EP3817986A1 - Épaulement tubulaire pour récipient - Google Patents
Épaulement tubulaire pour récipientInfo
- Publication number
- EP3817986A1 EP3817986A1 EP19829917.4A EP19829917A EP3817986A1 EP 3817986 A1 EP3817986 A1 EP 3817986A1 EP 19829917 A EP19829917 A EP 19829917A EP 3817986 A1 EP3817986 A1 EP 3817986A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- resin
- shoulder
- tubular
- composition
- density polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 230000004888 barrier function Effects 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 22
- 239000004713 Cyclic olefin copolymer Substances 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 17
- 239000004677 Nylon Substances 0.000 claims description 16
- 229920001778 nylon Polymers 0.000 claims description 16
- 229920001903 high density polyethylene Polymers 0.000 claims description 15
- 239000004700 high-density polyethylene Substances 0.000 claims description 15
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 14
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 11
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 9
- 229920005672 polyolefin resin Polymers 0.000 claims description 9
- 238000007906 compression Methods 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 239000011342 resin composition Substances 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229940063583 high-density polyethylene Drugs 0.000 claims 5
- 229920001684 low density polyethylene Polymers 0.000 claims 4
- 239000004702 low-density polyethylene Substances 0.000 claims 4
- 229920000092 linear low density polyethylene Polymers 0.000 claims 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims 3
- 241000680172 Platytroctidae Species 0.000 abstract description 15
- 229920013716 polyethylene resin Polymers 0.000 abstract description 7
- 230000006872 improvement Effects 0.000 abstract description 3
- 239000000796 flavoring agent Substances 0.000 description 12
- 235000019634 flavors Nutrition 0.000 description 12
- -1 polyethylene Polymers 0.000 description 12
- 239000004698 Polyethylene Substances 0.000 description 11
- 229920000573 polyethylene Polymers 0.000 description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
- 239000005977 Ethylene Substances 0.000 description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 9
- 239000004952 Polyamide Substances 0.000 description 7
- 229920002647 polyamide Polymers 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000000606 toothpaste Substances 0.000 description 4
- 229940034610 toothpaste Drugs 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000002114 nanocomposite Substances 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 235000019568 aromas Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000272470 Circus Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
Definitions
- Plastic containers are mainly used for food, cosmetic, and toiletry products. There are advantages and disadvantages of using plastics such as having a light weight, a low cost with long lifetime, and absorption of flavors.
- the plastic container In case of the plastic container, decomposition of the contents is caused due to oxygen remained therein and the inflow of oxygen through a container wall.
- the plastic container should have the wall composed of a multi-layered structure at a tune body and a barrier at a tube shoulder generally made of a single-layered polyolefin and bonded to the tube body. The contents with strong aromas and flavors can be deteriorated with the oxygen passed through the container at the shoulder area.
- a conventional method for producing the tube shoulder is compression molding using a single-layered polyolefin, etc , and. then the tube shoulder is bonded to the tube body. Barrier properties of the shoulder may be limited due to choices of tire plastics.
- the present invention provides a method of preparing tire tube shoulder with good hairier properties and adhesion to the tube body by dry-blending of a polyolefin resin.
- EP 0473176 B describes a melt-blended resin composition
- the present invention relates to a method of preparing a tube shoulder having improvement of barrier and adhesion to a tube body, blending of a polyethylene resin and a resin having barrier properties, and molding a composition resulted from the dry-blending according to the method.
- the present invention provides dry-blending a polyolefin resin, a tie resin, and a. resin having bander properties such as a polyamide, preferably nylon, an ethylene-vinyl alcohol (BVOH) copolymer, or an ethylene hydrophobic copolymer, a cyclic olefin copolymer (COC) prepared by using a conventional process.
- a polyamide preferably nylon
- BVOH ethylene-vinyl alcohol
- COC cyclic olefin copolymer
- the present invention is a means of avoiding the use of an insert made separately from a special material and served as a bander material. Therefore, the invention can solve all problems related to presence of the insert, much related to shelf life, good material compatibility, and an important aspect of production cost of a tube container.
- the present invention provides an improvement in barrier properties and adhesion of a tube shoulder using dry-blending a polyolefin resin, particularly a polyethylene (PE) resin, a tie resin, and a resin having barrier properties such as a polyamide, particularly nylon, and an ethylene- vinyl alcohol (EVC'H) copolymer, or an ethylene hydrophobic copolymer, particularly a cyclic olefin copolymer (COC).
- PE polyethylene
- tie resin a resin having barrier properties
- suitable embodiment according to this invention comprising component ratios of a mixture of the polyethylene resin, the tie resin, nylon, and EVOH/COC may be in suitable ranges which will be described in the detailed description of this Invention.
- the present invention is a means of obtaining the resin having high barrier-properties related to homogenization resulting in that finished product production achieves good barrier properties, and still uses a conventional process without any modified machines, special machines or special process. Therefore, this invention can provide producing of the product by a common process and can extremely reduce preparation of a general means for producing the tube container, where also mostly gives the properties according to requirements. Additionally, this invention also uses processing steps, processing time and processing cost substantially resulting in industrial production.
- polyolefin resins include: polyethylene (PE) or ethylene alpha-olefin copolymers which may be selected from ultra-low-density polyethylene (ULDPE), low-densit polyethylene (LDPE), medium-density polyethylene (MDPB), high-densi ty polyethylene (HDPE), or linear low-density polyethylene (LLDPE); propylene (PP) which may be selected from isotactic polypropylene, syndiotact.ic polypropylene; olefin copolymers which may be selected from ethylene/propylene copolymers, poly butylene-1 , ethylene/butaue- 1 copolymers, propylene/butane- 1 copolymers, ethylene/propylene/butane-1 copolymers, ethylene/vinyl acetate copolymers, ionically crosslinked olefin copolymers (ionomers), and ethylene/ acrylic ester copolymers.
- polyethylene PE
- polypropylene PP
- the polyolefin resin may be blended with additives such as pigments, anti-sticking agents, UV stabilizers, etc. according to a widely known recipe.
- an ethylene- vinyl alcohol (EVOH) copolymer is included in the polymer composition, the content of ethylene in the EVOH copolymer is preferably 10-50 %. If the content of the ethylene in the EVOH copolymer is less than 10%, poor processability may be obtained. If the content of the ethylene in the EVOH copolymer Is more t n 50 mo!e%, oxygen and water-vapor bander properties may not be sufficient.
- EVOH ethylene- vinyl alcohol
- Cyclic olefin copolymers basically include a!ieyciic hydrocarbon compounds having an ethylenicafiy imsaturated bond and a bicycle ring such as a norbomene ring.
- This COC consisting of linear olefins and transparent amorphous-based cyclic olefins in contrast to the partially crystalline polyethylene (PE) and polypropylene (PP).
- PE polyethylene
- PP polypropylene
- Polyamides can be nylon 6, nylon 8, nylon 11 , nylon 12, nylon 6,6, nylon 6,10, nylon 10,6 nylon 6/6, 6 copolymers and partly aromatic polyamides.
- the nylon layer preferably has a thickness of at least 5 to 100 microns in order to improve gas barrier properties.
- a tie resin according to ibis invention is an anhydride-modified linear low-density polyethylene (LLDPE) resin. It is preferably used as a mixed resin in order to improve bonding of various of resins together, over a wide range of processing conditions and equipments. They are most often used for adhering to EVOH, a polyamide, PE and COG, etc.
- LLDPE linear low-density polyethylene
- Heading methods are found extensively worldwide by compression molding, preferably extrusion molding, and injection molding.
- a molten donut of the resin material according to this invention dropped into the molding station and additionally compressed is performed in order to form the tube shoulder.
- a composition may be dry-prepared, and may optionally formed in a pellet form before preparing the tube shoulder.
- this invention provides an improved shoulder made of a polyethylene (PE) resin which may be selected from love-density, medium-density, high-density polyethylene, preferably high-density polyethylene (HDPE), blended with a polyamide which may be selected from nylon and an ethylene-vinyl alcohol (EVOH) copolymer in order to prepare a barrier composition, wherein the adhesive is a tie resin.
- PE polyethylene
- HDPE high-density polyethylene
- EVOH ethylene-vinyl alcohol
- said improved shoulder has weight ratios of resins contained in the dry-blended resin, based upon the total weight of the composition taken as 100%, comprising:
- this invention provides an improved shoulder made of a polyethylene (PE) resin which may be selected from high-density, medium-density, or low- densit polyethylene, preferably high-density polyethylene (HOPE), blended with a polyamide which may be selected from nylon and a cyclic olefin copolymer (COC) in order to prepare a barrier composition, wherein the adhesive is a tie resin.
- PE polyethylene
- HOPE high-density polyethylene
- COC cyclic olefin copolymer
- said improved shoulder has weight ratios of resins contained in the dry-blended resin composition, based upon the total weight of the composition taken as 100%, comprising:
- composition is subjected to a forming process using an injection process or a compression process in order to obtain a tubular product with said improved shoulder.
- a modified natural stress cracking resistance test is performed in order to monitor susceptibility of a polyolefin tube shoulder to natural stress-cracking, when it is subjected to the certain condition of the stress and in presence of the environment such as soaps, detergents and the like, etc.
- the tube shoulder may exhibit mechanical failure by breaking.
- a reagent used for preparing the environment is the fluoride toothpaste in water with the weight ratio of 3: 1.
- the tube shoulder is bent and immersed in the reagent at 60 °C for 72 hours. At least 20 specimens must be used in order to represent the stress-cracking failure of each sample.
- Standard toothpaste is filled into each tube sample, 5 tubes of each sample with equal amount, and each tube sample is weighed and then end-sealed. Thereafter, each tube sample filled with said standard toothpaste is placed into a glass jar conditioned to be at a temperature of 25 °C ana a relative humidity of 70%, and the tube samples are left in said conditions for 12 days, 27 days, 39 days, 45 days, 6.3 days, 78 days, 96 days, and 102 days. The weight loss (%) and the flavor loss are evaluated for each time interval according to the following details.
- Weight Loss (%) ((Initial Weight - Weight at Given Time Interval) + Initial Weight) x
- the flavor loss is evaluated by smelling: +-H- high flavor loss; ++ medium flavor loss;
- Each tube container with the shoulder made fro the mo lien-blended resin composition comprising the polyolefin resin, nylon, and EVOH or COC including tire tie resin causes the shelf life of the product contained therein to be lengthened by improving the properties in order to prevent the weight loss and the flavor loss of the contents as compared with the shoulder made from only HDPE.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Tubes (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TH1801004058A TH1801004058A (th) | 2018-07-06 | ส่วนไหล่รูปทรงหลอดสำหรับภาชนะบรรจุ | |
PCT/TH2019/000019 WO2020009667A1 (fr) | 2018-07-06 | 2019-06-26 | Épaulement tubulaire pour récipient |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3817986A1 true EP3817986A1 (fr) | 2021-05-12 |
EP3817986A4 EP3817986A4 (fr) | 2022-06-22 |
Family
ID=69060476
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19829917.4A Pending EP3817986A4 (fr) | 2018-07-06 | 2019-06-26 | Épaulement tubulaire pour récipient |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3817986A4 (fr) |
WO (1) | WO2020009667A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114379158B (zh) * | 2022-01-20 | 2022-08-30 | 广州市瑞高包装工业有限公司 | 一种防水型纸塑复合软管及其制备方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2771024B2 (ja) | 1990-08-30 | 1998-07-02 | 関西チューブ 株式会社 | 肩部バリヤー性の向上したラミネートチューブ容器 |
WO2005115706A1 (fr) | 2004-05-27 | 2005-12-08 | Lg Chem. Ltd. | Procede de preparation d'un epaulement de tube presentant des proprietes barriere |
DE102010042342A1 (de) | 2010-10-12 | 2012-04-12 | Huhtamaki Ronsberg Zn Der Huhtamaki Deutschland Gmbh & Co. Kg | Tubenlaminatfolie mit wenigstens einer orientierten Barrierelage sowie wenigstens teilweise aus dieser gebildete Tubenverpackung |
WO2017078633A1 (fr) | 2015-11-02 | 2017-05-11 | Kimpai Lamitube Co., Ltd. | Récipient tubulaire avec épaulement constitué de résine mélangée à l'état fondu |
SI3463872T1 (sl) * | 2016-05-26 | 2022-05-31 | Kimpai Lamitube Co., Ltd. | Večplastna fleksibilna folija z visokim zrcalnim sijajem |
EP3562670A4 (fr) * | 2016-12-27 | 2020-08-12 | Kimpai Lamitube Co., Ltd. | Tube stratifié en polyester pour contenant |
-
2019
- 2019-06-26 WO PCT/TH2019/000019 patent/WO2020009667A1/fr unknown
- 2019-06-26 EP EP19829917.4A patent/EP3817986A4/fr active Pending
Also Published As
Publication number | Publication date |
---|---|
WO2020009667A1 (fr) | 2020-01-09 |
EP3817986A4 (fr) | 2022-06-22 |
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