EP3827109B1 - Procédé de fabrication d'une tôle al-mg-mn laminée à chaud et son utilisation - Google Patents

Procédé de fabrication d'une tôle al-mg-mn laminée à chaud et son utilisation Download PDF

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Publication number
EP3827109B1
EP3827109B1 EP19722128.6A EP19722128A EP3827109B1 EP 3827109 B1 EP3827109 B1 EP 3827109B1 EP 19722128 A EP19722128 A EP 19722128A EP 3827109 B1 EP3827109 B1 EP 3827109B1
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hot
temperature
range
rolling
annealing
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German (de)
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EP3827109A1 (fr
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Nele Mareike Knaack
Bernd JACOBY
Andreas Harald BACH
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Novelis Koblenz GmbH
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Novelis Koblenz GmbH
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium
    • C22C21/06—Alloys based on aluminium with magnesium as the next major constituent

Definitions

  • the invention relates to a method of manufacturing an Al-Mg-Mn plate product.
  • the plate material can be used amongst others for civil engineering purposes like shipbuilding, truck trailers and silo construction.
  • aluminium alloy plate materials of the AA5083-series are one of the most widely applied aluminium alloys. This aluminium alloy provides a reasonable balance of mechanical strength, good corrosion resistance and weldability.
  • JP 2010-144186 A (Furukawa Sky Aluminum Corp .) discloses a storage vessel made from an alloy where the manufacturing method requires a hot mill exit temperature of at least 340°C.
  • CN 105177327 A (Alnan Aluminium Inc. ) describes a method for preparing a 5xxx-series high-magnesium aluminum alloy O-state plate.
  • CN 104357690 A (Guangxi Nannan Aluminum Proc. Co. Ltd. ) describes a preparation process for a medium-strength, corrosion-resistant, high-magnesium aluminum alloy plate.
  • US 6,280,543 B1 (Zonker, Harry R. ) describes a process and products for the continuous casting of flat-rolled sheet.
  • One of the preferred tempers is the H111, and involves hot rolling of the rolling feedstock, optionally cold rolling to final gauge annealing and moderate strain-hardening by stretching or levelling.
  • AIMgMn plate material suitable for civil engineering purposes that offers the possibility for down-gauging of the aluminium plate material applied. This requires an increased strength of the plate material while maintaining a good formability by reference to elongation and bendability, and also a good corrosion resistance and weldability.
  • aluminium alloy and temper designations refer to the Aluminium Association designations in Aluminum Standards and Data and the Registration Records, as published by the Aluminium Association in 2018 and are well known to the persons skilled in the art.
  • up to and “up to about”, as employed herein, explicitly includes, but is not limited to, the possibility of zero weight-percent of the particular alloying component to which it refers.
  • up to 0.1% Cu may include an alloy having no Cu.
  • the term "about" when used to describe a compositional range or amount of an alloying addition means that the actual amount of the alloying addition may vary from the nominal intended amount due to factors such as standard processing variations as understood by those skilled in the art.
  • the present invention providing a method of manufacturing a hot-rolled Al-Mg-Mn alloy product of 3 to 15 mm final gauge, the method comprising the steps, in that order, of: (a) providing a rolling feedstock material of an aluminium alloy having a composition comprising of, in wt.%, Mg 4.80% to 6.0%, Mn 0.30% to 1.25%, Zn up to about 0.9%, preferably 0.30% to 0.9%, Fe up to about 0.40%, preferably up to about 0.30%, Si up to about 0.30%, preferably up to about 0.20%, Cu up to about 0.20%, preferably up to about 0.10%, Cr up to about 0.25%, Zr up to about 0.25%, Ti up to about 0.25%, preferably about 0.005% to 0.10%, unavoidable impurities each ⁇ 0.05%, total ⁇ 0.2%, balance aluminium; (b) heating the rolling feedstock to a temperature in a range of about 480°C to
  • the method according to this invention allows for the production of Al-Mg-Mn-(Zn) plate products having a tensile yield strength of at least 150 MPa, an ultimate tensile strength of at least 310 MPa, and an elongation at fracture (A50) of at least 18%, and with improved values are herein described and claimed.
  • the method allows for the production of AI-Mg-Mn-(Zn) plate products having a very good bendability, in particular it allows bending angles of 180° at bending radii of 4 times, and preferably 3 times, and in the best example 2 times the material thickness.
  • the bendability is an important parameter as it allows the shaping or forming of products using the AI-Mg-Mn-(Zn) plate product into particular shapes.
  • the mechanical properties have been measured in accordance with DIN-EN-ISO 6892-1 (2016) and the bendability has been measured in accordance with DIN-EN-ISO 7438 (2016).
  • the plate products have a good corrosion resistance and are fusion weldable by means of various fusion welding techniques known in the art.
  • the method of the present invention can be operated more economically to provide a plate product having better mechanical properties than AA5083-H111.
  • the AI-Mg-Mn-(Zn) alloy can be provided as an ingot or slab for fabrication into rolling feedstock using casting techniques regular in the art for cast products, e.g. DC-casting, EMC-casting, EMS-casting, and preferably having an ingot thickness in a range of about 220 mm or more, e.g. 400 mm, 500 mm or 600 mm.
  • the thick as-cast ingot is commonly scalped to remove segregation zones near the cast surface of the ingot.
  • thin gauge slabs resulting from continuous casting e.g. belt casters or roll casters, also may be used, and having a thickness of up to about 40 mm.
  • the heating, e.g. by homogenization and/or pre-heating, prior to hot rolling is carried out at a temperature in the range of about 480°C to 550°C. In either case, it decreases the segregation of alloying elements in the as-cast material.
  • the Zr, Cr and Mn can be intentionally precipitated to control the microstructure of the hot mill exit feedstock. If the treatment is carried out below about 480°C, the resultant homogenisation effect is inadequate. It is preferred to have a temperature of more than 500°C. If the temperature is above about 550°C, eutectic melting might occur resulting in undesirable pore formation. It has been found that at higher-end temperature results in an increased elongation in the final plate product at a small trade-off of the tensile yield strength.
  • the preferred time of the above heat treatment is between 1 and 30 hours, for example 8 hours or 18 hours.
  • a separate homogenisation treatment is performed prior to pre-heating or heating the rolling feedstock.
  • the homogenisation treatment is performed in a temperature range of 480°C to 550°C.
  • the soaking time at the homogenisation temperature is preferably between 1 and 30 hours.
  • a pre-heat refers to the heating of an ingot to a set temperature and soaking at this temperature for a set time followed by the start of the hot rolling at about that temperature.
  • Homogenisation refers to a heating and cooling cycle applied to a rolling ingot in which the final temperature after homogenisation is ambient temperature.
  • step (b) where solely a heating or pre-heating is performed without a separate homogenisation treatment prior to that, then it is preferred that the heating or pre-heating is performed at a temperature in the range of about 480°C to 550°C. And it is preferred to have a set temperature of more than 500°C.
  • the pre-heat temperature is set in a range of 400°C to 550°C. It is preferred that the pre-heat temperature is in a range of 480°C to 550°C, and preferably above 500°C, followed by the start of the hot rolling process at about that temperature.
  • the rolling feedstock has been homogenized it has been subjected to at least one process step of heating to a temperature in a range of about 480°C to 550°C, even when the pre-heat temperature is set at a lower temperature followed by the start of the hot rolling process at that temperature.
  • the first hot rolling step begins while the heated or pre-heated feedstock is at a temperature in the range of about 400°C to 550°C, preferably about 480°C to 550°C, and is more preferably above about 500°C.
  • the first hot rolling operation of the preheated feedstock at the defined temperature is subjected to breakdown hot rolling in one or more passes using reversing or non-reversing mill stands that serve to reduce the thickness of the feedstock to a gauge range of 15 mm to 40 mm, and preferably of 15 mm to 30 mm, and more preferably of 15 mm to 25 mm.
  • the breakdown rolling starts at about 400°C to 550°C, preferably at about 480°C to 550°C, and more preferably at a temperature of about 500°C or more.
  • the hot-mill process temperature should be controlled such that after the last rolling pass the hot-mill exit temperature of the feedstock is in a range of about 370°C to 495°C.
  • a more preferred lower-limit is about 400°C.
  • a more preferred upper-limit is about 465°C.
  • the feedstock is supplied to a mill for hot finishing rolling in one or more passes to a final gauge in the range of 3 to 15 mm, preferably 3 to 10 mm, for example 4 mm or 5 mm.
  • the hot finishing rolling operation can be done for example using a reverse mill or a tandem mill.
  • the temperature of the hot rolled feedstock when the feedstock is inputted into the mill for hot finishing rolling is maintained preferably at a temperature of about 370°C to 495°C. A more preferred lower-limit is about 400°C. A more preferred upper-limit is about 465°C.
  • Control of the hot-mill exit temperature of the rolled feedstock is important to arrive at the desired balance of metallurgical and mechanical properties, and the hot-mill temperature should be controlled such that after the last rolling pass upon leaving the hot-mill the hot-mill exit temperature of the rolling feedstock is in a range of about 130°C to 285°C.
  • a preferred lower-limit is about 150°C, and more preferably about 175°C.
  • a preferred upper-limit is about 275°C, and more preferably about 250°C, and more preferably about 235°C. At a too low exit-temperature of the rolling feedstock the strength and the hardness of the final plate product will be too high.
  • a too low exit-temperature will also adversely affect the coiling behaviour of the feedstock following the hot-rolling operation as well as in a subsequent finishing operation. Whereas at too high exit-temperatures at least the strength and hardness of the feedstock will be too low and providing an unfavourable balance of properties.
  • the hot-rolled feedstock at final gauge is cooled to ambient temperature.
  • the hot-rolled feedstock at final gauge is cooled from hot-mill exit-temperature to ambient temperature by immediately coiling the hot-rolled feedstock and allowing the coil to cool, preferably by means of air cooling, in an ambient environment to ambient temperature and stored.
  • the hot rolling of the rolling feedstock to final gauge is without cold rolling the rolling feedstock prior to the final gauge.
  • the plate material at final gauge is annealed at a temperature in a range of about 300°C to 550°C, for example at about 400°C or 410°C.
  • a preferred lower-limit for the annealing temperature is about 360°C and more preferably about 380°C.
  • a preferred upper-limit for the annealing temperature is about 450°C, and more preferably about 430°C.
  • the annealing operation results in particular to an increase in the elongation at fracture of the plate product.
  • the plate material is being annealed in coiled condition.
  • an annealing operation is performed by placing one or more coils of ambient temperature in a furnace at a temperature of about 300°C to 550°C.
  • the coiled plate material is placed in the annealing furnace for about 1 to 10 hours soak time, preferably about 1 to 8 hours, and more preferably for about 1 to 6 hours, and subsequently removed from the annealing furnace and allowed to cool in an ambient environment to ambient temperature and stored.
  • the plate material is being annealed as individual plate material of limited length, for example 6 or 10 meters.
  • an annealing operation is performed by placing a single or multiple plates of ambient temperature in an annealing furnace at a soak temperature of about 300°C to 550°C.
  • the plate material is placed in the pre-heated annealing furnace for about 10 to 90 minutes soak time, preferably about 10 to 60 minutes, and subsequently removed from the annealing furnace and allowed to cool in an ambient environment to ambient temperature and stored.
  • the faster heat-up rate in this embodiment is preferred over coil annealing as it provides a desired increase in elongation at fracture of the final plate material.
  • the annealed hot-rolled plate at final gauge is cooled from annealing temperature to ambient temperature and stored.
  • the cooled plate material at final gauge is suitable for finishing operations such as levelling in case of coiled plate material or stretching (typically up to about 1.5%) in case of individual plate material to improve product flatness, edge-trimming and slitting, and cut-to-length.
  • the careful control of the hot-rolling process and annealing and cooling to ambient temperature results in an Al-Mg-Mn-(Zn) plate product having a fully recrystallized microstructure and providing the required balance of properties.
  • fully recrystallized is meant that the degree of recrystallization of the microstructure is more than about 75%, preferably more than about 80%, and more preferably not more than 90%.
  • the degree of recrystallization can be determined by any suitable method known in the art. For example, in a micrograph, such as a scanning electron micrograph or an optical micrograph.
  • the Mg-content should be in a range of about 4.80% to 6.0% and forms the primary strengthening element of the alloy.
  • a preferred lower-limit for the Mg-content is about 5.0%, and more preferably about 5.1%, to provide increased strength.
  • a preferred upper-limit for the Mg-content is about 5.8%.
  • the Mn-content should be in the range of about 0.30% to 1.25% and is another essential alloying element.
  • a preferred upper-limit for the Mn-content is about 1.1%, and more preferably about 0.9%, to provide a balance in strength and bendability.
  • a preferred lower-limit for the Mn-content is about 0.5%, and more preferably about 0.55%.
  • the Zn-content is up to 0.9%.
  • the Zn-content should be in the range of 0.30% to 0.9% and is then another essential alloying element to provide the required strength, elongation and corrosion resistance.
  • a purposive addition of either Cr or Zr each up to about 0.25% as dispersoid-forming elements whereby the addition of Zr is preferred.
  • a preferred addition of Zr is in a range of about 0.05% to 0.25%, and more preferably of about 0.05% to 0.20%.
  • Zr is added purposively then it is preferred that the Cr level does not exceed 0.1%, and is preferably less than about 0.05%.
  • Fe is a common impurity in aluminium alloys and should not exceed 0.40%.
  • the content should not exceed 0.30%, and preferably it does not exceed 0.25%.
  • Si is also a common impurity in aluminium alloys and should not exceed 0.30%.
  • the content should not exceed 0.25%, and preferably it does not exceed 0.20%.
  • Cu may have an adverse effect on the corrosion resistance of the aluminium alloy and its content should not exceed 0.20%, and preferably it does not exceed 0.10%.
  • Ti is important as a grain refiner during solidification of both ingots and welded joints produced using the hot-rolled aluminium alloy plate product of the invention. Ti levels should not exceed about 0.25%, and the preferred range for Ti is about 0.005% to 0.10%. Ti can be added as a sole element or with either boron or carbon serving as a casting aid for grain size control.
  • the Al-Mg-Mn-Zn alloy product consists of, in wt.%: Mg 4.80% to 6.0%, Mn 0.30% to 1.25%, Zn up to 0.9%, Fe up to 0.40%, Si up to 0.30%, Cu up to 0.20%, Cr up to 0.25%, Zr up to 0.25%, Ti up to 0.25%, unavoidable impurities each ⁇ 0.05%, total ⁇ 0.2%, balance aluminium; and with preferred narrower compositional ranges as herein described and claimed.
  • the method according to this invention enables the production of Al-Mg-Mn-(Zn) plate material having a composition as herein described and claimed and having in a gauge range of 3 mm to 15 mm, preferably 3 mm to 10 mm, a tensile yield strength in the LT-direction of at least 150 MPa, preferably of at least 160 MPa, and more preferably of at least 170 MPa.
  • the ultimate tensile strength in the LT-direction is at least 310 MPa, and preferably at least 320 MPa, and more preferably at least 330 MPa.
  • the elongation at fracture (A50) is at least 18%, preferably at least 20%, and more preferably at least 22%.
  • the elongation at fracture (A50) does not exceed 35%.
  • the method allows for the production of Al-Mg-Mn-(Zn) plate products having a very good bendability, in particular it allows bending angles of 180° at bending radii of 4 times, and preferably 3 times, and in the best examples 2 times the material thickness.
  • the plate material at final gauge obtained by the method according to this invention is an ideal candidate for use in civil constructions such as vessels for transporting goods, storage vessels like the hull of a silo in a trailer, truck or container.
  • the aluminium alloy consisted of 5.3% Mg, 0.8% Mn, 0.45% Zn, 0.1% Zr, 0.1% Fe, 0.08% Si, 0.01% Cu, 0.02% Ti, balance impurities and aluminium.
  • Table 1 Mechanical properties. Ingot Hot-mill entry Hot-mill exit YS [MPa] UTS [MPa] A50 [%] A 505°C 225°C 177 333 24.5 B 505°C 295°C 174 335 17.0

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)

Claims (15)

  1. Procédé de fabrication d'un produit laminé en tôle d'alliage aluminium-magnésium-manganèse comprenant les étapes consistant à :
    a) fournir un matériau de départ de laminage consistant en un alliage Al-Mg-Mn ayant une composition comprenant, en % en poids, Mg 4,80 % à 6,0 %, Mn 0,30 % à 1,25 %, Zn jusqu'à 0,9 %, Fe jusqu'à 0,40 %, Si jusqu'à 0,30 %, Cu jusqu'à 0,20 %, Cr jusqu'à 0,25 %, Zr jusqu'à 0,25 %, Ti jusqu'à 0,25 %,
    des impuretés inévitables, chacune < 0,05 %, au total < 0,2 %, le reste étant de l'aluminium ;
    b) chauffer le produit de départ de laminage à une température dans une plage allant de 480 °C à 550 °C ;
    c) laminer à chaud le produit de laminage chauffé dans une ou plusieurs étapes de laminage pour obtenir une tôle laminée à chaud ayant un gabarit final dans une plage allant de 3 mm à 15 mm, et dans lequel la température d'entrée du laminoir à chaud est dans une plage allant de 400 °C à 550 °C, et la température de sortie du laminoir à chaud est dans une plage allant de 130 °C à 285 °C ; et dans lequel le laminage à chaud du produit de départ de laminage au gabarit final se fait sans laminer à froid le produit de départ de laminage jusqu'au gabarit final ;
    d) recuire la tôle laminée à chaud au gabarit final à une température de recuit dans une plage allant de 300 °C à 550 °C ; et
    e) refroidir la tôle laminée à chaud recuite au gabarit final depuis la température de recuit jusqu'à la température ambiante.
  2. Procédé selon la revendication 1, dans lequel la tôle laminée à chaud au gabarit final est enroulée à la sortie du laminoir à chaud.
  3. Procédé selon la revendication 1, dans lequel la tôle laminée à chaud au gabarit final est enroulée à la sortie du laminoir à chaud et refroidie à température ambiante avant l'étape de recuit.
  4. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel, pendant l'étape (c), la température de sortie du laminoir à chaud est dans une plage allant de 130 °C à 250 °C, de préférence dans une plage allant de 175 °C à 250 °C.
  5. Procédé selon l'une quelconque des revendications 1 à 4, dans lequel le recuit consiste à recuire une tôle laminée à chaud enroulée pendant 1 à 8 heures, de préférence 1 à 6 heures, à une température dans une plage allant de 300 °C à 550 °C.
  6. Procédé selon l'une quelconque des revendications 1 à 4, dans lequel le recuit consiste à recuire la tôle laminée à chaud pendant 10 à 90 minutes à une température dans une plage allant de 300 °C à 550 °C.
  7. Procédé selon l'une quelconque des revendications 1 à 6, dans lequel la température de recuit est dans une plage allant de 300 °C à 450 °C.
  8. Procédé selon l'une quelconque des revendications 1 à 7, dans lequel l'alliage d'aluminium a une teneur en Zn dans une plage allant de 0,30 % à 0,9 %.
  9. Procédé selon l'une quelconque des revendications 1 à 8, dans lequel l'alliage d'aluminium a une teneur en Mn d'au maximum 1,1 %, et de préférence d'au maximum 0,90 %.
  10. Procédé selon l'une quelconque des revendications 1 à 9, dans lequel l'alliage d'aluminium a une teneur en Mg d'au moins 5,0 %, et de préférence d'au moins 5,10 %.
  11. Procédé selon l'une quelconque des revendications 1 à 10, dans lequel l'alliage d'aluminium a une teneur en Zr dans une plage allant de 0,05 % à 0,25 %.
  12. Procédé selon l'une quelconque des revendications 1 à 11, dans lequel la tôle laminée à chaud et recuite au gabarit final a un allongement à la rupture (A50) d'au moins 20 %, et de préférence d'au moins 22 %.
  13. Procédé selon l'une quelconque des revendications 1 à 12, dans lequel la tôle laminée à chaud et recuite au gabarit final a une résistance à la rupture en traction d'au moins 150 MPa, et de préférence d'au moins 160 MPa.
  14. Procédé selon l'une quelconque des revendications 1 à 13, dans lequel la tôle de départ laminée à chaud et recuite au gabarit final a une résistance ultime en traction d'au moins 310 MPa et de préférence d'au moins 320 MPa
  15. Utilisation d'une tôle en alliage d'aluminium obtenue au moyen du procédé selon l'une quelconque des revendications 1 à 14 dans un récipient de stockage, de préférence la coque d'un silo.
EP19722128.6A 2018-05-18 2019-05-07 Procédé de fabrication d'une tôle al-mg-mn laminée à chaud et son utilisation Active EP3827109B1 (fr)

Applications Claiming Priority (2)

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EP18173226.4A EP3569721B1 (fr) 2018-05-18 2018-05-18 Procédé de fabrication d'une tôle al-mg-mn laminée à chaud et son utilisation
PCT/EP2019/061681 WO2019219453A1 (fr) 2018-05-18 2019-05-07 Procédé de fabrication d'un produit de type tôle en alliage d'al-mg-mn

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EP3827109B1 true EP3827109B1 (fr) 2022-10-05

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CN114250390A (zh) * 2021-11-24 2022-03-29 大力神铝业股份有限公司 一种电脑键盘支架用铝合金材料及其制备方法
CN116179905B (zh) * 2022-12-22 2024-10-18 山东兖矿轻合金有限公司 一种大规格高性能的Al-Mg-Zn铝合金圆铸锭及其铸造方法

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US7211161B2 (en) 2002-03-22 2007-05-01 Alcan Rhenalu Al-Mg alloy products suitable for welded construction

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US6280543B1 (en) * 1998-01-21 2001-08-28 Alcoa Inc. Process and products for the continuous casting of flat rolled sheet
JP5379463B2 (ja) * 2008-12-16 2013-12-25 古河スカイ株式会社 Ｌｎｇ球形タンク用高強度アルミニウム合金の製造方法
CN101736183A (zh) * 2009-12-28 2010-06-16 东北轻合金有限责任公司 轨道交通用铝合金超塑性板材的制备方法
CN104357690B (zh) * 2014-11-21 2017-07-07 广西南南铝加工有限公司 一种中强耐蚀高镁铝合金板材的制备工艺
CN105177327A (zh) * 2015-09-11 2015-12-23 广西南南铝加工有限公司 5xxx系高镁铝合金ｏ态板材的制备方法

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Publication number Priority date Publication date Assignee Title
US7211161B2 (en) 2002-03-22 2007-05-01 Alcan Rhenalu Al-Mg alloy products suitable for welded construction

Non-Patent Citations (2)

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Title
ANONYMOUS: "International Alloy Designations and Chemical Composition Limits for Wrought Aluminum and Wrought Aluminum Alloys", THE ALUMINUM ASSOCIATION, 1 February 2009 (2009-02-01), pages 1 - 37, XP055593287, [retrieved on 20190603]
ANONYMOUS: "Rolling Aluminum: From the Mine Through the Mill", THE ALUMINUM ASSOCIATION, 1 December 2007 (2007-12-01), pages 1 - 135, XP055545409, [retrieved on 20190121]

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EP3827109A1 (fr) 2021-06-02
EP3569721A1 (fr) 2019-11-20
WO2019219453A1 (fr) 2019-11-21

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