EP3810286A1 - Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, and an alkylpolyglycoside - Google Patents
Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, and an alkylpolyglycosideInfo
- Publication number
- EP3810286A1 EP3810286A1 EP19730851.3A EP19730851A EP3810286A1 EP 3810286 A1 EP3810286 A1 EP 3810286A1 EP 19730851 A EP19730851 A EP 19730851A EP 3810286 A1 EP3810286 A1 EP 3810286A1
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- European Patent Office
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- alkyl
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/415—Aminophenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/884—Sequential application
Definitions
- Hair coloring composition comprising an oxidation dye, a scleroglucan gum, and a
- the present invention relates to the field of dyeing keratin fibers and more particularly to that of hair dyeing.
- this mode of coloring implements one or more oxidation dyes, usually one or more oxidation bases possibly associated with one or more couplers.
- oxidation bases are chosen from ortho- or para-phenylenediamines, ortho- or para-aminophenols as well as heterocyclic compounds. These oxidation bases are colorless or weakly colored compounds which, associated with oxidizing products, allow access to colored species.
- the nuances obtained with these oxidation bases are varied by associating them with one or more couplers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds, such as indole compounds.
- the oxidation dyeing processes therefore consist in using with these dye compositions, a composition comprising at least one oxidizing agent, in general hydrogen peroxide, under alkaline pH conditions in the vast majority of cases.
- This oxidizing agent has the role of revealing the coloring, by a reaction of oxidative condensation of the oxidation dyes between them.
- Oxidation coloring must also meet a certain number of requirements. Thus, it must be without drawbacks from the toxicological point of view, it must make it possible to obtain nuances in the desired intensity and have good resistance to external aggressions such as light, bad weather, washing, permanent undulations, the sweating and rubbing.
- the coloring process must also make it possible to cover white hair, and finally be the least selective possible, that is to say allow to obtain the smallest possible color differences throughout the same keratin fiber, which generally comprises differently sensitized (that is to say damaged) zones from its tip to its root, in order to obtain the most homogeneous coloration of the keratin fibers.
- the coloring compositions must also make it possible to confer good cosmetic properties on keratin fibers, in particular care, softness and / or discipline, have good qualities of use, in particular be easy to apply, while allowing achieve visible (i.e. intense, chromatic), consistent and tenacious color results.
- compositions used in a coloring process must, moreover, have good mixing and application properties on keratin fibers, and in particular good rheological properties so as not to run, when they are applied, on the face, the scalp, or outside the areas that it is proposed to dye, this allows in particular a homogeneous application from the roots to the tips.
- composition according to the invention also has very good stability over time for several weeks.
- coloring compositions which are stable over time for several weeks.
- stable in the sense of the present invention is meant in particular that physical characteristics such as appearance, pH and / or viscosity vary little or even does not vary over time, in particular that the viscosity of the composition does not change or changes little during storage and / or that the composition does not phase during storage.
- the coloring compositions are stable over time, in particular stable after 1 month at 45 ° C., or even after 2 months at 45 ° C.
- coloring compositions can sometimes be destabilized (phase shifted) by high contents of certain compounds, such as for example because of a high content of certain compounds and it is therefore desirable that these compositions are stable under these conditions, in particular which does not phase.
- composition (A) for dyeing keratin fibers, preferably human keratin fibers such as the hair, comprising:
- one or more scleroglucan gums in a total content greater than or equal to 0.5% by weight, relative to the weight of the composition
- nonionic surfactants chosen from alkyl (poly) glycosides
- surfactant preferably cationic
- composition (A) comprising:
- one or more scleroglucan gums in a total content greater than or equal to 0.5% by weight, relative to the weight of the composition
- nonionic surfactants chosen from alkyl (poly) glycosides
- surfactant preferably cationic (s)
- composition (B) comprising
- ready-to-use composition is understood within the meaning of the invention, any composition intended to be applied immediately to keratin fibers.
- the invention also relates to a process for dyeing keratin fibers, and in particular human keratin fibers such as the hair, implementing the application to the fibers of a coloring composition (A) as defined above, and of an oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from peroxide hydrogen, the oxidizing composition (B) being mixed with the coloring composition just before use (application to said fibers) (extemporaneously) or at the time of use, or else the coloring and oxidizing compositions being applied sequentially without intermediate rinsing.
- a coloring composition A
- an oxidizing composition comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s)
- a subject of the invention is also a device (or “kit”) with several compartments allowing the use of the composition for coloring keratin fibers, preferably comprising at least two compartments, a first compartment containing the coloring composition (A) as defined above, and the second compartment containing at least one oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) hydrogen peroxide, preferably from hydrogen peroxide, the compositions of the compartments being intended to be mixed before application, to give the formulation after mixing; in particular the kit can be an aerosol device.
- kit can be an aerosol device.
- composition for coloring or by “coloring composition”
- composition for coloring is meant a composition intended to be applied to keratin fibers, preferably human keratin fibers and in particular the hair, optionally after mixing with an oxidizing composition comprising at least one chemical oxidizing agent.
- ready-to-use coloring composition or “ready-to-use composition” is meant a composition resulting from the mixture of a coloring composition and a composition oxidizing.
- the ready-to-use coloring composition can be prepared just before application to said keratin fibers.
- compositions according to the invention thus make it possible to lead to very good dyeing performance of keratin fibers, in particular in terms of rise, intensity, chromaticity and / or selectivity. They also make it possible to obtain compositions having good rheological properties so as not to run, during their application, on the face, the scalp, or outside the areas which it is proposed to dye
- compositions according to the invention are stable.
- stable in the sense of the present invention is meant in particular that physical characteristics such as appearance, pH and / or viscosity vary little or even does not vary over time, in particular that the viscosity of the composition does not change or changes little during storage and / or that the composition does not phase during storage.
- compositions according to the invention have the advantage of being stable (do not phase shift) regardless of the pH and in particular with respect to extreme pH, in particular at alkaline pH greater than or equal to 9, for example at alkaline pH ranging from 9 to 12.
- compositions are preferably stable (do not phase shift) even in the presence of a high content of certain compounds, such as, for example, oxidation dyes and / or cationic compounds such as cationic polymers, and it is therefore desirable that these compositions are stable under these conditions, in particular that they do not phase shift.
- compositions of the invention are advantageously translucent, which gives them an aesthetic and attractive visual appearance for the consumer and they allow a contribution of styling effects, which can be translated in terms of contribution.
- Other characteristics and advantages of the invention will appear more clearly on reading the description and the examples which follow.
- the bounds of a domain of values are included in this domain, in particular in the expressions “included between” and “ranging from ... to ...” and “Varying from ... to ".
- the keratin fibers are preferably human keratin fibers, preferably the hair.
- the composition according to the invention has a thickened texture, and is in the form of a cream or gel, preferably a gel, preferably the composition is translucent.
- the composition according to the invention generally has at room temperature (25 ° C.) a viscosity greater than 50 cps, preferably between 200 and 100,000 cps, more preferably between 500 and 50,000 cps, and even more preferably between 800 to 10,000 cps, better from 1000 to 8000 cps measured at 25 ° C at a rotation speed of 200 rpm using a rheometer such as the rheomat RM 180 equipped with a mobile no.3 or 4, the measurement being carried out after 60 seconds of rotation of the mobile (time after which there is a stabilization of the viscosity and the speed of rotation of the mobile.
- a viscosity greater than 50 cps, preferably between 200 and 100,000 cps, more preferably between 500 and 50,000 cps, and even more preferably between 800 to 10,000 cps, better from 1000 to 8000 cps measured at 25 ° C at a rotation speed of 200 rpm using a rheometer such as the r
- composition according to the invention comprises one or more oxidation dyes.
- oxidation dye precursors which can be used in the present invention are generally chosen from oxidation bases, optionally combined with one or more couplers.
- the oxidation bases may preferably be chosen from para-phenylenediamines, bis-phenylalkylenediamines, para- aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts.
- the oxidation base or bases of the invention are chosen from paraphenylenediamines and heterocyclic bases.
- paraphenylenediamines mention may be made, for example, of paraphenylenediamine, paratoluylenediamine, 2-chloro paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl paraphenylenediamine, N, N- dimethyl paraphenylenediamine, N, N-diethyl paraphenylenediamine, N, N-dipropyl paraphenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N -bis- (-hydroxyethyl) paraphenylenediamine, 4-N, N-bis- (-hydroxyethyl) amino 2-methyl aniline, 4-N, N-bis
- paraphenylenediamine paratoluylenediamine, 2-isopropyl paraphenylenediamine, 2 ⁇ -hydroxyethyl paraphenylenediamine,
- N, N'-bis- (P-hydroxyethyl) N, N'-bis- (4'-aminophenyl) 1, 3-diamino propanol N , N'-bis- (P-hydroxyethyl) -N, N'-bis- (4'- aminophenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (-hydroxyethyl) -N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (4-methyl-aminophenyl) tetramethylenediamine, N, N'-bis- (ethyl) N, N '-bis- (4'- amino, 3' methylphenyl) ethylenediamine, 1, 8 -bis- (2, 5 -
- para-aminophenol there may be mentioned by way of example, para-amino phenol, 4-amino-3-methyl phenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethyl phenol, 4-amino-2-methyl phenol, 4-amino-2-hydroxymethyl phenol, 4-amino-2-methoxymethyl phenol, 4-amino-2-aminomethyl phenol, 4-amino 2- (-hydroxyethyl aminomethyl) phenol, 4-amino-2-fluoro phenol, and their addition salts with an acid.
- para-amino phenol 4-amino-3-methyl phenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethyl phenol, 4-amino-2-methyl phenol, 4-amino-2-hydroxymethyl phenol, 4-amino-2-methoxymethyl phenol, 4-amino-2-aminomethyl phenol, 4-
- heterocyclic bases there may in particular be pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.
- pyridine derivatives mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5 diamino pyridine, 2- (4-methoxyphenyl) amino 3 amino pyridine, 3, 4-diamino pyridine, and their addition salts.
- pyridine oxidation bases useful in the present invention are the 3-amino pyrazolo- [1,5 a] -pyridine oxidation bases or their addition salts described for example in patent application FR 2801308.
- pyrazolo [1, 5-a] pyridin-3-ylamine 2-acetylamino pyrazolo- [1,5-a] pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid; 2-methoxy-pyrazolo [1,5-a] pyridine-3-ylamino; (3-amino-pyrazolo [1,5-a] pyridine-7-yl) - methanol; 2- (3-amino-pyrazolo [1,5-a] pyridine-5-yl) -ethanol; 2-
- oxidation bases according to the invention are chosen from 3-aminopyrazolo- [1,5 a] -pyridines preferably substituted in position 2 by:
- a heterocycloalkyl group comprising from 5 to 7 members, and from 1 to 3 heteroatoms, cationic or not, optionally substituted by one or more (C 1 -C 6 ) alkyl groups such as di (C 1 -C 4 ) alkylpiperazinium;
- pyrimidine derivatives mention may be made of the compounds described, for example, in patents DE 2359399; JP 88 169571; JP 05-63 124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetra-aminopyrimidine, 4 hydroxy 2,5,6-triaminopyrimidine, 2 hydroxy 4,5,6-triaminopyrimidine, 2,4 dihydroxy 5,6-diaminopyrimidine 2,5 6 triaminopyrimidine and their addition salts and their tautomeric forms, when there is a tautomeric equilibrium.
- the heterocyclic oxidation bases of the invention are chosen from 4,5-diaminopyrazoles such as 4,5-diamino-1 - (-hydroxyethyl) pyrazole. It is also possible to use 4-5-diamino-1 - (-methoxyethyl) pyrazole.
- a 4,5-diaminopyrazole and even more preferably 4,5-diamino-l - (-hydroxyethyl) -pyrazole and / or one of its salts will be used.
- diamino N, N-dihydropyrazolopyrazolones and in particular those described in application FR-A-2 886 136 such as the following compounds and their addition salts: 2,3-diamino-6 , 7-dihydro- 1 H, 5H-pyrazolo [1,2, ajpyrazol- 1 -one, 2-amino-3-ethylamino-6,7-dihydro- 1 H, 5H- pyrazolo [1, 2-a] pyrazol- 1 -one, 2-amino-3-isopropylamino-6,7-dihydro- l H, 5H-pyrazolo [1, 2-a] pyrazol- 1 -one, 2-amino -3- (pyrrolidin- 1 -yl) -6,7- dihydro- 1 H, 5H-pyrazolo [1, 2-a] pyrazol- 1 -one, 4,5
- heterocyclic bases use will preferably be made of 4,5-diamino-l - (-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro- 1 H, 5H-pyrazolo [l, 2- a] pyrazol-l -one and / or a salt thereof.
- the oxidation base or bases used in the context of the invention are generally present in an amount ranging from 0.001 to 10% by weight approximately of the total weight of the coloring composition, preferably ranging from 0.005 to 5%.
- the additional couplers conventionally used for dyeing keratin fibers are preferably chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene couplers, heterocyclic couplers and also their addition salts.
- addition salts of the oxidation bases and of the couplers which can be used in the context of the invention are in particular chosen from addition salts with an acid such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
- an acid such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
- the coupler (s) when they are present, are generally present in a total amount ranging from 0.001 to 10% by weight approximately of the total weight of the coloring composition, preferably ranging from 0.005 to 5% by weight. weight relative to the total weight of the coloring composition.
- the total content of oxidation dyes in the composition according to the invention is between 0.001 to 20% by weight; preferably between 0.001% and 10% by weight, preferably between 0.01% and 5% by weight, relative to the weight of the composition.
- composition according to the invention preferably comprises at least one oxidation base and at least one coupler.
- the composition comprises one or more scleroglucan gums, in a total content greater than or equal to 0.5% by weight relative to the weight of the composition.
- Scleroglucan gums are polysaccharides of microbial origin produced by a fungus of the Sclerotium type, in especially Sclerotium rolfsii. These are polysaccharides made up solely of glucose units.
- Scleroglucan gums can be modified or not. Preferably the scleroglucan gums used in the present invention are unmodified.
- scleroglucan gums which can be used in the present invention are, without limitation, the products sold under the name ACTIGUM CS, in particular ACTIGUM CS 11, by the company SANOFI BIO INDUSTRIES and under the name AMIGUM or AMIGEL by the company ALBAN MULLER INTERNATIONAL.
- scleroglucan gums such as that treated with glyoxal described in French patent application No. 2,633,940, can also be used.
- the scleroglucan gum (s) which can be used according to the invention preferably represent a total content ranging from 0.5 to 10% by weight, more preferably from 0.5 to 5% by weight, and even more preferably from 0.5 to 3 % by weight, better 0.5 to 2% by weight relative to the total weight of the composition, preferably from 0.7 to 1.5% by weight.
- Composition (A) according to the invention comprises one or more nonionic surfactants chosen from alkyl (poly) glycosides.
- alkyl (poly) glycosides is meant alkylmonoglycosides and / or alkylpolyglycosides.
- the nonionic surfactants of the alkyl (poly) glycoside type are represented by the following general formula Ri O- (R 2 0) t- (G) v
- - Ri represents a linear or branched alkyl or alkenyl radical containing 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms, or an alkylphenyl radical in which the linear or branched alkyl radical contains 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms;
- - R 2 represents an alkylene radical containing 2 to 4 carbon atoms,
- - G represents a sugar unit comprising 5 to 6 carbon atoms
- - t denotes a value ranging from 0 to 10, preferably from 0 to 4,
- - v denotes a value ranging from 1 to 15, preferably from 1 to 4.
- alkyl (poly) glycoside surfactants are compounds of the formula described above in which:
- Ri denotes a saturated or unsaturated, linear or branched alkyl radical containing from 8 to 18 carbon atoms
- R 2 represents an alkylene radical containing 2 to 4 carbon atoms
- - t denotes a value ranging from 0 to 3, preferably equal to 0,
- - G denotes glucose, fructose or galactose, preferably glucose
- the degree of polymerization that is to say the value of v, which can range from 1 to 15, preferably from 1 to 4; the average degree of polymerization being more particularly between 1 and 2.
- the glucosidic bonds between the sugar units are preferably of the 1-6 or 1-4 type, preferably of the 1-4 type.
- the alkyl (poly) glycoside surfactant is an alkyl (poly) glucoside surfactant.
- the surfactant alkyl (poly) glycoside is selected from (C 6 -C 24 alkyl) (poly) glycosides, more preferably from (C 8 -C 8) (poly) glycosides, preferably from C 8 / Ci 6 alkyl - (poly) glucosides, preferably of type 1, 4, and preferably chosen from decylglucosides, cocoglucosides and / or caprylyl / capryl glucosides, preferably caprylyl / capryl glucosides.
- the nonionic surfactant (s) alkyl (poly) glycosides preferably alkyl (poly) glucosides are present in a total content ranging from 0.01 to 10%, more preferably from 0.05 to 5% in weight, better from 0.1 to 3% by weight relative to the total weight of the composition.
- the coloring composition also further comprises one or more additional surfactants other than the alkyl (poly) glycosides.
- the additional surfactant (s) can be chosen from anionic surfactants, amphoteric or zwitterionic surfactants, cationic surfactants, and nonionic surfactants other than alkylpolyglycosides, and their mixtures, preferably from cationic surfactants .
- composition according to the invention comprises one or more additional surfactants chosen from nonionic surfactants other than alkylpolyglycosides.
- the additional nonionic surfactants which can be used according to the invention can be chosen from:
- - condensates of ethylene oxide and propylene oxide on fatty alcohols - polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1 to 5 to 4;
- esters of polyoxyalkylenated fatty acids preferably polyoxyethylenated having from 2 to 150 moles of ethylene oxide including oxyethylenated vegetable oils;
- amine oxides such as the oxides of alkyl (Ci ClO 4) amines or oxides of N- (acyl Cio-Ci 4) - aminopropyl morpholine;
- composition according to the invention comprises one or more additional surfactants chosen from cationic surfactants.
- the cationic surfactant (s) are chosen from the salts of primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, quaternary ammonium salts, and their mixtures.
- the groups R 8 to Ru which may be identical or different, represent an aliphatic group, linear or branched, comprising from 1 to 30 carbon atoms, or an aromatic group such as aryl or alkylaryl, at least one of the groups Rs à Ru containing from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms carbon.
- the aliphatic groups can comprise heteroatoms such as in particular oxygen, nitrogen, sulfur and halogens.
- the aliphatic groups are for example chosen from C1-C30 alkyl, C1-C30 alkoxy, polyoxyalkylene (C 2 -C 6 ), C1-C30 alkylamide, (Ci 2 -C 2 2) amidoalkyl (C 2) -C6), (Ci 2 - C 22 ) alkyl acetate, and C1 -C30 hydroxyalkyl,
- X- is an anion chosen from the group of halides, phosphates, acetates, lactates, (Ci - C 4 ) alkyl sulfates, alkyl ( Ci -C 4 ) - or alkyl (Ci -C 4 ) aryl sulfonates.
- tetraalkylammonium chlorides are preferred on the one hand, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group contains approximately from 12 to 22 atoms of carbon, in particular behenyltrimethylammonium chlorides, distearyldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium or, on the other hand, distearoylethylhydroxyethylmethylammonium methosulfate, dipalmitoylethylhydroxyethylammethylethylammethylethylammethylethylammethylethylammethylammethylethylammoyl stearamidopropyldimethyl- (myristylacetate) - ammonium chloride marketed under the name CERAPHYL® 70 by the company VAN DY
- Ri 2 represents an alkenyl or alkyl group containing from 8 to 30 carbon atoms, for example derived from tallow fatty acids
- R 3 represents a hydrogen atom, an alkyl group - C 4 or an alkenyl or alkyl group having from 8 to 30 carbon atoms
- R 4 represents an alkyl group -C 4 alkyl
- Ri 5 represents a hydrogen atom, a C1 - alkyl group
- X is an anion selected from the group of halides, phosphates, acetates, lactates, (Ci -C 4) alkyl sulfates, alkyl (Ci -C 4) - alkyl or (Ci - C 4) aryl-sulfonates.
- R1 2 and R I 3 denote a mixture of alkenyl or alkyl groups containing from 12 to 21 carbon atoms, for example derived from tallow fatty acids, R I 4 denotes a methyl group, R 5 denotes an atom of hydrogen.
- R I 4 denotes a methyl group
- R 5 denotes an atom of hydrogen.
- REWOQUAT® W 75 Such a product is for example marketed under the name REWOQUAT® W 75 by the company REWO.
- R I 6 denotes an alkyl group comprising approximately from 16 to 30 carbon atoms optionally hydroxylated and / or interrupted by one or more oxygen atoms
- Ri 7 is chosen from hydrogen or an alkyl group containing from 1 to 4 carbon atoms or a group - (CH2) 3-N + (Ri 6a ) (Ri7a) (Ri 8a), Ri 6a, Ri 7a, Ri 8a, Ri s, R19, R20 and R21, identical or different, are chosen from hydrogen or an alkyl group containing from 1 to 4 carbon atoms, and
- X- is an anion selected from the group of halides, acetates, phosphates, nitrates, alkyl (Ci -C 4) alkyl sulfates, alkyl (Ci -C 4) - alkyl or (Ci - C 4) aryl-sulfonates, in particular methyl and ethyl sulfate.
- Such compounds are for example Finquat CT-P offered by the company FINETEX (Quaternium 89), Finquat CT offered by the company FINETEX (Quaternium 75).
- R 22 is selected from alkyl Ci -C 6 hydroxyalkyl or dihydroxyalkyl Ci -C 6 alkyl,
- R23 is chosen from:
- R25 is chosen from:
- R24, R26 and R28 are chosen from C7-C2 1 hydrocarbon groups, linear or branched, saturated or unsaturated,
- r, s and t are integers ranging from 2 to
- x and z are integers ranging from 0 to 10
- X- is a simple or complex anion, organic or inorganic, provided that the sum x + y + z is from 1 to 15, that when x is 0 then R23 is R27 and that when z is 0 then R25 is R29.
- the alkyl groups R22 can be linear or branched and more particularly linear.
- R22 denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl group, and more particularly a methyl or ethyl group.
- the sum x + y + z is worth from 1 to 10.
- R23 is a hydrocarbon group R27, it can be long and have from 12 to 22 carbon atoms, or short and have from 1 to 3 carbon atoms.
- R25 is a hydrocarbon group R29, it preferably has 1 to 3 carbon atoms.
- R24, R26 and R28 are chosen from C1 1 -C2 1 hydrocarbon groups, linear or branched, saturated or unsaturated, and more particularly from C1 1 -C2 1 alkyl and alkenyl groups, linear or branched, saturated or unsaturated.
- x and z are worth 0 or 1.
- y is equal to 1.
- r, s and t are worth 2 or 3, and even more particularly are equal to 2.
- the anion X- is preferably a halide, preferably chloride, bromide or iodide, a (Ci -C 4 ) alkyl, (Ci -C 4 ) alkyl - or (Ci -C 4 ) alkyl aryl sulfonate. It is however possible to use methanesulfonate, phosphate, nitrate, tosylate, an anion derived from organic acid such as acetate or lactate or any other anion compatible with ammonium having an ester function.
- the anion X is even more particularly chloride, methylsulfate or ethylsulfate.
- R22 denotes a methyl or ethyl group
- - z is 0 or 1
- - r, s and t are equal to 2
- - R-23 is chosen from:
- - R 25 is chosen from:
- R 24 , R 26 and R 28 are chosen from C1 3-C1 7 hydrocarbon groups, linear or branched, saturated or unsaturated, and preferably from C1 3- C 1 alkyl and alkenyl groups 7, linear or branched, saturated or unsaturated.
- the hydrocarbon groups are linear.
- acyl groups preferably have 14 to 18 carbon atoms and more particularly come from a vegetable oil such as palm or sunflower oil. When the compound contains several acyl groups, these can be the same or different.
- Such compounds are for example sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO.
- composition according to the invention can contain, for example, a mixture of mono-, di- and triester salts of quaternary ammonium with a majority by weight of diester salts.
- the ammonium salts containing at least one ester function contain two ester functions.
- the cationic surfactant (s) are chosen from cetyltrimethylammonium salts, behenyltrimethylammonium salts, dipalmitoylethylhydroxy ethylmethylammonium salts, and their mixtures, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, methosethylethylammonium hydroxide mixtures.
- composition according to the invention comprises one or more additional surfactants
- their total content preferably ranges from 0.01 to 20%, more preferably from 0.05 to 10% by weight, better still from 0.1 to 5% by weight relative to the total weight of the composition.
- the composition according to the invention comprises one or more additional cationic surfactants, in a total content preferably ranging from 0.01 to 10%, more preferably from 0.05 to 5% by weight, better still from 0.1 to 3% by weight relative to the total weight of the composition.
- composition according to the invention can also comprise one or more associative polymers.
- the associative polymers according to the invention are polymers comprising at least one C 8 -C 30 fatty chain and the molecules of which are capable, in the formulation medium, of associating with each other or with molecules of other compounds.
- the fatty chain contains from 10 to 30 carbon atoms.
- associative polymers are amphiphilic polymers, that is to say polymers comprising one or more hydrophilic parts which make them soluble in water and one or more hydrophobic zones (comprising at least one fatty chain) by which polymers interact and collect with each other or with other molecules.
- the associative polymers which can be used in the composition according to the invention can be chosen from nonionic, anionic, cationic and amphoteric associative polymers, and their mixtures.
- the associative polymer or polymers are present in the composition in a total weight content preferably between 0.01 and 10%, and even more preferably between 0.05 and 5% of the total weight of the composition, better between 0, 1 and 2% by weight relative to the total weight of the composition
- the composition comprises one or more cationic polymers different from the cationic associative polymers mentioned above.
- cationic polymers which can be used in the compositions according to the invention, there may be mentioned in particular:
- alkyl diallyl amine or dialkyl diallyl ammonium cyclopolymers Mention may more particularly be made of the homopolymer of dimethyldiallylammonium salts (for example chloride), for example sold under the name "MERQUAT 100" by the company NALCO, Preferably, the polymers are chosen from homopolymers of dialkyl diallyl ammonium.
- cationic polymers which consist of recurring units corresponding to the formula:
- the cationic polymer (s) is / are chosen from homopolymers of dialkyl diallyl ammonium, in particular homopolymers of dimethyldiallylammonium salts, poly (dimethyliminio) - 1, 3-propanediyl polymers (dimethyliminio) - 1, 6- hexanediyldichloride, whose INCI name is hexadimethrine chloride; and their mixtures.
- the total content of cationic polymers in the composition according to the present invention can vary from 0.01 to 10% by weight relative to the weight of the composition, preferably from 0.1 to 7%, relative to by weight of the composition, even more advantageously from 0.5 to 5% by weight, better still from 0.5 to 3% by weight relative to the weight of the composition.
- the coloring composition (A) according to the invention can advantageously comprise one or more carboxylic acids, and / or their addition salts and / or their solvates, said carboxylic acid (s) being aliphatic compounds, comprising from 2 to 10 atoms of carbon and preferably comprising at least two carboxylic groups.
- they are chosen from aliphatic dicarboxylic and / or tricarboxylic acids comprising from 2 to 10 carbon atoms, preferably from 2 to 8 carbon atoms, better still from 2 to 6 carbon atoms.
- carboxylic acid (s) is / are saturated or unsaturated, substituted or unsubstituted.
- the carboxylic acids can be chosen from oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, maleic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, and mixtures thereof.
- the carboxylic acid (s) comprise at least two carboxylic groups and are chosen from malonic acid, citric acid, maleic acid, glutaric acid, succinic acid and their mixtures; preferably chosen from malonic acid, citric acid, maleic acid, and mixtures thereof.
- the carboxylic acid is citric acid.
- the total content of carboxylic acid (s) and / or their addition salts and / or their solvates preferably ranges from 0.1% to 20% by weight, relative to the total weight of the composition (A) .
- the total content of carboxylic acid (s) varies from 0.1 to 20, preferably from 0.5% to 10% by weight, better still from 1% to 7% by weight, relative to the total weight of the composition, better still from 2 to 5% by weight relative to the total weight of the composition (A).
- the cosmetically acceptable medium suitable for dyeing keratin fibers also called dye "support” generally comprises water or a mixture of water and at least one organic solvent to dissolve the compounds which would not be sufficiently soluble. in water.
- the organic solvents are chosen from monoalcohols or diols, linear or branched, preferably saturated, comprising from 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2- methyl 2,4-pentanediol), neopentylglycol and 3-methyl- 1,5-pentanediol; glycerol; aromatic alcohols such as benzyl alcohol, phenylethyl alcohol; glycols or glycol ethers such as, for example, monomethyl, monoethyl and monobutyl ethers of ethylene glycol, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether, butylene glycol, dipropylene glycol; as well as the alkyl ethers of diethylene glycol, in particular Ci-C 4 , such as for example, the monoethyl ether or the monobutyl ether of di
- compositions used according to the invention generally comprise water or a mixture of water and one or more organic solvents or a mixture of organic solvents.
- composition according to the invention preferably comprises water.
- the water content varies from 5 to 95% by weight, more preferably from 10 to 90% by weight, better still from 20 to 80% by weight, relative to the total weight of the composition.
- the pH of the composition according to the invention generally varies from 1 to 12.
- the pH of the composition (A) according to the invention is basic.
- basic pH within the meaning of the present invention, is meant a pH greater than 7.
- the pH of the composition (A) according to the invention is greater than 8, and particularly ranges from 8.5 to 12.
- the pH of the composition ranges from 9 to 12.
- the cosmetically acceptable medium can be adjusted to the desired value by means of acidifying or basifying agents usually used in dyeing keratin fibers or even using conventional buffer systems.
- the acidifying agents there may be mentioned, by way of example, mineral acids such as for example hydrochloric acid, (ortho) phosphoric acid, boric acid, nitric acid, sulfuric acid or organic acids such as for example the compounds comprising at least one sulfonic acid function, a phosphonic acid function or a phosphoric acid function, or the compounds with a carboxylic acid function such as those described above.
- mineral acids such as for example hydrochloric acid, (ortho) phosphoric acid, boric acid, nitric acid, sulfuric acid or organic acids such as for example the compounds comprising at least one sulfonic acid function, a phosphonic acid function or a phosphoric acid function, or the compounds with a carboxylic acid function such as those described above.
- Alkaline agents According to a preferred embodiment, the composition according to the invention comprises one or more alkaline agents.
- the alkaline agent (s) also called basifying agents
- the composition according to the invention comprises a total content of alkaline agents ranging from 1 to 20% by weight, more preferably from 3 to 18% by weight, better still from 5 to 16% by weight relative to the total weight of the composition.
- the alkaline agent (s) are chosen from among the mineral alkaline agent (s), preferably chosen from ammonia, also called ammonium hydroxide, (or ammonia precursors such as ammonium salts (for example ammonium halides and in particular ammonium chloride), silicates, phosphates, carbonates or bicarbonates of alkali or alkaline earth metals, such as metasilicates alkali or alkaline earth metals, sodium or potassium carbonates or bicarbonates, sodium or potassium hydroxides, or mixtures thereof.
- ammonia also called ammonium hydroxide
- ammonia precursors such as ammonium salts (for example ammonium halides and in particular ammonium chloride)
- silicates phosphates, carbonates or bicarbonates
- the alkaline agents are chosen from ammonia (or ammonia precursor agents such as ammonium salts, for example ammonium halides and in particular ammonium chloride) and / or metasilicates. of alkali or alkaline earth metals
- the alkaline agent (s) are chosen from alkanolamines and / or amino acids.
- the alkaline agent (s) are chosen from alkanolamines.
- alkanolamine an organic amine comprising a primary, secondary or tertiary amine function, and one or more alkyl groups, linear or branched, in Ci to Cs carrying one or more hydroxy radicals.
- the organic amines selected from alkanolamines such as mono-, di- or tri-alkanolamine having one to three hydroxy radicals, identical or different, C l -C 4.
- the compounds of this type are preferably chosen from monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N, N-dimethylethanolamine, 2-amino-2-methyl-1-propanol, triisopropanol-amine, 2-amino-2-methyl-1, 3-propanediol, 3-amino- 1, 2-propanediol, 3-dimethylamino-l, 2-propanedio l, tris-hydroxymethylamino-methane., and their mixtures, preferably monoethanolamine (MEA).
- MEA monoethanolamine
- the alkaline agent (s) are chosen from amino acids.
- the alkaline agent (s) present in the composition according to the invention are chosen from ammonia, alkanolamines, and / or amino acids in neutral or ionic form, in particular basic amino acids, and preferably arginine, metasilicates of alkali or alkaline earth metals.
- composition according to the invention comprises one or more alkaline agents.
- composition according to the invention comprises:
- alkaline mineral agent preferably chosen from ammonia and / or metasilicates of alkali or alkaline earth metals, preferably ammonia;
- organic alkaline agents preferably chosen from alkanolamines and / or amino acids, preferably from alkanolamines, preferably monoethanolamine.
- the composition comprises ammonia (ammonium hydroxide)
- its content preferably ranges from 0.1 to 10% by weight, more preferably from 0.5 to 8% by weight, better still from 1 to 6% by weight relative to the total weight of the composition.
- the composition comprises one or more alkanolamines
- their total content preferably ranges from 0.5 to 10% by weight, more preferably from 1 to 9% by weight, better still from 2 to 8% by weight relative to the total weight of the composition.
- composition according to the invention may also contain various additives conventionally used in compositions for coloring the hair, such as mineral thickening agents, and in particular fillers such as clays, talc; organic thickening agents other than scleroglucan gums, antioxidants; penetration agents; sequestering agents; perfumes ; dispersing agents; film-forming agents; ceramides; preservatives; opacifying agents, fatty substances and / or additional direct dyes.
- mineral thickening agents such as clays, talc; organic thickening agents other than scleroglucan gums, antioxidants; penetration agents; sequestering agents; perfumes ; dispersing agents; film-forming agents; ceramides; preservatives; opacifying agents, fatty substances and / or additional direct dyes.
- the above additives are generally present in an amount for each of them of between 0.01 and 40% by weight relative to the weight of the composition, preferably between 0.1 and 20% by weight relative to the weight of the composition.
- Another object of the invention is a coloring process using a coloring composition (A) as described above, with an oxidizing composition (B) comprising one or more chemical oxidizing agents.
- the invention also relates to a process for dyeing keratin fibers, and in particular human keratin fibers such as the hair, implementing the application to the fibers of a coloring composition (A) as defined above, and an oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from hydrogen peroxide, the oxidizing composition (B) being mixed with the coloring composition (A) just before use (application to said fibers) (extemporaneously) or at the time of use, or else the coloring compositions and oxidants being applied sequentially without intermediate rinsing.
- a coloring composition A
- an oxidizing composition comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from hydrogen peroxide, the oxidizing composition (B) being mixed with the coloring composition (A
- the oxidizing composition (B) used with the coloring composition (A) according to the invention contains one or more chemical oxidizing agent (s), preferably chosen from hydrogen peroxide and / or one or more hydrogen peroxide generating system (s).
- chemical oxidizing agent is meant an oxidizing agent other than air oxygen.
- the chemical oxidizing agent (s) are chosen from hydrogen peroxide, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors, alkali or alkaline earth metal percarbonates such as hydrogen peroxide.
- alkali metal bromates or ferricyanides solid chemical oxidizing agents generating hydrogen peroxide such as urea peroxide and polymer complexes which can release hydrogen peroxide, in particular those comprising a vinyl heterocyclic monomer such as polyvinylpyrrolidone complexes / LLCL in particular in the form of powders; oxidases producing hydrogen peroxide in the presence of a suitable substrate (e.g. glucose in the case of glucose oxidase or uric acid with uricase).
- a suitable substrate e.g. glucose in the case of glucose oxidase or uric acid with uricase.
- the chemical oxidizing agent (s) are chosen from hydrogen peroxide, urea peroxide, bromates or ferricyanides of alkali metals, peroxygenated salts, and mixtures of these compounds,
- the chemical oxidizing agent is hydrogen peroxide.
- the chemical oxidizing agent (s) represent from 0.05 to 40% by weight, preferably from 0.5 to 30% by weight, more preferably from 1 to 20% by weight, and better still from 1.5 to 15% by weight relative to the total weight of the oxidizing composition (B).
- the oxidizing composition (B) according to the invention does not contain peroxygenated salts.
- the oxidizing composition (B) comprises one or more scleroglucan gums, preferably in a total content greater than or equal to 0.5% by weight relative to the weight of the composition.
- the scleroglucan gum (s) which can be used according to the invention preferably represent from 0.5 to 10% by weight, more preferably from 0.5 to 5% by weight, and even more preferably from 0.5 to 3% by weight, or even from 0.7 to 2% by weight, relative to the total weight of the oxidizing composition (B).
- the oxidizing composition (B) can also contain various additional compounds or various adjuvants conventionally used in compositions for coloring the hair, in particular as defined above.
- the oxidizing composition (B) is generally an aqueous composition.
- aqueous composition means a composition comprising more than 20% by weight of water, preferably more than 30% by weight of water, and even more advantageously more than 40% by weight of 'water.
- the oxidizing composition (B) usually comprises water which generally represents from 10 to 98% by weight, preferably from 20 to 96% by weight, preferably from 50 to 95% by weight, relative to the weight total of the composition.
- This oxidizing composition (B) can also comprise one or more water-soluble organic solvents as described above. It can also include one or more acidifying agents.
- acidifying agents there may be mentioned by way of example, mineral or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, lactic acid, sulfonic acids.
- mineral or organic acids such as hydrochloric acid, orthophosphoric acid, sulfuric acid, carboxylic acids such as acetic acid, tartaric acid, citric acid, lactic acid, sulfonic acids.
- composition (B) is less than 7.
- the pH of the composition (B) of the invention is advantageously between 1 and 7, preferably between 1 and 4, and more preferably from 1.5 to 3.5.
- the oxidizing composition (B) is in various forms, such as, for example, a solution, an emulsion or a gel.
- the method of the invention can be implemented by applying the coloring composition (A) as defined above and the oxidizing composition (B) successively and without intermediate rinsing, the order being indifferent.
- a ready-to-use composition obtained by extemporaneous mixing, at the time of use, of the coloring composition (A) as defined above and of the keratin materials, dry or wet, is applied.
- the weight ratio R of the quantities of (A) / (B) varies from 0.1 to 10, preferably from 0.2 to 2, better still from 0.3 to 1.
- the application of the ready-to-use composition to the keratin materials is left in place for a duration, in general, of the order of 1 minute to 1 hour, preferably from 5 minutes to 30 minutes.
- the temperature during the process is conventionally between room temperature (between 15 and 25 ° C) and 80 ° C, preferably between room temperature and 60 ° C.
- the keratin materials are optionally rinsed with water, possibly undergo a washing followed by a rinsing with water, before being dried or left to dry.
- the keratin fibers are human keratin fibers, preferably human hair.
- the invention also relates to and a ready-to-use coloring composition for keratin fibers, in particular human keratin fibers, such as the hair, obtained by extemporaneous mixing, at the time of use of a composition (A ) including:
- one or more scleroglucan gums in a total content greater than or equal to 0.5% by weight, relative to the weight of the composition
- nonionic surfactants chosen from alkylpolyglycosides
- surfactant preferably cationic
- composition (B) comprising
- extemporaneous is meant in particular less than 30 minutes, preferably less than 15 minutes, better still less than 5 minutes before application to the keratin fibers.
- the chemical oxidizing agent (s) preferably represent a total content varying from 0.1 to 20% by weight, preferably from 0.5 to 15% by weight, or even more preferably from 1 to 10% by weight, relative to the total weight of the ready-to-use composition.
- the invention relates to a device with several compartments comprising in a first compartment a coloring composition (A) as described above, and in a second, an oxidizing composition (B) comprising one or more oxidizing agents, these compositions having been described previously .
- the invention also has for its object and a device (or “kit”) with several compartments allowing the implementation of the composition for coloring keratin fibers, preferably comprising at least two compartments, a first compartment containing the composition coloring (A) as defined previously, and the second compartment containing at least one oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating peroxide of hydrogen, preferably from hydrogen peroxide, the compositions of the compartments being intended to be mixed before application, to give the formulation after mixing; in particular the kit can be an aerosol device.
- kit a device with several compartments allowing the implementation of the composition for coloring keratin fibers, preferably comprising at least two compartments, a first compartment containing the composition coloring (A) as defined previously, and the second compartment containing at least one oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s
- the color of the locks was evaluated in the CIE L * a * b * system, using a Datacolor Spectraflash SF600X Spectrocolorimeter.
- the three parameters respectively designate the color intensity (L *), a * indicates the green / red color axis and b * the blue / yellow color axis.
- L * the color intensity
- a * indicates the green / red color axis
- b * the blue / yellow color axis.
- the parameters L *, a * and b * represent the values measured on the locks of hair after coloring and the parameters Lo *, ao * and bo * represent the values measured on the locks of untreated hair.
- DE * the higher the value of DE *, the better the coloration of the keratin fibers.
- the stability of the coloring compositions was evaluated by observing the compositions at T0 (immediately after preparation of the composition) and then after 2 months of storage at 45 ° C.
- composition Al according to the invention is homogeneous and forms a translucent gel at T0. After 2 months at 45 ° the composition Al according to the invention is stable; it is homogeneous and translucent. Comparative compositions C l, C2 and C3 in which the scleroglucan gum has been replaced weight for weight by another thickening agent of the polysaccharide type are not stable. Indeed, they are not homogeneous, from T0 there is a phase shift of these compositions.
- compositions were prepared from the following ingredients in the following proportions indicated in grams:
- the stability of the coloring compositions was evaluated by observing the compositions at T0 (immediately after preparation of the composition) then after 2 months of storage at room temperature (25 ° C.), and after 2 months of storage at 45 ° C.
- composition A2 according to the invention which comprises a content of scleroglucan gum greater than or equal to 0.5% by weight relative to the total weight of the composition is stable at room temperature as well as at 45 ° for 2 months , unlike the comparative composition C4 which comprises a content of scleroglucan gum of 0.4% by weight, relative to the weight of the composition.
- Compositions A2 and C4 contain the same total content of thickening agent (s) (0.8%). The comparative composition C4 is therefore not stable.
- composition was prepared from the following ingredients in the following proportions indicated in grams:
- the stability of the coloring composition was evaluated by observing them at TO and then after 48 hours at room temperature (25 ° C), then after 2 months of storage at 45 ° C.
- composition A3 according to the invention is homogeneous and form a translucent gel at TO. After 2 months at 45 °, the composition A3 according to the invention is stable and in the form of a homogeneous and translucent gel.
- Example 4 Composition A3 of Example 3 was mixed with 1 time its weight of oxidant 20 volumes (6 g% ai in H2O2). The mixture thus obtained was applied to locks of natural hair containing 90% white hair.
- the bath ratio "mixture / wick” is respectively 10/1
Abstract
Description
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FR1855434A FR3082742B1 (en) | 2018-06-20 | 2018-06-20 | HAIR COLORING COMPOSITION COMPRISING AN OXIDATION DYE, A SCLEROGLUCAN GUM, AND AN ALKYLPOLYGLYCOSIDE. |
PCT/EP2019/066365 WO2019243509A1 (en) | 2018-06-20 | 2019-06-20 | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, and an alkylpolyglycoside |
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FR3082738B1 (en) | 2018-06-20 | 2020-07-10 | L'oreal | HAIR COLORING COMPOSITION COMPRISING AN OXIDATION DYE, A SCLEROGLUCAN GUM AND A CATIONIC POLYMER. |
FR3082735B1 (en) | 2018-06-20 | 2022-03-11 | Oreal | HAIR COLORING COMPOSITION COMPRISING OXIDATION DYE, SCLEROGLUCANE GUM AND ASSOCIATIVE POLYMER. |
FR3082740B1 (en) | 2018-06-20 | 2020-05-29 | L'oreal | HAIR COLORING COMPOSITION COMPRISING AN OXIDATION DYE, A SCLEROGLUCAN GUM, AN ALCALNOLAMINE AND A MINERAL ALKALINE AGENT. |
FR3082710B1 (en) | 2018-06-20 | 2021-11-26 | Oreal | DEVICE FOR DISTRIBUTION OF A HAIR COLORING PRODUCT IMPLEMENTING A COLORING COMPOSITION AND AN OXIDIZING COMPOSITION INCLUDING A SCLEROGLUCAN GUM. |
FR3082739B1 (en) | 2018-06-20 | 2020-05-29 | L'oreal | HAIR COLORING PROCESS USING A COLORING COMPOSITION AND AN OXIDIZING COMPOSITION, SAID COMPOSITIONS COMPRISING A SCLEROGLUCAN GUM. |
FR3082736B1 (en) | 2018-06-20 | 2020-05-29 | L'oreal | HAIR COLORING COMPOSITION COMPRISING AN OXIDATION DYE, A SCLEROGLUCANE GUM AND AN ALKALINE AGENT OF AMINO ACID TYPE. |
US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
MX2023005963A (en) | 2020-12-04 | 2023-06-07 | Procter & Gamble | Hair care compositions comprising malodor reduction materials. |
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FR3082740B1 (en) | 2018-06-20 | 2020-05-29 | L'oreal | HAIR COLORING COMPOSITION COMPRISING AN OXIDATION DYE, A SCLEROGLUCAN GUM, AN ALCALNOLAMINE AND A MINERAL ALKALINE AGENT. |
FR3082739B1 (en) | 2018-06-20 | 2020-05-29 | L'oreal | HAIR COLORING PROCESS USING A COLORING COMPOSITION AND AN OXIDIZING COMPOSITION, SAID COMPOSITIONS COMPRISING A SCLEROGLUCAN GUM. |
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2018
- 2018-06-20 FR FR1855434A patent/FR3082742B1/en active Active
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- 2019-06-20 WO PCT/EP2019/066365 patent/WO2019243509A1/en unknown
- 2019-06-20 EP EP19730851.3A patent/EP3810286A1/en active Pending
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WO2019243509A1 (en) | 2019-12-26 |
US11266589B2 (en) | 2022-03-08 |
CN112312973A (en) | 2021-02-02 |
BR112020025763A2 (en) | 2021-03-16 |
US20210128444A1 (en) | 2021-05-06 |
FR3082742A1 (en) | 2019-12-27 |
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