Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D11/00—Inks
  • C09D11/02—Printing inks
  • C09D11/10—Printing inks based on artificial resins
  • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D11/00—Inks
  • C09D11/30—Inkjet printing inks
  • C09D11/32—Inkjet printing inks characterised by colouring agents
  • C09D11/322—Pigment inks
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
  • C09D133/04—Homopolymers or copolymers of esters
  • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
  • C09D133/08—Homopolymers or copolymers of acrylic acid esters
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
  • C09J133/04—Homopolymers or copolymers of esters
  • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
  • C09J133/08—Homopolymers or copolymers of acrylic acid esters
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
  • C09J7/21—Paper; Textile fabrics
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
  • C09J7/29—Laminated material
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2400/00—Presence of inorganic and organic materials
  • C09J2400/20—Presence of organic materials
  • C09J2400/26—Presence of textile or fabric
  • C09J2400/263—Presence of textile or fabric in the substrate
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2423/00—Presence of polyolefin
  • C09J2423/006—Presence of polyolefin in the substrate
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2433/00—Presence of (meth)acrylic polymer
  • C09J2433/001—Presence of (meth)acrylic polymer in the barrier layer

Definitions

• the present invention relates to an adhesive tape, particularly a duct tape, having a digitally printed design thereon and to a method of making a duct tape having a digitally printed design, particularly to a method of making a duct tape having a customized, digitally printed design.
• Duct tape typically is relatively thin having a thickness in a range of 5 mils to 12 mils. Duct tape can be tom by hand; however, when unrolled it has a tendency to adhere to itself.
• duct tapes are printed two ways.
• the first method is reverse printing which allows the duct tape to be self-wound such that no release liner is required.
• Another option is to use surface printing; however, the print quality is generally very poor and the ink adhesion to the tape is also very poor.
• Both of these methods also require an investment in print plates and typically require substantial minimum order quantities.
• the idea behind custom digital printing is to create a tape product that requires no or small minimum order quantities» has very short lead times (on demand printing) and has performance comparable to printed duct tapes that are in the market today. Also, there is no investment in print plates required.
• the present invention relates to a digitally printed duct tape and to methods of making the digitally printed duct tape.
• the methods of the present invention are particularly suited to printing customized designs and to printing designs in small batches.
• the methods of the present invention produce a printed duct tape having a UV cured, ink system with the improved efficiencies and cost effectiveness of digital printing.
• the digital printed duct tape of the present invention may be made with or with or without a release liner.
• the digital printed duct tape may comprise a material or composition having overcoat properties, release properties, or a combination thereof,
• the method(s) of the presort invention may be used to make custom digital printed duct tape in the form of die-cuts, rolls, sheets, and banners.
• duct tapes and other tapes such as packaging and paper
• have become expressive tools for many crafters solidifies the need for further customization for the end user.
• It would be impossible to have every desirable design of duct tape Beyond this, many users desire to personalize their tape experience. They may want a personal photograph or picture on their duct tape or other tape. For example, a company may seek to have its logo or company name on the tape. Other opportunities include special occasions or events such as weddings, birthdays, reunions, anniversaries or graduations.
• An advantage of the methcd(s) of the present invention is the ability to feed or electronically send to a printer a design via an image file with no print plates required, such that the present method(s) is both inexpensive and fast
• Fig. 1 is a drawing illustrating a method of making the digital printed duct tape of the present invention.
• FIG. 2 is a drawing illustrating another method of making the digital printed duct tape of the present invention.
• FIG. 3 is a drawing illustrating another method of making the digital printed duct tape of the present invention.
• FIG. 4 is a drawing illustrating yet another method of making the digital printed duct tape of the present invention.
• FIG. 5 is a drawing illustrating still yet another method of making the digital printed duct tape of the present invention.
• Fig. 6A is a drawing illustrating a digital printed duct tape of the present invention.
• Fig, 6B is an exploded view of the film of the digital printed duct tape of Fig. 6A.
• Fig, 7 is a drawing illustrating an embodiment of the digital printed duct tape of the present invention.
• FIG. 1 A method of making the digital printed duct tape is shown in Fig. 1.
• a duct tape having an adhesive surface and a non-adhesive surface is provided, and the duct tape is unwound at point 1.
• Releasing the duct tape from a roll is somewhat tight and may require special web handling to facilitate unwinding.
• the duct tape travels over a rollers) with the adhesive surface of the duct tape in contact with the roller(s) until the duct tape teaches point 2.
• the roller(s) in contact with the adhesive surface of the tape are release coated.
• the duct tape undergoes tension and relaxation at point 2.
• the roller over which the duct tape passes is in contact with the non-adhesive surface of the duet tape.
• the adhesive surface of the duct tape passes over other rollers having a release coating, such as polytetrafluoroethylene (PTFE), shown at point 3.
• PTFE polytetrafluoroethylene
• the non-adhesive surface of the duet tape is treated at point 4 in preparation for printing, for example, by passing through a plasma or corona treater.
• Treatment of the non-adhesive surface of the duct tape may be for a purpose including, hut not limited to, preparing the surface for ink adherence and deadening the release so the release coating is not active.
• the release coating is a low adhesion coating designed to allow the adhesive surface of tape to peel from the surface to which the coating is applied, usually the backside of the tape backing. Deadening the release typically reduces or eliminates the release properties of the low adhesion coating either by removal, oxidation or other chemical or physical change. Plasma or corona treatment nullifies or partially eliminates the functionality (i.e. the release properties) of the release coating and improves surface energy.
• a design which may include a customized design or photograph, is fed or electronically sent via an image file (with no print plates required) to a digital printing station comprising an inkjet printer.
• the duct tape proceeds to the inkjet digital printing station at point 5.
• the print design is delivered to the inkjet digital printing station.
• inlget digital printing printing occurs on the non-adhesive surface of the duct tape.
• a backing table 8 is coated with a release coating such as PTFE, and the backing table 8 is in contact with the adhesive surface of the duct tape.
• UV ultraviolet
• the printed duct tape proceeds to ultraviolet (UV) curing, preferably dual stage UV curing. A first stage of the dual stage UV curing occurs at
• Station 1 shown at point 6, and a second stage of UV curing occurs at Station 2, shown at point 7.
• Station 1 is used to pin the ink and allows for higher machine output of up to 250 ft/min.
• Station 2 is a final UV cure to fully cure the ink.
• the duct tape proceeds to a flexography station at point 9 where a material or composition having release and/or overcoat properties is applied to the printed surface of the duct tape.
• This application may occur in a single operation. It is also contemplated that this application could occur in a multi-stage operation with application of a first material or composition having release properties and with application of a second material or composition having overcoat properties, or vice versa.
• an overcoat is to protect the ink.
• the overcoat prevents, for example, the ink printed design from being scratched off.
• the overcoat also allows the tope to be self-wound (i.e. wound onto itself) without a release liner.
• the ink is a child-safe (European standard) ink.
• any ink can be used that is compatible with the overcoat material or composition.
• the material or composition having overcoat properties is a flexographically applied UV chemistry. Flexographic application Uses photopolymer plate(s) to transfer the material or composition to the film.
• the material or composition having overcoat properties may be a varnish or any material or composition that is compatible with the ink.
• the material or a composition having overcoat properties is UV curable, hi another aspect of the invention, the material or composition having overcoat properties comprises an acrylic, urethane- acrylic, silicone-acrylic or other acrylic based chemistry.
• the printed duct tape proceeds to point 10 where the applied material or composition having release and/or overcoat properties is dried. Drying preferably occurs by curing and the type of drying equipment used is preferably ultraviolet From point 10, the duct tape proceeds to tape rewind at point 11.
• the method may further comprise winding the digitally printed duct tape for slitting.
• Fig. 1 illustrates unwind and web handling of the duct tape, for example, with the use of coatings to avoid adhesive build-up. It also illustrates a method of making the printed duct tape without use of a release liner.
• the line rate of digitally print duct tape is improved and speeds as high as 250 ft/mm, for example, may be attained.
• the equipment for use in the method(s) of the present invention may be capable of slitting inline.
• the equipment that is used may also be capable of sheeting and die-cutting.
• An example of suitable equipment is a UV curable custom digital printer that has the ability to deaden the release characteristic of the duct tape (via plasma, corona, chemical/primer or other treatment) and which allows the digital printed duct tape to be digitally printed at speeds as high as 150 to 250 ft/min. These rates are not typical for all digital printing; however, equipment employing dual UV curing technology allows for higher throughputs.
• Digital printing technology does not require costly print plates which allows for tile flexibility to execute very short runs. For example, 20 rolls of a custom design may be used to customize duct tape for use at a special occasion (Le. party favors).
• print plates also extend the lead time and, as a result, could lead to logistical problems.
• FIG. 2 Another method of making the digital printed duct tape in accordance with the present invention is shown in Fig. 2, As shown in Fig 2, a barrier layer such as a liner is laminated onto the duct tape to ease the web handling through die printing process and the liner is stripped before rewinding the tape. As shown in Fig. 2, a duct tape having an adhesive surface and a non-adhesive surface is provided, and the duct tape is unwound at point 21. Releasing the duct tape from a roll is somewhat tight and may require special web handling to facilitate unwinding. The duct tape travels over a roller(s) with the adhesive surface of the duct tape in contact with the roller(s) until the duet tape reaches point 22.
• a barrier layer such as a liner is laminated onto the duct tape to ease the web handling through die printing process and the liner is stripped before rewinding the tape.
• a duct tape having an adhesive surface and a non-adhesive surface is provided, and the
• the rollers) in contact with the adhesive surface of the tape are release coated.
• the duct tape undergoes tension and relaxation at point 22.
• the roller over which the duct tape passes is in contact with the non-adhesive surface of the duct tape.
• the adhesive surface of the duct tape passes over other rollers having a release coating, such as polytetrafluoroethylene (FITE).
• FITE polytetrafluoroethylene
• the duct tape then proceeds to a laminating station at point 23 where a liner is laminated onto the duct tape.
• the liner unwind occurs at point 24.
• the non-adhesive surface of the duct tape is treated at point 25 in preparation for printing, for example, by passing through a plasma or corona treater.
• the duct tape proceeds to an inkjet digital printing station at point 26 and then onto ultraviolet (UV) curing.
• a first stage of the dual stage UV curing occurs at Station 1, shown at point 27, and a second stage of UV curing occurs at Station 2, shown at point 28.
• Station 1 is used to pin the ink and allows for higher machine output of up to 2S0 ft/min.
• Station 2 is a final UV cure to fully cure fire ink.
• the duct tape proceeds to a flexography station at point 29 where a material or composition having release and/or overcoat properties is applied to the printed surface of the duct tape.
• a material or composition having release and/or overcoat properties is applied to the printed surface of the duct tape.
• This application may occur in a single operation; it is also contemplated that this application could occur in a multi-stage Operation with application of a first material or composition having release properties and with application of a second material or composition having overcoat properties, or vice versa.
• the printed duct tape proceeds to point 30 where the applied material or composition having release and/or overcoat properties is dried.
• Drying preferably occurs by curing and the type of drying equipment used is preferably ultraviolet From point 30, the printed duct tape proceeds to liner rewind at point 31 where the liner is removed and to tape rewind at point 32 where, for example, the printed duct tape is wound onto a roll,
• FIG. 3 Another method of making digital printed duct tape in accordance with the present invention is shown in Fig. 3.
• printing occurs on a film, preferably a thin film, and then a UV adhesive is applied to a surface of the printed film prior to lamination with a duct tape or subtape component.
• this method could be used if there are bonding issues using the overcoat material in the other methods.
• a polymeric film such as polyethylene Or polyethylene terephthalate goes through unwind at point 41 before undergoing surface treatment by passing through a plasma or corona treater at point 42, After treatment, the film proceeds to an inkjet digital printing station at point 43 and then onto ultraviolet (UV) curing.
• UV ultraviolet
• a first step of UV curing (pinning of the ink at Station 1) occurs at point 44, and a second step of UV curing to dry the ink (final curing at Station 2) occurs at point 45.
• the printed film proceeds to a flexography station at point 46 where a UV adhesive is applied.
• a duct tape or a subtape component is unwound from a roll at point 51.
• the duct tape undergoes tension and relaxation at point 50.
• the duct tape then proceeds to a laminating station where lamination with the printed film occurs at point 47 to form a laminated tape, UV curing of the UV adhesive of the laminated tape occurs at point 4S. Rewind of the laminated tape occurs at point 49.
• FIG. 4 Another method of making digital printed duct tape in accordance with the present invention is shown in Fig. 4.
• the method of Fig. 4 is the same as the method illustrated in Fig. 2 except instead of stripping the liner off, the liner is left on and sheets of the printed tape are cut Rolls can also be produced on a liner which may be desirable to some end users.
• a duct tape goes through tape unwind at point 61 before undergoing tension and relaxation at point 62.
• the duct tape then proceeds to a station at point 63 where a liner is laminated or applied to the duct tape.
• the liner unwind occurs at point 64.
• the duct tape then passes through a plasma or corona treater at point 65.
• the duct tape proceeds to an inkjet digital printing station at point 66 and then onto ultraviolet (UV) curing.
• a first step of UV curing (pinning of the ink at Station 1) occurs at point 67, and a second step of UV curing (final curing at Station 2) occurs at point 68.
• the duct tope proceeds to a flexography station at point 69 where a material or composition having release and/or overcoat properties is applied.
• the duct tape then proceeds to point 70 where the material or composition having release and/or overcoat properties is cured. From point 70, the duct tape proceeds to die-cutting or sheeting at point 71.
• the finished product has a release liner.
• FIG. 5 Another method of making the digital printed duct tape in accordance with the present invention is shown in Fig. 5.
• a barrier layer such as a release liner is laminated or applied to the duct tape to ease the web handling through the printing process and so that the liner is present when the printed duct tape is rewound.
• a duct tape having an adhesive surface and a non-adhesive surface is provided, and the duct tape is unwound at point 80. Releasing the duct tape from a roll is somewhat tight and may require special web handling to facilitate unwinding.
• the duct tape travels over a ro!ler(s) with the adhesive surface of the duct tape in contact with the rollers) until the duct tape reaches point 81.
• the roiler(s) in contact with the adhesive surface of the tape are release coated.
• the duet tape undergoes tension and relaxation at point 81.
• the roller over which the duet tape passes is in contact with the non-adhesive surface of the duct tape.
• the adhesive surface of the duct tape passes over other rollers having a release coating, such as polytetrafluoroethylene (PTFE).
• PTFE polytetrafluoroethylene
• the non-adhesive surface of die duct tape is treated at point 84 in preparation for printing, for example, by passing through a plasma or corona treater. From point 84, the duct tape proceeds to an inkjet digital printing station at point 85 and then onto ultraviolet (UV) curing. A first stage of the dual stage UV curing occurs at Station 1, shown at point 86, and a second stage of UV curing occurs at Station 2, shown at point 87. Station 1 is used to pin the ink and allows for higher machine output of up to 250 ftZmin. Station 2 is a final UV cure to fully cure the ink. After UV curing of the printed ink, the printed duct tape with barrier layer proceeds to tape rewind at point 88. This barrier layer protects the adhesive fiom adhering to the ink on the tape when rewound.
• UV ultraviolet
• the method(s) of the present invention is capable of producing finished roll products having features including, but not limited to, custom designs, custom colors, and photography with high resolution
• the methodfs) of the present invention is also conducive to producing surface printed sheets having features including, but not limited to, custom designs, custom colors, and photography with high resolution.
• the method(s) of the present invention is also suitable for making die-cut items such as letters, numbers, shapes, and stickers.
• the method(s) of the present invention with its digital printing capability provides for duet tape patterns that are not governed by print cylinder repeat
• the advantages of the method(s) of the present invention are the ability and flexibility to produce low cost proofs and to produce quick-turnaround mockups for customers.
• an adhesive tape having ink printed thereon comprises a duct tape having an adhesive surface and a non-adhesive surface, a white ink printed on the non-adhesive surface of the duct tape, and a colored ink printed on top of the printed white ink.
• an adhesive tape 100 having more than one ink layer is shown, preferably having two ink layers.
• the film 140, scrim 150, and adhesive layer 160 are collectively referred to as a duct tape.
• Release coating 100 preferably comprises a material selected from the group consisting of acrylic, silicone, poly vinyl octadecyl carbonate (PVQDC), fluorinated material, vinyl acetate, or a combination thereof.
• PVQDC poly vinyl octadecyl carbonate
• Film 140 comprises one or more layers of film.
• film 140 has a thickness in a range of 2 to 4 mils.
• film 140 comprises a polyolefin or blends thereof.
• Fig. 6B is an exploded view of film 140 of digital printed duct tape 100 of Fig. 6A.
• film 140 comprises a top layer 170, a core layer 180, and a bottom layer 190.
• Top layer 170 of film 140 is preferably comprised of a polymer selected from the group consisting of polyethylene or blends thereof, ethyl methyl acrylate (EMA), and a combination thereof.
• Core layer 180 of film 140 is preferably comprised of polyethylene or blends thereof
• Bottom layer 190 is preferably comprised of a polymer selected from the group consisting of polyethylene or blends thereof, ethyl methyl acrylate (EMA), and a combination thereof.
• bottom layer 190 may be comprised of a polyethylene blend such as LDPE, LLPDE or a combination thereof.
• Non-limiting examples of materials for scrim 150 include, but are not limited to, polyester-cotton, cotton, polyester, polyethylene, polypropylene, and combinations thereof
• scrim 150 is a cloth scrim.
• Non-limiting examples of adhesive 160 include, but are not limited to, natural rubber, synthetic rubber, acrylic, hot melt, polychloroprene, and combinations thereof. Adhesive may be used that gives the tape an unwind measured at 100 fpm (between 1 and 90 oz/in). Adhesive is preferably applied in a coat having a coat weight range of 1 to 7 oz/yd 2 .
• a duct tape has an adhesive surface and a non-adhesive surface, and a white ink is present in a layer on the non-adhesive surface of the duct tape.
• the white ink is digitally printed on the non-adhesive surface of the duct tape.
• the white ink is ultraviolet (UV) light curable.
• the white ink generally comprises at least one reactive co-monomer, a white pigment, a primary initiator, a . polymeric photoinitiator, and an antioxidant.
• the white ink comprises titanium dioxide as the white pigment, Preferably, titanium dioxide is present in a range of 5 weight % to 30 weight %.
• the white ink is present in a layer having a thickness up to 25 microns.
• the white ink comprises dipropyleneglycol diacrylate, 2-(2-vmyloxyetboxy) ethyl acrylate, titanium dioxide, substitute phosphine oxide, oligo[2-hydroxy-2-methyl-l [4- (1- methylvinyl)phenyl]propanone), and butylated hydroxytoluene.
• the white ink has a composition comprising 30 weight % to 50 weight % of dipropyleneglycol diacrylate, 20 weight % to
• % oligd[2-hydroxy-2-methyl-l[4- (1 -methylvinyl)phenyI]pmpanonej and less than or equal to I weight % butylated hydroxytoluene, wherein the weight % is based on die total weight of the composition.
• the colored ink is present in a layer on the white ink.
• the colored ink is digitally printed on the colored ink.
• the colored ink has a thickness up to 15 microns.
• the colored ink is ultraviolet (LTV) light curable.
• the colored ink generally comprises at least one reactive co-monomer, an optional white pigment, a primary initiator, a polymeric photoinitiator, a colored pigment, and an antioxidant
• the optional white pigment is preferably present in a range of 0 weight % to 30 weight %, wherein weight % is based on the total weight of the composition.
• the colored pigment can be any colored pigment kno wn to one of ordinary skill in the art
• the colored ink generally comprises dipropyleneglycol diacrylate, 2-(2-vinylpxyethoxy) ethyl acrylate, substitute phosphine oxide, oligo[2-hydroxy-2-methyl-l [4- (l-methylvinyl)phenyl]propanonej, a colored pigment(s), butylated hydroxytoluene, and 2-phenoxyethylaerylate.
• colored pigments include, but are not limited to, red, green, blue, cyan, magenta, yellow, and key (black).
• a non-limiting example of a black is carbon black.
• a non-limiting example of a red is lithql.
• a non-limiting example of a green is phthalocyanine green.
• a non-limiting example of a blue is pthalocyanine blue.
• a nonlimiting example of a yellow is an azo compound,
• a non-limiting example of a magenta is a quinacridone.
• the colored ink has a composition comprising 50 weight % to 70 weight % dipropyieneglyco! diacrylate, 5 weight % to 10 weight % 2-(2-vinyloxyethoxy) ethyl acrylate, 5 weight % to 10 weight % substitute phosphine oxide, 5 weight % to 10 weight % oligo[2-hydroxy-2-methyl- 1 [4- (1- methylvmyl)phenyI]propanone], 1 weight % to 10 weight % of a colored pigment less than or equal to 1 weight % butylated hydroxytoluene, and 5 weight % to 10 weight % 2- phenoxyethylacrylate,
• an optional white pigment is also present in a range of 0 weight % to 30 weight %. Weight percentages are based on the total weight of the composition.
• a self-wound roll of adhesive duct tape having digital printing on the non-adhesive surface of the duct tape is provided. Sheets and other forms of the adhesive tape may also be provided.
• an adhesive tape is provided comprised of multiple layers. Referring to Fig. 7, an adhesive tape 200 is shown in which there is a single layer of colored ink 220.
• Colored ink layer 220 is located below an optional release coat layer 210.
• a primer layer 230 that is used to improve the anchorage between a film 240 and the colored ink layer 220.
• Below film 240 is a scrim 250.
• Below the scrim is an adhesive layer 260. The film 240, scrim
• duct tape 250 and adhesive layer 260 are collectively referred to as duct tape.
• a purpose of primer layer 230 is to promote adhesion of colored ink layer 220 to film 240.
• the primer of the primer layer acts an adhesion promoter.
• Nonlimiting examples of primers include, but are not limited to, chlorinated polyolefins, acrylic modified polyolefins, acrylics, polyurethanes, polyethylene amines, titanium dioxide, and a combination thereof. Examples of trade name for commercially available primers are Nazdar 7035 and Colorific Adhesion Promoter 7200.
• a white ink may serve as the primer.
• the primer may comprise, consist essentially of, or consist of a white ink.
• Film 240 may comprise one or more layers. Film 240 may be pigmented within any of its layers in a variety of colors. White is a non-limiting example of a color. Film 24 may comprise a top layer, a core layer, and a bottom layer.
• the top layer of the film is preferably comprised of a polymer selected from the group consisting of polyethylene or blends thereof, ethyl methyl acrylate (EMA), ethyl vinyl acetate (EVA), ethlyene acrylic acid copolymer, titanium dioxide, calcium carbonate, clay and a combination thereof.
• EMA ethyl methyl acrylate
• EVA ethyl vinyl acetate
• ethlyene acrylic acid copolymer titanium dioxide, calcium carbonate, clay and a combination thereof.
• HP 98 a material having acrylic release chemistry commercially available from Omnova Solutions, Inc.
• HP 98 a material having acrylic release chemistry commercially available from Omnova Solutions, Inc.
• the liner was removed and samples slit.
• One roll was aged in an oven for 16 hours at 150 °F and 60% relative humidity (RH).
• the rolls were printed in lanes. Each lane was printed in a different combination. One lane had white ink under a blue ink Image. Another lane had blue ink and white ink, but did not have the white ink under the blue ink. There were two other lanes that had blue ink but no white ink. All of the rolls tested picked off the ink except for the lane that had a white ink printed first underneath the entire image before the blue ink logo was printed.
• the white ink appeared to bond better to the film and this was the only lane that was able to make a self-wound roll of tape without pick-off.
• the blue printed directly on the film had complete pick-off and the roll did not even need to be aged as it happened immediately.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Wood Science & Technology (AREA)
• Adhesive Tapes (AREA)

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• 2019
  • 2019-07-12 WO PCT/US2019/041575 patent/WO2020033104A1/en unknown
  • 2019-07-12 CN CN201980066119.XA patent/CN112930375A/zh active Pending
  • 2019-07-12 EP EP19846633.6A patent/EP3833718A4/de not_active Withdrawn
  • 2019-07-12 CA CA3108953A patent/CA3108953A1/en active Pending

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