252A patent/IL284252A/en unknown
Also Published As
Publication number | Publication date |
---|---|
FR3091277A1 (fr) | 2020-07-03 |
CN113226993A (zh) | 2021-08-06 |
US20220112113A1 (en) | 2022-04-14 |
JP2022515281A (ja) | 2022-02-17 |
FR3091277B1 (fr) | 2021-07-23 |
CA3120168A1 (fr) | 2020-07-02 |
BR112021009605A2 (pt) | 2021-08-10 |
AU2019414856A1 (en) | 2021-06-24 |
KR20210107013A (ko) | 2021-08-31 |
WO2020136212A1 (fr) | 2020-07-02 |
IL284252A (en) | 2021-08-31 |
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