EP3380310A1 - Perfectionnements apportés ou se rapportant à des composites renforcés de fibres - Google Patents

Perfectionnements apportés ou se rapportant à des composites renforcés de fibres

Info

Publication number
EP3380310A1
EP3380310A1 EP16801214.4A EP16801214A EP3380310A1 EP 3380310 A1 EP3380310 A1 EP 3380310A1 EP 16801214 A EP16801214 A EP 16801214A EP 3380310 A1 EP3380310 A1 EP 3380310A1
Authority
EP
European Patent Office
Prior art keywords
reinforcing composite
substrate
reinforcing
composite
layers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16801214.4A
Other languages
German (de)
English (en)
Inventor
Andreas GABOR
Esteban Villalon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexcel Holding GmbH
Hexcel Composites SAS
Original Assignee
Hexcel Holding GmbH
Hexcel Composites SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hexcel Holding GmbH, Hexcel Composites SAS filed Critical Hexcel Holding GmbH
Priority claimed from PCT/EP2016/078673 external-priority patent/WO2017089460A1/fr
Publication of EP3380310A1 publication Critical patent/EP3380310A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/86Incorporated in coherent impregnated reinforcing layers, e.g. by winding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00Use of unspecified macromolecular compounds as moulding material
    • B29K2101/10Thermosetting resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/26Scrap or recycled material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3002Superstructures characterized by combining metal and plastics, i.e. hybrid parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3055Cars

Definitions

  • the present invention relates to improvements in or relating to fibre reinforced composites.
  • Composites comprising fibre reinforced materials and in particular prepregs comprising fibres and thermosetting resins may be stacked to form preforms. These preforms are subsequently cured in a mould or a vacuum bag to form a reinforced composite material.
  • Such composite materials are known, they are lightweight and of high strength and are used in many structural applications such as in the automobile and aerospace industries and in industrial applications such as wind turbine components such as spars and the shells used to make the turbine blades.
  • Prepreg is the term used to describe fibres and/or fabric impregnated with a resin in the uncured state and ready for curing.
  • the fibres may be in the form of tows or fabrics.
  • the tows or fabrics generally comprise a plurality of thin fibres called filaments.
  • the selection of fibrous materials and resins employed in the prepregs depends upon the properties required of the cured composite material and also the use to which the composite is to be put.
  • prepregs Various methods have been proposed for the production of prepregs, one of the preferred methods being the impregnation of a moving fibrous web with a liquid, molten or semi-solid uncured thermosetting resin.
  • the prepreg produced by this method is then cut into sections of desired dimensions and a stack of the sections is moulded and cured by heating to produce the final fibre reinforced laminate.
  • Curing may be performed in a vacuum bag which may be placed in a mould for curing as is preferred in the manufacture of wind energy structures such as shells for the blades and spars.
  • the stack may be formed in a closed mould and cured directly in the mould by heating (compression moulding).
  • Epoxy resins are highly suitable resins although they can be brittle after cure causing the final laminate to crack or fracture upon impact and it is therefore common practice to include toughening materials such as thermoplastics or rubbers in the epoxy resin.
  • the prepreg can be in the form of an integral layer of reinforcement material or it can be in the form of elements oriented in random directions to form a quasi-isotropic material layer. Multiple prepreg layers or elements are conventionally combined to form composite laminate structures. The prepreg layers may be arranged in parallel, randomly in an in-plane direction (quasi-isotropic) or as isotropic or quasi-isotropic prepreg elements.
  • the laminate Following formation of the laminate, it may be cut to the required shape. This produces off- cuts which can be wasteful and costly.
  • the composites can be used to provide strength and reinforcement to articles such as automobiles, aircraft, railroad vehicles, boats and ships.
  • they may be laminated to metal components to provide reinforcement, particularly whilst also reducing the weight of the component.
  • the degree of reinforcement that is required may vary along the length or across the width of a component. For example, certain regions in a component may need extra strength as they may be more vulnerable to crash, or they may be at a location where any external force that may be applied to the article is greater than at other locations.
  • the composite has been provided across the entire component in an amount that provides the maximum required reinforcement, albeit that the maximum reinforcement may be required only at certain locations of the component. This is wasteful and costly as more composite material than is required is used, and it also results in an unnecessary and undesirable increase in the weight of the component. This can lead to increased fuel consumption in vehicles and the like.
  • the composite may be further adapted by cutting to suit particular applications. This has the disadvantage of creating scrap composite material which can be wasteful and inefficient.
  • the present inventions aim to obviate or at least mitigate the above described problems and/or to provide improvements generally.
  • the number of layers of reinforcing composite material that are employed at locations that are potentially subject to stress is determined according to the potential stresses evaluated at those locations, wherein more layers of composite material are provided at locations where there is the potential for higher stress.
  • the present invention provides a reinforcing composite comprising a plurality of layers of reinforcing composite material wherein the number of layers of reinforcing composite material that are employed at locations that are potentially subject to stress is determined according to the potential stresses evaluated at those locations, and wherein more layers of composite material are provided at locations where there is the potential for higher stress.
  • the reinforcing composite may be provided as strengthening material to any substrate particularly to metal substrates, wooden substrates and plastic substrates.
  • the substrates may be components used in automobiles, boats, aerospace vehicles and the like.
  • the invention therefore further provides a substrate that is reinforced by lamination with a composite material wherein the thickness of the composite material varies across the surface of the substrate, thicker sections of the composite material being provided at locations on the substrate that have the potential to being subject to higher stress.
  • the thickness of the reinforcing composite may be varied by adjusting the number of layers of reinforcing composite material provided at various locations across the surface of the substrate.
  • the reinforcing composite material may be pre-made, cured and then laminated to the substrate that is to be reinforced, or layers of the uncured reinforcing composite material (prepreg) may be laid up on the substrate and cured to both form the cured composite and adhere the composite to the substrate.
  • the reinforcing composite used in this invention may be used for reinforcing a substrate.
  • the reinforcing composite further comprises an adhesive for adhering the composite to the substrate. The adhesive improves the bond between the reinforcing composite and the substrate material.
  • the substrate material and the reinforcing composite are conjoined to form an integral moulding material.
  • the integral moulding material is located in a compression mould which is adapted to mould the integral moulding material to the desired shape followed by curing or whilst simultaneously curing the integral moulding material.
  • the integral moulding material may further comprise a release material for releasing the moulding material from a mould surface.
  • Suitable release materials may comprise polyolefin filim materials.
  • the polyolefin film material may comprise multiple layers of varying polyolefin polymers ranging from C2 (polyethylene) through to C6 and/or copolymers thereof.
  • suitable release material may comprise fluorinated thermoplastic films (such as polytetrafluorethylene (PTFE), fluorinated ethylene propylene (FEP), ethylene tetrafluorethylene (ETFE), polyvinyl fluoride (PVF), chlorinated thermoplastic films such as polyvinylchloride (PVC), low surface energy thermoplastic films (such as polymethylpentene PMP), thermoplastic films chemically modified to have low surface energy (such as siloxane treated polyethylene terephthalate (PET), thin metal foils (such as aluminium), pre-cured thermoset fibre reinforced lamiantes, films of low melting temperature waxes (such as paraffin wax) or synthetic waxes (such as substituted amide waxes) or salts of fatty acids (such as calcium stearate), woven fibre or veil layers infused with low melting temperature waxes (such as paraffin wax) or synthetic waxes (such as substituted amide waxes) or salts of fatty acids (such as calcium stearate) or
  • Suitable adhesive materials may be applied in film form, as a paste, or sprayed and could be selected from the group consisting of thermoset resins such as epoxy, cyanate ester, and phenolic resins or from groups consisting of thermoplastic bonding adhesives such as polyurethane, polyvinylacetate (PVA) and PVC.
  • thermoset resins such as epoxy, cyanate ester, and phenolic resins
  • thermoplastic bonding adhesives such as polyurethane, polyvinylacetate (PVA) and PVC.
  • Suitable epoxy resins include diglycidyl ethers of bisphenol A, diglycidyl ethers of bisphenol F, epoxy novolac resins and N-glycidyl ethers, glycidyl esters, aliphatic and cycloaliphatic glycidyl ethers, glycidyl ethers of aminophenols, glycidyl ethers of any substituted phenols and blends thereof. Also included are modified blends of the aforementioned thermosetting polymers.
  • These polymers are typically modified by rubber or thermoplastic addition such as carboxy terminated butyl rubber (CTBN/RAM) combinations where the olefinic nature of the modifier enhances enables the ability of the adhesive to absorb oil from a substrate surface and form a better bond.
  • CBN/RAM carboxy terminated butyl rubber
  • These polymers are often further modified by a surfactant or adhesion promoting chemical.
  • Any suitable catalyst may be used. The catalyst will be selected to correspond to the resin used.
  • One suitable catalyst for use with an epoxy resin is a dicyandiamide curing agent. The catalyst may be accelerated. Where a dicyandiamide catalyst is used, a substituted urea may be used as an accelerator.
  • Suitable accelerators include Diuron, Monuron, Fenuron, Chlortoluron, bis-urea of toluenediisocyanate and other substituted homologues.
  • the epoxy curing agent may be selected from Dapsone (DDS), Diamino- diphenyl methane (DDM), BF3-amine complex, substituted imidazoles, accelerated anhydrides, metaphenylene diamine, diaminodiphenylether, aromatic polyetheramines, aliphatic amine adducts, aliphatic amine salts, aromatic amine adducts and aromatic amine salts.
  • the adhesive comprises an epoxy resin, a dicyandiamide (DICY) curative, a substituted urea accelerator and an ethylene vinyl acetate.
  • the adhesive layer preferably comprises a woven fabric or scrim.
  • the scrim controls the bond line thickness between the moulding material and the substrate material. This ensures that the adhesive cannot leech away from the surface of the substrate when the sheet moulding compound or blank is subjected to pressure during moulding.
  • the scrim may be provided on the moulding material before the application of the adhesive layer.
  • Reinforcing composites according to this invention may comprise a composite of a reinforcement material and a resin material that is cured to produce the reinforcing composite.
  • the curing process transforms the resin from a plastic substance by a cross- linking process.
  • Energy and/or catalysts are added that cause the molecular chains to react at chemically active sites linking into a rigid, 3-D structure.
  • the cross-linking process forms a molecule with a larger molecular weight, resulting in a material with a higher melting point. During the reaction, the molecular weight increases to a point so that the melting point is higher than the surrounding ambient temperature, and the material forms into a solid material.
  • Suitable resin materials for use in the reinforcing composite materials used in this invention may be selected from the group consisting of thermoset resins such as epoxy, cyanate ester and phenolic resins.
  • Suitable epoxy resins include diglycidyl ethers of bisphenol A, diglycidyl ethers of bisphenol F, epoxy novolac resins and N-glycidyl ethers, glycidyl esters, aliphatic and cycloaliphatic glycidyl ethers, glycidyl ethers of aminophenols, glycidyl ethers of any substituted phenols and blends thereof. Also included are modified blends of the aforementioned thermosetting polymers. These polymers are typically modified by rubber or thermoplastic addition.
  • Any suitable catalyst may be used.
  • the catalyst will be selected to correspond to the resin used.
  • One suitable catalyst for use with an epoxy resin is a dicyandiamide curing agent.
  • the catalyst may be accelerated.
  • a dicyandiamide catalyst is used, a substituted urea may be used as an accelerator.
  • Suitable accelerators include Diuron, Monuron, Fenuron, Chlortoluron, bis-urea of toluenediisocyanate and other substituted homologues.
  • the epoxy curing agent may be selected from Dapsone (DDS), Diamino-diphenyl methane (DDM), BF3-amine complex, substituted imidazoles, accelerated anhydrides, metaphenylene diamine, diaminodiphenylether, aromatic polyetheramines, aliphatic amine adducts, aliphatic amine salts, aromatic amine adducts and aromatic amine salts.
  • the resins may further contain a dicyandiamide (DICY) curative, a substituted urea accelerator. They may also contain an ethylene vinyl acetate copolymer.
  • the resin materials may comprise a toughening agent.
  • Suitable toughening agents can be selected from liquid rubber (such as acrylate rubbers, or carboxyl-terminated acrylonitrile rubber), solid rubber (such as solid nitrite rubber, or core-shell rubbers) in the nano or macro size range, thermoplastics (such as poly (EtherSulphone), poly (Imide)), block copolymers (such as styrene-butadiene-methacrylate triblocks), High modulus particles (such as Silica) in the nano or macro size range or blends thereof.
  • liquid rubber such as acrylate rubbers, or carboxyl-terminated acrylonitrile rubber
  • solid rubber such as solid nitrite rubber, or core-shell rubbers
  • thermoplastics such as poly (EtherSulphone), poly (Imide)
  • block copolymers such as styrene-butadiene-methacrylate triblocks
  • High modulus particles such as Silica
  • the reinforcing composite material may comprise any fibrous material such as natural fibres (eg flax, hemp, straw, hay, seagrass, basalt), glass fibre, aramid, PAN or carbon fibre, including mixtures thereof, such as carbon fibres and glass fibres.
  • the fibrous reinforcement material may also comprise multiple layers of fibrous material.
  • the fibrous reinforcement layers comprises oriented fibres.
  • the fibrous material layer may comprise a weight ranging from 55 to 10000 gsm (g/m 2 ), preferably from 100 to 8000 gsm and more preferably from 150 to 4000 gsm.
  • the thickness of the fibrous layer may range from 0.05 mm to 10 mm, preferably from 0.1 mm to 8 mm.
  • the fibrous material may be unidirectional, woven, chopped, biaxial or triaxial.
  • the fibre length may vary from 1 mm to several meters, preferably from 5 mm to 100 mm, more preferably from 10 mm to 100mm or less.
  • the fibres in the reinforcing composite are aligned in different directions in the various layers of material employed at any particular location in the reinforcing composite.
  • the base section of the composite material which is of uniform thickness may comprise several layers and the orientation of the fibres within the layers may be parallel or at 90° to each other.
  • the additional layers of composite material that are provided at the locations where the potential for high stress is perceived may be aligned at 90° to the fibres in the base layer. Table 1 below illustrates how layers of moulding materials based on unidirectional fibres may be laid up with the fibres in differing orientations. Lay up
  • the invention is however equally applicable to composites in which the fibres within the layers have a random orientation or are parallel in all the layers.
  • the fibres may be provided as a woven fabric.
  • the reinforcing composite of the invention may comprise an insulating layer to prevent galvanic coupling between the fibrous reinforcement and a substrate to which the reinforcing composite is attached. This is particularly advantageous for metal substrates and carbon fibre reinforcement to prevent corrosion of the metal.
  • the adhesive layer when used may also comprise an insulating layer to prevent galvanic coupling between the substrate material and the fibrous reinforcement material.
  • the insulating layer in the adhesive layer may be formed by the adhesive or by another material.
  • the insulating layer material in the adhesive may differ from the insulating layer material of the moulding material.
  • Insulating layers may comprise a suitable insulating layer material having a conductivity of 1 S.m "1 or less, preferably 0.1 S.m "1 or less, and more preferably of 0.01 S.m "1 or less, or combinations of the aforesaid ranges.
  • Suitable insulating materials may comprise glass fibre, flax, hemp, rubber, thermoplastics such as polyamide, or ethylene/vinyl acetate copolymers.
  • the insulating material may be in the form of a veil, scrim of fabric.
  • Curing of the reinforcing material may take place in a single stage or in multiple stages such as two, three or more stages. Curing may take place following compression moulding or during compression moulding. If curing occurs in multiple stages, one or more stages may coincide with compression moulding.
  • typical initial cure cycles for the layer of the fibre reinforced composite include an increase in temperature from ambient to temperatures up to 30 to 200°C, preferably 30 to 160°C, and may be followed by a dwell stage at a fixed temperature ranging from 30 to 200°C, preferably 50 to 160°C, more preferably 80 to 150°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
  • the temperature is further increased to temperatures up to 60 to 200°C, preferably 60 to 160°C, followed by a cure stage at a fixed temperature ranging from 60 to 200°C, preferably 60 to 160°C, more preferably 80 to 160°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
  • Typical post cure cycles for the moulding material include an increase in temperature from ambient to temperatures up to 30 to 200°C, preferably 30 to 160°C, and may be followed by a dwell stage at a fixed temperature ranging from 30 to 200°C, preferably 50 to 160°C, more preferably 80 to 150°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
  • the temperature is further increased to temperatures up to 60 to 200°C, preferably 60 to 160°C, followed by a cure stage at a fixed temperature ranging from 60 to 200°C, preferably 60 to 160°C, more preferably 80 to 160°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
  • the article is moulded in a single step at a temperature ranging from 60 to 200°C, preferably 80 to 160°C over a period of from 20s to 8 minutes, preferably from 40s to 3 minutes, more preferably from 60s to 120s and/or combinations of the aforesaid periods.
  • the article may be cured or part cured.
  • the part cured article may proceed through to cure during other subsequent production steps such as assembly or coating.
  • At least one of the additional layers of composite material that are provided at the positions perceived to be vulnerable to high stress may be off cuts or scrap material, such as material obtained when prepregs are cut to the desired shape to provide the base reinforcement for the structure. In this way wastage can be reduced at the same time as providing the desired increased local reinforcement.
  • the off-cuts or scrap may be consolidated in a sheet material.
  • the off-cuts or scrap may be cut into multiple fiber elements prior to their consolidation.
  • the sheet material may be applied to form protrusions, channels or surfaces of complex curvature.
  • the invention can employ a laminate comprising multiple plies of tape material with selected areas comprising additional plies.
  • Each ply contains one or more sections of tape (also called courses) placed parallel to each other, and each ply is fused to one or more underlying plies.
  • the shape of each ply and the orientation, or angle, of the fibers in the ply relative to fibers in other plies in the laminate are chosen such that the final produced article will have the desired structural characteristics across its surface.
  • Layers may be tacked together and the method used to tack layers together and the degree to which they are tacked is another parameter that can vary in different embodiments.
  • Methods for tacking the courses to underlying plies could include contact heating, ultrasonic welding, induction welding, laser heating, hot gasses, or other methods of adhering plies to each other. Also, the method could be used with an articulating head or a moving substrate surface, or a combination of the two positioning approaches. Although an embodiment described herein uses a fixed material placement head that is positioned over a flat substrate surface that can move in the x and y directions as well as rotate, the relative motion between the placement head and the substrate surface could also be achieved by moving the placement head or a combination of the two.
  • a reinforcing composite comprising a plurality of layers of reinforcing composite material forming a stack wherein at least one layer of the composite material comprises a moulding compound comprising oriented resin impregnated fiber elements, wherein the fiber elements are obtained from off-cuts or scrap material derived from cutting the reinforcing composite material prior to its location in the stack.
  • the off-cuts or scrap material are derived from separating off- cuts or scrap material comprising multiple layers of reinforcing composite material. This enables scrap material to be re-used.
  • the off-cuts or scrap material are preferably cut into the fiber elements.
  • the moulding compound is in the form of a sheet or layer in which the fiber elements are randomly oriented.
  • the fiber elements comprise unidirectional fibers.
  • the fibre elements are consolidated following orientation.
  • the moulding compound layer is employed at one or more locations within the stack that are subject to elevated in-use stress in comparison with other locations within the stack according to an in-use stress evaluation of the stack.
  • a moulding compound comprising oriented resin impregnated fiber elements, wherein the fiber elements are obtained from off-cuts or scrap material derived from cutting a reinforcing composite comprising a plurality of layers of reinforcing composite material forming a stack.
  • the off-cuts or scrap material is derived from separating off-cuts or scrap material comprising multiple layers of reinforcing composite material.
  • the moulding compound may be adapted to form particular aspects of a moulded composite part including one or more of protrusions, rubs, channels and shapes of complex curvature.
  • the fiber elements may be consolidated by heating to form a sheet.
  • the elements are heated to a temperature of between 60 to 80°C.
  • the fibre elements are consolidated following orientation.
  • At least one layer of the composite material comprises a moulding compound obtained by means of the method of the present invention comprising the step of locating the moulding compound within the stack.
  • Figure 1 shows four reinforcing parts of composite reinforcing material according to an embodiment of the invention.
  • Figure 2 is a cross section on the line A-A of Figure 1.
  • Figure 3 is a cross section on the line B-B of Figure 1.
  • Figure 4 is a cross section on the line C-C of Figure 1 .
  • Figure 1 shows 4 parts each having a base section (1 ) from which a section of material has been removed from locations (2).
  • Figures 2, 3 and 4 show how the resulting multilayer composite provides additional reinforcement along the lines B-B and localized additional reinforcement at various locations along line A-A and C-C. Figures 2, 3 and 4 also illustrate how the orientation of the fibres in the various layers can be varied as required.
  • the materials shown are suitable for lamination to a substrate such as a metal automobile component, to provide structural reinforcement with localized additional reinforcement as shown for parts 1 and 3 in Figures 2 and 4.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

L'invention concerne un composite de renfort comprenant une pluralité de couches de matériau composite de renfort formant une pile, le nombre de couches et/ou l'orientation du matériau composite utilisé au niveau d'emplacements au sein de la pile étant soumis à une contrainte élevée en utilisation en comparaison avec d'autres emplacements dans la pile en fonction d'une évaluation de contrainte en utilisation de la pile, étant accru(e) avec des couches supplémentaires de matériau composite prévues au niveau des emplacements de contrainte en utilisation accrue.
EP16801214.4A 2015-11-25 2016-11-24 Perfectionnements apportés ou se rapportant à des composites renforcés de fibres Withdrawn EP3380310A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP2015196382 2015-11-25
PCT/EP2016/078673 WO2017089460A1 (fr) 2015-11-25 2016-11-24 Perfectionnements apportés ou se rapportant à des composites renforcés de fibres

Publications (1)

Publication Number Publication Date
EP3380310A1 true EP3380310A1 (fr) 2018-10-03

Family

ID=63286990

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16801214.4A Withdrawn EP3380310A1 (fr) 2015-11-25 2016-11-24 Perfectionnements apportés ou se rapportant à des composites renforcés de fibres

Country Status (1)

Country Link
EP (1) EP3380310A1 (fr)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Konstruieren mit Faser-Kunststoff-Verbunden 2. Ausgabe", 31 December 2007, SPRINGER, ISBN: 978-3-540-72189-5, article SCHÜRMANN HELMUT: "Konstruieren mit Faser-Kunststoff-Verbunden 2. Ausgabe", pages: 636 - 637, XP055848032 *

Similar Documents

Publication Publication Date Title
US10913223B2 (en) Fibre reinforced composites
AU2013348225B2 (en) Bonding of composite materials
KR102208691B1 (ko) 복합 재료의 결합
US20140023515A1 (en) Fibre-reinforced composite moulding and manufacture thereof
KR20200100789A (ko) 표면 제조를 위한 필 플라이 및 이를 이용한 결합 방법
WO2018049099A1 (fr) Liaison de matériaux composites
KR20180133882A (ko) 보강재를 갖는 복합재로 만들어진 부품의 제조 방법
WO2017089460A1 (fr) Perfectionnements apportés ou se rapportant à des composites renforcés de fibres
WO2012174623A1 (fr) Matière de support, mélange à mouler en feuille et procédé permettant de réaliser une matière à mouler
EP3380310A1 (fr) Perfectionnements apportés ou se rapportant à des composites renforcés de fibres
KR20190061662A (ko) 충격 흡수 및 진동 저감을 위한 준이방성 프리프레그 시트 및 이를 이용한 복합재료의 제조방법
CN114787252A (zh) 预浸料坯、层叠体及一体化成型品
JP7021216B2 (ja) セレーション状の縁部を備えた繊維強化プリフォーム
US20220372237A1 (en) Repair shape & technique for composite laminates
WO2023204131A1 (fr) Corps moulé en résine renforcée de fibres et son procédé de production

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20180625

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20211012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Effective date: 20220215