EP3512713B1 - Wertdokument mit sicherheitsmarkierung und verfahren zur identifikation der sicherheitsmarkierung - Google Patents
Wertdokument mit sicherheitsmarkierung und verfahren zur identifikation der sicherheitsmarkierung Download PDFInfo
- Publication number
- EP3512713B1 EP3512713B1 EP17767996.6A EP17767996A EP3512713B1 EP 3512713 B1 EP3512713 B1 EP 3512713B1 EP 17767996 A EP17767996 A EP 17767996A EP 3512713 B1 EP3512713 B1 EP 3512713B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- value
- ratio
- substances
- linear
- security marking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 46
- 239000000126 substance Substances 0.000 claims description 171
- 230000005855 radiation Effects 0.000 claims description 44
- 230000005284 excitation Effects 0.000 claims description 39
- 230000006978 adaptation Effects 0.000 claims description 24
- 238000000295 emission spectrum Methods 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- 238000000695 excitation spectrum Methods 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 230000006399 behavior Effects 0.000 description 37
- 238000004020 luminiscence type Methods 0.000 description 22
- 239000000203 mixture Substances 0.000 description 18
- 238000011156 evaluation Methods 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 11
- 238000005259 measurement Methods 0.000 description 10
- 229910052775 Thulium Inorganic materials 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000013598 vector Substances 0.000 description 6
- 229910052691 Erbium Inorganic materials 0.000 description 5
- 229910052769 Ytterbium Inorganic materials 0.000 description 5
- 229910052779 Neodymium Inorganic materials 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229910052689 Holmium Inorganic materials 0.000 description 3
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- -1 gallates Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 230000002123 temporal effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- 238000010972 statistical evaluation Methods 0.000 description 2
- 229910017119 AlPO Inorganic materials 0.000 description 1
- 229910016066 BaSi Inorganic materials 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- 229910004762 CaSiO Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 229910003668 SrAl Inorganic materials 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 239000005371 ZBLAN Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000011158 quantitative evaluation Methods 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical class [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/373—Metallic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
- G07D7/12—Visible light, infrared or ultraviolet radiation
- G07D7/1205—Testing spectral properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/21—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose for multiple purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/23—Identity cards
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/24—Passports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D2207/00—Paper-money testing devices
Definitions
- the present invention is in the technical field of the production and checking of documents of value and relates to a document of value with a security marking and a method for identifying the same.
- the pamphlet US 7762468 B2 shows an authentication method in which a combination of two luminescent substances with different decay times is used. In this process, the second, slower decaying luminescent substance detected only when the luminescence of the first luminescent substance has already decayed.
- the pamphlet US 9046486 B2 discloses a security marking and a method for identifying the same based on combinations of quasi-resonant luminescent substances with a different exponential decay behavior. With the help of a non-linear adaptation, both the amplitudes and the decay times are determined. The method described is not suitable for marking substances with a strongly non-exponential decay behavior, which limits the number of marking substances available. The analysis by means of non-linear adaptation also proves to be time-consuming and error-prone with regard to noise, so that the speed and quality of the evaluation are low.
- the US 2014/0001351 A1 discloses two luminescent materials intermingled in a security feature.
- the object of the present invention is to enable reliable, secure and rapid identification of the identification of a document of value with luminescent substances with complex time behavior.
- a document of value with a security marking is shown.
- value document means any objects to be protected against undesired or illegal copying, for example banknotes, checks, shares, tokens, ID cards, credit cards and passports as well as labels, seals, packaging or other objects for value protection.
- the security marking of the value document according to the invention can be assigned to at least one freely definable (binary) property of the value document, the property being given in the event of identification (presence of the security marking) and in the case of non-identification (absence the safety marking) is not given.
- the security marking can be assigned to the property “authenticity” as an authenticity marking or authenticity feature in order to recognize value documents as either authentic or forged. It is also conceivable that the security marking assigns value documents, for example, to a specific class or group, such as the note value or country of manufacture of bank notes.
- the security marking is designed in the form of at least two luminescent substances (hereinafter also referred to as luminescent substances).
- the luminescent substances can be incorporated into the value document or attached to the value document in the most varied of ways.
- the luminescent substances can be mixed into a paper or plastic mass for producing the document of value or a printing ink for printing the document of value. It is also conceivable to provide the luminescent substances as, for example, an invisible coating on the document of value.
- the luminescent substances can also be provided on or in a carrier material consisting, for example, of plastic, which is embedded in a paper or plastic compound for producing the document of value.
- the carrier material can be designed, for example, in the form of a security or identification thread, a mottled fiber or planchette.
- the carrier material can also be attached to the value document, for example in the form of a badge, for example in order to undertake a product security measure. In principle, any desired shape of the carrier material is possible.
- the at least two luminescent substances of the security marking can be excited jointly by a (same) excitation pulse (eg light flash). It is essential here that the time courses of the intensities of the emitted radiations of the luminescent substances excited by the excitation pulse differ from one another are, wherein at least one luminescent substance has a non-mono-exponential time course of the intensity of the emitted radiation.
- a excitation pulse eg light flash
- the security marking contains the at least two luminescent substances in a definable or defined quantity ratio in combination (preferably in the form of a mixture). This means that each luminescent substance is present in the security marking in a definable or defined, relative proportion, based on the total amount of luminescent substances.
- the security marking can thus be clearly identified on the basis of the quantitative ratio (mixing ratio) of the luminescent substances.
- each luminescent substance contributes with the intensity of its emitted luminescent radiation to the total intensity of the simultaneously emitted radiations of the excited luminescent substances of the security marking.
- total intensity refers here and in the following to a summary intensity of the luminescence radiation of the luminescent substances contained in combination in the security marking, excited by a (same) excitation pulse and detected at the same point in time.
- the security marking is designed so that, for identification of the security marking, the quantity ratio (mixing ratio) of the luminescent substances is determined by analyzing the time course of the total intensity of the emitted luminescence radiation (excited by an excitation pulse) on the basis of the time progression of the intensities of the luminescence radiation (excited by the same excitation pulse) the luminescent substances can be determined.
- the use of at least one luminescent substance with a non-mono-exponential has the particular advantage that a large number of substances that are suitable in principle are available and that, through the specific selection, improved security against forgery can be achieved. In addition, a relatively large difference in the clinking and / or decay behavior of the luminescent substances can be achieved, which allows reliable and secure identification of the security marking. If the excitation light is re-emitted with an (anti-) Stokes shifted wavelength due to intrinsic conversion processes, a clear separation of the excitation and emission radiation is easily possible by means of suitable filter techniques.
- the at least two luminescent substances are particularly advantageously selected so that the intensity of the emitted radiation of each luminescent substance is in a range from 5% to 95%, preferably 10% to 90%, and particularly preferably 15% to 85%, of the total intensity of the luminescent substances. This enables a particularly precise analysis of the time course of the total intensity of the security marking on the basis of the time course of the intensities of the luminescent radiation emitted by the respective luminescent substances, which contributes to improving the reliability of the identification of the security feature.
- the at least two luminescent substances are preferably selected so that the decay time, ie in particular the time between the end of the excitation pulse and the reaching of an intensity of 1 / e of the intensity at the end of the excitation pulse, is in a range from 100 ns to 100 ms, preferably 10 ⁇ s to 5 ms.
- This is advantageous for a precise analysis of the time course of the total intensity of the emitted luminescent radiation of the luminescent substances on the basis of the time course of the intensities of the luminescent radiation emitted by the respective luminescent substances, which further improves the reliability of the identification of the security feature.
- the at least two luminescent substances have overlapping, in particular identical, excitation spectra, which enables targeted and relatively strong excitation of the luminescent substances by a comparatively narrow-band excitation pulse (flash of light).
- the at least two luminescent substances particularly preferably have overlapping emission spectra, as a result of which the security against forgery of the security feature is advantageously further improved due to a significantly more difficult analysis of the emitted radiation.
- the at least two luminescent substances are designed such that the time courses of the intensities of the emitted radiation over a Bray-Curtis distance of greater than 0.10, preferably greater than 0.20, and particularly preferably greater than 0.25.
- This measure can also increase the accuracy of the analysis of the time course of the total intensity of the emitted luminescent radiation of the luminescent substances of the security marking on the basis of the time course of the intensities of the luminescent radiation emitted by the luminescent substances, which contributes to an even further improvement in the reliability of the identification of the security feature.
- the luminescent substances of the security marking of the document of value according to the invention can in principle be freely selected as long as it is ensured that they can be excited together by an excitation pulse and the time courses of the emitted radiations of the luminescent Substances are different from one another, at least one luminescent substance having a non-mono-exponential time course of the intensity of the emitted radiation.
- the excitation and emission of the luminescent substances can take place in the UV, VIS and / or IR range.
- luminescent substances can be used which are excited in the UV range and emit in the UV range or visible spectral range.
- luminescent substances can be used which are excited in the IR range and emit in the IR range or emit in the visible range (up converters).
- luminescent substances are advantageous which show a particularly strong non-monoexponential decay behavior after excitation.
- luminescent substances which each comprise a host lattice which is doped with at least one dopant selected from the rare earth metals and transition metals (or their ions).
- Suitable inorganic host lattices are, for example, oxides, borates, gallates, phosphates, garnets, perovskites, sulfides, oxysulfides, apatites, vanadates, tungstates, glasses, tantalates, niobates, halides, oxyhalides, in particular fluorides, silicates or aluminates.
- Host lattices such as YAG, ZnS, YGG, YAM, YAP, AlPO 5 , Zeolite, Zn 2 SiO 4 , YVO 4 , CaSiO 3 , KMgF 3 , Y 2 O 2 S, La 2 O 2 S, Ba 2 can be used as the host lattice P 2 O 7 , Gd 2 O 2 S, NaYW 2 O 6 , SrMoO 4 , MgF 2 , MgO, CaF 2 , Y 3 Ga 5 O 12 , KY (WO 4 ) 2 , SrAl 12 O 19 , ZBLAN, LiYF 4 , YPO 4 , GdBO 3 , BaSi 2 O 5 or SrBeO 7 can be used.
- Suitable dopants are, for example, the rare earths La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, or Bi, Pb, Ni, Sn, Sb, W, Tl , Ag, Cu, Zn, Ti, Mn, Cr and V (or their ions).
- Luminescent substances with a strongly non-mono-exponential time behavior of the intensity of the emitted radiation can be implemented by different mechanisms.
- energy transfer processes between different doping ions, in particular rare earth doping ions intrinsically multiple time constants can occur in the attack and decay behavior.
- Such energy transfer processes are, for example, for the doping ion combinations Yb / Er, Nd / Yb, Yb / Tm, Cr / Tm, Tm / Ho, Er / Tm, Er / Ho, Yb / Ho, Cr / Ho, Fe / Tm, Mn / Tm , Cr / Er, Fe / Er, Cr / Nd, Cr / Nd, Cr / Yb, in particular in combination with other doping ions, are known. According to the invention, the use of such doping ion combinations is preferred.
- luminescent substances with complex intrinsic energy transfer processes can show intensity profiles with strongly non-mono-exponential time behavior, wherein the luminescence intensity can increase even further after the end of the excitation phase.
- the combination of such substances together with classical substances, which show a monotonously decreasing behavior after excitation allows a targeted adjustment of the time behavior of the total intensity of the luminescent substances. In addition to falling emission sections, this can also have rises, plateaus, local maxima and / or minima.
- the security marking has a combination of at least one luminescent substance with non-monoexponential time behavior and at least one luminescent substance with monoexponential time behavior of the intensity of the emitted luminescence radiation.
- the security marking can have a combination of at least two luminescent substances, each with a different, non-mono-exponential time behavior of the intensity of the emitted luminescent radiation.
- luminescent substances in which several different transitions of a doping ion, which are very similar in terms of energy but have different lifetimes, contribute to the emission in a narrow wavelength range. These luminescent substances also often show non-mono-exponential time behavior. Examples are Pr and Er.
- luminescent substances can exhibit non-mono-exponential behavior due to inhomogeneities which occur randomly or which are specifically generated during production, for example an inhomogeneous grain size distribution or an inhomogeneous distribution of the dopants. This can occur, for example, when grains with a faster time behavior, ie a faster decay time and / or a faster rise time, as well as grains with a slower time response, ie a slower decay time and / or a slower rise time, arise.
- Their different properties are averaged in the relevant, macroscopic measurement, in which a relatively large number of individual grains are generally excited and measured at the same time. This overlap the individual time structures of the emissions of the individual grains in such a way that overall a non-mono-exponential time behavior can result.
- the person skilled in the art can determine whether or not it has a mono-exponential time behavior.
- the time course of the intensity in the decay phase is measured and an exponential curve is adapted to the decay curve.
- the coefficient of determination R 2 can be used as a measure of the quality of the adaptation, the decay curve being evaluated, for example, as "non-exponential" if R 2 0.98 applies.
- the signal-to-noise ratio at the beginning of the decay curve should be at least 50 so that a fit with a fit quality of R 2 ⁇ 0.98 is not obtained by chance with a mono-exponential decay curve.
- the invention further extends to a method for identifying (i.e. recognizing the presence or absence) of the security marking of a value document formed as described above.
- the procedure consists of the following steps:
- the running index i relates to the luminescent substances, n indicates the number of luminescent substances and t the time.
- the time courses I i (t) of the intensities of the luminescent substances can be determined (in advance) for each luminescent substance by excitation with the same excitation pulse and detection of the luminescence radiation.
- the linear coefficients c i each indicate the relative proportion of a time course I i (t) of an individual luminescent substance in the linear combination I (t).
- the relative proportion of each luminescent substance, based on the total amount of luminescent substances, in the security marking and thus the proportion (eg mixing ratio) of the luminescent substances in the security marking can be determined from the linear coefficients c i .
- the adaptation of the linear combination I (t), consisting of a sum of the known time curves I i (t) weighted with the linear coefficients c i , to the total intensity I (t) of the luminescence radiation emitted at the same time advantageously enables a particularly simple, reliable and very rapid determination of the quantity ratio (eg mixing ratio) of the luminescent substances in the security marking, which enables reliable identification of the security marking.
- the linear coefficients c i are determined in step iii) in such a way that absolute deviations of the linear combination I (t) from data points of the detected time course of the total intensity are minimized.
- the linear coefficients c i are preferably determined by the least squares method in such a way that the sum of the squared deviations of the linear combination I (t) of data points of the total detected intensity is minimized.
- the method of least squares is familiar to those skilled in the field of statistical evaluation of data sets, so that no further explanation is required here.
- this is a statistical standard method for determining a regression curve for a data set with the least possible deviation of the data points from the regression curve.
- step iv) comprises the following sub-steps:
- the ratio Mi is advantageously determined by the ratio of the linear coefficient c i to the sum of at least one, preferably all, linear coefficients c i (for example c 1 / (c 1 + c 2 )).
- the ratios Mi indicate the quantity ratio (eg mixing ratio) of the luminescent substances in the security marking.
- ratio Mi check whether the ratio M i lies within an associated, definable or defined value range W i , which advantageously corresponds to a scatter range around the previously known relative amount of the luminescent substance in the security marking.
- Identifying ie recognizing the presence of the security marking if the attribute “ratio accepted” has been assigned to all ratios M i , or non-identification (ie recognizing the non-existence) of the security marking if at least one ratio M i has the attribute “ratio not accepted "was assigned.
- the sub-steps iv-1) to iv-4) advantageously enable simple and reliable identification of the security marking on the basis of the linear coefficients c i .
- step v) which comprises the following sub-steps:
- the coefficient of determination R 2 is preferably used as the measure G.
- the coefficient of determination R 2 is familiar to those skilled in the field of statistical evaluation of data sets, so that no further explanation is required here.
- the coefficient of determination R 2 is a statistical standard method with which the quality of a linear approximation can be determined.
- Identifying ie recognizing that the safety marking is not present if the dimension G has been assessed with the attribute "Dimension accepted”, or non-identification (ie recognition of the non-presence) of the security marking if the dimension G was evaluated with the attribute “dimension not accepted”.
- sub-step v-4) Identifying the security marking, if all the ratios M i have been evaluated with the attribute “ratio accepted” and the dimension G has also been evaluated with the attribute “dimension accepted”, or non-identification (ie recognition of the non-presence) of the security marking, if at least a ratio M i was evaluated with the attribute “ratio not accepted” and / or the dimension G was evaluated with the attribute “dimension not accepted”.
- step v in particular in connection with sub-steps iv-1) to iv-4), the reliability of the identification of the security marking can be improved even further in a particularly advantageous manner.
- a total intensity can be used as a function of time (that is to say the Linear combination I (t)) can be defined and assigned to an item of information (e.g. authenticity).
- the linear combination I (t) is a combination of the time courses of the intensities I i (t) of the luminescent substances with the linear coefficients c i of the luminescent substances.
- the proportions of the luminescent substances are determined based on the defined linear combination I (t).
- the predetermined, desired linear combination I (t) thus results in a defined quantitative ratio and defined quantitative proportions of the luminescent substances.
- the respective time courses of the intensities I i (t) of the luminescent substances and, if applicable, the respective linear coefficients c i are considered and / or evaluated.
- a combination of the luminescent substances can thus be defined with the aid of a database in which the time courses of the intensities I i (t) are stored.
- the relative proportion of the respective luminescent substance can then be defined with the aid of the linear coefficients c i . It can be taken into account that in order to adjust the intensity I i (t) of the luminescent substance, it is provided with so-called camouflage substances.
- camouflage substances cause a reduction in the luminescence intensity of the luminescent substance, in particular by a factor that is constant over time, so that, depending on the amount of camouflage substance, the linear coefficient c i results in a different relative proportion for the respective luminescent substance.
- Fig. 1 considered, in which the measured time courses of the intensities of the emitted luminescence radiation from two different luminescent substances A, B are exemplified.
- the intensity I is plotted against the time t (in any time and intensity units).
- the measured data points are each connected to one another by a solid data line.
- the luminescent radiation of the two luminescent substances A, B are excited together by a single or the same excitation pulse (light flash).
- the duration and intensity of the excitation pulse are illustrated by the dashed lines.
- the duration of the flash of light is preferably in the range from 10 ⁇ s to 10 ms and is, for example, 40 ⁇ s.
- the time courses of the intensities of the two luminescent substances differ greatly from one another, with both luminescent substances showing a non-monoexponential emission behavior.
- the time courses of the intensities of the two luminescent substances have a Bray-Curtis distance of 0.25, which reflects a low and therefore preferred correlation behavior of the two emission courses.
- Fig. 2 shows the measured time course of the total intensity of the simultaneously emitted radiation of a mixture of the two luminescent substances A, B in the It diagram.
- the combination of the two luminescent substances A, B can be used as a security marking for a document of value.
- the excitation pulse for the joint excitation of the two luminescent substances A, B (which is the same as the excitation pulse in FIG Fig. 1 ) and an adaptation curve drawn in with a solid line.
- the luminescent substance A is present with a mixed proportion of 30% and the luminescent substance B with a mixed proportion of 70%, in each case based on the total amount of the luminescent substances A, B.
- the (previously known) quantity (mixing ratio) of the luminescent substances A, B is therefore 30% / 70%.
- the measurements of the total intensity take place at defined times.
- the measurements can take place at equidistant points in time, but also at non-equidistant points in time, the latter offering the advantage that, for example, with limited memory resources in the detection sensor, a reduced amount of data can be selected without significantly impairing the quality of adaptation.
- more measurement points are preferably taken in time segments in which the intensity profiles of the base substances differ greatly, whereas fewer measurement points are taken during the decay phase long after the excitation, when the luminescence has already decayed far.
- the formula (A) used for the linear adaptation is a linear combination of (sampled) basis vectors Ii (t).
- the index i characterizes the luminescent substances.
- the basic vectors I i (t) are definable or defined (previously known) time courses of the luminescent substances used and preferably result from beforehand determined temporal intensity measurements of the luminescent substances used.
- the basis vectors I i (t) are each to be weighted with the associated linear coefficients c i .
- the basic vectors I i (t) correspond to the previously known time courses I A (t), I B (t) of the two luminescent substances A, B, as shown in FIG Fig. 1 are shown.
- An adaptation of the linear combination I (t) to the data points of the measured total intensity requires a determination of the linear coefficients c i , which in the present case is carried out using the least squares method (least square fit method).
- the linear coefficients c i can hereby be determined in an efficient manner with a good adaptation of the compensation curve.
- the relative mixing proportions of the luminescent substances used in the security marking result from the linear coefficients c i , in each case based on the total amount of luminescent substances.
- the linear coefficients c i determined are combined as 2-tuples (c 1 , c 2 ) and converted into a scaling-independent value, a ratio M i .
- M 2 1 - M. 1
- a check is then made for the ratio M 1 or M 2 as to whether the ratio lies within an associated, definable or defined (predetermined) value range W 1 or W 2 .
- the value ranges W 1 , W 2 each indicate a scatter range around the previously known mixing proportions of the luminescent substances A, B in the security marking. Then, for the checked ratio M 1 or M 2, the attribute “ratio accepted” is assigned if the ratio lies within the associated value range, or the attribute “ratio not accepted” if the ratio lies outside the associated value range. In the present case, the ratios M 1 , M 2 are within the associated value ranges W 1 , W 2 , ie the correct, ie previously known, proportions of the two luminescent substances A, B, each based on the total amount of the luminescent substances A, B, were found within the scope of the scatter , or the previously known quantity ratio (mixing ratio) A / B is determined.
- the quality of the adaptation of the linear combination I (t) to the time curve of the total intensity of the two luminescent substances A, B is determined.
- the security marking is thus clearly identified (ie is present), since the ratio M 1 , M 2 has been assigned the attribute “ratio accepted” and the quality of the adaptation is above the desired threshold value. Due to the need for both conditions to be present (attribute ratio, quality of adaptation), a particularly high level of reliability can be achieved in the identification of the security marking.
- the mixing proportions of the luminescent substances A, B, C, in this order are 20%, 50%, 30%, in each case based on the total amount of luminescent substances.
- the mixing ratio A / B / C is therefore 20% / 50% / 30%.
- the combined intensity behavior was measured with a signal-to-noise ratio of approx. 20.
- the measurement data are in Fig. 4 shown. Following this, the above-mentioned linear combination of the general formula A with three basis vectors I A (t), I B (t), I C (t), as shown in Fig. 3 are adjusted, the linear coefficients c 1 , c 2 c 3 being determined by the least squares method.
- an elliptically shaped tolerance range for example, is defined in an ab plane (see FIG Fig. 5 ). Due to the shape of the temporal intensity behavior, this can be differently extended in different directions.
- the measured mixture tuple is represented by the filled circle, the target value (previously known mixture tuple) by the empty circle.
- the attribute “ratio accepted” is assigned if the ratio lies within the associated value range, or the attribute “ratio not accepted” if the ratio lies outside the associated value range.
- the two ratios M 1 , M 2 are within the associated value ranges W 1 , W 2 , the correct, ie previously known, relative mixing proportions of the two luminescent substances A, B, each based on the total amount of luminescent substances A, B, C were determined.
- the security marking has the previously known composition, with which the security marking was identified.
- Fig. 6 upper figure, taken.
- noise components with different normal distribution were added to the measurement points in a decay curve of a mixture of two luminescent substances with mono-exponential decay behavior.
- An evaluation was carried out using a linear adaptation method according to the present invention and a non-linear adaptation method known in the prior art.
- Fig. 6 lower figure, the evaluation is illustrated in a diagram in which the relative mixing proportion of a luminescent substance is plotted against the noise level. It can be seen that the determination of the relative mixing proportion according to the invention shows a lower susceptibility to noise compared to the method known in the prior art.
- Fig. 7 shows the time behavior of a mono-exponentially decaying luminescent substance that could be used, for example, for a counterfeit attack.
- Fig. 8 shows a value document 1 in the form of a bank note, for example, which has an identification thread 2 with a security marking 3.
- the security marking 3 can be designed as described above.
- the invention offers great advantages over the evaluation methods known in the prior art with non-linear adaptation in which, in addition to the amplitudes of the temporal intensity spectra, the decay times are also used as model parameters.
- a much faster and more stable evaluation ie faster convergence behavior of the adaptation routine
- predetermined time behavior in particular decay curves
- a quantitative evaluation results in a computing time reduced by approx. 3 orders of magnitude compared to the non-linear adaptation known in the prior art, which increases the efficiency with regard to the evaluation speed clarified.
- a fast evaluation method is essential, for example for the analysis on fast-running banknote processing machines with bank notes moving up to 12 m / s, since these essentially determine the processing speed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL17767996T PL3512713T3 (pl) | 2016-09-14 | 2017-09-14 | Dokument wartościowy z oznakowaniem zabezpieczającym i sposób identyfikacji oznakowania zabezpieczającego |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016011180.1A DE102016011180A1 (de) | 2016-09-14 | 2016-09-14 | Wertdokument mit Sicherheitsmarkierung und Verfahren zur Identifikation der Sicherheitsmarkierung |
PCT/EP2017/001087 WO2018050283A1 (de) | 2016-09-14 | 2017-09-14 | Wertdokument mit sicherheitsmarkierung und verfahren zur identifikation der sicherheitsmarkierung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3512713A1 EP3512713A1 (de) | 2019-07-24 |
EP3512713B1 true EP3512713B1 (de) | 2020-12-16 |
Family
ID=59887187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17767996.6A Active EP3512713B1 (de) | 2016-09-14 | 2017-09-14 | Wertdokument mit sicherheitsmarkierung und verfahren zur identifikation der sicherheitsmarkierung |
Country Status (11)
Country | Link |
---|---|
US (1) | US10766294B2 (ru) |
EP (1) | EP3512713B1 (ru) |
KR (1) | KR102265444B1 (ru) |
CN (1) | CN109863037B (ru) |
DE (1) | DE102016011180A1 (ru) |
ES (1) | ES2843602T3 (ru) |
HU (1) | HUE053301T2 (ru) |
PL (1) | PL3512713T3 (ru) |
PT (1) | PT3512713T (ru) |
RU (1) | RU2712380C1 (ru) |
WO (1) | WO2018050283A1 (ru) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102018007289A1 (de) * | 2018-09-14 | 2020-03-19 | Giesecke+Devrient Currency Technology Gmbh | Wertdokumentsystem |
DE102020131382A1 (de) * | 2020-11-26 | 2022-06-02 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Methode zur Kennzeichnung von Produkten mit optischem Sicherheitsmerkmal mit zeitlicher Dimension |
DE102021107759B4 (de) | 2020-12-22 | 2024-01-18 | PicoQuant Innovations GmbH | Verfahren zum Ermitteln von Lumineszenzlebensdauern einer lumineszenten Probe |
CN113035480B (zh) * | 2021-02-26 | 2022-02-11 | 中国科学院江西稀土研究院 | 一种磁制冷材料及其制备方法和应用 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997039428A1 (en) | 1996-04-15 | 1997-10-23 | De La Rue International Limited | Document of value |
EP1158459A1 (en) | 2000-05-16 | 2001-11-28 | Sicpa Holding S.A. | Method, device and security system, all for authenticating a marking |
WO2005035271A2 (de) | 2003-10-08 | 2005-04-21 | Giesecke & Devrient Gmbh | Codierungssystem für wertdokumente |
WO2005036479A2 (de) | 2003-10-08 | 2005-04-21 | Giesecke & Devrient Gmbh | Wertdokument |
EP1616929A2 (en) | 2004-07-13 | 2006-01-18 | Fabrica Nacional De Moneda Y Timbre - Real Casa De La Moneda | Luminescent pigments used in security documents, the process and device used to detect them |
WO2006024530A1 (en) | 2004-09-02 | 2006-03-09 | Giesecke & Devrient Gmbh | Value document with luminescent properties |
DE102006047851A1 (de) | 2006-10-10 | 2008-04-17 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in Form von lumineszierenden Substanzen |
WO2011082794A1 (de) | 2009-12-16 | 2011-07-14 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in form von lumineszierenden substanzen |
US20130015789A1 (en) | 2010-03-26 | 2013-01-17 | Panasonic Corporation | Electric tool |
US20140001351A1 (en) | 2012-06-27 | 2014-01-02 | Authentix Inc. | Security aspects of multiexponential decays |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04502260A (ja) | 1989-10-16 | 1992-04-23 | アムジエン・インコーポレーテツド | N―アセチルムラミダーゼ m1 |
US6091563A (en) | 1997-09-26 | 2000-07-18 | Iomega Corporation | Latent illuminance discrimination marker system for data storage cartridges |
DE19804021A1 (de) * | 1998-02-02 | 1999-08-05 | Giesecke & Devrient Gmbh | Wertdokument |
US7213757B2 (en) | 2001-08-31 | 2007-05-08 | Digimarc Corporation | Emerging security features for identification documents |
DE10326983A1 (de) * | 2003-06-12 | 2004-12-30 | Giesecke & Devrient Gmbh | Wertdokument mit einem maschinenlesbaren Echtheitskennzeichen |
EP1632908A1 (en) | 2004-09-02 | 2006-03-08 | Giesecke & Devrient GmbH | Value document with luminescent properties |
DE102007000888A1 (de) | 2007-11-12 | 2009-05-14 | Bundesdruckerei Gmbh | Dokument mit einer integrierten Anzeigevorrichtung |
WO2012003854A1 (de) * | 2010-07-09 | 2012-01-12 | Giesecke & Devrient Gmbh | Sicherheitsmerkmal |
DE102010026627A1 (de) * | 2010-07-09 | 2012-01-12 | Giesecke & Devrient Gmbh | Alkalimetall-und Erdalkalimetall-Niobate und -Tantalate als Sicherheitmerkmalsstoffe |
US20130015651A1 (en) | 2011-07-15 | 2013-01-17 | Honeywell International Inc. | Luminescent phosphor compounds, articles including such compounds, and methods for their production and use |
DE102012013244A1 (de) * | 2012-07-03 | 2014-01-09 | Giesecke & Devrient Gmbh | Wertdokument, Verfahren zur Überprüfung des Vorliegens desselben und Wertdokumentsystem |
DE102014018726A1 (de) * | 2014-12-16 | 2016-06-16 | Giesecke & Devrient Gmbh | Vorrichtung und Verfahren zur Prüfung von Merkmalsstoffen |
US9382432B1 (en) * | 2015-09-21 | 2016-07-05 | Ubiqd, Llc | Quantum dot security inks |
-
2016
- 2016-09-14 DE DE102016011180.1A patent/DE102016011180A1/de active Pending
-
2017
- 2017-09-14 RU RU2019110248A patent/RU2712380C1/ru active
- 2017-09-14 PL PL17767996T patent/PL3512713T3/pl unknown
- 2017-09-14 ES ES17767996T patent/ES2843602T3/es active Active
- 2017-09-14 KR KR1020197007769A patent/KR102265444B1/ko active IP Right Grant
- 2017-09-14 CN CN201780064057.XA patent/CN109863037B/zh active Active
- 2017-09-14 PT PT177679966T patent/PT3512713T/pt unknown
- 2017-09-14 US US16/332,869 patent/US10766294B2/en active Active
- 2017-09-14 WO PCT/EP2017/001087 patent/WO2018050283A1/de unknown
- 2017-09-14 HU HUE17767996A patent/HUE053301T2/hu unknown
- 2017-09-14 EP EP17767996.6A patent/EP3512713B1/de active Active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997039428A1 (en) | 1996-04-15 | 1997-10-23 | De La Rue International Limited | Document of value |
EP1158459A1 (en) | 2000-05-16 | 2001-11-28 | Sicpa Holding S.A. | Method, device and security system, all for authenticating a marking |
WO2005035271A2 (de) | 2003-10-08 | 2005-04-21 | Giesecke & Devrient Gmbh | Codierungssystem für wertdokumente |
WO2005036479A2 (de) | 2003-10-08 | 2005-04-21 | Giesecke & Devrient Gmbh | Wertdokument |
EP1616929A2 (en) | 2004-07-13 | 2006-01-18 | Fabrica Nacional De Moneda Y Timbre - Real Casa De La Moneda | Luminescent pigments used in security documents, the process and device used to detect them |
WO2006024530A1 (en) | 2004-09-02 | 2006-03-09 | Giesecke & Devrient Gmbh | Value document with luminescent properties |
DE102006047851A1 (de) | 2006-10-10 | 2008-04-17 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in Form von lumineszierenden Substanzen |
WO2011082794A1 (de) | 2009-12-16 | 2011-07-14 | Giesecke & Devrient Gmbh | Echtheitsmerkmal in form von lumineszierenden substanzen |
US20130015789A1 (en) | 2010-03-26 | 2013-01-17 | Panasonic Corporation | Electric tool |
US20140001351A1 (en) | 2012-06-27 | 2014-01-02 | Authentix Inc. | Security aspects of multiexponential decays |
Non-Patent Citations (3)
Title |
---|
"Fluorescence Lifetime MEASUREMENT SOFTWARE U11487-01 Instruction Manual", HAMAMATSU PHOTONICS K. K., May 2018 (2018-05-01), XP055848188 |
"Quantaurus-Tau. Fluorescence lifetime spectrometer. C 11367 series", HAMAMATSU PHOTONICS K. K., 2016, pages 1 - 8, XP055848184 |
SIRMANE LIANA: "Vacuum ultraviolet excitation spectroscopy of nanostructured complex oxide phosphors", PHD THESIS, 2017, XP055848180 |
Also Published As
Publication number | Publication date |
---|---|
US10766294B2 (en) | 2020-09-08 |
CN109863037A (zh) | 2019-06-07 |
WO2018050283A1 (de) | 2018-03-22 |
DE102016011180A1 (de) | 2018-03-15 |
EP3512713A1 (de) | 2019-07-24 |
RU2712380C1 (ru) | 2020-01-28 |
CN109863037B (zh) | 2020-12-22 |
PT3512713T (pt) | 2021-01-05 |
ES2843602T3 (es) | 2021-07-19 |
KR20190039291A (ko) | 2019-04-10 |
HUE053301T2 (hu) | 2021-06-28 |
PL3512713T3 (pl) | 2021-05-04 |
KR102265444B1 (ko) | 2021-06-15 |
US20190358990A1 (en) | 2019-11-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3612398B1 (de) | Wertdokument mit sicherheitsmarkierung mit variierender abklingzeit und verfahren zum identifizieren der sicherheitsmarkierung | |
EP3512713B1 (de) | Wertdokument mit sicherheitsmarkierung und verfahren zur identifikation der sicherheitsmarkierung | |
EP2512821B1 (de) | Echtheitsmerkmal in form von lumineszierenden substanzen | |
EP2591067A1 (de) | Sicherheitsmerkmal | |
EP2869997B1 (de) | Wertdokument, verfahren zur überprüfung des vorliegens desselben und wertdokumentsystem | |
EP2655549B1 (de) | Sicherheitsmerkmal | |
WO2020052812A1 (de) | Wertdokumentsystem | |
WO2014180557A1 (de) | Verfahren zur markierung eines merkmalsstoffes, sicherheitsmerkmal, wertdokument und verfahren zur prüfung desselben | |
EP4026882B1 (de) | Echtheitsmerkmal und verfahren zum prüfen eines echtheitsmerkmals | |
EP3049253B1 (de) | Wertdokument und verfahren zur überprüfung des vorliegens desselben | |
EP2794777A1 (de) | Sicherheitsmerkmal mit mehreren komponenten | |
DE102016007099A1 (de) | Verfahren zur Absicherung von Wertdokumenten mit Speicherleuchtstoffen | |
EP1631719B1 (de) | Wertdokument mit einem sicherheitselement und verfahren zur herstellung des wertdokuments | |
EP3049503B1 (de) | Wertdokument und verfahren zur überprüfung des vorliegens desselben | |
EP2794776A1 (de) | Sicherheitsmerkmal mit mehreren komponenten | |
EP3535735B1 (de) | Verfahren zur echtheitsprüfung eines sicherheitsmerkmals und anordnung zur echtheitsprüfung eines sicherheitsdokuments mit einem sicherheitsmerkmal | |
DE102016007063A1 (de) | Verfahren zur Absicherung von Wertdokumenten mit Speicherleuchtstoffen | |
EP2794775B1 (de) | Sicherheitsmerkmal mit mehreren komponenten | |
EP3866126A1 (de) | Verfahren zum überprüfen eines smartphone-verifizierbaren sicherheitsmerkmals, smartphone-verifizierbares sicherheitsmerkmal und wert- oder sicherheitsdokument |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20190415 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20200723 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502017008711 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Ref document number: 3512713 Country of ref document: PT Date of ref document: 20210105 Kind code of ref document: T Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20201229 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1345243 Country of ref document: AT Kind code of ref document: T Effective date: 20210115 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210317 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210316 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20201216 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
REG | Reference to a national code |
Ref country code: HU Ref legal event code: AG4A Ref document number: E053301 Country of ref document: HU |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2843602 Country of ref document: ES Kind code of ref document: T3 Effective date: 20210719 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R026 Ref document number: 502017008711 Country of ref document: DE |
|
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210416 |
|
26 | Opposition filed |
Opponent name: SICPA HOLDING SA Effective date: 20210913 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20210930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20210416 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210914 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210914 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210930 |
|
RAP4 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: GIESECKE+DEVRIENT CURRENCY TECHNOLOGY GMBH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PK Free format text: TITEL |
|
APBM | Appeal reference recorded |
Free format text: ORIGINAL CODE: EPIDOSNREFNO |
|
APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230520 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |
|
APBQ | Date of receipt of statement of grounds of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA3O |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20230906 Year of fee payment: 7 Ref country code: GB Payment date: 20230921 Year of fee payment: 7 Ref country code: CZ Payment date: 20230901 Year of fee payment: 7 Ref country code: BG Payment date: 20230915 Year of fee payment: 7 Ref country code: AT Payment date: 20230915 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20230921 Year of fee payment: 7 Ref country code: PT Payment date: 20230912 Year of fee payment: 7 Ref country code: PL Payment date: 20230901 Year of fee payment: 7 Ref country code: HU Payment date: 20230911 Year of fee payment: 7 Ref country code: FR Payment date: 20230918 Year of fee payment: 7 Ref country code: DE Payment date: 20230930 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: MT Payment date: 20230919 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20231019 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20230929 Year of fee payment: 7 Ref country code: CH Payment date: 20231001 Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20201216 |