EP3030620A1 - Composition formant une couche isolante et son utilisation - Google Patents

Composition formant une couche isolante et son utilisation

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Publication number
EP3030620A1
EP3030620A1 EP14744850.0A EP14744850A EP3030620A1 EP 3030620 A1 EP3030620 A1 EP 3030620A1 EP 14744850 A EP14744850 A EP 14744850A EP 3030620 A1 EP3030620 A1 EP 3030620A1
Authority
EP
European Patent Office
Prior art keywords
carbon
composition according
composition
bonded
polyorganosiloxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14744850.0A
Other languages
German (de)
English (en)
Inventor
Juliane Marauska
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hilti AG
Original Assignee
Hilti AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hilti AG filed Critical Hilti AG
Priority to EP14744850.0A priority Critical patent/EP3030620A1/fr
Publication of EP3030620A1 publication Critical patent/EP3030620A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C09D5/185—Intumescent paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds

Definitions

  • the present invention relates to an intumescent composition, in particular a composition with intumescent properties, which contains a binder based on addition-crosslinking polyorganosiloxanes, and their use for fire protection, in particular for coatings of components, such as supports, beams or truss rods, to increase the fire resistance time.
  • Intumescent compositions also called intumescent compositions, are commonly applied to the surface of components to form coatings to protect them from fire or high heat exposure due to, for example, fire.
  • Steel structures are now an integral part of modern architecture, even if they have a major disadvantage compared to reinforced concrete construction. Above about 500 ° C, the load bearing capacity of the steel decreases by 50%, ie the steel loses a large part of its stability and its load capacity. This temperature can be reached after about 5-10 minutes, depending on the fire load, such as direct fire (about 1000 ° C), which often leads to a loss of capacity of the construction.
  • the aim of fire protection is to delay the period of time until the loss of bearing capacity of a steel structure in case of fire to save human lives and valuable goods as long as possible.
  • F-classes such as F 30, F 60, F 90 (fire resistance classes according to DIN 4102-2) or American classes according to ASTM etc.
  • F 30 means that a load-bearing steel construction must withstand fire for at least 30 minutes in the event of a fire under standard conditions. This is usually achieved by delaying the heating rate of the steel, e.g. B. by coating the steel structure with intumescent coatings.
  • paints whose components foam in the event of fire to form a solid microporous carbon foam.
  • Essential for the achievable fire resistance is always the applied layer thickness of the coating, or the resulting ash crust.
  • Closed profiles, such as pipes require about twice the amount of comparable bulk, compared to open profiles, such as beams with a double T-profile.
  • the coatings In order to meet the required fire resistance times, the coatings must have a certain thickness and the ability to form a voluminous and thus well insulating ash crust when exposed to heat, which remains mechanically stable over the period of fire stress.
  • binders usually resins
  • solvent-based or water-based systems binders, usually resins, are applied to the component as a solution, dispersion or emulsion. These can be implemented as single or multi-component systems. After application, the solvent or water evaporates leaving a film that dries over time. It can also be distinguished between such systems in which the coating substantially does not change during drying, and those systems in which after evaporation of the binder primarily by oxidation and Polymerization reactions cures, which is induced for example by the atmospheric oxygen.
  • the 100% systems contain the components of the binder without solvent or water. They are applied to the component, wherein the "drying" of the coating takes place only by reaction of the binder components with each other.
  • the solvent or water-based systems have the disadvantage that the drying times, also called hardening times, are long and, in addition, several layers have to be applied, that is, require several operations in order to achieve the required layer thickness. Since every single layer must be dried accordingly before the application of the next layer, this leads to a high amount of work time and correspondingly high costs and a delay in the completion of the structure, since depending on climatic conditions sometimes several days pass until the required layer thickness is applied.
  • Another disadvantage is that due to the required layer thickness, the coating may tend to crack and flake during drying or exposure to heat, whereby in the worst case the substrate is partially exposed, especially in systems where the binder does not evaporate after evaporation of the solvent or of the water.
  • the invention is therefore an object of the invention to provide an intumescent composition for coating systems of the type mentioned above, which avoids the disadvantages mentioned, which is in particular not solvent or water-based and has a fast curing, due to appropriately tuned viscosity is easy to apply and due to the achievable good Intumeszenzrate, ie the formation of an effective ash crust layer, requires only a small layer thickness.
  • the invention accordingly provides an intumescent composition
  • an intumescent composition comprising (A) an addition-crosslinking polyorganosiloxane which has Si-bonded radicals with aliphatic carbon-carbon multiple bonds, (B) a polyorganosiloxane with Si-bonded hydrogen atoms, (C) a catalyst which is described in US Pat Capable of supporting the reaction between the Si-bonded aliphatic carbon-carbon multiple bond and the Si-bonded hydrogen atoms, and (D) an intumescent additive.
  • coatings having the required layer thickness for the respective fire resistance duration can be applied in a simple and fast manner.
  • the advantages achieved by the invention are that the slow cure times inherent in the solvent or water based systems could be significantly reduced, significantly reducing labor time. Due to the low viscosity of the composition in the application range, adjusted via suitable thickener systems or solvents, in contrast to epoxy-amine systems, application without heating of the composition is possible, as for example by the widespread airless spray process.
  • composition of the invention With the composition of the invention, a high degree of filling with fire protection additives can be achieved by the composition as two- or Multi-component system is assembled. Accordingly, the cost of materials decreases, which has a favorable effect on material costs, especially in the case of large-area application. This is achieved in particular by the use of a reactive system that does not dry physically and thus suffers no loss of volume by the drying of solvents or water-based systems of water, but hardens by polyaddition. Thus, in a classical system, a solvent content of about 25% is typical. In the composition according to the invention more than 95% of the coating remain on the substrate to be protected. Furthermore, the relative ashes crust stability is very high due to the advantageous structure of the foam formed in the event of fire.
  • compositions of the invention show excellent cohesion and impact resistance.
  • aliphatic compound comprises acyclic and cyclic, saturated or unsaturated hydrocarbon compounds which are not aromatic (PAC,
  • carbon is an organic compound which, due to incomplete combustion, is a carbon skeleton leaves behind and does not burn completely to carbon dioxide and water (carbonification), these compounds are also referred to as "carbon skeleton formers";
  • is an "acid generator” is a compound which forms under heat, ie above about 150 ° C, for example, by decomposition of a non-volatile acid and thereby acts as a catalyst for the carbonification; in addition, it can contribute to lowering the viscosity of the melt of the binder; equivalently, the term “dehydrogenation catalyst” is used; is a “blowing agent” is a compound which decomposes at elevated temperature to develop inert, ie non-combustible gases
  • the principal mode of action is that the carbon layers, which in themselves are very soft, are mechanically hardened by inorganic compounds; the addition of such an ash crust stabilizer contributes to a substantial stabilization of the intumescent crust in case of fire, since these additives increase the mechanical strength of the intumescent layer and / or prevent their dripping, whereby the insulating effect of the foam is maintained or enhanced.
  • polyorganosiloxanes As addition-crosslinking polyorganosiloxanes, it is advantageous to use those which cure by means of a transition-metal-catalyzed addition reaction, also called hydrosilylation, with polyorganosiloxane crosslinkers which contain SiH groups.
  • component (A) therefore polyorganosiloxanes are used which have Si-bonded radicals with aliphatic carbon-carbon multiple bonds.
  • the carbon-carbon multiple bond may be a carbon-carbon triple bond or carbon-carbon double bond, of which a carbon-carbon double bond is preferable.
  • the content of carbon-carbon multiple bonds is in the range of 0.01 to 3.0 mmol / g, and more preferably between 0.05 and 2.5 mmol / g.
  • the radicals with aliphatic carbon-carbon multiple bonds are terminating at the polysiloxane chains, so that the polyorganosiloxanes (A) have at least two radicals with aliphatic carbon-carbon multiple bonds.
  • the polyorganosiloxanes preferably have additional radicals having aliphatic carbon-carbon multiple bonds as side groups along the polysiloxane chain, so that the polyorganosiloxanes (A) preferably have at least three radicals with aliphatic carbon-carbon multiple bonds.
  • constituent (B) the polyorganosiloxane crosslinkers which are expediently polyatomosiloxanes with Si-bonded water atoms.
  • polyorganosiloxane crosslinker having a functionality greater than 2, in particular three or greater, is used, a polyorganosiloxane having only two radicals which have aliphatic carbon-carbon multiple bonds can also be used, and vice versa.
  • the polyorganosiloxanes having Si-bonded radicals having aliphatic carbon-carbon multiple bonds have the structure (I)
  • each R a independently represents an alkyl group, each R independently represents an alkenyl or alkynyl group, and n is selected such that the viscosity of the compound is about 30 to 200,000 mPa ⁇ s, preferably 40 to 100,000 mPa ⁇ s, and more preferably 100 to 10,000 mPa-s at 25 ° C, or structure (II)
  • each R a and R is as defined for structure (I), and n and m are selected such that the content of carbon-carbon multiple bonds, especially carbon-carbon double bonds, ranges from 0.01 to 3.0 mmol / g and the viscosity of the compound is about 100 to 4,000 mPa ⁇ s, preferably 120 to 3,000 mPa ⁇ s and even more preferably 200 to 1,500 mPa ⁇ s at 25 ° C.
  • the alkyl group is preferably a C 1 -C 8 -alkyl group, more preferably a C 1 -C 8 -alkyl group, and even more preferably a methyl or ethyl group, with a methyl group being most preferred.
  • the alkenyl group is preferably a C 2 -C 8 alkenyl group, more preferably a C 2 -C 4 alkenyl group, even more preferably a vinyl, allyl or hexenyl group, and most preferably a vinyl group.
  • the alkynyl group is preferably a C 2 -C 8 alkynyl group, more preferably a C 2 -C 4 alkynyl group such as ethyne, 1-propyne and 1-butyne.
  • the polyorganosiloxane crosslinker according to the invention is a polyorganosiloxane with Si-bonded hydrogen atoms.
  • the hydrogen atoms are essentially terminating.
  • additional Si-bonded hydrogens are included in the polysiloxane chain.
  • the content of Si-bonded hydrogen atoms is in the range of 1.0 to 10.0 mmol / g, and more preferably 2.0 to 8.0 mmol / g.
  • the polyorganosiloxanes having Si-bonded hydrogen atoms preferably have the structure (III)
  • R a is as defined above for the structures (I) and (II) and n and m are selected such that the content of Si-bonded hydrogen atoms in the range of 1, 0 to 10.0 mmol / g and the viscosity the compound is about 30 to 600 mPa ⁇ s, preferably 40 to 500 mPa ⁇ s and even more preferably 45 to 100 mPa ⁇ s at 25 ° C. It is also possible to use mixtures of polyorganosiloxanes of structure (III) and polyorganosiloxanes of structure (IV) as crosslinkers.
  • the catalyst is suitably a compound capable of promoting the reaction between the aliphatic carbon-carbon multiple bond and the SiH bond of the crosslinker.
  • Suitable catalysts include metal-based platinum group metal catalysts such as rhodium, ruthenium, palladium, osmium, iridium, or platinum-containing catalysts. Platinum-based catalysts are particularly preferred. They may be in any of the known forms, for example, platinum (O), such as activated carbon-deposited platinum, platinum chloride, platinum salts, chloroplatinic acid (s), and encapsulated forms thereof.
  • platinum such as activated carbon-deposited platinum, platinum chloride, platinum salts, chloroplatinic acid (s), and encapsulated forms thereof.
  • the catalyst is preferably built up from dilute solutions of highly reactive platinum complexes.
  • the complexes are dissolved in the vinyl-functional polydimethylsiloxanes or in divinyltetramethyldisiloxane (DE 1262271 B) or in methylvinylcyclosiloxane.
  • the catalyst is composed of divinyltetramethyldisiloxane platinum (0) complex or methylvinylcyclosiloxane-platinum (0) complex, such as the binuclear reaction product of 1, 1, 3,3-tetramethyl-1,3-divinyldisiloxane with
  • Hexachloridoplatinic acid in isopropanol (“Karstedt catalyst") is exemplified
  • the vinyl content of the solutions is 0.10 to 12.0 mmol / g, the platinum content is 500 to 20,000 ppm.
  • catalysts include the divinyltetramethyldisiloxane platinum (O) complex and the methylvinylcyclosiloxane platinum (0) complex, either dissolved in divinyltetramethyldisiloxane or methylvinylcyclosiloxane.
  • constituent (D) contains an intumescent additive, which additive may comprise both individual compounds and a mixture of several compounds.
  • intumescent additives such that form an inflating, insulating layer of flame-retardant material under the action of heat.
  • This layer protects the substrate from overheating and at least prevents or delays the change of the mechanical and static properties of structural components by heat.
  • a voluminous, insulating layer namely an ash layer
  • the voluminous insulating layer may be formed by puffing a single compound which, without a chemical reaction between two compounds, releases gases upon exposure to heat.
  • an intumescent layer by chemical intumescence generally requires at least three components, a carbon source, a dehydrogenation catalyst, and a propellant, which are included in a binder, for example, in coatings.
  • a carbon source for example, in coatings.
  • the binder softens and the fire protection additives are released so that they can react with each other in the case of chemical intumescence or inflate in the case of physical intumescence.
  • Thermal decomposition from the dehydrogenation catalyst forms the acid which serves as a catalyst for the carbonification of the carbon source.
  • the blowing agent thermally decomposes to form inert gases, causing the carbonized (charred) material and, optionally, the softened binder to expand, to form a voluminous, insulating foam.
  • the intumescent additive comprises at least one carbon back forming agent, if the binder can not be used as such, at least one acid generator, at least one propellant, and at least one inorganic scaffold.
  • the components of the additive are selected so that they can develop synergism, with some of the compounds capable of performing several functions.
  • Suitable carbon sources are the compounds commonly used in intumescent fire-retardant formulations and known to the person skilled in the art, such as starch-like compounds, for example starch and modified starch, and / or polyhydric alcohols (polyols), such as saccharides, oligosaccharides and polysaccharides, and / or a thermoplastic or thermosetting material polymeric resin binder such as a phenol resin, a urea resin, a polyurethane, polyvinyl chloride, poly (meth) acrylate, polyvinyl acetate, polyvinyl alcohol, a silicone resin and / or a rubber.
  • starch-like compounds for example starch and modified starch
  • polyhydric alcohols polyols
  • polyols such as saccharides, oligosaccharides and polysaccharides
  • thermoplastic or thermosetting material polymeric resin binder such as a phenol resin, a urea resin, a polyurethane, polyvin
  • Suitable polyols are polyols from the group consisting of sugar, pentaerythritol, dipentaerythritol, tripentaerythritol, polyvinyl acetate, polyvinyl alcohol, sorbitol, polyoxyethylene / polyoxypropylene (EO-PO) polyols. Preference is given to using pentaerythritol, dipentaerythritol or polyvinyl acetate. It should be noted that the binder itself may also have the function of a carbon supplier in case of fire.
  • Suitable dehydrogenation catalysts or acid formers are the compounds conventionally used in intumescent fire-retardant formulations and known to those skilled in the art, such as a salt or an ester of an inorganic, non-volatile acid selected from sulfuric acid, phosphoric acid or boric acid.
  • phosphorus-containing compounds are used whose range is very large, as they extend over several oxidation states of the phosphorus, such as phosphines, phosphine oxides, phosphonium compounds, phosphates, elemental red phosphorus, phosphites and phosphates.
  • the phosphoric acid compounds there can be exemplified monoammonium phosphate, diammonium phosphate, ammonium phosphate, ammonium polyphosphate, melamine phosphate, melamine resin phosphate, potassium phosphate, polyol phosphates such as pentaerythritol phosphate, glycerin phosphate, sorbitol phosphate, mannitol phosphate, dulcite phosphate, neopentyl glycol phosphate, ethylene glycol phosphate, dipentaerythritol phosphate and the like.
  • the phosphoric acid compound used is preferably a polyphosphate or an ammonium polyphosphate.
  • Melamine resin phosphates are compounds such as reaction products of Lamelite C (melamine-formaldehyde resin) with phosphoric acid.
  • sulfuric acid compounds there may be exemplified ammonium sulfate, ammonium sulfamate, nitroaniline bisulfate, 4-nitroaniline-2-sulfonic acid and 4,4-dinitrosulfanilamide, and the like.
  • boric acid compound melamine borate can be exemplified.
  • Suitable blowing agents are the compounds customarily used in fire protection formulations and known to the person skilled in the art, such as cyanuric acid or isocyanic acid and its derivatives, melamine and derivatives thereof.
  • the intumescent additive further comprises at least one thermally expandable compound, such as a graphite intercalation compound, also known as expanded graphite. These can also be incorporated into the binder.
  • expandable graphite for example, known insertion compounds of SO x , NO x , halogen and / or acids in graphite come into question. These are also referred to as graphite salts. Preference is given to expandable graphites which release S0 2 , S0 3 , NO and / or N0 2 at temperatures of, for example, 120 to 350 ° C. while being swelled.
  • the expandable graphite may for example be in the form of platelets with a maximum diameter in the range of 0, 1 to 5 mm. Preferably, this diameter is in the range 0.5 to 3 mm.
  • Expandable graphites suitable for the present invention are commercially available. In general, the expandable graphite particles are evenly distributed in the composition according to the invention.
  • the concentration of expandable graphite particles can also be varied selectively, pattern-like, areally and / or sandwich-like.
  • EP 1489136 A1 the contents of which are hereby incorporated by reference. Since the ash crust formed in the event of fire is in some cases too unstable and can therefore be blown by air currents, depending on their density and structure, which has a negative effect on the insulating effect of the coating, at least one ash crust stabilizer can be added to the components just mentioned.
  • the particulate metal may be in the form of a powder, platelets, flakes, fibers, filaments and / or whiskers, wherein the particulate metal in the form of powder, platelets or flakes has a particle size of ⁇ 50 pm, preferably from 0.5 to 10 pm has.
  • a thickness of 0.5 to 10 ⁇ m and a length of 10 to 50 ⁇ m is preferred.
  • an oxide or a compound of a metal from the group comprising aluminum, magnesium, iron or zinc may be used, in particular iron oxide, preferably iron trioxide, titanium dioxide, a borate, such as zinc borate and / or a glass frit of low-melting glasses a melting temperature of preferably at or above 400 ° C, phosphate or sulfate glasses, Melaminpolyzinksulfaten, Ferrogläsern or Calziumborosilikaten.
  • iron oxide preferably iron trioxide, titanium dioxide, a borate, such as zinc borate and / or a glass frit of low-melting glasses a melting temperature of preferably at or above 400 ° C, phosphate or sulfate glasses, Melaminpolyzinksulfaten, Ferrogläsern or Calziumborosilikaten.
  • one or more reactive flame retardants may be added to the composition of the invention.
  • Such compounds are incorporated in the binder.
  • An example according to the invention are reactive organophosphorus compounds, such as 9,10-dihydro-9-oxa-10-phosphaphenanthren-10-oxide (DOPO) and its derivatives, such as DOPO-HQ, DOPO-NQ, and adducts.
  • DOPO 9,10-dihydro-9-oxa-10-phosphaphenanthren-10-oxide
  • DOPO-HQ DOPO-HQ
  • DOPO-NQ DOPO-NQ
  • the intaglio-forming additive may be contained in an amount of from 30 to 99% by weight in the composition, the amount depending substantially on the application form of the composition (spraying, brushing and the like).
  • the proportion of constituent D in the overall formulation is set as high as possible.
  • the proportion of constituent D in the overall formulation is preferably from 35 to 85% by weight and more preferably from 40 to 85% by weight.
  • the composition may optionally contain, in addition to the intumescent additives, organic and / or inorganic additives and / or other additives.
  • additives and additives are customary auxiliaries, such as solvents, for example xylene or toluene, wetting agents, for example based on polyacrylates and / or polyphosphates, defoamers, such as silicone defoamers, thickeners, such as alginate thickeners, dyes, fungicides, plasticizers, such as chlorine-containing waxes, binders, Flame retardants or various fillers such as vermiculite, inorganic fibers, quartz sand, glass microspheres, mica, silica, mineral wool, and the like.
  • rheology additives such as anti-settling agents, anti-sagging agents and thixotropic agents, polyhydroxycarboxamides, urea derivatives, salts of unsaturated carboxylic acid esters, alkylammonium salts of acidic phosphoric acid derivatives, ketoximes, amine salts of p-toluenesulfonic acid, amine salts of sulfonic acid derivatives and aqueous or organic solutions or mixtures of the compounds are preferably used.
  • rheology additives based on pyrogenic or precipitated silicas or based on silanized pyrogenic or precipitated silicas can be used.
  • the rheology additive is preferably pyrogenic silicas, modified and unmodified phyllosilicates, precipitated silicas, cellulose ethers, polysaccharides, PU and acrylate thickeners, urea derivatives, castor oil derivatives, polyamides and fatty acid amides and polyolefins, if they are in solid form, pulverized celluloses and / or Suspending agents such as xanthan gum.
  • the composition of the invention can be formulated as a two- or multi-component system.
  • the catalyst may either be stored separately from components (A) and (B) or may be contained in one of these components or divided into both components. This ensures that the two components (A) and (B) of the binder are mixed together just prior to use and trigger the curing reaction. This makes the system easier to handle.
  • the component (D) can be contained as a total mixture or divided into individual components in a first component I and / or a second component II.
  • the division of the component (D) is dependent on the compatibility of the compounds contained in the composition, so that neither a reaction of the compounds contained in the composition with each other or a mutual interference nor a reaction of these compounds can be carried out with the compounds of the other ingredients. This depends on the connections used. This ensures that the highest possible proportion of fillers can be achieved. This leads to high intumescence, even with low layer thicknesses of the composition.
  • the component (D) which optionally comprises at least one carbon source, at least one blowing agent and at least one dehydrogenation catalyst, is divided among the components in such a way that these compounds are reaction-inhibitingly separate from one another.
  • ingredient D further includes an ash crust stabilizer, which is divided among the components such that each component contains at least a portion of the ash crust stabilizer.
  • the composition is applied as a paste with a brush, a roller or by spraying onto the substrate, in particular metallic substrate.
  • the composition is applied by means of an airless spray process.
  • the composition of the invention is characterized by a relatively rapid cure by an addition reaction, more specifically a catalyst assisted hydrosilylation reaction and thus unnecessary drying, as compared to the solvent and water based systems. This is particularly important when the coated components have to be loaded or further processed quickly, either by coating with a cover layer or by moving or transporting the components.
  • the coating is thus much less susceptible to external influences on the site, such as exposure to (rain) -water or dust and dirt, which can lead to leaching of water-soluble components such as ammonium polyphosphate in solvent or water-based systems, or when absorbing dust to a reduced intumescence. Due to the low viscosity of the composition despite the high solids content, the composition remains easy to process, especially by common spray methods.
  • the composition according to the invention is therefore suitable as a coating, in particular as a fire protection coating, preferably a sprayable coating for substrates on a metallic and non-metallic basis.
  • the substrates are not limited and include components, in particular steel components and wooden components, but also individual cables, cable bundles, cable trays and cable ducts or other lines.
  • the composition according to the invention is mainly used in the construction sector as a coating, in particular fire protection coating for steel construction elements, but also for construction elements made of other materials, such as concrete or wood, as well as fire protection coating for individual cables, cable bundles, cable trays and cable ducts or other lines.
  • composition according to the invention is therefore the use of the composition according to the invention as a coating, in particular as a coating for Structural elements or components made of steel, concrete, wood and other materials, such as plastics, in particular as fire protection coating.
  • the present invention also relates to objects obtained when the composition of the invention has cured.
  • the objects have excellent intumescent properties.
  • intumescent compositions For the preparation of intumescent compositions according to the invention, the individual components are mixed and homogenized as described below with the aid of a dissolver
  • the curing behavior was observed, then the intumescent factor and the relative ash crustal stability were determined.
  • the masses were each placed in a round Teflon mold with about 2 mm deep and 48 mm diameter.
  • the time for the curing corresponds to the time after which the samples were cured and the Teflon mold could be removed.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne une composition formant une couche isolante, qui contient un liant à base de polyorganosiloxanes réticulant par addition. Grâce à la composition selon l'invention, dont le taux d'expansion est relativement élevé, on peut appliquer, de manière simple et rapide, des revêtements présentant l'épaisseur de couche nécessaire pour la durée de résistance au feu en question, l'épaisseur de couche pouvant être réduite à un minimum et un effet isolant élevé pouvant néanmoins être obtenu. La composition selon l'invention convient en particulier pour la protection contre le feu, en particulier comme revêtement de substrats métalliques et non métalliques, par exemple des pièces en acier, telles que des montants, des supports, des barres de treillis, en vue d'augmenter la durée de la résistance au feu.
EP14744850.0A 2013-08-06 2014-07-30 Composition formant une couche isolante et son utilisation Withdrawn EP3030620A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP14744850.0A EP3030620A1 (fr) 2013-08-06 2014-07-30 Composition formant une couche isolante et son utilisation

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13179404.2A EP2835403A1 (fr) 2013-08-06 2013-08-06 Composition formant une couche isolante et son utilisation
EP14744850.0A EP3030620A1 (fr) 2013-08-06 2014-07-30 Composition formant une couche isolante et son utilisation
PCT/EP2014/066353 WO2015018704A1 (fr) 2013-08-06 2014-07-30 Composition formant une couche isolante et son utilisation

Publications (1)

Publication Number Publication Date
EP3030620A1 true EP3030620A1 (fr) 2016-06-15

Family

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Family Applications (2)

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EP13179404.2A Withdrawn EP2835403A1 (fr) 2013-08-06 2013-08-06 Composition formant une couche isolante et son utilisation
EP14744850.0A Withdrawn EP3030620A1 (fr) 2013-08-06 2014-07-30 Composition formant une couche isolante et son utilisation

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP13179404.2A Withdrawn EP2835403A1 (fr) 2013-08-06 2013-08-06 Composition formant une couche isolante et son utilisation

Country Status (5)

Country Link
US (1) US20160152842A1 (fr)
EP (2) EP2835403A1 (fr)
CA (1) CA2918648A1 (fr)
RU (1) RU2016107930A (fr)
WO (1) WO2015018704A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201505769D0 (en) 2015-04-02 2015-05-20 Advanced Insulation Plc Coating material
GB2554705A (en) * 2016-10-05 2018-04-11 Advanced Insulation Plc Thermal insulating structure
CN112795290A (zh) * 2020-12-26 2021-05-14 广东丰能环保科技股份有限公司 一种耐高隔热面层涂料及其制备方法
CN113136140B (zh) * 2021-04-20 2022-07-05 浙江清优材料科技有限公司 一种有机硅防火隔热涂层及其制备方法

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BE528016A (fr) 1953-05-13 1900-01-01
GB1074243A (en) 1963-08-13 1967-07-05 Monsanto Co Ammonium polyphosphates and compositions containing the same
NL131800C (fr) 1965-05-17
DE2509632B2 (de) 1974-03-06 1980-03-06 Sumitomo Chemical Co., Ltd., Osaka (Japan) Flammabweisende Beschichtungsmassen und ihre Verwendung zum Beschichten von Konstruktionsteilen aus Sperrholz oder Hartfaserplatten
IT1087952B (it) 1977-10-10 1985-06-04 Montedison Spa Vernici antifiamma.
DE2807697A1 (de) 1978-02-23 1979-09-06 Basf Ag Feuerschutzmasse
DE3466011D1 (en) 1983-08-23 1987-10-15 Dixon International Ltd Intumescent material
ZA847870B (en) 1983-10-07 1985-04-03 Dixon International Limited Intumescent composition
US4719251A (en) * 1985-08-19 1988-01-12 Dow Corning Corporation Silicone water base fire barriers
JPS6243435A (ja) * 1985-08-20 1987-02-25 Shin Etsu Chem Co Ltd 耐火性シリコ−ン発泡体組成物
US4719249A (en) * 1986-12-17 1988-01-12 Dietlein John E Intumescent foamable compositions
KR20050039838A (ko) * 2002-08-01 2005-04-29 폴리머스 오스트레일리아 프로프라이어터리 리미티드 내화성 실리콘 폴리머 조성물
CA2420319C (fr) * 2003-02-27 2007-11-27 Csl Silicones Inc. Methode de protection des surfaces contre l'incendie
CA2469534A1 (fr) 2003-06-18 2004-12-18 Hilti Aktiengesellschaft L'utilisation de composes d'insertion a base de graphite thermoextensibles pour la production de joints de protection contre les incendies et methode pour leur production

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See references of WO2015018704A1 *

Also Published As

Publication number Publication date
US20160152842A1 (en) 2016-06-02
WO2015018704A1 (fr) 2015-02-12
CA2918648A1 (fr) 2015-02-12
RU2016107930A (ru) 2017-09-14
EP2835403A1 (fr) 2015-02-11

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