EP3559295B1 - Objekt mit duplexedelstahl und verwendung davon - Google Patents

Objekt mit duplexedelstahl und verwendung davon Download PDF

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Publication number
EP3559295B1
EP3559295B1 EP17818553.4A EP17818553A EP3559295B1 EP 3559295 B1 EP3559295 B1 EP 3559295B1 EP 17818553 A EP17818553 A EP 17818553A EP 3559295 B1 EP3559295 B1 EP 3559295B1
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EP
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Prior art keywords
stainless steel
duplex stainless
object according
equal
content
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EP17818553.4A
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English (en)
French (fr)
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EP3559295A1 (de
Inventor
Tomas Forsman
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Sandvik Intellectual Property AB
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Sandvik Intellectual Property AB
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236—Cold rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0268—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment between cold rolling steps
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/001—Austenite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/005—Ferrite
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C2204/00—End product comprising different layers, coatings or parts of cermet

Definitions

  • the present disclosure relates to an object comprising a duplex stainless steel, in particular the object is suitable for use in spring applications or as a spring as such.
  • the present disclosure also relates to a method of producing the object.
  • Spring applications in the form of a wire or a strip may be statically or dynamically loaded.
  • the most important properties for steel grades aimed for static spring applications are high proof or yield strength, well-defined elastic modulus, high corrosion resistance and high stress relaxation resistance.
  • the most important properties for steel grades aimed for dynamic spring applications are high proof or yield strength, well-defined elastic modulus, high corrosion resistance, high stress relaxation resistance and high resistance towards fatigue failure.
  • JP 2010 059541 discloses a process wherein the final step is an annealing process aiming for obtaining the maximum elongation of a stainless steel which is a low alloyed duplex steel.
  • the austenite phase of such a grade is unstable and will partially transform to martensite upon plastic deformation.
  • Stainless spring steel grades of austenitic or martensitic origin typically possess excellent combinations of most of the above properties.
  • one major drawback of the austenitic steel grades is that the elastic modulus tends to decrease almost linearly with increasing load up to the proof stress (Rp 0.2 ) and as stated above steel grades aiming for spring applications should have an elastic modulus which remains at a high level also upon increasing load and which does not decrease in a linear fashion.
  • Martensitic steel grades may present an elastic modulus which does not decrease linearly with increasing load.
  • one major drawback of the martensitic steel grades is that these steels have problems with their corrosion resistance.
  • an aspect of the present disclosure is to provide an object manufactured from a duplex stainless steel according to the appended claims.
  • the term “about” means plus or minus 5% of the numerical value of the number with which it is being used.
  • the aberration "FCC” means austenite phase and the aberration "BCC” means ferrite phase.
  • the expression “essentially parallel” as used herein is intended to mean that the deviation from the plane is less than 10%.
  • the object comprising the duplex stainless steel as defined hereinabove or hereinafter will have no content of sigma phase and/or precipitated chromium nitride. Furthermore, said object will have an elastic modulus that will remain relatively high upon increasing load as compared to the behavior of pure austenitic stainless steel.
  • Another aspect of the present disclosure provides a method for manufacturing an object as defined hereinabove or hereinafter according to the appended claims.
  • the final step of the method must be a cold working process because this process will influence the microstructure of the duplex stainless steel the most and thereby have a great impact on the elastic modulus. Furthermore, the present method will provide the object with a higher strength after cold working and the cold working will also ensure that deformation hardening will happen in the object.
  • the present disclosure relates to an object manufactured from a duplex stainless steel, wherein the duplex stainless steel comprises the following composition, in weight%: C less than or equal to 0.040; Si less than or equal to 0.60; Mn 0.80 - 10.0; Cr 21.0-28.0; Ni 4.0-9.0; Mo 0.9 - 4.5; N 0.10-0.45; Cu less than or equal to 0.50; V less than or equal to 0.10; P less than or equal to 0.010; S less than or equal to 0.006;
  • the duplex stainless steel as defined hereinabove or hereinafter will provide the object with high resistance against corrosion. Furthermore, the alternating layers of ferrite phase and austenite phase will provide the object with a well-defined elastic modulus which will remain relatively high upon increasing load.
  • a well-defined elastic modulus means that the elastic modulus will remain at a high level upon increasing load on the material and will not decrease almost linearly with increasing load up to the proof stress (Rp 0.2 ). Thus, the object will be suitable for spring applications.
  • the duplex stainless steel has a PRE greater than 28.
  • the duplex stainless steel as defined hereinabove or hereinafter will therefore provide the object with high resistance against corrosion, especially against pitting corrosion due to its high PRE value in both ferrite and austenite phase, i.e. the PRE value for both the ferrite and the austenite phase is greater than about 28.
  • the respective amounts of Cr, Mo and N are chosen so that PRE is greater than about 28 in the austenite and ferrite phase respectively.
  • the duplex stainless steel as defined hereinabove or hereinafter consists of 55-70 vol% austenite phase and 30-45 vol% ferrite phase, such as 65-70 vol% austenite phase and 30-35 vol% ferrite phase.
  • the duplex stainless steel as defined hereinabove or hereinafter is highly alloyed and therefore the object will have the ability of undergoing cold deformation generated by cold working without transformation of its austenitic structure into martensitic structure.
  • the object as defined hereinabove or hereinafter is in the form of a sheet or a strip or a wire.
  • the sheet or the strip or the wire may be used for manufacturing a spring, thus the present disclosure also relates to a spring.
  • the at least one hot working process is hot rolling.
  • the hot working process is performed in a temperature of from 1050 to 1300 °C.
  • the at least one hot working process is performed one time or more than one time, e.g. in one embodiment, the hot rolling, may be performed on the body several times, such as e.g. 6 times or until the desired hot working reduction of the workpiece is obtained.
  • the hot working will also form layers of austenite phase and ferrite phase but the thickness of these layers is higher than in the final object.
  • the workpiece may be heated between the hot working steps.
  • the at least one cold working process is cold rolling
  • the cold working process is performed one time or more than one time.
  • the cold working process may be performed on the workpiece several times, e.g. 4 times or until the desired cold deformation of the final object is obtained.
  • the cold deformation of the final object thus meaning the deformation of the object, is at least 10%, such at least 25%, such as at least 50%, such as at least 75%, such as from 75 to 95%.
  • the thickness of the obtained final object in its cold rolled condition is of from 20 ⁇ m up to 5 mm.
  • the method comprises one hot working process, one cold working process, one hot working process and one cold working process. According to another embodiment, the method comprises one hot working process, one cold working process, one hot working process, one cold working process and one cold working process.
  • the method as defined hereinabove or hereinafter comprises a step of heat treatment, wherein the heat treatment is annealing the object obtained after a cold working step.
  • Annealing may be performed in order to reduce any formed intermetallic phases, such as sigma phase and chromium nitrides, or to reduce the strength of the object or for changing the content of austenite or ferrite phase in the object.
  • the annealing temperature will depend on both the composition and the thickness of the object. Usually, the annealing temperature is above 1000 °C.
  • the object is subjected to an annealing step at least between the second last and the last cold working step.
  • the object is annealed at a temperature range of from 1050°C to 1250°C for a period of from about 1 to 600 seconds.
  • the temperature ramping may be such that the time for passing said range is below about 2 minutes.
  • the last step in the process is a cold working step.
  • the present method also comprises a step of aging the object obtained either after cold working step or after an annealing step.
  • This step will provide an additional increase of the proof stress of the object and also a further improvement of the elastic modulus behavior.
  • the object Before being subjected to aging, the object may be subjected to a forming operation in which it is formed into a spring.
  • the aging may be performed for 0.25 to 4 hours at a temperature of from 400 to 450°C. As the aging step is performed at low temperatures, it may be performed after the final cold working process step.
  • the carbon content is limited to less than 0.040 wt%.
  • Mn has a deformation hardening effect and it counteracts the transformation from austenitic to martensitic structure upon deformation. In order to have these effects, Mn has to be present in at least or equal to 0.80 wt%. Additionally, Mn has an austenite stabilizing effect up to a content of about 10.0 wt%. Above that level, the stabilization of ferrite will be increased and it will therefore become difficult to add further ferrite stabilizing element, such as Cr and Mo, without obtaining too much ferrite. Thus, the maximum content of Mn should not be above 10.0 wt%. According to one embodiment, the content of Mn is equal to or less than 6.0 wt%.
  • the content of Mn is in the range of from 2 to 5 wt%.
  • Mn is present in amounts as suggested above, it will increase the deformation hardening ability of the duplex stainless steel to and also prevent the austenite phase from becoming so unstable, i.e. it will prevent the transformation from austenitic structure into martensitic structure upon deformation.
  • N has a positive effect on the corrosion resistance of the duplex stainless steel as defined hereinabove or hereinafter and has also a strong effect on the pitting corrosion resistance equivalent PRE as PRE is defined as Cr+3.3Mo+16. Furthermore, N contributes strongly to the solid solution strengthening and deformation hardening of the duplex stainless steel. N has also a strong austenite stabilizing effect and counteracts transformation from austenitic structure to martensitic structure upon plastic deformation. In order to contribute with all these positive effects, N is added in an amount of 0.10 wt% or higher. However, at too high levels, N tends to form chromium nitrides, which should be avoided due to the negative effects on ductility and corrosion resistance. Thus, the content of N must therefore be equal to or lower than 0.45 wt%. According to one embodiment, the content of N is of from 0.30 to 0.42 wt%.
  • Molybdenum, Mo has a strong influence on the corrosion resistance of the duplex stainless steel as defined hereinabove or hereinafter and it heavily influences the PRE and contributes strongly to both the solid solution strengthening and the deformation hardening. Therefore, Mo is added in amount of equal to or more than 0.9 wt%.
  • Mo also increases the temperature at which unwanted sigma phase is stable and promotes its generation rate and therefore the content of Mo should be equal to or less than 4.5 wt%. According to one embodiment, the content of Mo is of from 2 to 4 wt%.
  • Chromium, Cr has strong impact on the corrosion resistance of the duplex stainless steel as defined hereinabove or hereinafter, especially the pitting corrosion. Moreover, Cr improves the yield strength and counteracts transformation of austenitic structure to martensitic structure upon deformation of the duplex stainless steel. Cr also has a ferrite-stabilizing effect on the duplex stainless steel. Therefore, the content of Cr should be equal to or above 21.0 wt%. At high levels, an increasing content of Cr will result in a higher temperature for unwanted stable sigma phase and chromium nitrides and a more rapid generation of sigma phase. Therefore, the content of Cr is equal to or less than 28.0 wt%. According to one embodiment, the content of Cr is of from 24 to 28 wt%, such as 26 to 28 wt%.
  • Copper, Cu has a positive effect on the corrosion resistance. However, it is optional to add Cu to the duplex stainless steel as defined hereinabove or hereinafter. Often, Cu is present in scrapped goods used for the production of steel, and is allowed to remain in the steel at moderate levels.
  • the content of Cu is equal to or less than 0.50 wt%. According to one embodiment, the content of Cu is equal to or less than 0.02 wt%.
  • Nickel, Ni has a positive effect on the resistance against general corrosion. Ni also has a strong austenite-stabilizing effect and counteracts transformation from austenitic to martensitic structure upon deformation of the duplex stainless steel. The content of Ni is therefore equal to or more than 4.0 wt%. At levels above 9.0 wt%, Ni will result in austenite levels of above 70 %. The content of Ni should, therefore, not be more than or equal to 9.0 wt%. According to one embodiment, the content of Ni is of from 7.0 to 9.0 wt%.
  • Si is almost always present in duplex stainless steels since it may have been used for deoxidization or is in the scrap used for the duplex stainless steels, even though the aim is to have as low amounts as possible. It has a ferrite-stabilizing effect and, at least partly for that reason, the content of Si must be less than or equal to 0.60 wt%, such as between 0.40 to 0.60 wt%.
  • Vanadium, V may be present as an impurity element in duplex stainless steel and because it usually follows the scrap and it is therefore difficult to control the content.
  • the duplex stainless steel should preferably contain as low amounts as possible due to precipitations of carbide and for the present duplex stainless steel, the content of must be equal to or less than 0.10 wt%, such as equal to or less than 0.01 wt%.
  • Phosphorous (P) may be an impurity and is contained in the duplex stainless steel as defined hereinabove or hereinafter in an amount less than or equal to 0.010 wt%.
  • S may be an impurity contained in the duplex stainless steel as defined hereinabove or hereinafter. S may deteriorate the hot workability at low temperatures. Thus, the allowable content of S is less than or equal to 0.006 wt%.
  • alloying elements may be added to the duplex stainless steel as defined hereinabove or hereinafter in order to improve e.g. the machinability or the hot working properties, such as the hot ductility.
  • Such elements are As, Ca, Co, Ti, Nb, W, Sn, Ta, Mg, B, Pb and Ce.
  • the amounts of one or more of these elements are of max 0.5 wt%, such as max 0.1 wt%.
  • the present object comprises an duplex stainless steel consisting of all the elements mentioned hereinabove or hereinafter.
  • the remainder of elements of the duplex stainless steel as defined hereinabove or hereinafter is iron (Fe) and normally occurring impurities.
  • impurities are elements and compounds which have not been added on purpose, but cannot be fully avoided as they normally occur as impurities in e.g. the raw material or the additional alloying elements used for manufacturing of the duplex stainless steel.
  • the duplex stainless steel consists of the alloying elements and ranges mentioned above.
  • the step providing a body of the duplex stainless steel as defined hereinabove or hereinafter may include providing a melt of said duplex stainless steel and casting said melt in order to obtain a body of the duplex stainless steel as defined hereinabove or hereinafter.
  • the casting may include continuous casting of the melt.
  • the thickness of the layers will affect the proof stress of the product.
  • the average FCC thickness and the BCC thickness of each layer must be between 0.01 to about 4.5 ⁇ m, such as about 0.5 to about 4.5 ⁇ m, such as about 1.0 to about 4.5 ⁇ m, such as about 1.0 to about 4.2 ⁇ m, such as 2.0 to 4.2 ⁇ m.
  • the thickness of the product in its final cold worked condition may be of from 20 ⁇ m up to 5 mm.
  • the body comprising the duplex stainless steel as defined hereinabove or hereinafter is subjected to hot working, in which, according to one embodiment, the thickness of the body is reduced from about 100 to 200 mm to 2-15 mm.
  • the thickness measurement of the BCC and FCC phases respectively is performed by taking a perpendicular cross-section of the object (the strip, sheet or wire) and then polishing and etching in acid (such as HNO 3 ) to obtain a contrast between the two phases. The measurement is then performed in a light optical microscope using a suitable magnification (100-1000 times) so that each phase is visible and so that a large enough number of phase boundaries can be counted to obtain a reasonable statistical certainty (more than 30 phase boundaries).
  • An appropriate cross-sectional position for the measurement in a wire is at 25% of its diameter. A strip or sheet should be measured 25% of the width away from the edge, at the thickness center.
  • the thickness of each BCC and FCC phase, in the diameter direction of a wire or along the thickness direction of a strip or sheet, is measured and from this the average BCC and FCC thickness respectively is calculated.
  • Alloys having the chemical composition as seen in Table 1 were melted and casted to 1 kg ingots. After melting and casting, the obtained ingots were hot rolled to strips at a temperature of about 1250 °C using 9 rolling passes. The samples were reheated 3 times during the hot rolling in order to keep the temperature above 1050°C. The final thickness of the strips varied from 3.7 to 4.0 mm.
  • the hot rolled strips were then cold rolled until a cold reduction of about 75% was obtained. 5 passes were used in the cold rolling mill.
  • the ferrite content was determined by using magnetic scale measurements.
  • the magnetic scale measurement was performed according to IEC 60404-1.
  • the content of magnetic phase was assumed to equal the ferrite content and the remainder was assumed to be austenite. The values are found in Table 2.
  • the strength of the cold rolled strip was determined by tensile tests according to SS EN ISO 6891-1 in the rolling direction. Two tensile test specimens were water jet cut from each cold rolled strip specimen. The results are collected in table 3. As can be seen from the table, all samples had good tensile strength Examples 10 and 12 are reference examples not part of the invention. Table 1: Chemical composition of the samples - all values are given in weight% (wt%).
  • the obtained objects will have a proof stress Rp 0.2 above 1200 MPa after cold rolling thereof.
  • the objects of the present disclosure will have high yield strength in combination with good ductility and also good corrosion resistance and high tensile strength due to the solid solution strengthening and deformation hardening, the phase thickness and content.

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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
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Claims (15)

  1. Gegenstand, hergestellt aus einem Duplex-Edelstahl, wobei der Duplex-Edelstahl die folgende Zusammensetzung in Gew.-% umfasst: C Weniger als oder gleich 0,040; Si Weniger als oder gleich 0,60; Mn 0,80-10,0; Cr 21,0-28,0; Ni 4,0 - 9,0; Mo 0,9-4,5; N 0,1-0,45; Cu Weniger als oder gleich 0,50; V weniger als oder gleich 0,10; P Weniger als oder gleich 0,010; S weniger als oder gleich 0,006;
    Rest Fe und unvermeidbare Verunreinigungen;
    optional kleine Mengen anderer Legierungselemente, die As, Ca, Co, Ti, Nb, W, Sn, Ta, Mg, B, Pb und Ce sind, wobei die Mengen eines oder mehrerer dieser Elemente maximal 0,5 Gew.-% betragen; und wobei der Duplex-Edelstahl aus 55-70 Vol.-% Austenitphase und 30-45 Vol.-% Ferritphase besteht;
    und wobei das Objekt alternierende Schichten aus Ferritphase und Austenitphase aufweist, besagte alternierende Schichten im Wesentlichen parallel zur Ebene des Objekts sind und besagte alternierende Schichten eine mittlere Schichtdicke zwischen etwa 0,01 bis etwa 4,5 µm aufweisen, und wobei "etwa" ± 5 % bedeutet und wobei "im Wesentlichen parallel" bedeutet, dass die Abweichung von der Ebene weniger als 10 % beträgt.
  2. Gegenstand nach Anspruch 1, wobei die Mengen eines oder mehrerer dieser anderen Legierungselemente höchstens 0,1 Gew.-% betragen.
  3. Gegenstand nach Anspruch 1 oder 2, wobei der Duplex-Edelstahl aus 65-70 Vol.-% Austenitphase und 30-35 Vol.-% Ferritphase besteht.
  4. Gegenstand nach einem der Ansprüche 1 bis 3, wobei besagte abwechselnde Schichten eine durchschnittliche Schichtdicke zwischen etwa 0,5 bis etwa 4,5 µm, wie etwa 1,0 bis etwa 4,5 µm, wie etwa 1,0 bis etwa 4,2 µm, aufweisen.
  5. Gegenstand nach einem der Ansprüche 1 bis 4, wobei der Duplex-Edelstahl einen PRE-Wert von mehr als 28 aufweist und wobei PRE als PRE=Cr+3,3Mo+16N definiert ist.
  6. Gegenstand nach einem der Ansprüche 1 bis 5, wobei der Mn-Gehalt im Duplex-Edelstahl im Bereich von 2 bis 5 Gew.-% liegt.
  7. Gegenstand nach einem der Ansprüche 1 bis 6, wobei der N-Gehalt im Duplex-Edelstahl im Bereich von 0,3 bis 0,42 Gew.-% liegt.
  8. Gegenstand nach einem der Ansprüche 1 bis 7, wobei der Mo-Gehalt im Duplex-Edelstahl im Bereich von 2 bis 4 Gew.-% liegt.
  9. Gegenstand nach einem der Ansprüche 1 bis 8, wobei der Cr-Gehalt im Duplex-Edelstahl im Bereich von 24 bis 28 Gew.-% liegt, wie beispielsweise 26 bis 28 Gew.-%.
  10. Gegenstand nach einem der Ansprüche 1 bis 9, wobei der Ni-Gehalt im Duplex-Edelstahl im Bereich von 7,0 bis 9,0 Gew.-% liegt.
  11. Gegenstand nach einem der Ansprüche 1 bis 10, wobei der Gegenstand ein Blech oder Streifen oder Draht ist.
  12. Feder, umfassend den Gegenstand nach einem der Ansprüche 1 bis 11.
  13. Verfahren zur Herstellung eines Gegenstandes nach einem der Ansprüche 1 bis 12, umfassend die Schritte:
    Bereitstellen eines Körpers des Duplex-Edelstahls, wie in einem der Ansprüche 1 bis 11 definiert;
    - ein oder mehrere Warmwalzvorgänge, um den Körper zu einem Werkstück von 2-15 mm umzuformen, wobei das Warmwalzen bei einer Temperatur von etwa 1050 bis etwa 1300 °C durchgeführt wird;
    - ein oder mehrere Kaltwalzvorgänge, um das Werkstück in das Objekt mit einer Dicke von 20 µm - 5 mm umzuformen;
    wobei der letzte Schritt des Verfahrens ein Kaltwalzen sein muss.
  14. Verfahren nach Anspruch 13, wobei das Verfahren auch einen oder mehrere Wärmebehandlungsschritte umfasst, wobei der eine oder die mehreren Wärmebehandlungsschritte ein Glühen ist, das bei einer Temperatur von über 1000 bis 1250 °C bei einer Glühzeit von 1-600 Sekunden durchgeführt wird, und wobei die Zeit, die während des Erhitzens zwischen 750 °C und 1000 °C vergeht, unter 2 Minuten liegt, und wobei der eine oder die mehreren Glühschritte zwischen den Kaltwalzschritten stattfindet.
  15. Verfahren nach einem der Ansprüche 13 bis 14, umfassend einen weiteren Schritt des Alterns des Objekts für 0,25 bis 4 Stunden bei einer Temperatur von 400 °C bis 450 °C, wobei das Altern nach dem letzten Kaltwalzschritt durchgeführt wird.
EP17818553.4A 2016-12-21 2017-12-18 Objekt mit duplexedelstahl und verwendung davon Active EP3559295B1 (de)

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EP16205963 2016-12-21
PCT/EP2017/083408 WO2018114865A1 (en) 2016-12-21 2017-12-18 An object comprising a duplex stainless steel and the use thereof

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JP7266976B2 (ja) * 2018-07-27 2023-05-01 日鉄ステンレス株式会社 スポット溶接部の強度と耐食性に優れたフェライト・オーステナイト二相ステンレス鋼板及びその製造方法
CN111893370B (zh) * 2020-07-09 2022-04-01 洛阳双瑞特种装备有限公司 一种高湿热海洋环境用高氮双相不锈钢制备方法
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JPH02153044A (ja) * 1988-12-02 1990-06-12 Kubota Ltd 亀裂発生抵抗の高い二相ステンレス鋼
CN1201028C (zh) * 2001-04-27 2005-05-11 浦项产业科学研究院 具有优越热加工性能的高锰二联不锈钢及其制造方法
SE524951C2 (sv) * 2001-09-02 2004-10-26 Sandvik Ab Användning av en duplex rostfri stållegering
SE527175C2 (sv) * 2003-03-02 2006-01-17 Sandvik Intellectual Property Duplex rostfri ställegering och dess användning
TWI394848B (zh) * 2007-10-10 2013-05-01 Nippon Steel & Sumikin Sst 雙相不銹鋼線材、鋼線及螺釘以及其製造方法
JP5546178B2 (ja) * 2008-08-04 2014-07-09 新日鐵住金ステンレス株式会社 耐鋳塊割れ性と加工性に優れたフェライト・オーステナイト系ステンレス鋼およびその製造方法
CN102605288B (zh) * 2012-03-13 2015-03-25 宝山钢铁股份有限公司 一种具有良好焊接性的经济型双相不锈钢及其制造方法
JP6302722B2 (ja) * 2014-03-31 2018-03-28 新日鐵住金ステンレス株式会社 ばね疲労特性に優れた高強度複相ステンレス鋼線材、及びその製造方法、ならびにばね疲労特性に優れた高強度複相ステンレス鋼線
CN107429365A (zh) * 2015-04-10 2017-12-01 山特维克知识产权股份有限公司 生产双相不锈钢的管的方法

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WO2018114865A1 (en) 2018-06-28
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US20190323110A1 (en) 2019-10-24
CN110088323B (zh) 2022-03-22

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