EP3670738A1 - Matériau textile de protection contre la chaleur, les incendies et / ou la fumée - Google Patents

Matériau textile de protection contre la chaleur, les incendies et / ou la fumée Download PDF

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Publication number
EP3670738A1
EP3670738A1 EP18215385.8A EP18215385A EP3670738A1 EP 3670738 A1 EP3670738 A1 EP 3670738A1 EP 18215385 A EP18215385 A EP 18215385A EP 3670738 A1 EP3670738 A1 EP 3670738A1
Authority
EP
European Patent Office
Prior art keywords
textile
fire
heat
dispersion
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP18215385.8A
Other languages
German (de)
English (en)
Inventor
Claude Hosotte
Markus LÄPPLE
Barbara Niederberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nolax AG
Original Assignee
Nolax AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nolax AG filed Critical Nolax AG
Priority to EP18215385.8A priority Critical patent/EP3670738A1/fr
Priority to CN201980076160.5A priority patent/CN113167015A/zh
Priority to PCT/EP2019/083278 priority patent/WO2020126433A1/fr
Priority to EP19809112.6A priority patent/EP3899131A1/fr
Priority to US17/416,131 priority patent/US20220042237A1/en
Publication of EP3670738A1 publication Critical patent/EP3670738A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00Condition, form or state of the materials
    • D06N2205/02Dispersion
    • D06N2205/023Emulsion, aqueous dispersion, latex
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/06Properties of the materials having thermal properties
    • D06N2209/067Flame resistant, fire resistant
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/06Building materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/26Vehicles, transportation
    • D06N2211/263Cars

Definitions

  • EP 1 429 104 discloses a thermal camouflage tarpaulin for covering heat sources against detection of thermal imaging cameras.
  • the aluminum powder is contained in a coating based on silicone elastomer and / or polyurethane.
  • the carrier textile includes glass filament.
  • the thermal camouflage can only be exposed to high temperatures of over 1000 ° C for periods of a few minutes and is therefore not powerful enough for use in the high temperature range.
  • the textile, flat substrate can be a fabric, scrim or fleece.
  • the fabric, scrim or fleece can be fibers, in particular glass fibers or include mineral fibers.
  • Polyaramide fibers for example Kevlar, or oxidized, thermally stabilized polyacrylonitrile (PAN) fibers, for example Panox®, are also conceivable.
  • the metal pigments can be in the form of flakes or flakes and / or have a maximum diameter in the area of 1 to 100 ⁇ m, preferably 5 to 45 ⁇ m, which can be determined by sieve analysis.
  • the metal pigments of the non-leafing type which are distributed uniformly in the film matrix are preferably used.
  • the metal pigments are preferably used in the form of a VOC-free paste for aqueous systems.
  • the dispersion or emulsion can contain organic solvents. However, the solvent content should not exceed 6% by weight. A low solvent content helps to protect the environment on the one hand and increases occupational safety on the other.
  • the dispersion or emulsion preferably has a pH between 6 and 10 at the time of application.
  • the solids content of the dispersion or emulsion is preferably above 50 percent by weight and particularly preferably between 60 and 80 percent by weight.
  • the viscosity values were determined using the Brookfield method with a Brookfield DVI +. The measurements for the viscosities from 500 to 40,000 mPa ⁇ s were carried out at 23 ° C with a spindle 4 at 20 rpm.
  • An isoGLAS filament fabric (GIVIDI) with a weight of 420 g / m 2 and a thickness of 0.5 mm was used as the textile, flat substrate.
  • Table 1 lists the raw materials for two exemplary aqueous coatings.
  • the isoGLAS filament fabric (approx. 60 x 30 cm) was coated on one side with the respective aqueous formulation for PK1 or PK2 (approx. 80 g / m 2 , dry). The sample was then dried in an oven at 50 ° C. for 20 minutes and activated at 230 ° C. for 20 minutes. The sample sizes required for the test methods (to be taken from the method specification in each case) were cut. Storage of samples for one day.
  • an isoGLAS filament fabric (GIVIDI) with a weight of 420 g / m 2 and a thickness of 0.5 mm (approx. 60 x 30 cm) was provided.
  • an aqueous formulation consisting of 35% by weight heat-sealable adhesive based on aqueous ethylene-acrylic acid copolymer dispersion (nolax S35.3110), 52% by weight aqueous Me / Ph-Si resin emulsion (50% solids content, Silres MPF 52 M from Wacker Silicone), 13% by weight calcined kaolin (Kamin 70), 0.02% by weight defoamer (Agitan 701, Münzing) and 0.5% by weight dispersant.
  • aqueous formulation consisting of 35% by weight heat-sealable adhesive based on aqueous ethylene-acrylic acid copolymer dispersion (nolax S35.3110), 52% by weight aqueous Me / Ph-Si
  • the aqueous formulation was applied to the matt side of an aluminum foil with a thickness of 25 ⁇ m (approx. 70 g / m 2 ).
  • the isoGLAS filament fabric (a piece of approx. 20x30cm) was placed lengthways (with the back downwards) directly into the still wet film and pressed on evenly.
  • the swatch was oven dried at 50 ° C for 20 minutes and activated at 230 ° C for 20 minutes. The sample sizes required for the test methods were cut. Storage of samples for one day.
  • test specimens were placed on a stainless wire mesh made of tungsten.
  • An infrared source was arranged below the test specimen at a distance of 20 mm from the grate.
  • a Krelus quartz heater with a nominal power of 2KW was used as the infrared heater.
  • the firing test was carried out using a BBW kiln from Wazau, Berlin.
  • the test specimens (including comparison samples) were cut to a size of 56 cm x 16 cm and fixed on a support.
  • the Bunsen burner was lit and left to burn for at least 2 minutes before the start of the test.
  • the burner was then aimed at the specimen at a distance of 2 cm from the test specimen.
  • the test specimen was flamed horizontally for 5 seconds (ignition test) and horizontally for 15 seconds (flammability test).

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
EP18215385.8A 2018-12-21 2018-12-21 Matériau textile de protection contre la chaleur, les incendies et / ou la fumée Withdrawn EP3670738A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP18215385.8A EP3670738A1 (fr) 2018-12-21 2018-12-21 Matériau textile de protection contre la chaleur, les incendies et / ou la fumée
CN201980076160.5A CN113167015A (zh) 2018-12-21 2019-12-02 织物热、火和/或烟防护材料
PCT/EP2019/083278 WO2020126433A1 (fr) 2018-12-21 2019-12-02 Matériau textile de protection contre la chaleur, l'incendie et ou la fumée
EP19809112.6A EP3899131A1 (fr) 2018-12-21 2019-12-02 Matériau textile de protection contre la chaleur, l'incendie et ou la fumée
US17/416,131 US20220042237A1 (en) 2018-12-21 2019-12-02 Textile heat-, fire- and/or smoke-proof material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP18215385.8A EP3670738A1 (fr) 2018-12-21 2018-12-21 Matériau textile de protection contre la chaleur, les incendies et / ou la fumée

Publications (1)

Publication Number Publication Date
EP3670738A1 true EP3670738A1 (fr) 2020-06-24

Family

ID=64901372

Family Applications (2)

Application Number Title Priority Date Filing Date
EP18215385.8A Withdrawn EP3670738A1 (fr) 2018-12-21 2018-12-21 Matériau textile de protection contre la chaleur, les incendies et / ou la fumée
EP19809112.6A Pending EP3899131A1 (fr) 2018-12-21 2019-12-02 Matériau textile de protection contre la chaleur, l'incendie et ou la fumée

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP19809112.6A Pending EP3899131A1 (fr) 2018-12-21 2019-12-02 Matériau textile de protection contre la chaleur, l'incendie et ou la fumée

Country Status (4)

Country Link
US (1) US20220042237A1 (fr)
EP (2) EP3670738A1 (fr)
CN (1) CN113167015A (fr)
WO (1) WO2020126433A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4201665A1 (fr) * 2021-12-21 2023-06-28 Nolax AG Matière composite en tant que matière de protection contre la chaleur, le feu et/ou la fumée

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114392500A (zh) * 2021-12-22 2022-04-26 南通大学 一种快速展开的避火罩

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4994317A (en) * 1988-12-21 1991-02-19 Springs Industries, Inc. Flame durable fire barrier fabric
DE69400857T2 (de) * 1993-08-26 1997-03-06 Wacker Chemie Gmbh Beschichtetes Gewebe für Airbags
DE29716362U1 (de) * 1996-09-14 1998-01-08 C.F. Ploucquet GmbH & Co, 89522 Heidenheim Wärmetarnplane
EP1429104A1 (fr) 2002-12-12 2004-06-16 Texplorer GmbH Revêtement pour camoufler la chaleur
US6872440B1 (en) 1999-11-30 2005-03-29 Elk Premium Building Products, Inc. Heat reflective coated structural article
EP1522534A2 (fr) 2003-10-06 2005-04-13 General Electric Company Revêtement en aluminate pour un substrat contenant du silicium
US7147671B2 (en) * 2003-06-02 2006-12-12 General Electric Company Silicone based flame retardant systems for textiles
DE102006048912A1 (de) 2006-10-17 2008-04-24 Zipper-Technik Gmbh Verfahren zur Herstellung eines Wärmeschutzes
US20100258371A1 (en) 2008-07-01 2010-10-14 Desai Umesh C Waterborne film-forming compositions having heat reflective properties

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5952445A (en) * 1998-04-09 1999-09-14 Bayer Corporation Water dispersible compounds containing alkoxysilane groups
US20040028826A1 (en) * 2002-07-01 2004-02-12 Stefanie Goecke Process for coating to obtain special surface effects

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4994317A (en) * 1988-12-21 1991-02-19 Springs Industries, Inc. Flame durable fire barrier fabric
DE69400857T2 (de) * 1993-08-26 1997-03-06 Wacker Chemie Gmbh Beschichtetes Gewebe für Airbags
DE29716362U1 (de) * 1996-09-14 1998-01-08 C.F. Ploucquet GmbH & Co, 89522 Heidenheim Wärmetarnplane
US6872440B1 (en) 1999-11-30 2005-03-29 Elk Premium Building Products, Inc. Heat reflective coated structural article
EP1429104A1 (fr) 2002-12-12 2004-06-16 Texplorer GmbH Revêtement pour camoufler la chaleur
US7147671B2 (en) * 2003-06-02 2006-12-12 General Electric Company Silicone based flame retardant systems for textiles
EP1522534A2 (fr) 2003-10-06 2005-04-13 General Electric Company Revêtement en aluminate pour un substrat contenant du silicium
DE102006048912A1 (de) 2006-10-17 2008-04-24 Zipper-Technik Gmbh Verfahren zur Herstellung eines Wärmeschutzes
US20100258371A1 (en) 2008-07-01 2010-10-14 Desai Umesh C Waterborne film-forming compositions having heat reflective properties

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4201665A1 (fr) * 2021-12-21 2023-06-28 Nolax AG Matière composite en tant que matière de protection contre la chaleur, le feu et/ou la fumée
WO2023117297A1 (fr) * 2021-12-21 2023-06-29 Nolax Ag Matériau composite utilisé en tant que matériau de protection thermique, ignifuge et/ou de régulation de fumée

Also Published As

Publication number Publication date
US20220042237A1 (en) 2022-02-10
WO2020126433A1 (fr) 2020-06-25
CN113167015A (zh) 2021-07-23
EP3899131A1 (fr) 2021-10-27

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