EP3898516A4 - Verfahren zur rückgewinnung von lithium aus sole unter zugabe von alkali - Google Patents

Verfahren zur rückgewinnung von lithium aus sole unter zugabe von alkali Download PDF

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Publication number
EP3898516A4
EP3898516A4 EP19900707.1A EP19900707A EP3898516A4 EP 3898516 A4 EP3898516 A4 EP 3898516A4 EP 19900707 A EP19900707 A EP 19900707A EP 3898516 A4 EP3898516 A4 EP 3898516A4
Authority
EP
European Patent Office
Prior art keywords
brine
alkali
addition
recovering lithium
recovering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19900707.1A
Other languages
English (en)
French (fr)
Other versions
EP3898516A1 (de
Inventor
Craig Johnstone Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Lithium Ltd
Original Assignee
Standard Lithium Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/224,463 external-priority patent/US11534748B2/en
Priority claimed from US16/410,523 external-priority patent/US11518686B2/en
Application filed by Standard Lithium Ltd filed Critical Standard Lithium Ltd
Publication of EP3898516A1 publication Critical patent/EP3898516A1/de
Publication of EP3898516A4 publication Critical patent/EP3898516A4/de
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/145—Ultrafiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/38—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving specific interaction not covered by one or more of groups B01D15/265 and B01D15/30 - B01D15/36, e.g. affinity, ligand exchange or chiral chromatography
    • B01D15/3804—Affinity chromatography
    • B01D15/3828—Ligand exchange chromatography, e.g. complexation, chelation or metal interaction chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/282—Porous sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/10—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/02—Column or bed processes
    • B01J47/026—Column or bed processes using columns or beds of different ion exchange materials in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
    • B01J49/06—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing cationic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/12—Addition of chemical agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/18—Details relating to membrane separation process operations and control pH control
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/18—Use of gases
    • B01D2321/185—Aeration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Removal Of Specific Substances (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
EP19900707.1A 2018-12-18 2019-05-14 Verfahren zur rückgewinnung von lithium aus sole unter zugabe von alkali Pending EP3898516A4 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US16/224,463 US11534748B2 (en) 2017-12-27 2018-12-18 Process for recovery of lithium from brine
PCT/CA2018/000240 WO2019126862A1 (en) 2017-12-27 2018-12-20 Process for recovery of lithium from brine
US16/410,523 US11518686B2 (en) 2017-12-27 2019-05-13 Process for recovery of lithium from brine
PCT/CA2019/000064 WO2020124192A1 (en) 2018-12-18 2019-05-14 Process for recovery of lithium from brine with addition of alkali

Publications (2)

Publication Number Publication Date
EP3898516A1 EP3898516A1 (de) 2021-10-27
EP3898516A4 true EP3898516A4 (de) 2022-10-26

Family

ID=71102349

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19900707.1A Pending EP3898516A4 (de) 2018-12-18 2019-05-14 Verfahren zur rückgewinnung von lithium aus sole unter zugabe von alkali

Country Status (12)

Country Link
EP (1) EP3898516A4 (de)
JP (1) JP7455125B2 (de)
KR (1) KR102758996B1 (de)
CN (1) CN113439070B (de)
AU (1) AU2019409881B2 (de)
CA (1) CA3123943A1 (de)
CL (1) CL2021001596A1 (de)
MX (1) MX2021007232A (de)
NZ (1) NZ777697A (de)
PH (1) PH12021551420A1 (de)
UA (1) UA130220C2 (de)
WO (1) WO2020124192A1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3184777A1 (en) * 2020-06-08 2021-12-16 Standard Lithium Ltd. Process for recovery of lithium from brine
KR20230058051A (ko) * 2020-08-28 2023-05-02 리투스 인크. 수성 용액으로부터 리튬의 추출 및 회수에 유용한 나노물질 복합체
CN115945162B (zh) * 2023-01-31 2024-06-14 北京碧水源膜科技有限公司 一种盐湖提锂钛系吸附材料的制备方法、所述制备方法得到的产品及其应用
CN116747914A (zh) * 2023-06-16 2023-09-15 北京北大先锋科技股份有限公司 一种从废弃锂分子筛中连续回收锂盐的方法及系统

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7157065B2 (en) * 1998-07-16 2007-01-02 Chemetall Foote Corporation Production of lithium compounds directly from lithium containing brines
US20080119350A1 (en) * 2006-11-20 2008-05-22 Korea Institute Of Geosciences And Mineral Resources Ion exchange type lithium adsorbent using filter and method for preparing the same
KR101047986B1 (ko) * 2010-11-26 2011-07-13 한국지질자원연구원 Ｃｃｄ 공정을 이용한 리튬 이온의 흡착/탈착 장치 및 그 방법
KR101533674B1 (ko) * 2011-05-27 2015-07-03 엠파이어 테크놀로지 디벨롭먼트 엘엘씨 리튬 이온 배터리 폐기물로부터 리튬의 효과적인 회수
JP5979712B2 (ja) * 2011-06-20 2016-08-31 国立研究開発法人日本原子力研究開発機構 金属吸着材とその製造方法及び金属吸着材を用いた金属捕集方法
MX2018001457A (es) * 2015-08-06 2018-05-28 Inneovation Pty Ltd Extraccion de litio a partir de salmuera.
PL3500362T3 (pl) * 2016-08-18 2024-06-10 Exsorbtion Inc. Ekstrakcja jonów metali z solanek
CN106345394B (zh) * 2016-11-02 2019-06-25 海西永正锂业有限公司 一种从卤水中提取锂并制备高纯锂浓液的方法
EP4438749A3 (de) * 2016-11-14 2025-01-08 Lilac Solutions, Inc. Lithiumextraktion mit beschichteten ionenaustauschteilchen
CN107128955B (zh) * 2017-05-15 2019-01-15 李陇岗 一种从温泉水中提取碳酸锂的方法
US20200299805A1 (en) * 2017-06-27 2020-09-24 Purlucid Treatment Solutions (Canada) Inc. Method and apparatus for the treatment of water with the recovery of metals
CN108187606B (zh) * 2018-01-22 2020-07-17 天津市职业大学 一种导电性钛系锂离子筛及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
No further relevant documents disclosed *

Also Published As

Publication number Publication date
CN113439070A (zh) 2021-09-24
BR112021011997A2 (pt) 2021-09-21
PH12021551420A1 (en) 2022-05-02
UA130220C2 (uk) 2025-12-24
KR102758996B1 (ko) 2025-01-23
CN113439070B (zh) 2023-10-03
WO2020124192A1 (en) 2020-06-25
EP3898516A1 (de) 2021-10-27
CA3123943A1 (en) 2020-06-25
JP7455125B2 (ja) 2024-03-25
JP2022515389A (ja) 2022-02-18
KR20210107722A (ko) 2021-09-01
AU2019409881B2 (en) 2025-09-25
CL2021001596A1 (es) 2022-04-01
AU2019409881A1 (en) 2021-07-22
MX2021007232A (es) 2021-09-23
NZ777697A (en) 2025-11-28

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