EP3719427A1 - Procédé et appareil de distillation cryogénique pour produire de l'air sous pression au moyen d'un accélérateur de détente en liaison avec un détendeur d'azote pour le freinage - Google Patents

Procédé et appareil de distillation cryogénique pour produire de l'air sous pression au moyen d'un accélérateur de détente en liaison avec un détendeur d'azote pour le freinage Download PDF

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Publication number
EP3719427A1
EP3719427A1 EP17933288.7A EP17933288A EP3719427A1 EP 3719427 A1 EP3719427 A1 EP 3719427A1 EP 17933288 A EP17933288 A EP 17933288A EP 3719427 A1 EP3719427 A1 EP 3719427A1
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EP
European Patent Office
Prior art keywords
nitrogen
tower
expander
air
heat exchanger
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP17933288.7A
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German (de)
English (en)
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EP3719427A4 (fr
Inventor
Bowei ZHAO
Alain Briglia
Fengjie XUE
Eric Day
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of EP3719427A1 publication Critical patent/EP3719427A1/fr
Publication of EP3719427A4 publication Critical patent/EP3719427A4/fr
Withdrawn legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04024—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of purified feed air, so-called boosted air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
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    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109—Arrangements of compressors and /or their drivers
    • F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
    • F25J3/04121—Steam turbine as the prime mechanical driver
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
    • F25J3/04218—Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/04309—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
    • F25J3/04381—Details relating to the work expansion, e.g. process parameter etc. using work extraction by mechanical coupling of compression and expansion so-called companders
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
    • F25J3/04387—Details relating to the work expansion, e.g. process parameter etc. using liquid or hydraulic turbine expansion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
    • F25J3/04393—Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04763—Start-up or control of the process; Details of the apparatus used
    • F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
    • F25J3/04951—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
    • F25J3/04957—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network and inter-connecting equipments upstream of the fractionation unit (s), i.e. at the "front-end"
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    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/50—Oxygen or special cases, e.g. isotope-mixtures or low purity O2
    • F25J2215/54—Oxygen production with multiple pressure O2
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    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
    • F25J2240/10—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream the fluid being air
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    • F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • F25J2240/46—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval the fluid being oxygen

Definitions

  • the present invention relates to a low-temperature rectification air separation process and device.
  • cryogenic distillation to separate air into nitrogen and oxygen products is a common and mature technology.
  • At least two air separation towers operating at different pressures - a medium pressure tower and a low pressure tower - are brought into communication by means of heat exchange via a main condensing evaporator.
  • a pressurized, purified and cooled air feed gas is input into the medium pressure tower and/or the low pressure tower, and by means of rectification, gaseous and/or liquid nitrogen and oxygen are obtained. All or part of the nitrogen and oxygen undergo heat exchange with the air feed gas in the main heat exchanger to obtain gaseous nitrogen and oxygen products at room temperature.
  • the design of an air separation device and process is generally based on the requirements of customers for the status, pressure and output of nitrogen and oxygen products.
  • an external pressurization method by which room temperature oxygen or nitrogen, which has been reheated by means of the main heat exchanger, is pressurized by means of a corresponding booster, or an internal pressurization method by which low-temperature liquid oxygen or liquid nitrogen is boosted to a desired pressure by means of a pump and then reheated by means of the main heat exchanger may be selected.
  • the internal pressurization process is generally used.
  • a high pressure warm stream is required for evaporating and vaporizing the high pressure liquid oxygen in the main heat exchanger, wherein this warm stream is generally a high pressure air feed gas, or may also be circulating high pressure nitrogen. If a high pressure air feed gas is used, the air feed gas that has reached a pressure for the medium pressure tower by means of a main air compressor needs to be further pressurized to a higher pressure by means of a booster, and this is an energy-consuming process.
  • a technical problem to be solved by the present invention is to improve the utilization of the rectification capacity of an air separation tower, especially a low pressure tower.
  • Another technical problem to be solved by the present invention is to reduce the energy consumption required for the pressurization of an air feed gas.
  • Still another technical problem to be solved by the present invention is how to flexibly provide nitrogen with different output and pressure to a customer.
  • the present invention provides a method for producing nitrogen and oxygen by means of the cryogenic distillation of air, comprising: providing a first tower working at a higher pressure, i.e. a medium pressure tower, and a second tower working at a lower pressure, i.e.
  • a lower pressure tower wherein the first tower and the second tower are brought into communication by means of heat exchange via a main condensing evaporator; providing at least one air pre-cooling system, one air purification system, one main air compressor, at least one air booster, at least one main heat exchanger, and one supercooler; further treating an air feed gas, which has been pressurized to a first pressure range by means of the main air compressor, by means of the pre-cooling system and the purification system, then sending part of the air feed gas to the main heat exchanger for heat exchange with gas products produced by means of rectification and then to the first tower, subjecting the other part of the air feed gas to pressurization by means of the air booster and several stages of expander boosters, to heat exchange in the main heat exchanger with gas and liquid products produced by means of rectification and then to expansion or throttling for decompression to the first pressure range, and then sending this other part to the first tower, or supercooling a part of separated liquid by means of the supercooler, followed by
  • a part of pure nitrogen at the first nitrogen product pressure is partially reheated in the main heat exchanger, decompressed to a second nitrogen product pressure by means of a nitrogen expander, then further reheated by means of the main heat exchanger, and output as a product; and the nitrogen expander is braked by means of a first expander booster, the first expander booster further pressurizes the part of air feed gas that has been pressurized by means of the air booster and reaches a second pressure range to a third pressure range, and the air feed gas within the third pressure range enters, directly or optionally after undergoing further pressurization, the main heat exchanger for heat exchange with the gas and liquid products produced by means of rectification, and is then decompressed to the first pressure range by means of a liquid expander and then sent to the first tower, or a part of liquid is supercooled by means of the supercooler, then throttled and sent to the second tower.
  • the present invention further provides an apparatus for producing nitrogen and oxygen by means of the cryogenic distillation of air, comprising: a first tower working at a higher pressure and a second tower working at a lower pressure, wherein the first tower and the second tower are brought into communication by means of heat exchange via a main condensing evaporator; at least one air pre-cooling system, one air purification system, one main air compressor, one air booster, a first expander booster, at least one main heat exchanger, one nitrogen expander, at least one liquid expander, one liquid oxygen pump and one supercooler; a pipeline for sending an air feed gas to the first tower via the main air compressor, the air pre-cooling system, the air purification system and the main heat exchanger; a pipeline for sending oxygen-enriched liquid air at the bottom of the first tower to the supercooler for supercooling and to the second tower; a pipeline for sending pure liquid nitrogen at the top of the first tower to the supercooler for supercooling and to the upper part of the second tower; optionally, a
  • a nitrogen product is only extracted from the top of the first tower, and the pressure of this nitrogen product is generally a medium pressure of 5-6 bara. If a customer needs nitrogen with a higher pressure, the reheated nitrogen can be further pressurized using a booster. If a customer needs nitrogen with a lower pressure, instead of the common practice of extracting low pressure nitrogen from a pure nitrogen tower at the top of a low pressure tower, the present invention uses the expansion of medium pressure nitrogen to obtain desired low pressure nitrogen. Furthermore, the above-mentioned nitrogen expander may be braked by means of an expander booster for compressing air. It can be seen therefrom that the present invention can flexibly produce nitrogen with different pressures, while the energy consumption for producing pressurized air can be reduced by utilizing the expansion work of nitrogen.
  • air feed gas refers to a mixture mainly comprising oxygen and nitrogen.
  • pure nitrogen covers gaseous fluids with a nitrogen content of not less than 99 mole percent
  • impure nitrogen covers gaseous fluids with a nitrogen content of not less than 95 mole percent, with the content of nitrogen in the "impure nitrogen” being less than that in the "pure nitrogen”.
  • oxygen-enriched liquid air refers to a liquid fluid with a molar percentage of oxygen greater than 30, and the term “pure liquid oxygen” covers liquid fluids with a molar percentage of oxygen greater than 99, with the content of oxygen in the “pure liquid oxygen” being higher than that in the "oxygen-enriched liquid air”.
  • pure liquid nitrogen refers to a liquid fluid with a molar percentage of nitrogen greater than 99
  • impure liquid nitrogen refers to a liquid fluid with a molar percentage of nitrogen greater than 96, with the content of nitrogen in the “impure liquid nitrogen” being less than that in the "pure liquid nitrogen”.
  • the low temperature rectification of the present disclosure is a rectification method carried out at least in part at a temperature of 150 K or less.
  • “Tower” herein means a distillation or fractionation tower or zone in which liquid and gas phases come into countercurrent contact for effectively separating a fluid mixture.
  • the operating pressure of the "first tower” in the present disclosure is generally 5 to 6.5 bara, which is higher than the general operating pressure of the "second tower” by 1.1 to 1.5 bara.
  • the second tower can be installed vertically at the top of the first tower or the two towers are installed side by side.
  • the "first tower” is also generally referred to as a medium pressure tower or a lower tower, and the “second tower” is also generally referred to as a low pressure tower or an upper tower.
  • the main condensing evaporator is generally located at the top of the "first tower", and it can make pure nitrogen produced at the top of the first tower condense by means of heat exchange with pure liquid oxygen produced at the bottom of the second tower to obtain pure liquid nitrogen at the top of the first tower, while the liquid oxygen is partially evaporated.
  • Types for the main condensing evaporator include a tube and shell type, a falling film type, an immersion bath type, etc., and in the present invention, an immersion bath type condensing evaporator may be used.
  • the air pre-cooling system in the present invention is used for pre-cooling high temperature air (70-120°C) discharged from the main air compressor to a temperature suitable for entering the air purification system (generally 10-25°C).
  • High-temperature air generally comes into contact with ordinary circulating cooling water and low-temperature water (generally 5-20°C) in an air cooling tower for heat exchange to achieve the purpose of cooling.
  • Low-temperature water can be obtained by bringing ordinary circulating cooling water into contact with gas products or byproducts produced by the air separation apparatus, such as contact with impure nitrogen for heat exchange, or by means of a refrigerator.
  • the air purification system refers to a purification device that removes dust, water vapor, CO 2 , hydrocarbons etc. from the air.
  • a pressure swing adsorption method is generally used, wherein an adsorbent is involved which may optionally be a molecular sieve plus alumina, or a molecular sieve only.
  • the compressed, pre-cooled and purified air feed gas undergoes non-contact heat exchange with gas and/or liquid products produced by means of rectification, and is cooled close or equal to the rectification temperature of the first tower, generally less than 150 K.
  • Common main heat exchangers include split or integrated types, etc.
  • the main heat exchangers are divided into high pressure (> 20 bara pressure) and low pressure ( ⁇ 20 bara pressure) heat exchangers according to suitable pressure ranges.
  • both a high pressure plate heat exchanger and a low pressure plate heat exchanger, or an integral combined heat exchanger may be used.
  • the first pressure range is consistent with the range of the working pressure of the first tower or medium pressure tower, and is generally 5 to 6 bara, and the air feed gas at atmospheric pressure can be compressed by the main air compressor to reach this pressure range.
  • the second pressure range is a pressure range achieved by pressurizing the air feed gas within the first pressure range by means of the air booster, and is generally 40 to 60 bara.
  • the third pressure range is achieved by further pressurizing the air feed gas within the second pressure range by means of the first expander booster and/or the second expander booster, and is generally 60 to 75 bara.
  • the air feed gases within the second and third pressure ranges are required to be capable of exchanging heat with pressurized liquid oxygen in the main heat exchanger and causing same to evaporate and vaporize, and therefore, the specific pressure thereof is determined by the pressure of the liquid oxygen that needs to be vaporized.
  • the first nitrogen product pressure refers to the pressure of the pure nitrogen extracted from the top of the first tower or medium pressure tower, and is generally 4 to 5 bara. According to customer requirements, the pure nitrogen with the first nitrogen product pressure can be expanded and decompressed to obtain the second nitrogen product pressure, which is generally about 1.1 bara; alternatively, the pure nitrogen with the first nitrogen product pressure can be pressurized by means of the nitrogen booster to obtain the third nitrogen product pressure, which is generally greater than 7 bara.
  • the second and third nitrogen product pressures can both be flexibly determined according to customer requirements.
  • the Rahman's principle points out that when the upper tower or the low pressure tower is used to produce pure oxygen, the rectification capacity of the low pressure tower is not fully utilized.
  • one or more of the following measures are used to improve this situation, in order to increase the efficiency of the entire air separation system, reduce energy consumption, and even reduce the volume of the tower.
  • One of the measures is to introduce part of the air feed gas directly into the upper tower, i.e., the low pressure tower, so as to utilize the excess rectification capacity of this tower; a second one of the measures is to draw the pure nitrogen produced at the top of the medium pressure tower as a nitrogen product, and correspondingly, the amount of pure liquid nitrogen obtained after condensation by the main condenser will be reduced, that is, the amount of the reflux liquid sent to the low pressure tower will be reduced.
  • the reduction of the reflux liquid will make further use of the rectification capacity of the low pressure tower; on the other hand, the reduction of the reflux liquid requires a reduction in the processing capacity of the low pressure tower, and the diameter of the low pressure tower can be reduced accordingly, causing easier transportation.
  • the pressure of pure nitrogen drawn from the top of the medium pressure tower is generally 4 to 5 bara. If the pressure of a nitrogen product required by a customer is greater than 4 to 5 bara, such as 10 bara, the energy consumption for pressurizing the pure nitrogen extracted from the medium pressure tower to 10 bara is greatly reduced than that for pressurizing the pure nitrogen extracted from the low pressure tower to 10 bara.
  • the pure nitrogen extracted from the medium pressure tower can be expanded to 1 bara, and the expansion work can be used for power generation or a shaft-linked expander booster, thereby reducing the energy consumption of the entire air separation system.
  • part 101 of the air enters a low pressure main heat exchanger 1 for indirect heat exchange with medium pressure pure nitrogen 123 resulting from rectification and part of impure nitrogen 121 for cooling to about -170°C and is then sent to the lower part of a first tower 11 for rectification.
  • the other part 102 thereof is further pressurized to about 52 bara by means of an air booster 22, and then divided into two streams, wherein one stream 103 thereof is pressurized by means of a first expander booster 24 to become a stream 105 of 58 bara, and all is sent to a second expander booster 26 for further pressurization to become a stream 106 of 77 bara; and the other stream 104 of 102 is sent to a high pressure main heat exchanger 2, partially cooled, then extracted from the middle part, decompressed to 6 bara by means of an air expander 25, and then also sent to the lower part of the first tower 11 for rectification. Since the stream 105 that enters the second expander compressor 26 all comes from the first expander booster 24, the two form a series.
  • the first expander booster 24 and the second expander booster 26 are respectively linked with a nitrogen expander 23 and the air expander 25, and absorb the work done by the expanders.
  • the stream 106 pressurized to 77 bara enters the high pressure main heat exchanger 2 for indirect heat exchange with pure liquid oxygen 122, which has been pressurized to 88 bara, and part of impure liquid nitrogen 121 for condensation into a liquid while the high pressure pure liquid oxygen 122 evaporates and vaporizes and is output as a high pressure oxygen product.
  • the condensed air feed gas is decompressed to 6 bara by means of the liquid expander 28 and then separated into gas and liquid phases, one of which is a gaseous stream 107 that is directly sent to the lower part of the first tower 11, and the other one of which is a part of liquid stream 108 that is supercooled by means of a supercooler 3 and then sent to the middle part of the second tower 13.
  • the air feed gas introduced into the first tower 11 is rectified in the first tower to produce oxygen-enriched liquid air 110 at the bottom of the tower and pure nitrogen at the top of the tower.
  • a part of pure nitrogen is condensed into pure liquid nitrogen.
  • the part of pure liquid nitrogen mentioned above is used as a reflux liquid to the first tower.
  • a part is sent to a storage tank as a liquid nitrogen product, and the other part 112 is supercooled and then input into the upper part of the second tower 13 as a reflux liquid.
  • gases that are supercooled and input into the second tower also include the oxygen-enriched liquid air 110, and optionally, the impure liquid nitrogen 111 extracted from the middle part of the first tower 11 and the part of liquid air feed gas 108.
  • the above-mentioned streams are throttled and decompressed to about 1.3 to 1.4 bara and then transported to the second tower 13, and participate in rectification therein, and then, the impure nitrogen 121 with a pressure of about 1.3 bara can be extracted from the upper part of the second tower, while the pure liquid oxygen 122 with a pressure of about 1.4 bara is obtained at the bottom of the second tower.
  • the pure liquid oxygen can be pressurized to about 88 bara by means of a liquid oxygen pump 31, and then evaporated and vaporized by the high pressure air feed gas 106, 104 in the high pressure main heat exchanger 2 to obtain the high pressure oxygen product.
  • a part of high pressure liquid oxygen from the liquid oxygen pump can be throttled and decompressed to obtain medium pressure liquid oxygen with a pressure of about 30 bara, which is then similarly evaporated and vaporized by the high pressure air feed gas 106, 104 in the high pressure main heat exchanger 2 to obtain the medium pressure oxygen product.
  • the only nitrogen product is the medium pressure pure nitrogen 123 with a pressure of about 5.5 bara drawn from the top of the first tower 11.
  • the following operations can be carried out.
  • part 124 of the medium pressure pure nitrogen 123 which has been partially reheated, is extracted, decompressed to a desired pressure, which is referred to as a second nitrogen product pressure, by means of the nitrogen expander 23, then returned to the main heat exchanger, and completely reheated to obtain a second nitrogen product.
  • the nitrogen expander 23 is braked by means of the first expander booster 24, thereby converting the expansion work into energy required for the compressed air feed gas.
  • this remaining part can be output at the first nitrogen product pressure as a first nitrogen product, or pressurized to a third nitrogen product pressure, as required by a customer, by means of a nitrogen booster and output as a third nitrogen product.
  • the main difference between the embodiments shown in Figure 2 and Figure 1 is the connection relationship between the first expander compressor 24 and the second expander compressor 26.
  • the two are connected in parallel. Specifically, after air feed gas that has been pressurized to 6 bara in a main air compressor 21 is pre-cooled by means of a pre-cooling system and purified by means of a purification system, part 101 of the air feed gas enters a low pressure main heat exchanger 1 for indirect heat exchange with medium pressure pure nitrogen 123 resulting from rectification and part of impure nitrogen 121 for cooling to about -170°C and is then sent to the lower part of a first tower 11 for rectification.
  • the other part 102 thereof is further pressurized to about 52 bara by means of an air booster 22, and then divided into three streams, wherein one stream 115 thereof is pressurized by means of the first expander booster 24 to become a stream 116 of 76 bara; another stream 117 of 102 is sent to a high pressure main heat exchanger 2, partially cooled, then extracted from the middle part, decompressed to 6 bara by means of an air expander 25, and then also sent to the lower part of the first tower 11 for rectification; a third stream 118 of 102 is input into the second expander booster 26 and then also pressurized to form a stream 119 of 76 bara, which is mixed with the stream 116, then enters the high pressure main heat exchanger 2 for indirect heat exchange with pure liquid oxygen 122, which has been pressurized to 88 bara, and part of impure liquid nitrogen 121 for partial condensation into a liquid while the high pressure pure liquid oxygen 122 evaporates and vaporizes and is output as a high pressure oxygen product.
  • the condensed air feed gas 120 is decompressed to 6 bara by means of a liquid expander 28 and can be then separated into two streams by means of a gas-liquid separator, one of which is a gaseous stream 107 that is directly sent to the lower part of the first tower 11, and the other one of which is a liquid stream 108 that is supercooled by means of a supercooler 3 and then sent to the middle part of the second tower 13.
  • the first expander booster 24 and the second expander booster 26 are respectively linked with a nitrogen expander 23 and the air expander 25, and absorb the work done by the expanders.
  • Figure 2 shows a process flow as an embodiment according to the present invention
  • Figure 3 shows a process flow as a comparative example.
  • the upper part of a second tower is provided with a pure nitrogen tower 14, and low pressure pure nitrogen 140 with a pressure of about 1.3 bara is directly extracted from the top of the pure nitrogen tower.
  • the low pressure pure nitrogen 140 is reheated by means of a supercooler 3 and a main heat exchanger 1 and then output as a second nitrogen product.
  • part 101 of the air feed gas enters a low pressure main heat exchanger 1 for indirect heat exchange with medium pressure pure nitrogen 123 resulting from rectification and part of impure nitrogen 121 and low pressure pure nitrogen 140 for cooling to about -170°C and is then sent to the lower part of a first tower 11 for rectification.
  • the other part 102 thereof is further pressurized to about 51 bara by means of an air booster 22, and then divided into two streams, wherein one stream 131 is sent to a high pressure main heat exchanger 2, partially cooled, then extracted from the middle part, and decompressed by means of an air expander 25 to become a stream 132 of 6 bara, which is then also sent to the lower part of the first tower 11 for rectification; and the other stream 133 is pressurized to 76 bara by means of a second expander booster 26, then enters the high pressure main heat exchanger 2 for indirect heat exchange with pure liquid oxygen 122, which has been pressurized to 88 bara, and part of impure liquid nitrogen 121 for partial condensation into a liquid while the high pressure pure liquid oxygen 122 evaporates and vaporizes and is output as a high pressure oxygen product.
  • the condensed air feed gas is decompressed to 6 bara by means of a liquid expander 28 and can be then separated into two streams by means of a gas-liquid separator, one of which is a gaseous stream 107 that is directly sent to the lower part of the first tower 11, and the other one of which is a liquid stream 108 that is supercooled by means of a supercooler 3 and then sent to the middle part of the second tower 13.
  • a gas-liquid separator one of which is a gaseous stream 107 that is directly sent to the lower part of the first tower 11, and the other one of which is a liquid stream 108 that is supercooled by means of a supercooler 3 and then sent to the middle part of the second tower 13.
  • the simulation calculations listed in the following table are carried out using ASPEN software for an air separation system with an oxygen output of 100,000 Nm 3 /h.
  • a main heat exchanger is involved which is of an aluminum plate-fin type, and a main air compressor (MAC) and an air booster (BAC) are involved which are both steam turbines driven by high pressure steam.
  • the calculation of the operating cost is based on a high pressure steam price of 100 RMB/ton and is evaluated based on 5 years of operation. Table 1.
  • the recovery of O 2 obtained according to the present invention is slightly lower than that of the comparative example; however, the loss here is much less than the overall energy saving achieved by the present invention.
  • the "medium pressure pure nitrogen extraction” refers to the flow rate of the medium pressure pure nitrogen extracted from the top of the first tower
  • the “low pressure pure nitrogen extraction” refers to the flow rate of the low pressure pure nitrogen extracted from the top of the pure nitrogen tower
  • the "flow rate of conversion of medium pressure pure nitrogen to low pressure pure nitrogen” refers to the flow rate of the part of medium pressure pure nitrogen that is drawn from the middle part of the main heat exchanger and sent to the nitrogen expander 23.
  • the work required for producing the air feed gas with substantially the same pressure and flow rate by the air booster (BAC) is reduced, and the corresponding high pressure steam consumed is also reduced. Based on a total of five years, an operating cost of about 10 million can be saved.

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EP17933288.7A 2017-11-29 2017-11-29 Procédé et appareil de distillation cryogénique pour produire de l'air sous pression au moyen d'un accélérateur de détente en liaison avec un détendeur d'azote pour le freinage Withdrawn EP3719427A4 (fr)

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