EP3433557B1 - System for treating a gas produced by the evaporation of a cryogenic liquid and for supplying a gas engine with pressurised gas - Google Patents
System for treating a gas produced by the evaporation of a cryogenic liquid and for supplying a gas engine with pressurised gas Download PDFInfo
- Publication number
- EP3433557B1 EP3433557B1 EP17716577.6A EP17716577A EP3433557B1 EP 3433557 B1 EP3433557 B1 EP 3433557B1 EP 17716577 A EP17716577 A EP 17716577A EP 3433557 B1 EP3433557 B1 EP 3433557B1
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- EP
- European Patent Office
- Prior art keywords
- gas
- exchanger
- liquid
- heat exchanger
- compressed
- Prior art date
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- 239000007788 liquid Substances 0.000 title claims description 61
- 238000001704 evaporation Methods 0.000 title claims description 16
- 230000008020 evaporation Effects 0.000 title claims description 13
- 239000007789 gas Substances 0.000 claims description 170
- 230000006835 compression Effects 0.000 claims description 32
- 238000007906 compression Methods 0.000 claims description 32
- 238000001816 cooling Methods 0.000 claims description 20
- 239000007791 liquid phase Substances 0.000 claims description 19
- 238000011144 upstream manufacturing Methods 0.000 claims description 18
- 239000012530 fluid Substances 0.000 claims description 13
- 239000007792 gaseous phase Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 230000008016 vaporization Effects 0.000 claims description 7
- 238000009834 vaporization Methods 0.000 claims description 4
- 230000009347 mechanical transmission Effects 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 32
- 239000003949 liquefied natural gas Substances 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000003345 natural gas Substances 0.000 description 15
- 239000003507 refrigerant Substances 0.000 description 13
- 239000012071 phase Substances 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 239000000446 fuel Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 3
- 238000005057 refrigeration Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000004378 air conditioning Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IKVXBIIHQGXQRQ-UHFFFAOYSA-N propan-2-yl 2-(n-benzoyl-3-chloro-4-fluoroanilino)propanoate Chemical compound C=1C=C(F)C(Cl)=CC=1N(C(C)C(=O)OC(C)C)C(=O)C1=CC=CC=C1 IKVXBIIHQGXQRQ-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
- F25J1/0025—Boil-off gases "BOG" from storages
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
- F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0221—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop
- F25J1/0224—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop in combination with an internal quasi-closed refrigeration loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
- F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
- F25J1/023—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the combustion as fuels, i.e. integration with the fuel gas system
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0275—Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
- F25J1/0277—Offshore use, e.g. during shipping
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
- F25J1/0288—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0292—Refrigerant compression by cold or cryogenic suction of the refrigerant gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0294—Multiple compressor casings/strings in parallel, e.g. split arrangement
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0296—Removal of the heat of compression, e.g. within an inter- or afterstage-cooler against an ambient heat sink
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/62—Liquefied natural gas [LNG]; Natural gas liquids [NGL]; Liquefied petroleum gas [LPG]
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/08—Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/30—Compression of the feed stream
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/02—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams using a pump in general or hydrostatic pressure increase
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/60—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being (a mixture of) hydrocarbons
Definitions
- the present invention relates to a system and a method for treating gas resulting from the evaporation of a cryogenic liquid and for supplying pressurized gas to a gas engine.
- the field of the present invention is more particularly the maritime transport of cryogenic liquids and even more particularly of Liquefied Natural Gas (LNG).
- LNG Liquefied Natural Gas
- the systems and methods which will be proposed later could also find applications in terrestrial installations.
- LNG carriers use the natural gas they transport as fuel to ensure their propulsion.
- engine that run on natural gas.
- the present invention relates more particularly to those which are supplied with natural gas in a high pressure gaseous phase.
- gas is pumped out of a liquefied natural gas tank on board the LNG carrier, then is pressurized using a pump before being vaporized in order to be able to power the motor.
- the document EP-2 746 707 A1 is interested in a natural gas evaporating from liquefied natural gas storage tanks, typically arranged on board a seagoing vessel, which is compressed in a compressor with several compression stages. At least part of the compressed natural gas stream being sent to a liquefier, which typically operates according to a Brayton cycle, in order to be reliquefied. The temperature of the compressed natural gas coming from the final stage is reduced to a value below 0 ° C by passing through a heat exchanger.
- the first compression stage here functions as a cold compressor, and the resulting cold compressed natural gas is used in the heat exchanger so as to provide the necessary cooling of the flow from the compression stage.
- the cold compressed natural gas Downstream of its passage through the heat exchanger, the cold compressed natural gas circulates through the remaining stages of the compressor. If desired, part of the compressed natural gas can be used as fuel to supply the engines of the ocean-going vessel. In an alternative embodiment ( ⁇ [0026]), it is planned to cool the compressed gas in the gaseous state. before its liquefaction with partly compressed liquid before it is expanded for use in an engine or turbine.
- a refrigerant loop with nitrogen in the Brayton cycle implies providing specific equipment for the refrigerant. So, for example, when a nitrogen refrigerant circuit is provided on board a ship (or elsewhere), a nitrogen treatment (purification) unit is necessary to allow its use in the cryogenic field. It is also advisable to provide a specific tank, valves and other devices for regulating the circulation of nitrogen.
- the object of the present invention is therefore to provide an optimized system making it possible to reliquefy gas which has evaporated and to supply a gas engine under high pressure.
- the proposed system will make it possible to optimize the quantity of liquid recovered with regard to the portion of gas to be reliquefied.
- the proposed system could also be used on board a ship such as an LNG carrier.
- the system will operate without using a refrigerant such as nitrogen or the like to avoid having two separate circuits with fluids of different natures.
- the proposed solution will also preferably not be more expensive to produce than the solutions of the prior art.
- the present invention provides a system for treating a gas resulting from the evaporation of a cryogenic liquid and for supplying pressurized gas to a gas engine, said system comprising, on the one hand, from upstream to downstream, a reliquefaction unit with compression means, a first heat exchanger and expansion means, and, on the other hand, a pressurized gas supply line comprising from upstream to downstream a pump for putting liquid under pressure and high pressure vaporization means.
- the pressurized gas supply line has, upstream of the vaporization means, a bypass for supplying a second heat exchanger between, on the one hand, liquid under pressure from the supply line and , on the other hand, a line of the reliquefaction unit downstream of the first heat exchanger and upstream of the expansion means, characterized in that the gas resulting from the evaporation of a cryogenic liquid, then compressed and cooled is condensed at least partially within the first heat exchanger (17).
- the proposed solution makes it possible to create a synergy between the reliquefaction of the gas which has evaporated and the production of gas under pressure to supply an engine, for example a MEGI engine. Indeed, on the one hand there are needs to cool the gas and on the other hand there are needs to heat the liquid before vaporizing it.
- the second proposed exchanger thus makes it possible both to limit the (cooling) requirements of the reliquefaction unit and the (heat) requirements of the high pressure gas supply line.
- This pressurized liquid must then be relaxed in order to be able to be reintroduced into the reservoirs which are substantially at atmospheric pressure (just a little above to prevent air from entering the interior).
- part of the condensed gas is vaporized.
- this gas is subcooled and this makes it possible to limit, during expansion, the portion of condensed gas which revaporates.
- the bypass can supply a cooling system downstream of the second exchanger. It may for example be a third exchanger mounted in series with and downstream of the second exchanger and / or a heat exchanger mounted in parallel with the second exchanger.
- a particular variant of a system as described above provides that it further comprises, downstream of the expansion means, a balloon separating the gas phase from the liquid phase in the expanded fluid; that a line conducts the gas phase to a collector to mix it with the gas resulting from the evaporation of the cryogenic liquid, and that the bypass supplies a heat exchanger to cool the gas phase before its introduction into the collector.
- the system described above is particularly well suited to a reliquefaction unit which uses as coolant the same fluid as the fluid to be liquefied.
- said unit thus comprises for example, downstream of its compression means, a bypass to a loop comprising second expansion means, and the loop joins the circuit upstream of the compression means after passing through the first heat exchanger. heat in the opposite direction to the fraction of gas in the circuit not diverted by the loop.
- the compression means to include several compression stages each with a compression wheel
- the second expansion means to include an expansion turbine and for each compression wheel and the expansion turbine are associated with the same mechanical transmission.
- This third exchanger makes it possible to increase the exchanges and thus to optimize the system.
- the third heat exchanger can be mounted in parallel with the second heat exchanger and according to another alternative variant embodiment, the third heat exchanger may be mounted in series with the second heat exchanger.
- the present invention also relates to a ship, in particular an LNG carrier, propelled by a gas engine, characterized in that it comprises a system for treating a gas resulting from the evaporation of a cryogenic liquid and for supplying gas. under pressure from a gas engine as described above.
- the present invention proposes a method for treating a gas flow resulting from the evaporation of a cryogenic liquid and for supplying a high pressure gas to an engine, said gas flow being first of all compressed. then cooled and condensed at least partially within a first heat exchanger before being expanded, and the supply of gas under high pressure being carried out by pressurizing cryogenic liquid then by vaporizing it, and after its compression, the flow of liquid under pressure being separated into a first part of liquid flow and a second part of liquid flow, and the first part of the liquid flow being used to cool compressed and condensed gas within a second exchanger before expansion of the condensed gas, and the second part of the liquid flow receiving the first part of the liquid flow after the latter has cooled compressed gas, the whole of the liquid flow then being vaporized.
- the flow of pressurized liquid is also used to cool gas before it is condensed.
- part of the compressed gas is taken from within the first exchanger to be expanded within an expansion turbine, and that the expanded gas is introduced into the first exchanger. against the current to cool the compressed gas and cause it to condense.
- the fluid to be reliquefied is also used as refrigerant fluid and it is then not necessary to provide a refrigerant circuit using another fluid to allow reliquefaction.
- FIGS. 1 to 8 are each a schematic view, according to several variants, of a cryogenic liquid reservoir associated with a system for recovering the gas evaporating from said reservoir, with a system for treating part of the gas recovered to liquefy it and with a line high pressure gas supply to a gas engine.
- a reservoir 1 is illustrated. Throughout the remainder of the description, it will be assumed that this is a Liquefied Natural Gas (or LNG) tank among several other similar tanks on board an LNG-type ocean-going vessel.
- LNG Natural Gas
- the tank 1 stores the LNG at a temperature of the order of -163 ° C which corresponds to the usual storage temperature of LNG at a pressure close to atmospheric pressure. This temperature obviously depends on the composition of the natural gas and the storage conditions.
- the atmosphere around tank 1 being at a much higher temperature than that of LNG, although tank 1 is very well thermally insulated, calories are added to the liquid which heats up and vaporizes.
- the volume of gas evaporating being much greater than that of the corresponding liquid, the pressure in the reservoir 1 therefore tends to increase as time passes and as calories are added to the liquid.
- the gas which evaporates is gradually withdrawn from tank 1 (and from the other tanks of the ship) and is found in a manifold 2 connected to several tanks.
- the gas which has evaporated is called “gas” even when it is subsequently reliquefied. It can thus be distinguished from LNG which is taken in liquid form from the tanks to supply an engine.
- the aim here is to avoid losing the evaporated gas and therefore either using it on board the ship, or recovering it and returning it, in the liquid phase, to the tank 1.
- first compression unit 3 which can be, as illustrated in the drawing, multistage.
- the gas passes through a intercooler 4 in which it is cooled without significantly modifying its pressure.
- the gas which has been reheated during its compression is at a temperature of the order of 40 to 45 ° C. at the outlet of the intercooler (these values are given purely by way of illustration and apply in particular for natural gas).
- the gas thus compressed and cooled can then be sent in the gaseous phase via a pipe 5 to a generator on board the ship.
- the gas requirements at the ship's generator (s) are often less than the "production" of evaporative gas in all tanks that are on board the ship.
- the gas not used in the generator (s) is then sent to a reliquefaction unit 10.
- the reliquefaction unit 10 comprises at its inlet a valve 6 intended in particular to control the pressure of the gas in line 5, then a main circuit and a loop which will be described below.
- the main circuit allows from the gas (in the gas phase and which is at a pressure of the order of a few bars to about 50 bar - non-limiting values -) to obtain gas in the liquid phase which can return to the tank 1 .
- a multistage compressor comprising here three successive stages with the references 11, 12 and 13. Each stage is formed by a compression wheel and the three compression wheels are driven by the same one. transmission 15 with shafts and pinions.
- the line between the compression stages in the figures symbolizes the mechanical connection between them.
- the gas arriving in the multistage compressor arrives in the second stage 12 of this compressor. Depending on the system, it may as well arrive at the first - as illustrated in the other figures of the drawing - or at the third (or more generally nth stage) of this compressor.
- the gas passes into an intercooler 16. Its pressure is then a few tens of bars, for example. example about 50 bar, and its temperature is again around 40 to 45 ° C.
- the gas thus compressed is then cooled and condensed within a first multi-flow exchanger 17.
- the gas circulates in this first exchanger 17 in a first direction.
- the fluids circulating in the opposite direction (with respect to this first direction) and used to cool it will be described below.
- the compressed gas cooled to a temperature of the order of -110 to -120 ° C. is mainly (almost entirely) in the liquid phase and is sent, always at a pressure of the order of a few tens of bars (for example around 50 bar) via an insulated pipe 22 to an expansion valve 30.
- Expansion through condensed gas expansion valve 30 provides both methane-rich liquid phase gas and nitrogen-rich gas phase gas.
- the separation of this liquid phase and this gas phase is carried out within a balloon 40 in which the pressure is of the order of a few bars, for example between 3 and 5 bar.
- the gas in the gaseous phase of the balloon 40 is preferably returned to the manifold 2. In this way, it can be used either as fuel in a generator, or to pass back into the reliquefaction unit 10. This gas being cold, it can be used either as fuel in a generator. used to cool and condense the compressed gas in the first exchanger 17. It is therefore planned to make it circulate in the opposite direction in this first exchanger 17 before returning it to the manifold 2.
- a set of valves 31, 32 controls the sending of the gas in the gaseous phase from the balloon 40 respectively to the manifold 2 via a connection pipe 35 or to a combustion unit (not shown).
- the gas in the liquid phase recovered at the bottom of the tank 40 is for its part intended to return to the tank 1.
- the gas in the liquid phase can be sent directly to the tank 1 (passage controlled by a valve 33 ), or using a pump 41 (passage controlled by a valve 34).
- the return of the gas in liquid phase from the balloon 40, directly or by the pump 41, to the reservoir 1 is effected by means of an insulated pipe 36 provided here with a valve 54, for example a valve. stop.
- cooling of the compressed gas in the multistage compressor should be ensured.
- This cooling is usually done using a separate thermodynamic machine, operating for example according to a Brayton cycle, and using nitrogen as refrigerant. It is possible to use in the reliquefaction unit 10 such a refrigeration machine which then cools and condenses the gas within the first exchanger 17.
- a cooling loop using natural gas as refrigerant. This loop begins with a branch pipe 18 which separates the gas flow downstream of the multistage compressor (stages 11, 12, 13) into a first flow, or main flow, which corresponds to the main circuit described above, and into a second flow, or derivative flow.
- the bypass pipe 18 is preferably connected to the main circuit at the level of the first exchanger 17.
- the gas in the gas phase which therefore enters the bypass pipe 18 is at "high pressure" (approximately 50 bar in the numerical example given ) and at an intermediate temperature between 40 ° C and -110 ° C.
- the gas taken by the bypass pipe 18 is expanded within expansion means formed by an expansion turbine 14.
- This expansion turbine 14 is, in the preferred embodiment illustrated in the drawing, mechanically connected to the three compression wheels. corresponding to stages 11, 12 and 13 of the multistage compressor of the reliquefaction unit 10.
- the transmission 15 by shafts and pinions connects the expansion turbine 14 and the compression wheels of the multistage compressor. This transmission 15 is symbolized by a line connecting in the figures the expansion turbine 14 to the stages 11, 12 and 13.
- the gas is expanded for example to a pressure level which corresponded to its pressure level when entering the reliquefaction unit 10, or about 15 to 20 bar. Its temperature drops below -120 ° C.
- This gas flow (gas phase) is then sent into the first exchanger 17 in the opposite direction to cool and condense the pressurized gas from the main circuit, first of all in a portion 19 located downstream of the bypass pipe 18 then in a portion of this main circuit in the first exchanger 17 upstream of this bypass pipe 18.
- the expanded gas returns to temperatures of the order of 40 ° C and can be reinjected in the gas phase into the main circuit of the reliquefaction unit, upstream of the multistage compressor via a return line 21.
- An open cooling loop is thus produced which uses as gas for cooling the same gas as that which is to be liquefied.
- the illustrated system also has a gas supply line under (high) pressure to a gas engine, for example a MEGI type engine (not illustrated).
- a gas engine for example a MEGI type engine (not illustrated).
- This supply line starts from a tank 1. It is first of all supplied by an immersed pump 50 which supplies cryogenic liquid (LNG) to a pipe 51 to lead it to a high pressure pump 48. The high pressure liquid is then carried by a pipe 56 in a vaporizer 61, for example carrying out a heat exchange with water vapor, to produce vapor (natural gas in the gaseous phase) under high pressure which can then supply an engine of the MEGI type by a supply line 62.
- LNG cryogenic liquid
- vaporizer 61 for example carrying out a heat exchange with water vapor
- bypass 57 On the pipe 56.
- This bypass 57 will supply liquid under pressure, still in the liquid phase, a second exchanger 60 intended to sub-cool the condensate leaving the first exchanger 17 in the main circuit of the reliquefaction unit 10.
- This second exchanger 60 in the embodiment illustrated on figure 1 , is here provided to make a heat exchange between on one side the pressurized liquid of the pipe 56 supplying the MEGI motor (or other) and derived by the bypass 57 and on the other hand the condensate in the pipe isolated 22 between the first exchanger 17 and the expansion valve 30.
- the liquid derived in the bypass 57 is located at approximately -150 ° C upstream of the second exchanger 60 and emerges from the latter for example at -140 ° C. (still in the liquid phase).
- the condensed gas leaving the first exchanger 17 passes for example from -120 ° C to -135 ° C.
- the regulation of the flow in the pipe 56 and the bypass 57 is provided by means of a valve 55 placed on the line 56 upstream of the bypass 57 and another valve 59 integrated in the bypass 57 (illustrated in downstream of the second exchanger 60, but the person skilled in the art understands that this valve 59 could equally be placed upstream of this second exchanger 60).
- a valve 58 manually or automatically controlled, is also provided between the two points of connection of the bypass 57 with the pipe 56.
- the figure 2 illustrates an alternative embodiment of the system of the figure 1 with two modifications totally independent of each other. Provision is made here first of all, as already mentioned above, to inject the compressed gas in the first compression unit 3 into the first stage 11 of the multistage compressor of the reliquefaction unit. Then, provision is made for the regulation at the second heat exchanger 60 in a slightly different manner. Instead of adjusting the exchanges in the exchanger by varying the flow rates in bypass 57 ( figure 1 ), provision is made here to vary the flow rates passing through the exchanger at the level of the insulated pipe 22. It is thus provided in the embodiment of the figure 2 to pass through the second exchanger 60 between 0% and 100% of the flow (mixture between gas and liquid phase but mainly in liquid phase) circulating in the insulated pipe 22.
- a bypass pipe 66 short-circuits the second exchanger 60.
- a three-way valve 65 is provided upstream of the second exchanger 60 to regulate the flow of the insulated pipe 22 passing through the second exchanger 60 and that passing through the bypass pipe 66.
- Other means of regulation could be considered (such as for example at bypass 57, with a valve upstream of the bypass line and a valve in the bypass line and / or in the circuit branch containing the second exchanger).
- the embodiment of the figure 2 simply provides for providing each branch of the bypass 57, an upstream branch and a downstream branch of the second exchanger 60, with a valve 64a and 64b, respectively, manually or controlled.
- a valve 63 is arranged between the two points of connection of the bypass 57 with the pipe 56 of the engine supply line (not shown).
- FIGS. 5 and 6 illustrate embodiments implementing a third heat exchanger 70 to cool the gas in the gaseous phase entering the refrigeration open loop of the reliquefaction unit 10.
- the exchange is here carried out between the liquid from line 56 and the compressed gas in the gaseous phase and already partially cooled from the branch pipe 18.
- the third exchanger 70 is mounted in parallel with the second exchanger 60, while in the embodiment of the figure 6 , the third exchanger 70 is mounted in series with (and downstream of) the second exchanger 60.
- the figure 7 proposes an embodiment in which four heat exchangers 80a-d are provided in various places of the main circuit of the reliquefaction unit 10 to cool the gas still in the gaseous phase before liquefying it.
- the exchanger 80a is here intended to cool the compressed gas in the first stage 11 of the multistage compressor before it enters the second stage 12 of this compressor.
- the exchanger 80b is disposed in a similar manner between the second stage 12 and the third stage 13.
- Another exchanger 80c is disposed downstream of the multistage compressor, before or after the intercooler 16 and before the first exchanger 17.
- it is proposed here to also have a heat exchanger 80d on the connecting pipe 35 to cool the gas returning to the manifold 2.
- This embodiment is intended to be illustrative (and not limiting) of the various possibilities for positioning exchangers supplied with cryogenic liquid under high pressure.
- These exchangers may be four in number, or more, or much less. They are preferably mounted in parallel as illustrated, the exchangers 80n forming an exchange system mounted in series with the second exchanger 60. Other assemblies (series or parallel) can be envisaged. It is also possible to provide exchangers on the open loop cooling circuit.
- FIG 8 is attached to illustrate that the pressurized liquid (still liquid phase) in line 56 can also be used, in part, to cool other elements within a cooling system 90 on board the ship.
- the liquid used for the cooling system 90 is preferably disposed downstream of the second exchanger 60 so that the liquid from the line 56 taken from the bypass 57 primarily serves for cooling at the level of the reliquefaction unit 10.
- the cooling system can be for example an air conditioning unit, industrial refrigeration, ....
- the system proposed here achieves cooperation between a liquefaction unit and a high pressure gas supply, for example for the supply of a MEGI type motor.
- a synergy is created between these two sub-systems, one having cooling needs to liquefy a gas and the other requiring energy to vaporize liquid at high pressure.
- the system as proposed makes it possible to increase the efficiency of the reliquefaction unit, that is to say to increase the proportion of the evaporated gas which is reliquefied, to limit the cooling requirements to be supplied to carry out the reliquefaction of evaporated gas and at the same time to limit the energy needs to obtain a high pressure gas to supply an engine (MEGI engine or other system operating with gas under high pressure).
- the system proposed here is particularly well suited to a reliquefaction unit having an open loop of refrigerant gas corresponding to refrigerated gas with production of cold at two different temperatures, a temperature of around -120 ° C at the outlet of the expansion turbine. and a temperature of about -160 ° C at the outlet of the expansion valve.
- the system is independent of the engines on board the vessel which are powered by evaporated gas. There can be two different types of gas engines, one being supplied by the high pressure supply line and the other by the evaporated gas compressed by the first compression unit.
- the system also allows, from the evaporated gas, independently of any other external cold source, to achieve liquefaction.
- the cold production can be matched to the load of the reliquefaction unit and can be regulated over a wide range.
- the proposed system does not require a nitrogen treatment unit or the like. Its structure is simplified by the use of a refrigerant gas of the same nature as the gas to be refrigerated and to be liquefied and which also serves as fuel for an engine (or similar).
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Description
La présente invention concerne un système et un procédé de traitement de gaz issu de l'évaporation d'un liquide cryogénique et pour l'alimentation en gaz sous pression d'un moteur à gaz.The present invention relates to a system and a method for treating gas resulting from the evaporation of a cryogenic liquid and for supplying pressurized gas to a gas engine.
Le domaine de la présente invention est plus particulièrement le transport maritime de liquides cryogéniques et encore plus particulièrement de Gaz Naturel Liquéfié (GNL). Cependant, les systèmes et les procédés qui seront proposés plus loin pourraient aussi trouver des applications dans des installations terrestres.The field of the present invention is more particularly the maritime transport of cryogenic liquids and even more particularly of Liquefied Natural Gas (LNG). However, the systems and methods which will be proposed later could also find applications in terrestrial installations.
Si l'on considère le gaz naturel liquéfié, celui-ci présente, à pression ambiante, une température de l'ordre -163°C (ou moins). Lors du transport maritime de GNL, ce dernier est mis dans des réservoirs sur un navire, un méthanier. Bien que ces réservoirs soient isolés thermiquement, des fuites thermiques existent et le milieu extérieur apporte de la chaleur au liquide contenu dans les réservoirs. Le liquide se réchauffe donc et s'évapore. Compte tenu de la taille des réservoirs se trouvant sur un méthanier, en fonction des conditions d'isolation thermique et des conditions extérieures, plusieurs tonnes de gaz peuvent s'évaporer par heure.If we consider liquefied natural gas, it has, at ambient pressure, a temperature of the order of -163 ° C (or less). During maritime transport of LNG, the latter is placed in tanks on a ship, an LNG carrier. Although these tanks are thermally insulated, thermal leaks exist and the external environment brings heat to the liquid contained in the tanks. The liquid therefore heats up and evaporates. Given the size of the tanks on an LNG carrier, depending on thermal insulation conditions and external conditions, several tonnes of gas can evaporate per hour.
Il n'est pas possible de maintenir le gaz évaporé dans les réservoirs du navire pour des raisons de sécurité. La pression dans les réservoirs augmenterait dangereusement. Il faut donc laisser le gaz qui s'évapore s'échapper hors des réservoirs. La règlementation interdit de rejeter ce gaz (s'il s'agit de gaz naturel) dans l'atmosphère en l'état. Il faut le brûler.It is not possible to keep evaporated gas in the vessel's tanks for safety reasons. The pressure in the tanks would increase dangerously. It is therefore necessary to allow the gas which evaporates to escape from the tanks. The regulations prohibit discharging this gas (if it is natural gas) into the atmosphere as it is. It must be burnt.
Pour éviter de perdre ce gaz qui s'évapore, il est aussi connu, d'une part, de l'utiliser comme carburant pour les moteurs à bord du navire le transportant et, d'autre part, de le reliquéfier pour le remettre dans les réservoirs desquels il provient.To avoid losing this gas which evaporates, it is also known, on the one hand, to use it as fuel for the engines on board the ship transporting it and, on the other hand, to reliquefy it to put it back in. the reservoirs from which it comes.
Pour reliquéfier le gaz qui s'est évaporé, il est connu de refroidir ce gaz pour le ramener à nouveau dans des conditions de température et de pression lui permettant de repasser en phase liquide. Cet apport de froid est le plus souvent réalisé par échange de chaleur avec un circuit réfrigérant comportant par exemple une boucle de fluide réfrigérant tel de l'azote.In order to reliquefy the gas which has evaporated, it is known practice to cool this gas in order to bring it back again to temperature and pressure conditions allowing it to return to the liquid phase. This cold intake is the most often carried out by heat exchange with a refrigerant circuit comprising, for example, a loop of refrigerant fluid such as nitrogen.
En outre, certains méthaniers utilisent le gaz naturel qu'ils transportent comme carburant pour assurer leur propulsion. Il existe plusieurs types de moteur fonctionnant avec du gaz naturel. La présente invention concerne plus particulièrement ceux qui sont alimentés par du gaz naturel sous phase gazeuse à haute pression. Pour alimenter alors le moteur de propulsion du méthanier, du gaz est pompé hors d'un réservoir de gaz naturel liquéfié se trouvant à bord du méthanier, puis est mis sous pression à l'aide d'une pompe avant d'être vaporisé pour pouvoir alimenter le moteur.In addition, some LNG carriers use the natural gas they transport as fuel to ensure their propulsion. There are several types of engine that run on natural gas. The present invention relates more particularly to those which are supplied with natural gas in a high pressure gaseous phase. To then supply the propulsion engine of the LNG carrier, gas is pumped out of a liquefied natural gas tank on board the LNG carrier, then is pressurized using a pump before being vaporized in order to be able to power the motor.
Le document
La présence d'une boucle réfrigérante avec de l'azote dans le cycle de Brayton, ou bien tout autre gaz réfrigérant distinct du fluide à réfrigérer, implique de prévoir des équipements spécifiques pour le fluide réfrigérant. Ainsi par exemple lorsqu'un circuit réfrigérant à l'azote est prévu à bord d'un navire (ou ailleurs), une unité de traitement (purification) de l'azote est nécessaire pour permettre son utilisation dans le domaine cryogénique. Il convient également de prévoir un réservoir spécifique, des vannes et autres dispositifs pour la régulation de la circulation de l'azote.The presence of a refrigerant loop with nitrogen in the Brayton cycle, or any other refrigerant gas distinct from the fluid to be refrigerated, implies providing specific equipment for the refrigerant. So, for example, when a nitrogen refrigerant circuit is provided on board a ship (or elsewhere), a nitrogen treatment (purification) unit is necessary to allow its use in the cryogenic field. It is also advisable to provide a specific tank, valves and other devices for regulating the circulation of nitrogen.
Lorsque le gaz naturel alimentant les moteurs du méthanier est directement prélevé dans les réservoirs du navire, il est préférable d'avoir un rendement élevé au niveau de la liquéfaction car la consommation de gaz sous phase gazeuse est alors limitée.When the natural gas supplying the engines of the LNG tanker is taken directly from the tanks of the vessel, it is preferable to have a high efficiency in terms of liquefaction because the consumption of gas in the gas phase is then limited.
La présente invention a alors pour but de fournir un système optimisé permettant de reliquéfier du gaz qui s'est évaporé et d'alimenter sous haute pression un moteur à gaz. De préférence, le système proposé permettra d'optimiser la quantité de liquide recouvré pour ce qui concerna la part de gaz à reliquéfier. Avantageusement, le système proposé pourra également être utilisé à bord d'un navire tel un méthanier. De manière préférée, le système fonctionnera sans utilisation d'un fluide frigorigène tel de l'azote ou autre pour éviter d'avoir deux circuits distincts avec des fluides de natures différentes. La solution proposée ne sera également de préférence pas plus chère à réaliser que les solutions de l'art antérieur.The object of the present invention is therefore to provide an optimized system making it possible to reliquefy gas which has evaporated and to supply a gas engine under high pressure. Preferably, the proposed system will make it possible to optimize the quantity of liquid recovered with regard to the portion of gas to be reliquefied. Advantageously, the proposed system could also be used on board a ship such as an LNG carrier. Preferably, the system will operate without using a refrigerant such as nitrogen or the like to avoid having two separate circuits with fluids of different natures. The proposed solution will also preferably not be more expensive to produce than the solutions of the prior art.
À cet effet, la présente invention propose un système de traitement d'un gaz issu de l'évaporation d'un liquide cryogénique et d'alimentation en gaz sous pression d'un moteur à gaz, ledit système comportant, d'une part, d'amont en aval, une unité de reliquéfaction avec des moyens de compression, un premier échangeur de chaleur et des moyens de détente, et, d'autre part, une ligne d'alimentation en gaz sous pression comportant d'amont en aval une pompe pour mettre du liquide sous pression et des moyens de vaporisation sous haute pression.To this end, the present invention provides a system for treating a gas resulting from the evaporation of a cryogenic liquid and for supplying pressurized gas to a gas engine, said system comprising, on the one hand, from upstream to downstream, a reliquefaction unit with compression means, a first heat exchanger and expansion means, and, on the other hand, a pressurized gas supply line comprising from upstream to downstream a pump for putting liquid under pressure and high pressure vaporization means.
Selon la présente invention, la ligne d'alimentation en gaz sous pression présente, en amont des moyens de vaporisation, une dérivation pour alimenter un deuxième échangeur de chaleur entre, d'une part, du liquide sous pression de la ligne d'alimentation et, d'autre part, une ligne de l'unité de reliquéfaction en aval du premier échangeur de chaleur et en amont des moyens de détente, caractérisé en ce que le gaz issu de l'évaporation d'un liquide cryogénique, puis comprimé et refroidi est condensé au moins partiellement au sein du premier échangeur de chaleur (17) .According to the present invention, the pressurized gas supply line has, upstream of the vaporization means, a bypass for supplying a second heat exchanger between, on the one hand, liquid under pressure from the supply line and , on the other hand, a line of the reliquefaction unit downstream of the first heat exchanger and upstream of the expansion means, characterized in that the gas resulting from the evaporation of a cryogenic liquid, then compressed and cooled is condensed at least partially within the first heat exchanger (17).
La solution proposée permet de créer une synergie entre la reliquéfaction du gaz qui s'est évaporé et la production de gaz sous pression pour alimenter un moteur, par exemple un moteur MEGI. En effet, d'un côté il y a des besoins pour refroidir du gaz et d'un autre côté il y a des besoins pour réchauffer du liquide avant de le vaporiser. Le deuxième échangeur proposé permet ainsi à la fois de limiter les besoins (en froid) de l'unité de reliquéfaction et les besoins (en chaleur) de la ligne d'alimentation en gaz sous haute pression. De manière originale, il est proposé ici de « sous-refroidir » du gaz condensé. En effet, après le premier échangeur le gaz comprimé est suffisamment refroidi pour se condenser et se trouver majoritairement en phase liquide sous pression. Ce liquide sous pression doit alors être détendu pour pouvoir être réintroduit dans les réservoirs qui sont sensiblement à la pression atmosphérique (juste un peu au-dessus pour éviter à de l'air de pénétrer à l'intérieur). Lors de cette détente, une partie du gaz condensé se revaporise. En refroidissant avant détente le gaz condensé, étant donc sous phase liquide, ce gaz est sous refroidi et ceci permet de limiter lors de la détente la portion de gaz condensé qui se revaporise.The proposed solution makes it possible to create a synergy between the reliquefaction of the gas which has evaporated and the production of gas under pressure to supply an engine, for example a MEGI engine. Indeed, on the one hand there are needs to cool the gas and on the other hand there are needs to heat the liquid before vaporizing it. The second proposed exchanger thus makes it possible both to limit the (cooling) requirements of the reliquefaction unit and the (heat) requirements of the high pressure gas supply line. In an original manner, it is proposed here to “sub-cool” the condensed gas. Indeed, after the first exchanger, the compressed gas is sufficiently cooled to condense and be found mainly in the liquid phase under pressure. This pressurized liquid must then be relaxed in order to be able to be reintroduced into the reservoirs which are substantially at atmospheric pressure (just a little above to prevent air from entering the interior). During this expansion, part of the condensed gas is vaporized. By cooling the condensed gas before expansion, therefore being in the liquid phase, this gas is subcooled and this makes it possible to limit, during expansion, the portion of condensed gas which revaporates.
Pour optimiser encore l'utilisation de la source de froid provenant du flux de liquide sous pression destiné à être vaporisé pour alimenter un moteur, la dérivation peut alimenter en aval du deuxième échangeur un système de refroidissement. Il peut par exemple s'agir d'un troisième échangeur monté en série avec et en aval du deuxième échangeur et/ou d'un échangeur de chaleur monté en parallèle du deuxième échangeur.To further optimize the use of the cold source coming from the flow of pressurized liquid intended to be vaporized to supply an engine, the bypass can supply a cooling system downstream of the second exchanger. It may for example be a third exchanger mounted in series with and downstream of the second exchanger and / or a heat exchanger mounted in parallel with the second exchanger.
On peut prévoir dans le système décrit ci-dessus que la dérivation alimente outre le deuxième échangeur, un ou plusieurs échangeurs pour refroidir du gaz avant sa reliquéfaction.In the system described above, provision can be made for the bypass to supply, in addition to the second exchanger, one or more exchangers for cooling gas before its reliquefaction.
Une variante particulière d'un système tel que décrit ci-dessus prévoit qu'il comporte en outre, en aval des moyens de détente un ballon séparant la phase gazeuse de la phase liquide dans le fluide détendu ; qu'une ligne conduit la phase gazeuse vers un collecteur pour le mélanger au gaz issu de l'évaporation du liquide cryogénique, et que la dérivation alimente un échangeur de chaleur pour refroidir la phase gazeuse avant son introduction dans le collecteur.A particular variant of a system as described above provides that it further comprises, downstream of the expansion means, a balloon separating the gas phase from the liquid phase in the expanded fluid; that a line conducts the gas phase to a collector to mix it with the gas resulting from the evaporation of the cryogenic liquid, and that the bypass supplies a heat exchanger to cool the gas phase before its introduction into the collector.
Le système décrit ci-dessus est particulièrement bien adapté à une unité de reliquéfaction qui utilise comme liquide réfrigérant le même fluide que le fluide à liquéfier. Dans cette variante avantageuse, ladite unité comporte ainsi par exemple, en aval de ses moyens de compression une dérivation vers une boucle comportant de seconds moyens de détente, et la boucle rejoint le circuit en amont des moyens de compression après avoir traversé le premier échangeur de chaleur à contresens par rapport à la fraction de gaz du circuit non dérivée par la boucle. Dans cette forme de réalisation, il est de préférence prévu que les moyens de compression comportent plusieurs étages de compression avec chacun une roue de compression, que les seconds moyens de détente comportent une turbine de détente et que chaque roue de compression et la turbine de détente sont associées à une même transmission mécanique. On peut éventuellement prévoir aussi que le système, avec une telle unité de reliquéfaction, comporte en outre un troisième échangeur de chaleur entre du liquide sous pression dérivé de la ligne d'alimentation et du gaz entre les moyens de compression et les seconds moyens de détente. Ce troisième échangeur permet d'augmenter les échanges et ainsi donc d'optimiser le système. Comme évoqué plus haut, selon une première variante de réalisation, le troisième échangeur peut être monté en parallèle du deuxième échangeur et selon une autre variante de réalisation alternative, le troisième échangeur peut être monté en série avec le deuxième échangeur.The system described above is particularly well suited to a reliquefaction unit which uses as coolant the same fluid as the fluid to be liquefied. In this advantageous variant, said unit thus comprises for example, downstream of its compression means, a bypass to a loop comprising second expansion means, and the loop joins the circuit upstream of the compression means after passing through the first heat exchanger. heat in the opposite direction to the fraction of gas in the circuit not diverted by the loop. In this embodiment, provision is preferably made for the compression means to include several compression stages each with a compression wheel, for the second expansion means to include an expansion turbine and for each compression wheel and the expansion turbine are associated with the same mechanical transmission. Provision may also be made for the system, with such a reliquefaction unit, to further include a third heat exchanger between pressurized liquid derived from the supply line and gas between the compression means and the second expansion means. . This third exchanger makes it possible to increase the exchanges and thus to optimize the system. As mentioned above, according to a first variant embodiment, the third heat exchanger can be mounted in parallel with the second heat exchanger and according to another alternative variant embodiment, the third heat exchanger may be mounted in series with the second heat exchanger.
La présente invention concerne également un navire, notamment un méthanier, propulsé par un moteur à gaz, caractérisé en ce qu'il comporte un système de traitement d'un gaz issu de l'évaporation d'un liquide cryogénique et d'alimentation en gaz sous pression d'un moteur à gaz tel que décrit plus haut.The present invention also relates to a ship, in particular an LNG carrier, propelled by a gas engine, characterized in that it comprises a system for treating a gas resulting from the evaporation of a cryogenic liquid and for supplying gas. under pressure from a gas engine as described above.
Enfin, la présente invention propose un procédé de traitement d'un flux de gaz issu de l'évaporation d'un liquide cryogénique et d'alimentation d'un moteur en gaz à haute pression, ledit flux de gaz étant tout d'abord comprimé puis refroidi et condensé au moins partiellement au sein d'un premier échangeur de chaleur avant d'être détendu, et l'alimentation en gaz sous haute pression étant réalisée en mettant sous pression du liquide cryogénique puis en le vaporisant, et après sa compression, le flux de liquide sous pression étant séparé en une première partie de flux de liquide et une seconde partie de flux de liquide, et la première partie du flux de liquide étant utilisée pour refroidir du gaz comprimé et condensé au sein d'un deuxième échangeur avant détente du gaz condensé, et la seconde partie du flux du liquide recevant la première partie du flux de liquide après que cette dernière ait refroidi du gaz comprimé, l'ensemble du flux liquide étant ensuite vaporisé.Finally, the present invention proposes a method for treating a gas flow resulting from the evaporation of a cryogenic liquid and for supplying a high pressure gas to an engine, said gas flow being first of all compressed. then cooled and condensed at least partially within a first heat exchanger before being expanded, and the supply of gas under high pressure being carried out by pressurizing cryogenic liquid then by vaporizing it, and after its compression, the flow of liquid under pressure being separated into a first part of liquid flow and a second part of liquid flow, and the first part of the liquid flow being used to cool compressed and condensed gas within a second exchanger before expansion of the condensed gas, and the second part of the liquid flow receiving the first part of the liquid flow after the latter has cooled compressed gas, the whole of the liquid flow then being vaporized.
Dans ce procédé on prévoit avantageusement que plus de la moitié, et de préférence au moins 90% en masse du gaz comprimé est condensé avant d'être refroidi au sein du deuxième échangeur.In this process it is advantageously provided that more than half, and preferably at least 90% by mass of the compressed gas is condensed before being cooled within the second exchanger.
Pour augmenter le rendement au niveau de la reliquéfaction, il est avantageusement prévu que le flux de liquide sous pression soit également utilisé pour refroidir du gaz avant qu'il ne soit condensé.In order to increase the efficiency of the reliquefaction, it is advantageously provided that the flow of pressurized liquid is also used to cool gas before it is condensed.
Dans un procédé tel que décrit ci-avant, on prévoit avantageusement qu'une partie du gaz comprimé est prélevée au sein du premier échangeur pour être détendue au sein d'une turbine de détente, et que le gaz détendu est introduit dans le premier échangeur à contre-courant pour refroidir le gaz comprimé et provoquer sa condensation. De la sorte, le fluide à reliquéfier est utilisé aussi comme fluide réfrigérant et il n'est alors pas nécessaire de prévoir un circuit réfrigérant utilisant un autre fluide pour permettre la reliquéfaction.In a method as described above, it is advantageously provided that part of the compressed gas is taken from within the first exchanger to be expanded within an expansion turbine, and that the expanded gas is introduced into the first exchanger. against the current to cool the compressed gas and cause it to condense. In this way, the fluid to be reliquefied is also used as refrigerant fluid and it is then not necessary to provide a refrigerant circuit using another fluid to allow reliquefaction.
Des détails et avantages de la présente invention apparaitront mieux de la description qui suit, faite en référence au dessin schématique annexé sur lequel :
Les
The
Sur chacune des figures annexées, un réservoir 1 est illustré. Dans toute la suite de la description, on supposera qu'il s'agit d'un réservoir de Gaz Naturel Liquéfié (ou GNL) parmi plusieurs autres réservoirs similaires à bord d'un navire de haute mer de type méthanier.In each of the appended figures, a reservoir 1 is illustrated. Throughout the remainder of the description, it will be assumed that this is a Liquefied Natural Gas (or LNG) tank among several other similar tanks on board an LNG-type ocean-going vessel.
Les valeurs numériques dans la description qui suit sont données à titre d'exemples numériques purement illustratifs et nullement limitatifs. Elles sont adaptées au traitement de GNL à bord d'un navire mais peuvent varier, notamment si la nature du gaz change.The numerical values in the description which follows are given by way of purely illustrative numerical examples and in no way limiting. They are suitable for the treatment of LNG on board a ship but may vary, in particular if the nature of the gas changes.
Le réservoir 1 stocke le GNL à une température de l'ordre de -163°C qui correspond à la température de stockage habituelle du GNL à une pression proche de la pression atmosphérique. Cette température dépend bien entendu de la composition du gaz naturel et des conditions de stockage. L'atmosphère autour du réservoir 1 étant à une température bien plus élevée que celle du GNL, bien que le réservoir 1 soit très bien isolé thermiquement, des calories sont apportées au liquide qui se réchauffe et se vaporise. Le volume du gaz s'évaporant étant bien plus important que celui du liquide correspondant, la pression dans le réservoir 1 tend donc à augmenter au fur et à mesure que le temps s'écoule et que des calories sont apportées au liquide.The tank 1 stores the LNG at a temperature of the order of -163 ° C which corresponds to the usual storage temperature of LNG at a pressure close to atmospheric pressure. This temperature obviously depends on the composition of the natural gas and the storage conditions. The atmosphere around tank 1 being at a much higher temperature than that of LNG, although tank 1 is very well thermally insulated, calories are added to the liquid which heats up and vaporizes. The volume of gas evaporating being much greater than that of the corresponding liquid, the pressure in the reservoir 1 therefore tends to increase as time passes and as calories are added to the liquid.
Pour éviter d'atteindre des pressions trop importantes, le gaz qui s'évapore est retiré au fur et à mesure du réservoir 1 (et des autres réservoirs du navire) et se retrouve dans un collecteur 2 relié à plusieurs réservoirs. Dans la suite de la description, le gaz qui s'est évaporé est appelé « gaz » même lorsque par la suite il est reliquéfié. On le distingue ainsi du GNL qui est prélevé sous forme liquide dans les réservoirs pour alimenter un moteur.To avoid reaching excessively high pressures, the gas which evaporates is gradually withdrawn from tank 1 (and from the other tanks of the ship) and is found in a
Il est prévu dans les systèmes illustrés au dessin d'utiliser le gaz qui s'est évaporé comme source d'énergie à bord du navire (par exemple pour fabriquer de l'électricité) et de reliquéfier le surplus de gaz. Le but est ici d'éviter de perdre le gaz évaporé et donc soit de l'utiliser à bord du navire, soit de le récupérer et le renvoyer, en phase liquide, dans le réservoir 1. En outre, il est prévu une ligne d'alimentation en gaz à haute pression d'un moteur à gaz de type moteur MEGI à partir de GNL liquide prélevé dans les réservoirs du navire.In the systems illustrated in the drawing, provision is made to use the gas which has evaporated as a source of energy on board the ship (for example to produce electricity) and to reliquefy the surplus gas. The aim here is to avoid losing the evaporated gas and therefore either using it on board the ship, or recovering it and returning it, in the liquid phase, to the tank 1. In addition, there is provided a dc line. 'high pressure gas supply to a gas engine of the MEGI engine type from liquid LNG taken from the ship's tanks.
Pour être utilisé à bord du navire, le gaz évaporé des réservoirs doit être tout d'abord comprimé. Cette compression est alors réalisée au sein d'une première unité de compression 3 qui peut être, comme illustré au dessin, multi-étagée. Cette unité, à titre d'exemple numérique illustratif et nullement limitatif, porte la pression du gaz collecté dans le collecteur 2 d'une pression sensiblement égale à la pression atmosphérique à une pression de l'ordre de 15 à 20 bar (1 bar=105 Pa).To be used on board the ship, the gas evaporated from the tanks must first be compressed. This compression is then carried out within a first compression unit 3 which can be, as illustrated in the drawing, multistage. This unit, by way of illustrative and in no way limiting numerical example, takes the pressure of the gas collected in the
Après cette première étape de compression, le gaz passe dans un refroidisseur intermédiaire 4 dans lequel il est refroidi sans modifier de manière sensible sa pression. Le gaz qui a été réchauffé lors de sa compression est à une température de l'ordre de 40 à 45°C à la sortie du refroidisseur intermédiaire (ces valeurs sont données à titre purement illustratif et s'appliquent notamment pour du gaz naturel). Le gaz ainsi comprimé et refroidi peut alors être envoyé en phase gazeuse par une conduite 5 vers un générateur à bord du navire.After this first compression step, the gas passes through a intercooler 4 in which it is cooled without significantly modifying its pressure. The gas which has been reheated during its compression is at a temperature of the order of 40 to 45 ° C. at the outlet of the intercooler (these values are given purely by way of illustration and apply in particular for natural gas). The gas thus compressed and cooled can then be sent in the gaseous phase via a pipe 5 to a generator on board the ship.
Les besoins en gaz au niveau du (des) générateur(s) du navire sont souvent inférieurs à la "production" de gaz par évaporation dans tous les réservoirs qui sont à bord du navire. Le gaz non utilisé dans le(s) générateur(s) est alors envoyé vers une unité de reliquéfaction 10.The gas requirements at the ship's generator (s) are often less than the "production" of evaporative gas in all tanks that are on board the ship. The gas not used in the generator (s) is then sent to a
L'unité de reliquéfaction 10 comprend à son entrée une vanne 6 destinée notamment à contrôler la pression du gaz dans la conduite 5, puis un circuit principal et une boucle qui vont être décrits ci-après.The
Le circuit principal permet à partir du gaz (en phase gazeuse et qui se trouve à une pression de l'ordre de quelques bars à environ 50 bar -valeurs non limitatives-) d'obtenir du gaz en phase liquide pouvant retourner dans le réservoir 1.The main circuit allows from the gas (in the gas phase and which is at a pressure of the order of a few bars to about 50 bar - non-limiting values -) to obtain gas in the liquid phase which can return to the tank 1 .
Le procédé pour obtenir ce gaz en phase liquide à remettre dans le réservoir est classique. Il s'agit de comprimer le gaz, de le refroidir pour le condenser puis de le détendre pour qu'il retrouve la pression régnant dans les réservoirs. Cette manière de faire est classique dans le domaine de la cryogénie.The process for obtaining this gas in liquid phase to be returned to the reservoir is conventional. This involves compressing the gas, cooling it to condense it and then expanding it so that it regains the pressure prevailing in the reservoirs. This way of doing things is classic in the field of cryogenics.
On trouve ainsi dans le circuit principal tout d'abord un compresseur multi-étagé comprenant ici trois étages successifs avec les références 11, 12 et 13. Chaque étage est formé par une roue de compression et les trois roues de compression sont entrainées par une même transmission 15 à arbres et pignons. Le trait entre les étages de compression sur les figures symbolise la liaison mécanique entre eux. Dans la forme de réalisation illustrée sur la
Après cette seconde compression, le gaz passe dans un refroidisseur intermédiaire 16. Sa pression est alors de quelques dizaines de bars, par exemple environ 50 bar, et sa température est à nouveau de l'ordre de 40 à 45°C.After this second compression, the gas passes into an
Le gaz ainsi comprimé est alors refroidi et condensé au sein d'un premier échangeur 17 multiflux. Le gaz circule dans ce premier échangeur 17 dans un premier sens. Les fluides circulant à contresens (par rapport à ce premier sens) et utilisés pour le refroidir seront décrits plus loin.The gas thus compressed is then cooled and condensed within a first
En sortie du premier échangeur 17, le gaz comprimé refroidi à une température de l'ordre de -110 à -120°C se trouve majoritairement (presque intégralement) en phase liquide et est envoyé, toujours à une pression de l'ordre de quelques dizaines de bars (par exemple environ 50 bar) par une conduite isolée 22 à une vanne de détente 30.At the outlet of the
La détente à travers la vanne de détente 30 du gaz condensé fournit à la fois du gaz en phase liquide riche en méthane et un gaz en phase gazeuse riche en azote. La séparation de cette phase liquide et de cette phase gazeuse est réalisée au sein d'un ballon 40 dans lequel la pression est de l'ordre de quelques bars, par exemple entre 3 et 5 bar.Expansion through condensed
Le gaz en phase gazeuse du ballon 40 est renvoyé de préférence vers le collecteur 2. De la sorte, il peut être utilisé soit comme carburant dans un générateur, soit repasser dans l'unité de reliquéfaction 10. Ce gaz étant froid, il peut être utilisé pour refroidir et condenser le gaz comprimé dans le premier échangeur 17. Il est donc prévu de le faire circuler à contresens dans ce premier échangeur 17 avant de le faire retourner dans le collecteur 2.The gas in the gaseous phase of the
Si le gaz en phase gazeuse du ballon 40 pour diverses raisons, notamment lors de phases transitoires, ne peut pas être recyclé vers le collecteur 2, il est prévu de l'envoyer à une torchère ou une unité de combustion. Un jeu de vannes 31, 32 contrôle l'envoi du gaz en phase gazeuse du ballon 40 respectivement vers le collecteur 2 par une conduite de liaison 35 ou vers une unité de combustion (non représentée).If the gas in the gaseous phase of the
Le gaz en phase liquide récupéré au fond du ballon 40 est quant à lui destiné à retourner dans le réservoir 1. En fonction des conditions de fonctionnement, le gaz en phase liquide peut être envoyé directement dans le réservoir 1 (passage contrôlé par une vanne 33), soit à l'aide d'une pompe 41 (passage contrôlé par une vanne 34).The gas in the liquid phase recovered at the bottom of the
Le retour du gaz en phase liquide en provenance du ballon 40, directement ou par la pompe 41, vers le réservoir 1 se fait par l'intermédiaire d'une conduite isolée 36 munie ici d'une vanne 54, par exemple une soupape d'arrêt.The return of the gas in liquid phase from the
Dans l'unité de reliquéfaction 10, il convient d'assurer le refroidissement du gaz comprimé dans le compresseur multi-étagé (étages 11, 12 et 13). Ce refroidissement se fait habituellement à l'aide d'une machine thermodynamique distincte, fonctionnant par exemple selon un cycle de Brayton, et utilisant de l'azote comme fluide frigorigène. Il est possible d'utiliser dans l'unité de reliquéfaction 10 une telle machine de réfrigération qui vient alors refroidir et condenser le gaz au sein du premier échangeur 17. Toutefois, il est proposé ici comme mentionné plus haut, de munir cette unité de reliquéfaction d'une boucle de refroidissement utilisant le gaz naturel comme fluide frigorigène. Cette boucle commence par une conduite dérivée 18 qui sépare le flux de gaz en aval du compresseur multi-étagé (étages 11, 12, 13) en un premier flux, ou flux principal, qui correspond au circuit principal décrit précédemment, et en un second flux, ou flux dérivé.In the
La conduite de dérivation 18 est de préférence reliée au circuit principal au niveau du premier échangeur 17. Le gaz en phase gazeuse qui pénètre donc dans la conduite de dérivation 18 se trouve à "haute pression" (environ 50 bar dans l'exemple numérique donné) et à une température intermédiaire entre 40°C et -110°C.The
Le gaz prélevé par la conduite de dérivation 18 est détendu au sein de moyens de détente formés par une turbine de détente 14. Cette turbine de détente 14 est, dans la forme de réalisation préférée illustrée sur le dessin, relié mécaniquement aux trois roues de compression correspondant aux étages 11, 12 et 13 du compresseur multi-étagé de l'unité de reliquéfaction 10. La transmission 15 par arbres et pignons relie la turbine de détente 14 et les roues de compression du compresseur multi-étagé. Cette transmission 15 est symbolisée par un trait reliant sur les figures la turbine de détente 14 aux étages 11, 12 et 13.The gas taken by the
Le gaz est détendu par exemple à un niveau de pression qui correspondait à son niveau de pression en entrant dans l'unité de reliquéfaction 10, soit environ 15 à 20 bar. Sa température descend en dessous de -120°C. Ce flux de gaz (phase gazeuse) est alors envoyé dans le premier échangeur 17 à contresens pour refroidir et condenser le gaz sous pression du circuit principal, tout d'abord dans une portion 19 se trouvant en aval de la conduite de dérivation 18 puis dans une portion de ce circuit principal dans le premier échangeur 17 en amont de cette conduite de dérivation 18. En sortie du premier échangeur 17, le gaz détendu retrouve des températures de l'ordre de 40°C et peut être réinjecté en phase gazeuse dans le circuit principal de l'unité de reliquéfaction, en amont du compresseur multi-étagé par une conduite de retour 21.The gas is expanded for example to a pressure level which corresponded to its pressure level when entering the
On réalise ainsi une boucle de refroidissement ouverte qui utilise comme gaz pour le refroidissement le même gaz que celui qui doit être liquéfié.An open cooling loop is thus produced which uses as gas for cooling the same gas as that which is to be liquefied.
Comme indiqué plus haut, le système illustré présente aussi une ligne d'alimentation en gaz sous (haute) pression d'un moteur à gaz, par exemple un moteur de type MEGI (non illustré). Cette ligne d'alimentation part d'un réservoir 1. Elle est tout d'abord alimentée par une pompe immergée 50 qui alimente en liquide cryogénique (GNL) une conduite 51 pour le conduire vers une pompe haute pression 48. Le liquide sous haute pression est alors mené par une conduite 56 dans un vaporiseur 61, réalisant par exemple un échange thermique avec de la vapeur d'eau, pour produire de la vapeur (gaz naturel en phase gazeuse) sous haute pression pouvant alimenter alors un moteur de type MEGI par une conduite d'alimentation 62.As indicated above, the illustrated system also has a gas supply line under (high) pressure to a gas engine, for example a MEGI type engine (not illustrated). This supply line starts from a tank 1. It is first of all supplied by an immersed
On remarque sur les figures la présence d'une dérivation 57 sur la conduite 56. Cette dérivation 57 va alimenter en liquide sous pression, toujours en phase liquide, un deuxième échangeur 60 destiné à sous-refroidir du condensat sortant du premier échangeur 17 dans le circuit principal de l'unité de reliquéfaction 10. Ce deuxième échangeur 60, dans la forme de réalisation illustrée sur la
À titre d'exemple numérique simplement illustratif et non limitatif, le liquide dérivé dans la dérivation 57 se trouve à environ -150°C en amont du deuxième échangeur 60 et ressort de ce dernier par exemple à -140°C (toujours en phase liquide). Dans la conduite isolée 22, le gaz condensé sortant du premier échangeur 17 passe quant à lui par exemple de -120°C à -135°C.By way of merely illustrative and non-limiting numerical example, the liquid derived in the
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Cette forme de réalisation se veut illustrative (et non limitative) des diverses possibilités de positionnement d'échangeurs alimentés par du liquide cryogénique sous haute pression. Ces échangeurs peuvent être au nombre de quatre, ou bien plus, ou bien moins. Ils sont de préférence montés en parallèle comme illustré, les échangeurs 80n formant un système d'échange monté en série avec le deuxième échangeur 60. D'autres montages (série ou parallèle) peuvent être envisagés. On peut aussi prévoir des échangeurs sur le circuit de refroidissement en boucle ouverte.This embodiment is intended to be illustrative (and not limiting) of the various possibilities for positioning exchangers supplied with cryogenic liquid under high pressure. These exchangers may be four in number, or more, or much less. They are preferably mounted in parallel as illustrated, the exchangers 80n forming an exchange system mounted in series with the
Enfin la
Les variantes proposées dans les diverses formes de réalisation peuvent être combinées de diverses manières pour réaliser d'autres formes de réalisation selon la présente invention mais non illustrées.The variations provided in the various embodiments can be combined in various ways to achieve other embodiments according to the present invention but not illustrated.
Le système proposé ici réalise une coopération entre une unité de liquéfaction et une alimentation en gaz à haute pression, par exemple pour l'alimentation d'un moteur de type MEGI. Une synergie est créée entre ces deux sous-systèmes, l'un ayant des besoins en froid pour liquéfier un gaz et l'autre nécessitant de l'énergie pour vaporiser du liquide à haute pression. Le système tel que proposé permet d'augmenter le rendement de l'unité de reliquéfaction, c'est-à-dire d'augmenter la proportion du gaz évaporé qui est reliquéfiée, de limiter les besoins en froid à fournir pour réaliser la reliquéfaction de gaz évaporé et à la fois de limiter les besoins énergétiques pour obtenir un gaz à haute pression pour alimenter un moteur (moteur MEGI ou autre système fonctionnant avec du gaz sous haute pression).The system proposed here achieves cooperation between a liquefaction unit and a high pressure gas supply, for example for the supply of a MEGI type motor. A synergy is created between these two sub-systems, one having cooling needs to liquefy a gas and the other requiring energy to vaporize liquid at high pressure. The system as proposed makes it possible to increase the efficiency of the reliquefaction unit, that is to say to increase the proportion of the evaporated gas which is reliquefied, to limit the cooling requirements to be supplied to carry out the reliquefaction of evaporated gas and at the same time to limit the energy needs to obtain a high pressure gas to supply an engine (MEGI engine or other system operating with gas under high pressure).
Le système proposé ici est particulièrement bien adapté à une unité de reliquéfaction présentant une boucle ouverte de gaz réfrigérant correspondant au gaz réfrigéré avec une production de froid à deux températures différentes, une température d'environ -120°C en sortie de la turbine de détente et une température d'environ -160°C en sortie de la vanne de détente.The system proposed here is particularly well suited to a reliquefaction unit having an open loop of refrigerant gas corresponding to refrigerated gas with production of cold at two different temperatures, a temperature of around -120 ° C at the outlet of the expansion turbine. and a temperature of about -160 ° C at the outlet of the expansion valve.
Le système est indépendant des moteurs se trouvant à bord du navire et qui sont alimentés par le gaz évaporé. On peut avoir deux types de moteurs à gaz différents, l'un étant alimenté par la ligne d'alimentation haute pression et l'autre par le gaz évaporé comprimé par la première unité de compression. Le système permet aussi, à partir du gaz évaporé, indépendamment de toute autre source de froid extérieure, de réaliser une liquéfaction.The system is independent of the engines on board the vessel which are powered by evaporated gas. There can be two different types of gas engines, one being supplied by the high pressure supply line and the other by the evaporated gas compressed by the first compression unit. The system also allows, from the evaporated gas, independently of any other external cold source, to achieve liquefaction.
Dans la dérivation créée sur la ligne d'alimentation en gaz sous haute pression, la production de froid peut être adaptée à la charge de l'unité de reliquéfaction et peut être régulée sur une large plage.In the bypass created on the high pressure gas supply line, the cold production can be matched to the load of the reliquefaction unit and can be regulated over a wide range.
Le système proposé ne nécessite pas d'unité de traitement d'azote ou similaire. Sa structure est simplifiée par l'utilisation d'un gaz réfrigérant de même nature que le gaz à réfrigérer et à liquéfier et qui sert en outre de carburant à un moteur (ou similaire).The proposed system does not require a nitrogen treatment unit or the like. Its structure is simplified by the use of a refrigerant gas of the same nature as the gas to be refrigerated and to be liquefied and which also serves as fuel for an engine (or similar).
Bien entendu, la présente invention ne se limite pas aux formes de réalisation des systèmes et procédés décrits ci-dessus à titre d'exemples non limitatifs mais elle concerne également toutes les variantes de réalisation à la portée de l'homme du métier dans le cadre des revendications ci-après.Of course, the present invention is not limited to the embodiments of the systems and methods described above by way of nonlimiting examples, but it also relates to all the variant embodiments within the reach of those skilled in the art in the context of of the following claims.
Claims (14)
- System for treating a gas produced by the evaporation of a cryogenic liquid and for supplying a gas engine with pressured gas, said system comprising, on the one hand, from upstream to downstream, a reliquefaction unit (10) with compression means (11, 12, 13), a first heat exchanger (17) and expansion means (30), and, on the other hand, a pressurized gas supply line comprising from upstream to downstream a pump (48) to pressurize liquid and vaporization means (61) under high pressure, the pressurized gas supply line having, upstream of the vaporization means (61), a bypass (57) for feeding a second heat exchanger (60) between, on the one hand, pressurized fluid from the supply line (56) and, on the other hand, a line (22) of the reliquefaction unit (10) downstream of the first heat exchanger (17) and upstream of the expansion means (30),
characterized in that the gas resulting from evaporation of a cryogenic liquid, then compressed and cooled is at least partially condensed in the first heat exchanger (17). - System according to claim 1, characterized in that the bypass (57) feeds downstream of the second exchanger (60) a cooling system.
- System according to claim 2, characterized in that it comprises a third exchanger (70) mounted in series with and downstream of the second exchanger (60).
- System according to one of claims 1 or 2, characterized in that it comprises a heat exchanger (70) mounted in parallel with the second exchanger (60).
- System according to one of claims 1 to 4, characterized in that the bypass (56) further feeds the second exchanger (60), one or more heat exchangers for cooling the gas prior to its liquefaction.
- System according to one of claims 1 to 5, characterized in that it comprises downstream of the expansion means (30) a balloon (40) separating the gaseous phase from the liquid phase in the expanded fluid, in that a line leads the gaseous phase to a manifold for mixing it with the gas from the evaporation of the cryogenic liquid, and in that the bypass (56) feeds a heat exchanger (80dd') for cooling the gaseous phase prior to introduction into the manifold (2).
- System according to one of claims 1 to 6, characterized in that the reliquefaction unit comprises downstream of the compression means (11, 12, 13) a bypass to a loop having second expansion means (14), and in that the loop joins the circuit upstream of the compression means (11, 12, 13) after having passed through the first heat exchanger (17) in the opposite direction to the gas fraction of the circuit not bypassed by the loop.
- System according to claim 7, characterized in that the compression means comprise several compression stages (11, 12, 13) each with a compressor wheel, in that the second expansion means comprise an expansion turbine (14), and in that each compressor wheel and the expansion turbine (14) are associated with a same mechanical transmission (15).
- System according to claim 3 as well as according to one of claims 7 or 8, insofar as they depend on claim 3, characterized in that the third heat exchanger (70) exchanges heat between pressurized liquid derived from the supply line (56) and gas between the compression means (11, 12, 13) and the second expansion means (14).
- Vessel, in particular LNG carrier, propelled by a gas engine, characterized in that it comprises a system for treating a gas produced by the evaporation of a cryogenic liquid and for supplying a gas engine with pressurized gas according to one of claims 1 to 9.
- Method for treating a gas flow produced by the evaporation of a cryogenic liquid and for supplying an engine with gas under high pressure,
said gas flow being first compressed then cooled in a first heat exchanger (17) before being expanded, and
the supply in gas under high pressure being achieved by pressurizing cryogenic liquid then vaporizing it,
characterized in that after its compression, the flow of pressurized liquid is separated into a first part of liquid flow and a second part of liquid flow,
in that the first part of the liquid flow is used to cool compressed and condensed gas within a second exchanger (60) prior to expansion of the condensed gas, and
in that the second part of the liquid flow receives the first part of the liquid flow after the latter has cooled compressed gas, the entire liquid flow then being vaporized, characterized in that the gas resulting from the evaporation of a cryogenic liquid and subsequently compressed and cooled is at least partially condensed within the first heat exchanger. - Method according to claim 11, characterized in that for more than half, and preferably at least 90% by mass of the compressed gas, is condensed before being cooled within the second exchanger (60).
- Method according to one of claims 11 or 12, characterized in that the flow of pressurized fluid is also used to cool gas before it is condensed.
- Method according to one of claims 11 to 13, characterized in that part of the compressed gas is taken from the first heat exchanger to be expanded within an expansion turbine (14), and in that the expanded gas is introduced into the first heat exchanger (17) counter currently to cool the compressed gas and cause its condensation.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR1652504A FR3049341B1 (en) | 2016-03-23 | 2016-03-23 | SYSTEM FOR TREATING A GAS FROM THE EVAPORATION OF A CRYOGENIC LIQUID AND THE PRESSURIZED GAS SUPPLY OF A GAS ENGINE |
PCT/FR2017/050669 WO2017162984A1 (en) | 2016-03-23 | 2017-03-22 | System for treating a gas produced by the evaporation of a cryogenic liquid and for supplying a gas engine with pressurised gas |
Publications (2)
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EP3433557A1 EP3433557A1 (en) | 2019-01-30 |
EP3433557B1 true EP3433557B1 (en) | 2020-09-02 |
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EP17716577.6A Active EP3433557B1 (en) | 2016-03-23 | 2017-03-22 | System for treating a gas produced by the evaporation of a cryogenic liquid and for supplying a gas engine with pressurised gas |
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US (1) | US10914516B2 (en) |
EP (1) | EP3433557B1 (en) |
JP (1) | JP6882322B2 (en) |
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CN (1) | CN109154471B (en) |
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KR102387172B1 (en) * | 2017-12-29 | 2022-04-15 | 대우조선해양 주식회사 | Boil-Off Gas Treating Apparatus and Method of Liquefied Gas Regasification System |
FR3087525B1 (en) * | 2018-10-22 | 2020-12-11 | Air Liquide | LIQUEFACTION PROCESS OF AN EVAPORATION GAS CURRENT FROM THE STORAGE OF A LIQUEFIED NATURAL GAS CURRENT |
JP6595143B1 (en) * | 2019-07-03 | 2019-10-23 | 株式会社神戸製鋼所 | Compressor unit and control method of compressor unit |
FR3101408B1 (en) * | 2019-09-30 | 2022-05-13 | Gaztransport Et Technigaz | System for treating a gas contained in a tank for storing and/or transporting gas in liquid and gaseous state |
FR3124830A1 (en) * | 2021-06-30 | 2023-01-06 | Gaztransport Et Technigaz | Gas supply system for appliances using high and low pressure gas |
FR3119013B1 (en) * | 2021-01-19 | 2023-03-17 | Gaztransport Et Technigaz | Gas supply system for appliances using high and low pressure gas |
FR3133907B1 (en) * | 2022-03-22 | 2024-02-09 | Eifhytec | Product transformation system |
FR3134431A1 (en) * | 2022-04-07 | 2023-10-13 | Gaztransport Et Technigaz | Gas supply system for high and low pressure gas consuming appliances and method of controlling such a system |
FR3134430A1 (en) * | 2022-04-07 | 2023-10-13 | Gaztransport Et Technigaz | Gas supply system for high and low pressure gas consuming appliances and method of controlling such a system |
CN115711360B (en) * | 2022-11-15 | 2023-12-08 | 中国船舶集团有限公司第七一一研究所 | Deep cooling type evaporation gas reliquefaction system |
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KR100638925B1 (en) * | 2005-01-18 | 2006-10-26 | 대우조선해양 주식회사 | Operating system for sub-cooled liquefaction boil-off gas of LNG ship |
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KR101386543B1 (en) * | 2012-10-24 | 2014-04-18 | 대우조선해양 주식회사 | System for treating boil-off gas for a ship |
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KR101640768B1 (en) * | 2013-06-26 | 2016-07-29 | 대우조선해양 주식회사 | Method for building a ship |
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2016
- 2016-03-23 FR FR1652504A patent/FR3049341B1/en active Active
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2017
- 2017-03-22 US US16/087,135 patent/US10914516B2/en active Active
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RU2733125C2 (en) | 2020-09-29 |
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FR3049341A1 (en) | 2017-09-29 |
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CN109154471B (en) | 2021-05-11 |
US10914516B2 (en) | 2021-02-09 |
JP2019510943A (en) | 2019-04-18 |
ES2829266T3 (en) | 2021-05-31 |
CN109154471A (en) | 2019-01-04 |
EP3433557A1 (en) | 2019-01-30 |
WO2017162984A1 (en) | 2017-09-28 |
KR20180122723A (en) | 2018-11-13 |
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