EP3640356B1 - Alliage de magnésium à conductivité thermique élevée, boîtier d'onduleur, onduleur et automobile - Google Patents

Alliage de magnésium à conductivité thermique élevée, boîtier d'onduleur, onduleur et automobile Download PDF

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Publication number
EP3640356B1
EP3640356B1 EP18818152.3A EP18818152A EP3640356B1 EP 3640356 B1 EP3640356 B1 EP 3640356B1 EP 18818152 A EP18818152 A EP 18818152A EP 3640356 B1 EP3640356 B1 EP 3640356B1
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EP
European Patent Office
Prior art keywords
magnesium alloy
thermal conductivity
high thermal
inverter
magnesium
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EP18818152.3A
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German (de)
English (en)
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EP3640356A4 (fr
EP3640356A1 (fr
Inventor
Qiang Guo
Mengmeng Cao
Quanyu GONG
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BYD Co Ltd
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BYD Co Ltd
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C23/00—Alloys based on magnesium
    • C22C23/02—Alloys based on magnesium with aluminium as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C23/00—Alloys based on magnesium
    • C22C23/06—Alloys based on magnesium with a rare earth metal as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C2202/00—Physical properties

Definitions

  • This application relates to the field of materials technologies, and specifically, to a magnesium alloy with high thermal conductivity and application thereof, and more specifically, to a magnesium alloy with high thermal conductivity, an inverter housing of which at least a part is formed by the magnesium alloy with high thermal conductivity, an inverter including the inverter housing, and a vehicle including the inverter.
  • a conventional die casting magnesium alloy on the current market is AZ91D, including main components as follows: Al: 8.5 ⁇ 9.5%, Zn: 0.45 ⁇ 0.90%, Mn: 0.17 ⁇ 0.4%, Si: ⁇ 0.05%, Cu: 0.025%, Ni: ⁇ 0.001%, Fe: ⁇ 0.004%, and magnesium.
  • This material has good fluidity and formability, low costs, and relatively high mechanical properties.
  • the thermal conductivity of this material is relatively low, which is less than 60 W/m ⁇ K, thereby limiting broad application of magnesium alloys.
  • the US patent application US 2017 129006 A1 discloses a Mg alloy composition that has been developed to improve upon the AZ91D alloy to offer better castability, creep strength, ductility and corrosion resistance for use in automotive applications such as housings.
  • an objective of this application is to provide a die casting magnesium alloy having good thermal conductivity or having ideal mechanical properties as well.
  • this application provides a magnesium alloy with high thermal conductivity.
  • the magnesium alloy with high thermal conductivity includes: 2.0-4.0 wt% of Al, 0.1-0.3 wt% of Mn, 1.0-2.0 wt% of La, 2.0-4.0 wt% of Ce, 0.1-1.0 wt% of Nd, 0.5-2.0 wt% of Zn, 0.1-0.5 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the magnesium alloy including the foregoing components has extremely high thermal conductivity and ideal mechanical properties at the same time, and can be effectively applied to conditions and environments that require high thermal conductivity and a light weight, for example, being used to manufacture an inverter housing of a vehicle, thereby greatly expanding the application scope of magnesium alloys.
  • this application provides an inverter housing.
  • at least a part of the inverter housing is formed by the foregoing magnesium alloy with high thermal conductivity.
  • the inverter housing has extremely high thermal conductivity and good heat-dissipation performance, so that the safety and service life of an inverter using the inverter housing are improved significantly.
  • this application provides an inverter.
  • the inverter includes the foregoing inverter housing. It is found that the inverter has good heat-dissipation performance, so that the safety is greatly improved and the service life is significantly increased.
  • this application provides a vehicle.
  • the vehicle includes the foregoing inverter.
  • the vehicle has all the foregoing features and advantages of the inverter, which are not described herein again.
  • this application provides a magnesium alloy with high thermal conductivity.
  • the magnesium alloy with high thermal conductivity includes: 2.0-4.0 wt% of Al, 0.1-0.3 wt% of Mn, 1.0-2.0 wt% of La, 2.0-4.0 wt% of Ce, 0.1-1.0 wt% of Nd, 0.5-2.0 wt% of Zn, 0.1-0.5 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the magnesium alloy including the foregoing components has extremely high thermal conductivity and ideal mechanical performance at the same time, and can be effectively applied to conditions and scenarios that require high thermal conductivity and a light weight, for example, being used to manufacture an inverter housing of a vehicle, thereby greatly expanding the application scope of magnesium alloys.
  • magnesium alloy aluminum can improve the strength and anti-corrosion performance of the magnesium alloy and manganese can improve the elongation and toughness of the magnesium alloy.
  • Adding rare earth elements such as La, Ce and Nd can obviously enhance the high-temperature performance of the magnesium alloy and refine particles of the magnesium alloy during the casting process.
  • magnesium can form a solid solution with the foregoing rare earth elements, a zone rich in magnesium is a simple eutectic zone with a low melting point, and magnesium is distributed in the shape of a net at the grain boundary to prohibit the formation of micro pores, thereby improving the casting performance and thermal conductivity of the magnesium alloy.
  • Nd has relatively large impact on fine-grain strengthening of the magnesium alloy.
  • the refining effect of Ce on micro structures helps to improve the mechanical properties and anti-corrosion performance of the magnesium alloy.
  • Zinc can achieve solution strengthening and form a strengthening phase.
  • Both a small amount of Ca and a small amount of Sr can prevent the magnesium alloy from oxidation during the process of smelting.
  • These components are mixed according to the foregoing proportions to form the magnesium alloy. Due to the synergistic effect of these components, the obtained magnesium alloy has high thermal conductivity and mechanical properties at the same time, and can be effectively applied to multiple fields, especially to scenarios that require relatively high thermal conductivity.
  • the magnesium alloy may include: 0.15-0.3 wt% of Mn and 2.5-4.0 wt% of Ce. In this way, it is ensured that the magnesium alloy has ideal thermal conductivity and high mechanical properties at the same time, to better satisfy usage requirements of different operating environments and conditions.
  • the magnesium alloy may include: 3.0 wt% of Al, 0.25 wt% of Mn, 1.55 wt% of La, 3.0 wt% of Ce, 0.13 wt% of Nd, 0.6 wt% of Zn, 0.15 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the magnesium alloy may include: 2.0 wt% of Al, 0.15 wt% of Mn, 2.0 wt% of La, 2.5 wt% of Ce, 0.1 wt% of Nd, 2.0 wt% of Zn, 0.1 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the magnesium alloy may include: 4.0 wt% of Al, 0.1 wt% of Mn, 1.0 wt% of La, 2.0 wt% of Ce, 1.0 wt% of Nd, 0.5 wt% of Zn, 0.5 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the magnesium alloy may include: 2.5 wt% of Al, 0.3 wt% of Mn, 1.0 wt% of La, 4.0 wt% of Ce, 0.5 wt% of Nd, 1.5 wt% of Zn, 0.3 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the magnesium alloy including the foregoing components has high thermal conductivity and ideal mechanical properties at the same time.
  • the magnesium alloy according to the embodiments of this application has thermal conductivity obviously higher than that of an existing magnesium alloy.
  • Experimental results show that the thermal conductivity of the magnesium alloy including the foregoing components with the corresponding proportions may be greater than 110 w/m ⁇ K.
  • the magnesium alloy can be effectively applied to scenarios that require relatively high thermal conductivity.
  • the magnesium alloy has advantages such as a low density, a high specific strength, a high specific modulus, a high property of tremble elimination, and high resistance to corrosion caused by organic matter and alkali.
  • the magnesium alloy according to the embodiments of this application may further satisfy at least one of the following conditions: a tensile strength is greater than 220 MPa; a yield strength is greater than 150 MPa; and an elongation is greater than 4%.
  • the magnesium alloy may satisfy only one of the foregoing conditions.
  • the magnesium alloy may only satisfy the condition that the tensile strength is greater than 220 MPa, or may only satisfy the condition that the yield strength is greater than 150 MPa, or may only satisfy the condition that the elongation is greater than 4%.
  • the magnesium alloy may satisfy two of the foregoing conditions.
  • the magnesium alloy may satisfy the condition that the tensile strength is greater than 220 MPa and the condition that the yield strength is greater than 150 MPa, or may satisfy the condition that the tensile strength is greater than 220 MPa and the condition that the elongation is greater than 4%, or may satisfy the condition that the yield strength is greater than 150 MPa and the condition that the elongation is greater than 4%.
  • the magnesium alloy may also satisfy the three conditions that the tensile strength is greater than 220 MPa, the yield strength is greater than 150 MPa and the elongation is greater than 4%. In this way, it is ensured that the magnesium alloy has ideal thermal conductivity and better mechanical properties at the same time, and can satisfy usage requirements in different fields as well as different operating environments and conditions.
  • this application provides an inverter housing.
  • at least a part of the inverter housing is formed by the foregoing magnesium alloy with high thermal conductivity.
  • the inverter housing has extremely high thermal conductivity and high heat-dissipation performance, so that the safety and service life of an inverter using the inverter housing are improved significantly.
  • the specific structure of the inverter housing is not particularly limited and may be any existing structure of an inverter housing in the field.
  • a person skilled in the art may choose flexibly according to an actual demand.
  • a part of the inverter housing such as a part that requires higher thermal conductivity, may be prepared by using the magnesium alloy in this application.
  • the entire inverter housing may be prepared by using the magnesium alloy in this application.
  • a person skilled in the art may also choose flexibly according to costs and usage requirements.
  • this application provides an inverter.
  • the inverter includes the foregoing inverter housing. It is found that the inverter has good heat-dissipation performance, so that the safety is greatly improved and the service life is significantly increased. Moreover, a person skilled in the art may understand that the inverter has all the features and advantages of the foregoing inverter housing, which are not described herein again.
  • the inverter apart from the inverter housing, the inverter further includes necessary structures and parts of a conventional inverter, such as an inverter bridge, control logic and a filter circuit, which are not described in further detail herein.
  • a conventional inverter such as an inverter bridge, control logic and a filter circuit
  • this application provides a vehicle.
  • the vehicle includes the foregoing inverter.
  • the inverter of the vehicle has good thermal conductivity and mechanical properties, thereby greatly improving the safety.
  • the inverter housing is prepared by using a magnesium alloy, which helps to reduce the weight of the vehicle and improve user experience.
  • the vehicle has all the features and advantages of the foregoing inverter, which are not described herein again.
  • the vehicle apart from the inverter, the vehicle has necessary structures and parts of a conventional vehicle, such as a body, an engine, wheels and interior decoration items, which are not described in further detail herein.
  • Components of the magnesium alloy 3.0 wt% of Al, 0.25 wt% of Mn, 1.55 wt% of La, 3.0 wt% of Ce, 0.13 wt% of Nd, 0.6 wt% of Zn, 0.15 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • Preparation procedure put a pure magnesium ingot and a pure aluminum ingot into a smelting furnace, where the smelting temperature is 700-750°C; add an Mg-Ca master alloy, an Mg-Mn master alloy and an Mg-Zn master alloy into the smelting furnace and completely melt down the master alloys, where the smelting temperature is 700-750°C; add an Mg-La master alloy, an Mg-Ce master alloy and an Mg-Nd master alloy into the smelting furnace, where the smelting temperature is 700-750°C, and at the same time add a covering agent onto the surface of the melt; perform a 15-minute refining treatment on the melt using an RJ-5 flux, where the refining temperature is 730-760°C, and then let the melt stand for 80-120 minutes, where the temperature is 650-730°C.
  • Sr and Cu may be introduced using impurities of the foregoing raw materials, and therefore, it is unnecessary to add Sr and Cu separately
  • Components of the magnesium alloy 2.0 wt% of Al, 0.15 wt% of Mn, 2.0 wt% of La, 2.5 wt% of Ce, 0.1 wt% of Nd, 2.0 wt% of Zn, 0.1 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • Components of the magnesium alloy 4.0 wt% of Al, 0.1 wt% of Mn, 1.0 wt% of La, 2.0 wt% of Ce, 1.0 wt% of Nd, 0.5 wt% of Zn, 0.5 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • Components of the magnesium alloy 2.5 wt% of Al, 0.3 wt% of Mn, 1.0 wt% of La, 4.0 wt% of Ce, 0.5 wt% of Nd, 0.5 wt% of Zn, 0.3 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • Components of the magnesium alloy 6 wt% of Al, 0.4 wt% of Mn, 0.48 wt% of Zn, 1.2 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • Components of the magnesium alloy 6.0 wt% of Al, 0.25 wt% of Mn, 1.55 wt% of La, 3.0 wt% of Ce, 0.013 wt% of Nd, 0.6 wt% of Zn, 0.15 wt% of Ca, less than 0.1 wt% of Sr, less than 0.1 wt% of Cu, and magnesium.
  • the mechanical properties and material molding fluidity of the magnesium alloy prepared in Embodiment 1 and an AZ91D magnesium alloy are tested.
  • the test standard for mechanical properties is ISO 6892-1.
  • a sample for testing the material molding fluidity is die-cast at atmospheric pressure by using a mosquito-repellent incense mold, where the mold temperature is 200°C and the die-casting temperature is 700°C.
  • An injection speed is 3 circles per second.
  • a second-speed starting position is 140 mm.
  • the length of the injected mosquito-repellent incense mold is recorded as an analogy of the material fluidity. Results are respectively shown in Table 2 and Table 3.
  • the magnesium alloy with high thermal conductivity in this application has extremely high thermal conductivity and heat-dissipation capability, as well as a relatively high tensile strength, yield strength and elongation, and also has high formability and recovery capability.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cooling Or The Like Of Electrical Apparatus (AREA)
  • Conductive Materials (AREA)

Claims (10)

  1. Alliage de magnésium à conductivité thermique élevée, dans lequel sur la base de la masse totale de l'alliage de magnésium à conductivité thermique élevée, l'alliage de magnésium à conductivité thermique élevée comprend : entre 2,0 et 4,0 % en poids d'Al, entre 0,1 et 0,3 % en poids de Mn, entre 1,0 et 2,0 % en poids de La, entre 2,0 et 4,0 % en poids de Ce, entre 0,1 et 1,0 % en poids de Nd, entre 0,5 et 2,0 % en poids de Zn, entre 0,1 et 0,5 % en poids de Ca, moins de 0,1 % en poids de Sr, moins de 0,1 % en poids de Cu, et des résidus contenant du magnésium.
  2. Alliage de magnésium à conductivité thermique élevée selon la revendication 1, dans lequel sur la base de la masse totale de l'alliage de magnésium à conductivité thermique élevée, l'alliage de magnésium à conductivité thermique élevée comprend : entre 0,15 et 0,3 % en poids de Mn et entre 2,5 et 4,0 % en poids de Ce.
  3. Alliage de magnésium à conductivité thermique élevée selon la revendication 1, dans lequel sur la base de la masse totale de l'alliage de magnésium à conductivité thermique élevée, l'alliage de magnésium à conductivité thermique élevée comprend :
    3,0 % en poids d'Al, 0,25 % en poids de Mn, 1,55 % en poids de La, 3,0 % en poids de Ce, 0,13 % en poids de Nd, 0,6 % en poids de Zn, 0,15 % en poids de Ca, moins de 0,1 % en poids de Sr, moins de 0,1 % en poids de Cu, et des résidus contenant du magnésium.
  4. Alliage de magnésium à conductivité thermique élevée selon la revendication 1, dans lequel sur la base de la masse totale de l'alliage de magnésium à conductivité thermique élevée, l'alliage de magnésium à conductivité thermique élevée comprend :
    2,0 % en poids d'Al, 0,15 % en poids de Mn, 2,0 % en poids de La, 2,5 % en poids de Ce, 0,1 % en poids de Nd, 2,0 % en poids de Zn, 0,1 % en poids de Ca, moins de 0,1 % en poids de Sr, moins de 0,1 % en poids de Cu, et des résidus contenant du magnésium.
  5. Alliage de magnésium à conductivité thermique élevée selon la revendication 1, dans lequel sur la base de la masse totale de l'alliage de magnésium à conductivité thermique élevée, l'alliage de magnésium à conductivité thermique élevée comprend :
    4,0 % en poids d'Al, 0,1 % en poids de Mn, 1,0 % en poids de La, 2,0 % en poids de Ce, 1,0 % en poids de Nd, 0,5 % en poids de Zn, 0,5 % en poids de Ca, moins de 0,1 % en poids de Sr, moins de 0,1 % en poids de Cu, et des résidus contenant du magnésium.
  6. Alliage de magnésium à conductivité thermique élevée selon la revendication 1, dans lequel sur la base de la masse totale de l'alliage de magnésium à conductivité thermique élevée, l'alliage de magnésium à conductivité thermique élevée comprend :
    2,5 % en poids d'Al, 0,3 % en poids de Mn, 1,0 % en poids de La, 4,0 % en poids de Ce, 0,5 % en poids de Nd, 0,5 % en poids de Zn, 0,3 % en poids de Ca, moins de 0,1 % en poids de Sr, moins de 0,1 % en poids de Cu, et des résidus contenant du magnésium.
  7. Alliage de magnésium à conductivité thermique élevée selon l'une quelconque des revendications 1 à 6, dans lequel la conductivité thermique est supérieure à 110 W/mK.
  8. Alliage de magnésium à conductivité thermique élevée selon l'une quelconque des revendications 1 à 7, dans lequel au moins l'une des conditions suivantes est satisfaite :
    une résistance à la traction est supérieure à 220 MPa ;
    une limite d'élasticité est supérieure à 150 MPa ;et
    un allongement est supérieur à 4 %.
  9. Boîtier d'onduleur, dans lequel une partie du boîtier d'onduleur est formée par l'alliage de magnésium à conductivité thermique élevée selon l'une quelconque des revendications 1 à 8.
  10. Onduleur, comprenant le boîtier d'onduleur selon la revendication 9.
EP18818152.3A 2017-06-15 2018-04-25 Alliage de magnésium à conductivité thermique élevée, boîtier d'onduleur, onduleur et automobile Active EP3640356B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710453134.2A CN109136699B (zh) 2017-06-15 2017-06-15 高导热镁合金、逆变器壳体、逆变器及汽车
PCT/CN2018/084488 WO2018228059A1 (fr) 2017-06-15 2018-04-25 Alliage de magnésium à conductivité thermique élevée, boîtier d'onduleur, onduleur et automobile

Publications (3)

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EP3640356A4 EP3640356A4 (fr) 2020-04-22
EP3640356A1 EP3640356A1 (fr) 2020-04-22
EP3640356B1 true EP3640356B1 (fr) 2021-03-31

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US (1) US20210147963A1 (fr)
EP (1) EP3640356B1 (fr)
CN (1) CN109136699B (fr)
WO (1) WO2018228059A1 (fr)

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EP3640356A4 (fr) 2020-04-22
EP3640356A1 (fr) 2020-04-22
CN109136699A (zh) 2019-01-04
WO2018228059A1 (fr) 2018-12-20
CN109136699B (zh) 2021-07-09
US20210147963A1 (en) 2021-05-20

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