EP3717669A1 - Plant for drying pretreated flexible sheet products - Google Patents
Plant for drying pretreated flexible sheet productsInfo
- Publication number
- EP3717669A1 EP3717669A1 EP18827240.5A EP18827240A EP3717669A1 EP 3717669 A1 EP3717669 A1 EP 3717669A1 EP 18827240 A EP18827240 A EP 18827240A EP 3717669 A1 EP3717669 A1 EP 3717669A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- drying
- plant
- series
- bars
- feeding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001035 drying Methods 0.000 title claims abstract description 59
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- 230000005672 electromagnetic field Effects 0.000 claims abstract description 23
- 238000007664 blowing Methods 0.000 claims abstract description 11
- 230000008859 change Effects 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims description 6
- 239000004020 conductor Substances 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 2
- 230000010355 oscillation Effects 0.000 abstract description 4
- 239000010985 leather Substances 0.000 description 13
- 238000011282 treatment Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000010028 chemical finishing Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B1/00—Manufacture of leather; Machines or devices therefor
- C14B1/58—Drying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B15/00—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form
- F26B15/10—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form with movement in a path composed of one or more straight lines, e.g. compound, the movement being in alternate horizontal and vertical directions
- F26B15/12—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form with movement in a path composed of one or more straight lines, e.g. compound, the movement being in alternate horizontal and vertical directions the lines being all horizontal or slightly inclined
- F26B15/18—Machines or apparatus for drying objects with progressive movement; Machines or apparatus with progressive movement for drying batches of material in compact form with movement in a path composed of one or more straight lines, e.g. compound, the movement being in alternate horizontal and vertical directions the lines being all horizontal or slightly inclined the objects or batches of materials being carried by endless belts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/02—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
- F26B3/04—Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour circulating over or surrounding the materials or objects to be dried
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/32—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
- F26B3/34—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects
- F26B3/343—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects in combination with convection
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/32—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action
- F26B3/34—Drying solid materials or objects by processes involving the application of heat by development of heat within the materials or objects to be dried, e.g. by fermentation or other microbiological action by using electrical effects
- F26B3/347—Electromagnetic heating, e.g. induction heating or heating using microwave energy
Definitions
- the present invention generally finds application in the field of tanning and particularly relates to a plant for drying pretreated flexible sheet products, such as industrial hides, skins, imitation leather or leather derivatives.
- hides are known to often exhibit surface defects that were naturally formed during the life of the animals (scratches due to goring, contact with barbed wire or thorns) or caused by poor leather preservation after flaying.
- the compound is initially deposited in a predetermined amount on the grain side of the hides and later dried to form a layer that binds with the fibers, to thereby be integrated with the hide.
- the finishing chemical compound is typically applied by spraying or by using rotating rollers that contact the hides as they are being fed.
- the chemical compound drying process is typically carried out using an oven or a tunnel operating with infrared rays, catalytic gas and more often with hot air.
- the plants for surface treatment of hides comprise one or more drying units, with hot air being conveyed thereto by high-flow compressors and blowers, whose flow rates may reach thousands of m 3 /h.
- the drying temperatures in these apparatus generally range from 80 °C to 160 °C.
- a first drawback of these plants is that the manufacturing energy costs associated with high hot air flows for drying the hides and with plant operation are very high.
- a further drawback is that the hides dried as described above have a very high surface temperature and cannot be easily handled and stacked.
- completely dried hides may be typically cooled using a cooling device, such as a cold air chiller, which has high power consumption.
- any shrinking effect of the hot drying process will cause shrinkage in the hides, thereby leading to a significant reduction of the useful leather area, and to a reduction of the final inherent value of the treated hides.
- EP2935631 by the proprietor hereof, discloses a plant for drying of the hides with a pair of operating units comprising respective radiofrequency electromagnetic field applicators located in a chamber and connected to respective high-frequency AC voltage generators.
- the two operating units are configured to dry different finishing chemical compounds that have been previously deposited on the hides by one or more deposition units.
- a first drawback of this arrangement is that this plant does not allow feedback-responsive adjustment of the operation of the generator and the applicator according to the operating conditions of the drying unit.
- a further drawback is that the hides must undergo both drying processes for optimal finishing. This drawback involves an increase of the overall machining costs.
- Electrodes are arranged in the drying unit with a conventional geometry that cannot be changed to optimize the application of the electromagnetic field on the hides as they are being fed.
- the technical problem addressed by the present invention is to ensure combined adjustment and control of the various thermal and fluid-dynamic parameters of the plant for efficient and quick drying of finishing chemical compounds after the latter have been deposited on the products.
- the object of the present invention is to solve the above problem, by providing a drying plant for drying pretreated flexible sheet products that is highly efficient and relatively cost-effective.
- a particular object of the present invention is to provide a plant as described hereinbefore that affords combined and feedback-responsive control and adjustments of the sheet product drying components.
- a further object of the invention is to provide a plant as described hereinbefore that can quickly and efficiently dry the finishing chemical compound, regardless of the amount thereof that has been deposited on the sheet products.
- Another object of the invention is to provide a plant as described hereinbefore that can optimize the overall energy costs.
- Yet another object of the present invention is to provide a plant as described hereinbefore that can use a combination of different drying modes.
- a further object of the present invention is to provide a plant as described hereinbefore that can remove the residual moisture accumulated in the drying units.
- Yet another object of the present invention is to provide a plant as described hereinbefore that can modify the electromagnetic field applicator to optimize application efficiency on the products.
- the plant comprises feeding means for feeding the sheet products in a longitudinal direction and drying means for drying the products as they are being fed.
- the drying means have at least one operating unit with a chamber through which the feeding means are designed to pass, and with at least one applicator therein, connected to a respective generator for application of an AC electromagnetic field in the RF range, to dry the chemical compound deposited on the products during processing.
- the plant also comprises at least one control unit for controlling the generator and/or the applicator.
- the AC electromagnetic field has an oscillation frequency that ranges from 300 kHz to 300MHz and is preferably 27.12 MHz, with tolerances in the admitted ISM bands, and at least one air blowing means (18) for delivering hot air and/or at least one suction means (19) are provided.
- the blowing means are controlled to deliver hot air at a predetermined temperature and the suction means are configured to draw in the moisture removed during drying from the chamber.
- the control unit is configured to change the speed of the feeding means or to change the electromagnetic field application time and sensor means are provided in the chamber for detecting one or more physical and/or thermodynamic parameters of the at least one operating unit such as the temperature and/or the residual humidity in the chamber and the temperature of the hides and also for controlling the feeding means, the blowing means and the suction means separately from or in combination with one another to ensure complete drying of the chemical compound layer.
- FIG. 1 is a perspective view of the drying plant of the invention
- FIG. 2 is a lateral view of the plant of Fig. 1 ;
- FIG. 3 is a front view of the plant of FIG. 1 .
- FIG. 4 is a lateral broken-away view of the plant of Fig. 1 ;
- FIG. 5 is a lateral broken away view of the plant of Fig. 4.
- a plant for drying pretreated flexible sheet products such as industrial hides, skins, imitation leather or leather derivatives, generally designated by numeral 1 .
- Hides are known to comprise a grain side and a flesh side and have a layer of previously deposited finishing chemical compound on one of the two sides, preferably the grain side.
- the finishing chemical compound may be deposited by known deposition means, such as spray or roll deposition means.
- the latter are configured to deposit a layer of chemical compound layer on at least one side of the sheet product with a surface density that ranges from 0.001 g/m 2 to 500 g/m 2 , preferably from 5 g/m 2 to 150 g/m 2 .
- the deposited chemical compounds may act as a base, color and finishing coat, and may be selected from the group comprising polymeric compounds such as acrylic and polyurethane resins, inorganic compounds such as iron oxides and pigments and natural compounds.
- the plant 1 comprises feeding means 2 for feeding the sheet products in a longitudinal direction L and drying means 3 for drying the products as they are being fed.
- the feeding means 2 may comprise an annular belt or wire conveyor 4 with the belt or wires tensioned by end rollers and defining a feeding plane p for the sheet products with their top sections.
- the drying means 3 comprise at least one operating unit 5 with a chamber 6 through which the feeding means 2 pass.
- the chamber 6 may be at least partially closed and delimited by a box-like structure 7 having an inlet 8 and an outlet 9 for the passage of the feeding means 2.
- the drying chamber 6 comprises therein at least one applicator 10 connected to a high-frequency voltage generator 1 1 for applying an AC electromagnetic field with an oscillation frequency that ranges from 300 kFIz to 300MFIz to dry the chemical compound deposited on the products during processing, irrespective of its surface density.
- the generator 1 1 is configured in such a manner that the oscillation frequency of the electromagnetic field will have a value of 27.12 MFIz with tolerances within the admitted ISM bands.
- the electromagnetic field applied to the flexible sheet products flexible that are being fed in the operating unit 5 can heat the chemical compound to a predetermined temperature.
- the generator 1 1 may be selected from the group comprising power triodes, inverter-controlled power triodes, modular electronic power amplifiers, converter power amplifiers, possibly with of solid-state technology or a combination thereof.
- the applicator 10 comprises at least one series of electrodes arranged in the drying chamber 6 and connected to a pair of terminals of the generator 1 1 .
- the electrodes may comprise at least one pair of substantially parallel plates made of a conductive material having the function of an anode and a cathode respectively, for applying the radiofrequency electromagnetic field.
- the plates may be placed below and above the feeding plane p at an adjustable distance, to selectively change the intensity of the electromagnetic field applied to the products during processing.
- the electrodes may comprise first 12 and second series of transverse bars 13 made of a conductive material, which are connected to first and second terminals of the generator 1 1 respectively.
- the electrodes of one series 12 are connected in parallel and have the function of a cathode, and the electrodes of the other series 13 are also connected in parallel and have the function of an anode.
- the bars 12, 13 may be also placed at adjustable distances, to thereby adjust the electromagnetic field intensity, as described above concerning the plates.
- the bars of a series 12 may be secured to a longitudinal beam 14 that moves in a respective vertical direction by means of appropriate drive means 15 to move the first bars toward or away from the bars of the other series 13.
- the first 12 and second series 13 of bars may be placed below or above the feeding plane p of the conveyor 4.
- the bars of the first series 12 may be longitudinally offset from and alternated to the bars of the second series 13 and each bar of the first series 12 may define a respective applicator 10, in combination with the bar of the second adjacent series 13.
- the bars of one series 12 may be placed below the feeding plane p whereas the bars of the other series 13 may be placed above the feeding plane TT.
- the bars of the first series 12 irrespective of whether they are placed below or above the feeding plane, will longitudinally offset from and alternated to the bars of the second series 13.
- each bar of the first series 12, placed either below or above defines a respective applicator 10 with the bar of the second series 13, placed either above or below, and longitudinally offset from the first series.
- the plant may comprise at least one control unit 16 which is configured to control the generator 1 1 and/or the applicator 10 and/or the feeding means 2 for complete drying of the chemical compound that has been previously deposited on at least one of the sides of the sheet product in the operating unit 5.
- control unit 16 may be configured to set the speed of the feeding means 2 to a predetermined value ranging from 0.01 m/min to 30 m/min, preferably from 6 m/min to 15 m/min, or to change the electromagnetic field application time or intensity.
- control unit 16 may comprise a control algorithm installed therein and a memory portion.
- the latter may store data and information corresponding to a plurality of drying programs.
- the software may be configured to select the most suitable drying program according to the characteristics of the sheet product to be treated.
- control unit 16 may comprise interface means 17 adapted to be actuated by the operator for management thereof.
- the operating unit 5 may comprise at least one air blowing means 18 and/or at least one suction means 19, in fluid communication from the drying chamber 6.
- blowing means 18 and suction means 19 may also be connected to the control unit 16 to adjust the drying temperature of the sheet products and further dry the chemical compound.
- the blowing means 18 may be controlled to deliver hot air at a predetermined temperature, whereas the suction means may be configured to draw in the moisture removed during drying from the chamber 6.
- Sensor means may be further provided in the drying chamber 6 and connected to the control unit 16.
- the sensor means are configured to detect one or more physical and/or thermodynamic parameters of the operating unit 5, e.g. the temperature of the chamber and/or the temperature of the hides and/or the residual humidity in the chamber 6.
- control unit 16 may be configured to manually or automatically control at least one of a generator 1 1 , an applicator 10 and at least one feeding means 2 separately from or in combination with one another, possibly based on the physical and/or thermodynamic parameters as detected by the sensor means.
- the temperature of the sheet products as a result of the drying process carried out by the operating unit 5 is determined according to the environmental conditions of use of the plant 1 .
- this feature may avoid the use of cold air chillers, which have high costs and maintenance requirements, downstream from the operating unit.
- the system 1 comprises a plurality of operating units 5A, 5B, 5C, one downstream from the other in the longitudinal direction of feed L.
- the number of units 5A, 5B, 5C may be also other than that as shown in the figures, without departure from the scope of the present invention.
- the units 5A, 5B, 5C may be connected by the above described feeding means 2 otherwise an operator may manually transfer the sheet products from one operating unit to the other at the end of the respective drying treatment.
- Each of the units 5A, 5B, 5C comprises at least one respective generator 1 1 A, 1 1 B, 1 1 C, one respective applicator 10A, 10B, 10C and possibly one respective control unit 16A, 16B, 16C to generate an electromagnetic field of suitable intensity in the respective chamber 6A, 6B, 6C.
- each of of operating units 5A, 5B, 5c may comprise respective blowing means 18A, 18B, 18C, and/or suction/drying means 19A, 19B, 19C and/or sensors, which are adapted to operate as described above for least one operating unit and are connected to the control unit 16A, 16B, 16C.
- the present invention may find application in industry, because it can be produced on an industrial scale in tanning factories, particularly in surface treatment of hides, skins, imitation leather and derivatives.
Landscapes
- Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Biotechnology (AREA)
- Electromagnetism (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Drying Of Solid Materials (AREA)
- Treatment Of Fiber Materials (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL18827240T PL3717669T3 (en) | 2017-11-30 | 2018-11-30 | Plant for drying pretreated flexible sheet products |
RS20211163A RS62369B1 (en) | 2017-11-30 | 2018-11-30 | Plant for drying pretreated flexible sheet products |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT201700138238 | 2017-11-30 | ||
PCT/IB2018/059494 WO2019106615A1 (en) | 2017-11-30 | 2018-11-30 | Plant for drying pretreated flexible sheet products |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3717669A1 true EP3717669A1 (en) | 2020-10-07 |
EP3717669B1 EP3717669B1 (en) | 2021-06-30 |
Family
ID=61581593
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18827240.5A Active EP3717669B1 (en) | 2017-11-30 | 2018-11-30 | Plant for drying pretreated flexible sheet products |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP3717669B1 (en) |
KR (1) | KR102667839B1 (en) |
CN (1) | CN111417733B (en) |
ES (1) | ES2890998T3 (en) |
PL (1) | PL3717669T3 (en) |
PT (1) | PT3717669T (en) |
RS (1) | RS62369B1 (en) |
WO (1) | WO2019106615A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX2020005578A (en) * | 2017-11-30 | 2021-01-08 | Officine Di Cartigliano S P A | Improved staking machine. |
IT202000009586A1 (en) * | 2020-04-30 | 2021-10-30 | Officine Di Cartigliano S P A | ROLLING MACHINE FOR FLEXIBLE LAMINARY MATERIALS |
IT202100030023A1 (en) * | 2021-11-26 | 2023-05-26 | Todesco S R L | APPARATUS FOR CLEANING THE WIRE OF A WIRE CONVEYOR AND SYSTEM INCLUDING SUCH APPARATUS |
CN116393343B (en) * | 2023-04-12 | 2023-11-07 | 燕山大学 | Lithium battery pole piece drying equipment |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3521061A1 (en) * | 1985-06-12 | 1986-12-18 | Dokoupil, Jiří, Dipl-Ing., 6251 Gückingen | METHOD AND DEVICE FOR CONDITIONING LEATHER, FURS, FURS AND THE LIKE. |
CN2260293Y (en) * | 1996-03-19 | 1997-08-20 | 程方 | Machine for quickly drying tobacco |
FR2792225A1 (en) * | 1999-04-14 | 2000-10-20 | Rohm & Haas France | Electromagnetic energy assisted curing of a waterborne coating composition, by applying the coating composition to a surface of a substrate, and exposing the composition and the surface to an electromagnetic energy |
CN102455117A (en) * | 2010-10-22 | 2012-05-16 | 机械科学研究总院先进制造技术研究中心 | Novel tunnel-type microwave dying method and device applied in textile dyeing and finishing industry |
WO2014047300A1 (en) * | 2012-09-21 | 2014-03-27 | Eagle Ottawa, Llc | Finish curing method and system for leather-based substrates |
EP2906739B1 (en) * | 2012-10-09 | 2016-11-30 | Europlasma nv | Apparatus and method for applying surface coatings |
ITVI20120338A1 (en) * | 2012-12-19 | 2014-06-20 | Cartigliano Off Spa | METHOD AND EQUIPMENT FOR SKIN DRYING DURING THE FINISHING PROCESS |
IT201900002463A1 (en) * | 2019-02-20 | 2020-08-20 | Officine Di Cartigliano S P A | COMBINED MACHINE FOR THE HEAT TREATMENT OF DRYING OF DIELECTRIC PRODUCTS |
-
2018
- 2018-11-30 PT PT188272405T patent/PT3717669T/en unknown
- 2018-11-30 CN CN201880077177.8A patent/CN111417733B/en active Active
- 2018-11-30 WO PCT/IB2018/059494 patent/WO2019106615A1/en unknown
- 2018-11-30 KR KR1020207016743A patent/KR102667839B1/en active IP Right Grant
- 2018-11-30 PL PL18827240T patent/PL3717669T3/en unknown
- 2018-11-30 ES ES18827240T patent/ES2890998T3/en active Active
- 2018-11-30 EP EP18827240.5A patent/EP3717669B1/en active Active
- 2018-11-30 RS RS20211163A patent/RS62369B1/en unknown
Also Published As
Publication number | Publication date |
---|---|
PL3717669T3 (en) | 2022-01-10 |
CN111417733B (en) | 2022-03-04 |
ES2890998T3 (en) | 2022-01-25 |
EP3717669B1 (en) | 2021-06-30 |
PT3717669T (en) | 2021-09-23 |
KR102667839B1 (en) | 2024-05-21 |
KR20200094158A (en) | 2020-08-06 |
CN111417733A (en) | 2020-07-14 |
WO2019106615A1 (en) | 2019-06-06 |
RS62369B1 (en) | 2021-10-29 |
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