EP3586995B2 - Procédé de préparation d'un mélange de sable de fonderie - Google Patents
Procédé de préparation d'un mélange de sable de fonderie Download PDFInfo
- Publication number
- EP3586995B2 EP3586995B2 EP18180868.4A EP18180868A EP3586995B2 EP 3586995 B2 EP3586995 B2 EP 3586995B2 EP 18180868 A EP18180868 A EP 18180868A EP 3586995 B2 EP3586995 B2 EP 3586995B2
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- EP
- European Patent Office
- Prior art keywords
- cleaning water
- sand
- moulding
- foundry sand
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004576 sand Substances 0.000 title claims description 72
- 239000000203 mixture Substances 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 91
- 238000004140 cleaning Methods 0.000 claims description 86
- 239000011230 binding agent Substances 0.000 claims description 64
- 238000000465 moulding Methods 0.000 claims description 34
- 238000005266 casting Methods 0.000 claims description 29
- 239000002002 slurry Substances 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 24
- 239000012634 fragment Substances 0.000 claims description 20
- 238000001035 drying Methods 0.000 claims description 17
- 239000000654 additive Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- 230000003472 neutralizing effect Effects 0.000 claims description 8
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- 230000006378 damage Effects 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims 1
- 239000003110 molding sand Substances 0.000 description 69
- 239000012778 molding material Substances 0.000 description 26
- 238000000926 separation method Methods 0.000 description 8
- 239000000428 dust Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 206010065929 Cardiovascular insufficiency Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/04—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by grinding, blending, mixing, kneading, or stirring
- B22C5/0409—Blending, mixing, kneading or stirring; Methods therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/18—Plants for preparing mould materials
- B22C5/185—Plants for preparing mould materials comprising a wet reclamation step
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/04—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by grinding, blending, mixing, kneading, or stirring
- B22C5/0409—Blending, mixing, kneading or stirring; Methods therefor
- B22C5/0463—Plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/04—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by grinding, blending, mixing, kneading, or stirring
- B22C5/0409—Blending, mixing, kneading or stirring; Methods therefor
- B22C5/0472—Parts; Accessories; Controlling; Feeding; Discharging; Proportioning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/10—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by dust separating
Definitions
- the invention relates to a method for recovering molding sand from a foundry sand mixture which comprises at least a proportion of molding material fragments or loose molding material grains which accrue when a casting is removed from a mold as a result of the destruction of casting cores or molded parts which represent the casting and which have been formed from the molding sand (F) and an inorganic binder and one or more additives for adjusting the properties of the molding material.
- the foundry sand mixture is mixed with cleaning water to form a slurry in order to dissolve the inorganic binder residues contained in the foundry sand mixture and any additives present from the molding sand and to rinse them out of the foundry sand mixture.
- the cleaning water contaminated with the inorganic binder residues is then separated from the molding sand contained in the slurry.
- Such a procedure is known, for example, from WO 2007/082747 A1 known, whereby this method is particularly suitable for the preparation of foundry sand mixtures in which an inorganic binder, in particular a water glass binder, is present.
- the casting cores or molded parts that arise when a casting is demolded from a so-called "lost" mold, i.e. a mold that was destroyed during demolding, are mechanically crushed.
- a suspension is formed from the crushed fragments by adding water. This is followed by separation of the components of the suspension.
- a new ready-to-use core or molding sand mixture is prepared from the molding sand obtained during the separation.
- the initial crushing of the core and molded part fragments is intended to separate as far as possible from the molding sand grains any impurities that adhere to the molding sand grains from which the cores and molded parts in question were formed.
- the impurities contained therein can be removed and the individual components of the mixture can be fed to their respective intended further processing.
- Another known document of the state of the art is the DE102005041519 .
- the invention has solved this problem by the method specified in claim 1.
- the process temperature of the slurry formed from the cleaning water and the foundry sand mixture in step a) is now 80 - 100 °C.
- the temperature window specified by the invention is set in such a way that the processing of the foundry sand mixture can be integrated into a water- and energy-saving cycle.
- the invention allows the process temperature and the process times to be coordinated in such a way that the foundry sand produced can be effectively processed at minimal cost. Practical tests have shown that at process temperatures within a temperature range of 80 - 100 °C, the separation of the molding sand from the inorganic binder can be carried out in particularly short process times. For example, the mixing of the foundry sand mixture with the cleaning water to form a slurry and the associated dissolving and rinsing of the inorganic binder residues (step a) of the process according to the invention) can typically be completed within 5 min - 60 min.
- this crushing does not primarily serve to separate binder residues from the molding sand grains, but rather to increase the attack surface for the cleaning water as much as possible in order to accelerate the dissolution of the binder when the foundry sand mixture is mixed with the cleaning water.
- the foundry sand mixture intended for the processing according to the invention contains predominantly coarse fragments
- All devices known from the state of the art for this purpose are suitable for the mechanical comminution of the foundry sand mixture, such as a lump breaker or the like.
- waste heat is available from another process section of the method according to the invention or from a process in the plant in which the method according to the invention is also used, which would otherwise remain unused, it can be expedient, with a view to minimizing the effort required for the temperature control provided according to the invention, to preheat the foundry sand mixture before mixing it with the cleaning water.
- the heating devices provided for heating the cleaning water or the slurry to the respective process temperature can be designed for low outputs and can be implemented and operated at correspondingly low costs.
- the contaminated cleaning water from step b) can be used to heat the fresh water.
- the contaminated cleaning water can be passed through a heat exchanger in which heat is transferred from the contaminated cleaning water to fresh cleaning water without the contaminated and fresh cleaning water mixing.
- the contaminated water is used for another run through step a). This reuse is repeated until the solubility of the binder in the contaminated water is reached, i.e. so much binder is dissolved in the water that no more binder can be dissolved, or the proportion of suspended matter predominates, i.e. the contamination of the water with foreign bodies carried in it has increased so much that rinsing the molding sand with the contaminated water no longer has a cleaning effect.
- the foundry sand mixture to be processed can pass through a heat exchanger before step a), through which contaminated and still warm cleaning water separated from the molding sand in step b) is passed in order to preheat the foundry sand mixture.
- This variant is useful if the cleaning water obtained in step b), which may have been reused several times beforehand, is so contaminated that it is no longer advisable to reuse it.
- the fresh cleaning water supplied in each case can also be heated by means of an additional heat source, such as by means of a continuous flow heater or the like, in such a way that the slurry formed in step a) by mixing with the foundry sand mixture, which is also optionally preheated, reaches a process temperature which lies in the range prescribed according to the invention.
- an additional heat source such as by means of a continuous flow heater or the like
- the molding sand obtained from the foundry sand mixture, freed from the binder and other residues, can be dried in the usual way, dedusted if necessary and divided into different grain size classes.
- the molding sand is to be used for a wider range of applications, in particular those for which molding materials with organic binders are to be provided, the molding sand is subjected to an additional treatment after the separation of the residues of the inorganic binder according to the invention (step b)) in which its pH value is adjusted to values of 7 - 8 -, whereby if the molding sand obtained in step b) is to be used for molding materials with an organic binder, the pH value of the molding sand is adjusted to 7 - 8.
- the molding sand is rinsed or wetted with a neutralizing solution.
- a neutralizing solution such as water-diluted hydrochloric acid, sulfuric acid or organic acids (carbonic acid, citric acid) are suitable as neutralizing solutions.
- buffer substances such as carbonate buffers (e.g. sodium hydrogen carbonate) can also be used for neutralization.
- the molding sand can be mixed with the neutralizing solution.
- Stirring devices and the like are available on the market for this purpose.
- the molding sand can undergo a rinsing step to remove excess neutralizing solution.
- the molding sand obtained in step b) and adjusted in terms of its pH value can be subjected to mechanical dewatering.
- the molding sand can be placed on sieves, for example, through which liquid residues in the molding sand drip while the molding sand grains are retained, or presses, drying belts and the like are used, which are available in the state of the art for this purpose, in order to mechanically expel moisture from a free-flowing mass that is comparable to the molding sand obtained according to the invention.
- Mechanical dewatering can reduce the effort that may be required to dry the molding sand before it is further processed into molding material.
- the molding sand obtained according to the invention must be sufficiently dry.
- the molding sand obtained in step b) can be dried by supplying heat, with typical drying temperatures being in the range of 80 - 800 °C.
- drying temperatures of less than 500 °C, in particular 100 - 300 °C, are suitable, with temperatures of 200 - 250 °C being particularly practical.
- foundries produce foundry sands which, in addition to a portion that comes from casting cores or molded parts made of molding materials with inorganic binders, also contain a portion of fragments or grains of casting cores or molded parts that have been formed from a molding material that has been formed from the molding sand and an organic binder and one or more additives to adjust the properties of the molding material.
- the residues of the organic binder that have not been dissolved from the molding sand grains by the work steps a) and b) of the method according to the invention can be removed by an annealing treatment in which the molding sand present after work step b) is heated to such an extent that the organic binder residues burn off.
- this annealing treatment can also be carried out during the drying step.
- the molding sand obtained by the processing according to the invention can be subjected to a classification in which it is divided depending on the size of its grains. At the same time, the molding sand can be dedusted in order to ensure its optimal suitability for the production of molding material.
- the figure shows a schematic of a workflow in the preparation of a foundry sand mixture, as typically occurs in a foundry in which cast parts (not shown here), such as components for vehicles, are produced in a conventional manner from a light metal melt, in particular an Al or Al alloy melt, using casting molds (also not shown here).
- casting molds include casting cores or molded parts that are made from a molding compound that contains a molding sand that has been tried and tested in practice and an equally tried and tested inorganic binder, such as water glass.
- the binder is activated in the usual way by applying heat in order to ensure that the molding sand grains hold together in a dimensionally stable manner.
- Another part of the casting molds contains casting cores or molded parts that are made from a molding compound that contains a molding sand that has been tried and tested in practice and an organic binder that has also been tried and tested.
- a chemical reaction of the binder is caused by the addition of a reaction medium, such as a gas, through which the binder develops its solidifying effect and ensures that the grains of the molding sand hold together in a dimensionally stable manner.
- the moulding material fragments and loose moulding material grains falling off the casting form a foundry sand mixture G, in which moulding sand F, hardened inorganic and organic binders and possibly also combustion residues are present, which are the result of the combustion or decomposition of parts of the binder present in the respective core or molded part as a result of the heat supply during the casting process or the subsequent thermal treatment.
- the foundry sand mixture G may also contain common additives that are added in practice to molding materials intended for the production of cores or molded parts in order, for example, to ensure optimal flow behavior during the molding of the respective core or molded part ("core shooting").
- the mixture consisting of a proportion FAB of fragments or grains originating from mouldings or casting cores made of moulding material with an inorganic binder and a proportion FOB of fragments or grains originating from mouldings or casting cores made of moulding material with an organic binder is placed in the Fig.1 fed into the processing process shown.
- the foundry sand mixture G first passes through a grain separation device 1 in which the coarse fragments contained in the foundry sand mixture G are crushed in a manner known per se until only grains and smaller fragments remain.
- the foundry sand mixture G which has been separated into grains and optionally preheated in a heat exchanger (not shown here), is introduced into a mixing device 2 by means of gravity or, for example, by means of compressed air support.
- the foundry sand mixture G is flowed through or stirred with cleaning water RW, which has been previously heated in a continuous flow heater, for example using a fluidized bed or an agitator, in order to form a slurry S.
- cleaning water RW which has been previously heated in a continuous flow heater, for example using a fluidized bed or an agitator
- the slurry S formed in the mixing device 2 is intensively circulated in order to ensure turbulence that supports the detachment of the inorganic binder and other contaminants. If necessary, heat is added to bring the slurry S to a process temperature that is in the optimal range of 80 - 100 °C. Excess cleaning water RWK contaminated with inorganic binder residues and other contaminants, such as molding additives and combustion residues, is drained from the mixing device 2.
- the mixing of the cleaning water RW with the foundry sand mixture G is so intensive that the inorganic binder in particular dissolves essentially completely in the cleaning water RW within a short time.
- the combustion residues and any additive residues present are absorbed by the cleaning water RW from the foundry sand mixture G.
- the residence times of the slurry S in the mixing device 2 provided for this purpose are 5 - 60 minutes.
- the slurry S passes into a rinsing device 3, in which it is rinsed with cleaning water RW in order to rinse the inorganic binder residues dissolved in the slurry S from the molding sand grains and other impurities from the molding sand grains F of the slurry S.
- the rinsing device 3 can be designed as a conventional screening machine in which the slurry S is placed on a sieve and sprayed with cleaning water RW, which is applied by means of nozzles arranged above the sieve.
- the resulting cleaning water RWK which is contaminated with inorganic binder residues and other contaminants, is collected and fed to a pre-cleaning device 4, in which the insoluble inorganic binder residues are separated from the contaminated cleaning water RWK.
- the excess contaminated cleaning water RWK discharged from the mixing device 2 is also fed to the pre-cleaning device 4.
- a partial flow RWKV' of the pre-cleaned contaminated cleaning water RWK can be reused by feeding it to the mixing device 2 as cleaning water RW.
- the total volume flow of the cleaning water RW fed to the mixing device 2 can be made up of a partial flow of fresh cleaning water RWF and the partial flow RWKV' of the pre-cleaned cleaning water RWV.
- another partial flow RWKV" of the pre-cleaned contaminated cleaning water RWK can be fed to the rinsing device 3 for rinsing the slurry S.
- the total volume flow of the cleaning water RW fed to the rinsing device 3 can be composed of a partial flow of fresh cleaning water RWF and the partial flow RWKV' of the pre-cleaned cleaning water RWV as well as a further partial flow RWK' of contaminated cleaning water RWK, which comes from one or more of the process steps explained below.
- Contaminated cleaning water RWKE which is so heavily contaminated that it can no longer perform a cleaning function, is drained from the process and fed into a separate treatment plant.
- the molding sand F separated from the slurry S in the rinsing device 3 is to be used for the production of molding material which comprises an organic binder
- the molding sand F passes through a treatment device 5 in which it is wetted with an acidic neutralizing solution NL in order to adjust its pH value to a value of 7 - 8 which is optimal for this purpose.
- the molding sand F whose pH value has been adjusted in this way, is then rinsed in a rinsing device 6 with fresh cleaning water RWF in order to remove excess neutralizing solution NL.
- the resulting cleaning water RWN which is contaminated with neutralization solution, is collected and disposed of.
- the adjustment of the pH value in the treatment device 5 and the subsequent rinsing in the rinsing device 6 can be skipped if the molding sand F is intended exclusively for the production of molding material comprising an inorganic binder.
- the molding sand F which is still loaded with cleaning water RW, is transported after rinsing in the rinsing device 3 or the optionally passed through stations "treatment device 5 and rinsing device 6" to a dewatering device 7, in which dewatering is carried out using mechanical means.
- the dewatering machine 7 can be designed as a screening machine known for these purposes in the prior art, as a vacuum belt dryer or as a press.
- the mechanical dewatering reduces the moisture of the molding sand F to such an extent that significantly less energy is required during the subsequent thermal drying to achieve the required degree of dryness.
- the contaminated cleaning water RWK arising during mechanical dewatering is, for example, fed to the rinsing device 3 as a further partial flow of the cleaning water RW fed there.
- the mechanically dewatered molding sand F is fed to a drying device 8, which can be a rotary kiln, a belt dryer or the like. If the foundry sand mixture G used includes a proportion of molding material fragments and grains that contain organic binders or binder residues, the temperature Tw at which the thermal drying takes place is set to >500 - 700 °C, so that the organic binder residues still adhering to the corresponding portion of the molding sand F burn off.
- thermal drying can be carried out at temperatures in the range of 100 - 300 °C.
- the water vapor generated during thermal drying is collected, condensed and fed into the process as fresh cleaning water RWF.
- the fresh cleaning water RWF obtained during thermal drying also forms a partial flow of the cleaning water RW fed into the rinsing device 3.
- the molding sand F passes through a dust removal device 9 in which the fine dust FS present in the molding sand F is separated from the remaining grains of the molding sand F.
- the fine dust FS can no longer be used for casting purposes and is therefore deposited in the usual way or used for another purpose.
- the dust removal device 9 is based, for example, on the principle of stream classification, in which air is used as the separation medium (so-called "air classification"). The air used here can be reused or released into the environment.
- the dedusted molding sand F finally reaches a classification device 10, in which the molding sand F is divided into at least two molding sand partial quantities Fk, Fm according to at least two molding sand classes, of which one molding sand partial quantity Fk comprises the part of the molding sand F whose grains do not exceed a certain limit size, while the other molding sand partial quantity Fm contains the part of the molding sand F whose grains have a size that is at least equal to this limit size.
- the classification step can also be carried out in combination with dedusting.
- fluid basins are usually used in which the molding sand F is fed in from above, air is passed through a sintering plate attached to the floor and is set into vibration using unbalanced motors.
- the fine dust FS is transported away by means of the air via a suction device.
- the grain classes are extracted at opposite ends of the basin.
- the finer parts rise higher and have to overcome a barrier.
- the coarse parts do not rise as high and are therefore deducted below a barrier.
- the fresh cleaning water RWF and reused contaminated cleaning water RWK required in the treatment process according to the invention or the cleaning water RW possibly formed by mixing them can, if necessary, be preheated via heat exchangers not shown here, in which waste heat generated in the process according to the invention itself or in other processes is used to heat the respective cleaning water RWF, RWK, RW to an optimal temperature for the respective process step.
- Fig.1 The process flow followed by the foundry sand mixture G, the slurry S 40 formed from it and the molding sand F contained therein is shown in solid lines.
- new molding material FA which contains inorganic binder
- new molding material FO which contains organic binder
- Cores or molded parts for casting molds can be produced in a conventional manner from the molding materials FA and FO.
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- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Claims (11)
- rocédé de récupération de sable de moulage (F) à partir d'un mélange de sable de fonderie (G) qui comporte au moins une proportion (FAB) de fragments de matériau de moulage ou des granulés de matériau de moulage en vrac se produisant lors du démoulage d'une pièce moulée hors du moule de coulage à la suite de la destruction des noyaux de coulée ou des parties de moulage formant la pièce moulée, lesquels sont formés à partir du sable de moulage (F) ainsi que d'un liant inorganique et d'un ou plusieurs additifs pour ajuster les propriétés du matériau de moulage, le procédé comportant les étapes de travail suivantes :a) mélanger le mélange de sable de fonderie (G) avec de l'eau de nettoyage (RW) pour former une boue (S) afin de dissoudre les résidus de liant inorganique (AB), contenus dans le mélange de sable de fonderie (G), ainsi que les additifs présents dans le sable de moulage (F) et de les rincer hors du mélange de sable de fonderie (G),
etb) séparer l'eau de nettoyage (RWK) contaminée par les résidus de liants inorganiques du sable de moulage (F) contenu dans la boue (S),caractérisé en ce quela température de procédé de la boue (S) formée par l'eau de nettoyage et le mélange de sable de fonderie (G) (étape de travail a)) est de 80 - 100 °C,le mélange de sable de fonderie (G) avec l'eau de nettoyage (RW) en formant une boue (S) et la dissolution et le rinçage des résidus de liant inorganiques (AB) qui en découlent (étape de travail a)) est effectué en l'espace de 5 min à 60 min, l'eau de nettoyage (RWK) contaminée récupérée dans l'étape de travail b) est réutilisée au moins une fois pour l'étape de travail a),la réutilisation est répétée jusqu'à atteindre la solubilité du liant dans l'eau ou jusqu'à ce que la proportion de matière en suspension contenue dans l'eau prédomine.le pH du sable de moulage (F) obtenu dans l'étape de travail b) est réglé sur un pH de 7 - 8 par rinçage ou mouillage avec une solution neutralisante (NL). - Procédé selon l'une des revendications précédentes, caractérisé en ce que les fragments de matériau de moulage contenus dans le mélange de sable de fonderie (G) sont granulés mécaniquement avant d'être mélangés avec l'eau de nettoyage (étape de travail a)).
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le mélange de sable de fonderie (G) passe, avant l'étape de travail a), dans un échangeur de chaleur, à travers lequel est dirigée de l'eau de nettoyage (RWK), encore chaude, contaminée et séparée, dans l'étape de travail b), du sable de moulage (F) afin de préchauffer le mélange de sable de fonderie (G).
- Procédé selon l'une des revendications précédentes, caractérisé en ce que l'eau de nettoyage (RWK) contaminée séparée, dans l'étape de travail b), du sable de moulage (F) passe dans échangeur de chaleur dans lequel est réchauffée l'eau de nettoyage (RW) affluente pour l'étape de travail a).
- Procédé selon l'une des revendications précédentes, caractérisé en ce qu'un acide dilué est utilisé en tant que solution neutralisante (NL).
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le sable de moulage (F) obtenu dans l'étape de travail b) est déshydraté mécaniquement.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le sable de moulage (F) obtenu dans l'étape de travail b) est séché à une température de séchage de 80 - 800 °C.
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le mélange de sable de fonderie (G) contient une proportion (FOB) de fragments ou de granulats de noyaux de moulage ou de parties de moulage formés à partir d'un matériau de moulage qui a été formé à partir du sable de moulage (F) ainsi que d'un liant organique et éventuellement à partir d'un ou plusieurs additifs pour ajuster les propriétés du matériau de moulage.
- Procédé selon la revendication 8, caractérisé en ce que le sable de moulage (F) obtenu dans l'étape de travail b) est chauffé à une température étant au moins de 500 °C afin de brûler des résidus de liant organique adhérant sur le sable de moulage (F).
- Procédé selon l'une des revendications 7 et 9, caractérisé en ce que la combustion des résidus de liant organique a lieu pendant le séchage du sable de moulage (F).
- Procédé selon l'une des revendications précédentes, caractérisé en ce que le sable de moulage obtenu dans l'étape de travail b) est soumis à une classification.
Priority Applications (11)
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HUE18180868A HUE054926T2 (hu) | 2018-06-29 | 2018-06-29 | Eljárás öntödei homokkeverék elõállítására |
EP18180868.4A EP3586995B2 (fr) | 2018-06-29 | 2018-06-29 | Procédé de préparation d'un mélange de sable de fonderie |
PL18180868T PL3586995T3 (pl) | 2018-06-29 | 2018-06-29 | Sposób przerobu mieszaniny masy formierskiej |
ES18180868T ES2874204T3 (es) | 2018-06-29 | 2018-06-29 | Procedimiento para la preparación de una mezcla de arena de fundición |
MX2020014218A MX2020014218A (es) | 2018-06-29 | 2019-07-01 | Procedimiento para tratar una mezcla de arena de fundición. |
KR1020207036136A KR20210010908A (ko) | 2018-06-29 | 2019-07-01 | 주물사 혼합물 처리 방법 |
JP2020572871A JP2021529667A (ja) | 2018-06-29 | 2019-07-01 | 鋳物砂混合物の処理方法 |
US17/256,280 US11707777B2 (en) | 2018-06-29 | 2019-07-01 | Method for preparing a foundry sand mixture |
PCT/IB2019/055584 WO2020003277A1 (fr) | 2018-06-29 | 2019-07-01 | Procédé de préparation d'un mélange de sable de fonderie |
CN201980043992.7A CN112512723A (zh) | 2018-06-29 | 2019-07-01 | 铸造用砂混合物的处理方法 |
BR112020026856-9A BR112020026856B1 (pt) | 2018-06-29 | 2019-07-01 | Processo para a recuperação de areia de moldagem |
Applications Claiming Priority (1)
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EP18180868.4A EP3586995B2 (fr) | 2018-06-29 | 2018-06-29 | Procédé de préparation d'un mélange de sable de fonderie |
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Publication Number | Publication Date |
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EP3586995A1 EP3586995A1 (fr) | 2020-01-01 |
EP3586995B1 EP3586995B1 (fr) | 2021-04-14 |
EP3586995B2 true EP3586995B2 (fr) | 2024-04-24 |
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EP18180868.4A Active EP3586995B2 (fr) | 2018-06-29 | 2018-06-29 | Procédé de préparation d'un mélange de sable de fonderie |
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US (1) | US11707777B2 (fr) |
EP (1) | EP3586995B2 (fr) |
JP (1) | JP2021529667A (fr) |
KR (1) | KR20210010908A (fr) |
CN (1) | CN112512723A (fr) |
BR (1) | BR112020026856B1 (fr) |
ES (1) | ES2874204T3 (fr) |
HU (1) | HUE054926T2 (fr) |
MX (1) | MX2020014218A (fr) |
PL (1) | PL3586995T3 (fr) |
WO (1) | WO2020003277A1 (fr) |
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CN116393655A (zh) * | 2023-06-06 | 2023-07-07 | 河北光德精密机械股份有限公司 | 一种速溶型芯及其制备方法 |
Citations (3)
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CN103056291A (zh) † | 2012-12-12 | 2013-04-24 | 青岛三合山精密铸造有限公司 | 水玻璃旧砂的回收再生方法 |
DE102012011384A1 (de) † | 2012-06-11 | 2013-12-12 | DEANTEC GmbH | Vorrichtung zum Regenerieren anorganisch gebundener Gießereisande |
CN104759584A (zh) † | 2015-04-22 | 2015-07-08 | 莒州集团有限公司 | 水玻璃废砂再生优化处理方法及系统 |
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JPS5299924A (en) * | 1976-02-18 | 1977-08-22 | Hitachi Ltd | Old sand cleaning reproduction process |
SU921664A1 (ru) | 1980-04-25 | 1982-04-23 | Предприятие П/Я А-1125 | Способ регенерации формовочной и стержневой смеси с в жущими в виде гидроалюмината или гидрограната кальци |
SU910309A1 (ru) | 1980-09-05 | 1982-03-07 | Государственный Проектный И Технологический Институт Кузнечно-Прессового Машиностроения | Установка дл регенерации формовочных смесей |
WO1985003462A1 (fr) | 1984-02-02 | 1985-08-15 | Giesserei-Technik H.-G. Lorek Vdg | Procede et installation pour eliminer les restes de liants organiques et inorganiques provenant de sable de fonderie |
DE4004553C1 (fr) | 1990-02-14 | 1991-10-10 | Saz Sommer Aluminium Zug Ag, Zug, Ch | |
BR9105097A (pt) | 1990-03-20 | 1992-06-02 | Kuettner Gmbh & Co Kg Dr | Processo para a regeneracao de areia usada de fundicao |
JP4679718B2 (ja) | 2000-12-15 | 2011-04-27 | 国立大学法人豊橋技術科学大学 | 回収鋳物砂の再生方法 |
DE102005004519A1 (de) | 2005-01-31 | 2006-08-10 | Behr Gmbh & Co. Kg | Kondensator für eine Klimaanlage, insbesondere eines Kraftfahrzeuges |
DE102005041519A1 (de) | 2005-08-31 | 2007-03-01 | Klein Anlagenbau Ag | Verfahren zum Behandeln von Gießereiformstoffen |
WO2007082747A1 (fr) | 2006-01-18 | 2007-07-26 | Hos Hottinger Systems Gbr | Procédé et dispositif pour recycler un mélange noyau-sable de fonderie |
DE102007008149A1 (de) | 2007-02-19 | 2008-08-21 | Ashland-Südchemie-Kernfest GmbH | Thermische Regenerierung von Gießereisand |
CN101209485B (zh) * | 2007-12-21 | 2013-10-16 | 李江平 | 一种旧砂再生方法及其旧砂再生系统 |
JP2011088125A (ja) | 2009-10-26 | 2011-05-06 | Acreco:Kk | 遠赤外線放射材料 |
CN103394638A (zh) * | 2013-08-20 | 2013-11-20 | 武汉纺织大学 | 一种逆洗再生铸造旧砂的方法与装置 |
-
2018
- 2018-06-29 EP EP18180868.4A patent/EP3586995B2/fr active Active
- 2018-06-29 ES ES18180868T patent/ES2874204T3/es active Active
- 2018-06-29 PL PL18180868T patent/PL3586995T3/pl unknown
- 2018-06-29 HU HUE18180868A patent/HUE054926T2/hu unknown
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2019
- 2019-07-01 KR KR1020207036136A patent/KR20210010908A/ko not_active Application Discontinuation
- 2019-07-01 CN CN201980043992.7A patent/CN112512723A/zh active Pending
- 2019-07-01 JP JP2020572871A patent/JP2021529667A/ja active Pending
- 2019-07-01 US US17/256,280 patent/US11707777B2/en active Active
- 2019-07-01 MX MX2020014218A patent/MX2020014218A/es unknown
- 2019-07-01 WO PCT/IB2019/055584 patent/WO2020003277A1/fr active Application Filing
- 2019-07-01 BR BR112020026856-9A patent/BR112020026856B1/pt active IP Right Grant
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DE102012011384A1 (de) † | 2012-06-11 | 2013-12-12 | DEANTEC GmbH | Vorrichtung zum Regenerieren anorganisch gebundener Gießereisande |
CN103056291A (zh) † | 2012-12-12 | 2013-04-24 | 青岛三合山精密铸造有限公司 | 水玻璃旧砂的回收再生方法 |
CN104759584A (zh) † | 2015-04-22 | 2015-07-08 | 莒州集团有限公司 | 水玻璃废砂再生优化处理方法及系统 |
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Also Published As
Publication number | Publication date |
---|---|
EP3586995A1 (fr) | 2020-01-01 |
JP2021529667A (ja) | 2021-11-04 |
EP3586995B1 (fr) | 2021-04-14 |
BR112020026856A2 (pt) | 2021-04-06 |
PL3586995T3 (pl) | 2021-10-25 |
BR112020026856B1 (pt) | 2024-03-12 |
US11707777B2 (en) | 2023-07-25 |
WO2020003277A1 (fr) | 2020-01-02 |
US20210260647A1 (en) | 2021-08-26 |
ES2874204T3 (es) | 2021-11-04 |
HUE054926T2 (hu) | 2021-10-28 |
MX2020014218A (es) | 2021-05-27 |
KR20210010908A (ko) | 2021-01-28 |
CN112512723A (zh) | 2021-03-16 |
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