EP3519900B1 - Uhrkomponente aus hoch-entropie-legierung - Google Patents
Uhrkomponente aus hoch-entropie-legierung Download PDFInfo
- Publication number
- EP3519900B1 EP3519900B1 EP17745346.1A EP17745346A EP3519900B1 EP 3519900 B1 EP3519900 B1 EP 3519900B1 EP 17745346 A EP17745346 A EP 17745346A EP 3519900 B1 EP3519900 B1 EP 3519900B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- entropy alloy
- following formula
- comprised
- timepiece component
- high entropy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000956 alloy Substances 0.000 title claims description 59
- 229910045601 alloy Inorganic materials 0.000 title claims description 59
- 239000006104 solid solution Substances 0.000 claims description 6
- 238000005275 alloying Methods 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 238000005097 cold rolling Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B1/00—Driving mechanisms
- G04B1/10—Driving mechanisms with mainspring
- G04B1/14—Mainsprings; Bridles therefor
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B1/00—Driving mechanisms
- G04B1/10—Driving mechanisms with mainspring
- G04B1/14—Mainsprings; Bridles therefor
- G04B1/145—Composition and manufacture of the springs
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C27/00—Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
- C22C27/06—Alloys based on chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/30—Ferrous alloys, e.g. steel alloys containing chromium with cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B13/00—Gearwork
- G04B13/02—Wheels; Pinions; Spindles; Pivots
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B29/00—Frameworks
- G04B29/02—Plates; Bridges; Cocks
- G04B29/027—Materials and manufacturing
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B5/00—Automatic winding up
- G04B5/02—Automatic winding up by self-winding caused by the movement of the watch
- G04B5/16—Construction of the weights
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Adornments (AREA)
- Heat Treatment Of Articles (AREA)
- Springs (AREA)
- Heat Treatment Of Steel (AREA)
Claims (8)
- Uhrenkomponente aus einer Hoch-Entropie-Legierung, wobei die Hoch-Entropie-Legierung aus 4 bis 6 Elementen gebildet ist, die eine einzige feste Lösung bilden, und die Hoch-Entropie-Legierung eine Konzentration jedes Hauptelements von 1 bis 55 Atom-% aufweist, wobei die Hoch-Entropie-Legierung der folgenden Formel entspricht: Fe80-xMnxCo10Cr10, wobei x zwischen 25 und 79 Atom-% liegt und x vorzugsweise zwischen 25 und 45 Atom-% liegt.
- Uhrenkomponente nach dem vorhergehenden Anspruch, wobei die Hoch-Entropie-Legierung der folgenden Formel entspricht: FeaMnbCocCrd, wobei a, b, c und d zwischen 1 und 55 Atom-% liegen.
- Uhrenkomponente nach Anspruch 1, wobei die Hoch-Entropie-Legierung der folgenden Formel entspricht: FeaMnbNieCocCrd, wobei a, b, c, d und e zwischen 1 und 55 Atom-% liegen.
- Uhrenkomponente aus einer Hoch-Entropie-Legierung, wobei die Hoch-Entropie-Legierung aus 5 Elementen gebildet ist, die eine einzige feste Lösung bilden, wobei die Hoch-Entropie-Legierung eine Konzentration jedes Hauptelements zwischen 1 und 55 Atom-% aufweist, und die Hoch-Entropie-Legierung der folgenden Formel entspricht: TaaNbbHfcZrdCre, wobei a, b, c, d und e zwischen 1 und 55 Atom-% liegen.
- Uhrenkomponente aus einer Hoch-Entropie-Legierung, wobei die Hoch-Entropie-Legierung aus 5 Elementen gebildet ist, die eine einzige feste Lösung bilden, und die Hoch-Entropie-Legierung eine Konzentration jedes Hauptelements aufweist, die zwischen 1 und 55 Atom-% liegt: AlaLibMgcScdTie, wobei a, b, c, d und e zwischen 1 und 55 Atom-% liegen.
- Uhrenkomponente aus einer Hoch-Entropie-Legierung, wobei die Hoch-Entropie-Legierung aus 6 Elementen gebildet ist, die eine einzige feste Lösung bilden, wobei die Hoch-Entropie-Legierung eine Konzentration jedes Hauptelements zwischen 1 und 55 Atom-% aufweist, und die Hoch-Entropie-Legierung der folgenden Formel entspricht: AlaCobCrcCudFeeNif, wobei a, b, c, d, e und f zwischen 1 und 55 Atom-% liegen.
- Uhrenkomponente nach einem der vorhergehenden Ansprüche, wobei die Hoch-Entropie-Legierung ein oder mehrere Zwischengitterelemente aus den folgenden Elementen enthält: C, N, B.
- Uhrenkomponente nach einem der vorhergehenden Ansprüche, wobei die Hoch-Entropie-Legierung ein oder mehrere Strukturhärtungselemente aus den folgenden Elementen enthält: Ti, AI, Be, Nb.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16191867.7A EP3301520A1 (de) | 2016-09-30 | 2016-09-30 | Uhrkomponente aus hoch-entropie-legierung |
PCT/EP2017/069219 WO2018059795A1 (fr) | 2016-09-30 | 2017-07-28 | Composant horloger comportant un alliage haute entropie |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3519900A1 EP3519900A1 (de) | 2019-08-07 |
EP3519900B1 true EP3519900B1 (de) | 2021-05-05 |
Family
ID=57103844
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16191867.7A Withdrawn EP3301520A1 (de) | 2016-09-30 | 2016-09-30 | Uhrkomponente aus hoch-entropie-legierung |
EP17745346.1A Active EP3519900B1 (de) | 2016-09-30 | 2017-07-28 | Uhrkomponente aus hoch-entropie-legierung |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16191867.7A Withdrawn EP3301520A1 (de) | 2016-09-30 | 2016-09-30 | Uhrkomponente aus hoch-entropie-legierung |
Country Status (6)
Country | Link |
---|---|
US (3) | US20190235441A1 (de) |
EP (2) | EP3301520A1 (de) |
JP (1) | JP6892914B2 (de) |
CN (1) | CN109804321B (de) |
RU (1) | RU2715832C1 (de) |
WO (1) | WO2018059795A1 (de) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH714235A1 (fr) * | 2017-10-13 | 2019-04-15 | Hublot Sa Geneve | Alliage à haute entropie. |
JP7471078B2 (ja) | 2019-12-24 | 2024-04-19 | 山陽特殊製鋼株式会社 | 軟化抵抗、強度と伸びのバランス、耐摩耗性に優れた多元系合金 |
EP4060425A1 (de) | 2021-03-16 | 2022-09-21 | Nivarox-FAR S.A. | Spiralfeder für uhrwerk |
US20220307114A1 (en) * | 2021-03-23 | 2022-09-29 | City University Of Hong Kong | High entropy alloy, method of preparation and use of the same |
CN114058888B (zh) * | 2021-10-25 | 2022-07-05 | 重庆大学 | 一种FeCrCoNiAl高熵合金的冶炼方法 |
CN115121801B (zh) * | 2022-06-15 | 2023-06-23 | 中国人民解放军陆军装甲兵学院 | 铁基材料损伤件的激光增材修复方法及其采用的修复粉末 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB647783A (en) * | 1947-05-03 | 1950-12-20 | Elgin Nat Watch Co | Process of making power springs and other articles of high elastic strength |
CH299223A (de) * | 1952-01-14 | 1954-05-31 | Reinhard Dr Straumann | Verfahren zur Herstellung einer Triebfeder für Uhren sowie nach diesem Verfahren erhaltene Triebfeder. |
FR1151350A (fr) * | 1955-06-11 | 1958-01-29 | Genevoise Degrossissage D Or | Alliage inoxydable présentant une grande résistance à la fatigue et à la déformation et ressort pour mouvement d'horlogerie en cet alliage |
US3928085A (en) * | 1972-05-08 | 1975-12-23 | Suwa Seikosha Kk | Timepiece mainspring of cobalt-nickel base alloys having high elasticity and high proportional limit |
CH621577A5 (de) * | 1976-07-15 | 1981-02-13 | Straumann Inst Ag | |
EP1039352B1 (de) * | 1999-03-26 | 2003-10-08 | Rolex Sa | Selbstkompensierende Spiralfeder für Uhrwerkspiralfederunruh und Verfahren zur Behandlung derselben |
RU2004121454A (ru) * | 2001-12-14 | 2005-06-10 | Эй Ти Ай Пропертиз, Инк. (Us) | Способ обработки бета титановых сплавов |
JP2005140674A (ja) | 2003-11-07 | 2005-06-02 | Seiko Epson Corp | 時計用ばね、ぜんまい、ひげぜんまい、及び時計 |
FR2905707B1 (fr) * | 2006-09-08 | 2009-01-23 | Centre Nat Rech Scient | Procede pour deposer sur un substrat une couche mince d'alliage metallique et alliage metallique sous forme de couche mince. |
CN101320617A (zh) * | 2007-06-08 | 2008-12-10 | 财团法人工业技术研究院 | 软磁薄膜电感器及磁性多元合金薄膜 |
TWI347978B (en) * | 2007-09-19 | 2011-09-01 | Ind Tech Res Inst | Ultra-hard composite material and method for manufacturing the same |
CN102216480B (zh) * | 2008-11-17 | 2014-08-20 | 财团法人电气磁气材料研究所 | 磁性不灵敏高硬度恒弹性合金及其制造方法、以及游丝、机械式驱动装置及钟表 |
CN102776430B (zh) * | 2012-08-20 | 2014-08-06 | 太原理工大学 | AlCoCrFeNiTix高熵合金材料及其制备方法 |
CN102787266A (zh) * | 2012-09-04 | 2012-11-21 | 四川大学 | 基于高熵合金粘结相的碳氮化钛基金属陶瓷及其制备方法 |
CN102796933A (zh) * | 2012-09-04 | 2012-11-28 | 四川大学 | 一种基于高熵合金粘结相的含氮硬质合金及其制备方法 |
CN103194656A (zh) * | 2013-04-19 | 2013-07-10 | 梧州漓佳铜棒有限公司 | AlxCrFeNiCuVTi高熵合金材料及其制备方法 |
EP2813906A1 (de) * | 2013-06-12 | 2014-12-17 | Nivarox-FAR S.A. | Bauteil für Uhrwerk |
CN103556146B (zh) * | 2013-11-06 | 2016-01-20 | 四川建筑职业技术学院 | 制备高熵合金涂层的方法 |
CN104651828B (zh) * | 2013-11-22 | 2017-06-06 | 沈阳工业大学 | 一种铁基合金表面制备高熵合金基复合材料改性层用粉料 |
JP6459272B2 (ja) * | 2014-07-23 | 2019-01-30 | 日立金属株式会社 | 合金構造体 |
KR101728936B1 (ko) * | 2014-07-28 | 2017-04-21 | 세종대학교산학협력단 | 우수한 강도 및 연성을 갖는 하이엔트로피 합금 |
CN104213013B (zh) * | 2014-09-28 | 2016-09-21 | 哈尔滨工业大学 | 一种TiZrNbMoxHfy多主元高温合金及其制备方法 |
CN105671392B (zh) * | 2014-11-19 | 2017-11-03 | 北京科技大学 | 一种氮强化的TiZrHfNb基高熵合金及其制备方法 |
US10190197B2 (en) | 2015-12-11 | 2019-01-29 | The Trustees Of Dartmouth College | Oxidation resistant high-entropy alloys |
CN105950946B (zh) * | 2016-07-01 | 2017-11-21 | 广西大学 | 一种基于组元间偏聚情况进行高熵合金成分设计的方法 |
-
2016
- 2016-09-30 EP EP16191867.7A patent/EP3301520A1/de not_active Withdrawn
-
2017
- 2017-07-28 JP JP2019513437A patent/JP6892914B2/ja active Active
- 2017-07-28 US US16/331,038 patent/US20190235441A1/en not_active Abandoned
- 2017-07-28 RU RU2019112854A patent/RU2715832C1/ru active
- 2017-07-28 CN CN201780059624.2A patent/CN109804321B/zh active Active
- 2017-07-28 WO PCT/EP2017/069219 patent/WO2018059795A1/fr unknown
- 2017-07-28 EP EP17745346.1A patent/EP3519900B1/de active Active
-
2020
- 2020-01-29 US US16/775,657 patent/US11042120B2/en active Active
-
2021
- 2021-02-17 US US17/177,426 patent/US20210263470A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US11042120B2 (en) | 2021-06-22 |
JP2019534378A (ja) | 2019-11-28 |
RU2715832C1 (ru) | 2020-03-03 |
EP3519900A1 (de) | 2019-08-07 |
WO2018059795A1 (fr) | 2018-04-05 |
US20210263470A1 (en) | 2021-08-26 |
CN109804321A (zh) | 2019-05-24 |
US20190235441A1 (en) | 2019-08-01 |
US20200241475A1 (en) | 2020-07-30 |
JP6892914B2 (ja) | 2021-06-23 |
CN109804321B (zh) | 2021-07-27 |
EP3301520A1 (de) | 2018-04-04 |
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