EP3380310A1 - Perfectionnements apportés ou se rapportant à des composites renforcés de fibres - Google Patents
Perfectionnements apportés ou se rapportant à des composites renforcés de fibresInfo
- Publication number
- EP3380310A1 EP3380310A1 EP16801214.4A EP16801214A EP3380310A1 EP 3380310 A1 EP3380310 A1 EP 3380310A1 EP 16801214 A EP16801214 A EP 16801214A EP 3380310 A1 EP3380310 A1 EP 3380310A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reinforcing composite
- substrate
- reinforcing
- composite
- layers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 96
- 239000000835 fiber Substances 0.000 title claims description 29
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 59
- 239000000463 material Substances 0.000 claims description 65
- 239000000758 substrate Substances 0.000 claims description 43
- 230000002787 reinforcement Effects 0.000 claims description 23
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 239000003822 epoxy resin Substances 0.000 claims description 9
- 229920000647 polyepoxide Polymers 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000004634 thermosetting polymer Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 239000012745 toughening agent Substances 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- 229920003235 aromatic polyamide Polymers 0.000 claims description 2
- 238000005728 strengthening Methods 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 238000011156 evaluation Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 43
- 238000000034 method Methods 0.000 description 12
- 238000000465 moulding Methods 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 10
- 239000005060 rubber Substances 0.000 description 10
- 229920001169 thermoplastic Polymers 0.000 description 10
- 239000004416 thermosoftening plastic Substances 0.000 description 10
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 8
- 239000000206 moulding compound Substances 0.000 description 8
- 239000004593 Epoxy Substances 0.000 description 6
- 239000004202 carbamide Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 239000002657 fibrous material Substances 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 229920001187 thermosetting polymer Polymers 0.000 description 5
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 238000000748 compression moulding Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 150000003672 ureas Chemical class 0.000 description 4
- 150000004982 aromatic amines Chemical class 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 2
- 239000005510 Diuron Substances 0.000 description 2
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 2
- 241000208202 Linaceae Species 0.000 description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000009120 camo Nutrition 0.000 description 2
- 235000005607 chanvre indien Nutrition 0.000 description 2
- JXCGFZXSOMJFOA-UHFFFAOYSA-N chlorotoluron Chemical compound CN(C)C(=O)NC1=CC=C(C)C(Cl)=C1 JXCGFZXSOMJFOA-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000004643 cyanate ester Substances 0.000 description 2
- 229960000860 dapsone Drugs 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 239000011487 hemp Substances 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- BMLIZLVNXIYGCK-UHFFFAOYSA-N monuron Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C=C1 BMLIZLVNXIYGCK-UHFFFAOYSA-N 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920009441 perflouroethylene propylene Polymers 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000306 polymethylpentene Polymers 0.000 description 2
- 239000011116 polymethylpentene Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 240000007058 Halophila ovalis Species 0.000 description 1
- 241000545744 Hirudinea Species 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000003677 Sheet moulding compound Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical group C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000004463 hay Substances 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000004093 laser heating Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011208 reinforced composite material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/86—Incorporated in coherent impregnated reinforcing layers, e.g. by winding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/10—Thermosetting resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/26—Scrap or recycled material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3002—Superstructures characterized by combining metal and plastics, i.e. hybrid parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3055—Cars
Definitions
- the present invention relates to improvements in or relating to fibre reinforced composites.
- Composites comprising fibre reinforced materials and in particular prepregs comprising fibres and thermosetting resins may be stacked to form preforms. These preforms are subsequently cured in a mould or a vacuum bag to form a reinforced composite material.
- Such composite materials are known, they are lightweight and of high strength and are used in many structural applications such as in the automobile and aerospace industries and in industrial applications such as wind turbine components such as spars and the shells used to make the turbine blades.
- Prepreg is the term used to describe fibres and/or fabric impregnated with a resin in the uncured state and ready for curing.
- the fibres may be in the form of tows or fabrics.
- the tows or fabrics generally comprise a plurality of thin fibres called filaments.
- the selection of fibrous materials and resins employed in the prepregs depends upon the properties required of the cured composite material and also the use to which the composite is to be put.
- prepregs Various methods have been proposed for the production of prepregs, one of the preferred methods being the impregnation of a moving fibrous web with a liquid, molten or semi-solid uncured thermosetting resin.
- the prepreg produced by this method is then cut into sections of desired dimensions and a stack of the sections is moulded and cured by heating to produce the final fibre reinforced laminate.
- Curing may be performed in a vacuum bag which may be placed in a mould for curing as is preferred in the manufacture of wind energy structures such as shells for the blades and spars.
- the stack may be formed in a closed mould and cured directly in the mould by heating (compression moulding).
- Epoxy resins are highly suitable resins although they can be brittle after cure causing the final laminate to crack or fracture upon impact and it is therefore common practice to include toughening materials such as thermoplastics or rubbers in the epoxy resin.
- the prepreg can be in the form of an integral layer of reinforcement material or it can be in the form of elements oriented in random directions to form a quasi-isotropic material layer. Multiple prepreg layers or elements are conventionally combined to form composite laminate structures. The prepreg layers may be arranged in parallel, randomly in an in-plane direction (quasi-isotropic) or as isotropic or quasi-isotropic prepreg elements.
- the laminate Following formation of the laminate, it may be cut to the required shape. This produces off- cuts which can be wasteful and costly.
- the composites can be used to provide strength and reinforcement to articles such as automobiles, aircraft, railroad vehicles, boats and ships.
- they may be laminated to metal components to provide reinforcement, particularly whilst also reducing the weight of the component.
- the degree of reinforcement that is required may vary along the length or across the width of a component. For example, certain regions in a component may need extra strength as they may be more vulnerable to crash, or they may be at a location where any external force that may be applied to the article is greater than at other locations.
- the composite has been provided across the entire component in an amount that provides the maximum required reinforcement, albeit that the maximum reinforcement may be required only at certain locations of the component. This is wasteful and costly as more composite material than is required is used, and it also results in an unnecessary and undesirable increase in the weight of the component. This can lead to increased fuel consumption in vehicles and the like.
- the composite may be further adapted by cutting to suit particular applications. This has the disadvantage of creating scrap composite material which can be wasteful and inefficient.
- the present inventions aim to obviate or at least mitigate the above described problems and/or to provide improvements generally.
- the number of layers of reinforcing composite material that are employed at locations that are potentially subject to stress is determined according to the potential stresses evaluated at those locations, wherein more layers of composite material are provided at locations where there is the potential for higher stress.
- the present invention provides a reinforcing composite comprising a plurality of layers of reinforcing composite material wherein the number of layers of reinforcing composite material that are employed at locations that are potentially subject to stress is determined according to the potential stresses evaluated at those locations, and wherein more layers of composite material are provided at locations where there is the potential for higher stress.
- the reinforcing composite may be provided as strengthening material to any substrate particularly to metal substrates, wooden substrates and plastic substrates.
- the substrates may be components used in automobiles, boats, aerospace vehicles and the like.
- the invention therefore further provides a substrate that is reinforced by lamination with a composite material wherein the thickness of the composite material varies across the surface of the substrate, thicker sections of the composite material being provided at locations on the substrate that have the potential to being subject to higher stress.
- the thickness of the reinforcing composite may be varied by adjusting the number of layers of reinforcing composite material provided at various locations across the surface of the substrate.
- the reinforcing composite material may be pre-made, cured and then laminated to the substrate that is to be reinforced, or layers of the uncured reinforcing composite material (prepreg) may be laid up on the substrate and cured to both form the cured composite and adhere the composite to the substrate.
- the reinforcing composite used in this invention may be used for reinforcing a substrate.
- the reinforcing composite further comprises an adhesive for adhering the composite to the substrate. The adhesive improves the bond between the reinforcing composite and the substrate material.
- the substrate material and the reinforcing composite are conjoined to form an integral moulding material.
- the integral moulding material is located in a compression mould which is adapted to mould the integral moulding material to the desired shape followed by curing or whilst simultaneously curing the integral moulding material.
- the integral moulding material may further comprise a release material for releasing the moulding material from a mould surface.
- Suitable release materials may comprise polyolefin filim materials.
- the polyolefin film material may comprise multiple layers of varying polyolefin polymers ranging from C2 (polyethylene) through to C6 and/or copolymers thereof.
- suitable release material may comprise fluorinated thermoplastic films (such as polytetrafluorethylene (PTFE), fluorinated ethylene propylene (FEP), ethylene tetrafluorethylene (ETFE), polyvinyl fluoride (PVF), chlorinated thermoplastic films such as polyvinylchloride (PVC), low surface energy thermoplastic films (such as polymethylpentene PMP), thermoplastic films chemically modified to have low surface energy (such as siloxane treated polyethylene terephthalate (PET), thin metal foils (such as aluminium), pre-cured thermoset fibre reinforced lamiantes, films of low melting temperature waxes (such as paraffin wax) or synthetic waxes (such as substituted amide waxes) or salts of fatty acids (such as calcium stearate), woven fibre or veil layers infused with low melting temperature waxes (such as paraffin wax) or synthetic waxes (such as substituted amide waxes) or salts of fatty acids (such as calcium stearate) or
- Suitable adhesive materials may be applied in film form, as a paste, or sprayed and could be selected from the group consisting of thermoset resins such as epoxy, cyanate ester, and phenolic resins or from groups consisting of thermoplastic bonding adhesives such as polyurethane, polyvinylacetate (PVA) and PVC.
- thermoset resins such as epoxy, cyanate ester, and phenolic resins
- thermoplastic bonding adhesives such as polyurethane, polyvinylacetate (PVA) and PVC.
- Suitable epoxy resins include diglycidyl ethers of bisphenol A, diglycidyl ethers of bisphenol F, epoxy novolac resins and N-glycidyl ethers, glycidyl esters, aliphatic and cycloaliphatic glycidyl ethers, glycidyl ethers of aminophenols, glycidyl ethers of any substituted phenols and blends thereof. Also included are modified blends of the aforementioned thermosetting polymers.
- These polymers are typically modified by rubber or thermoplastic addition such as carboxy terminated butyl rubber (CTBN/RAM) combinations where the olefinic nature of the modifier enhances enables the ability of the adhesive to absorb oil from a substrate surface and form a better bond.
- CBN/RAM carboxy terminated butyl rubber
- These polymers are often further modified by a surfactant or adhesion promoting chemical.
- Any suitable catalyst may be used. The catalyst will be selected to correspond to the resin used.
- One suitable catalyst for use with an epoxy resin is a dicyandiamide curing agent. The catalyst may be accelerated. Where a dicyandiamide catalyst is used, a substituted urea may be used as an accelerator.
- Suitable accelerators include Diuron, Monuron, Fenuron, Chlortoluron, bis-urea of toluenediisocyanate and other substituted homologues.
- the epoxy curing agent may be selected from Dapsone (DDS), Diamino- diphenyl methane (DDM), BF3-amine complex, substituted imidazoles, accelerated anhydrides, metaphenylene diamine, diaminodiphenylether, aromatic polyetheramines, aliphatic amine adducts, aliphatic amine salts, aromatic amine adducts and aromatic amine salts.
- the adhesive comprises an epoxy resin, a dicyandiamide (DICY) curative, a substituted urea accelerator and an ethylene vinyl acetate.
- the adhesive layer preferably comprises a woven fabric or scrim.
- the scrim controls the bond line thickness between the moulding material and the substrate material. This ensures that the adhesive cannot leech away from the surface of the substrate when the sheet moulding compound or blank is subjected to pressure during moulding.
- the scrim may be provided on the moulding material before the application of the adhesive layer.
- Reinforcing composites according to this invention may comprise a composite of a reinforcement material and a resin material that is cured to produce the reinforcing composite.
- the curing process transforms the resin from a plastic substance by a cross- linking process.
- Energy and/or catalysts are added that cause the molecular chains to react at chemically active sites linking into a rigid, 3-D structure.
- the cross-linking process forms a molecule with a larger molecular weight, resulting in a material with a higher melting point. During the reaction, the molecular weight increases to a point so that the melting point is higher than the surrounding ambient temperature, and the material forms into a solid material.
- Suitable resin materials for use in the reinforcing composite materials used in this invention may be selected from the group consisting of thermoset resins such as epoxy, cyanate ester and phenolic resins.
- Suitable epoxy resins include diglycidyl ethers of bisphenol A, diglycidyl ethers of bisphenol F, epoxy novolac resins and N-glycidyl ethers, glycidyl esters, aliphatic and cycloaliphatic glycidyl ethers, glycidyl ethers of aminophenols, glycidyl ethers of any substituted phenols and blends thereof. Also included are modified blends of the aforementioned thermosetting polymers. These polymers are typically modified by rubber or thermoplastic addition.
- Any suitable catalyst may be used.
- the catalyst will be selected to correspond to the resin used.
- One suitable catalyst for use with an epoxy resin is a dicyandiamide curing agent.
- the catalyst may be accelerated.
- a dicyandiamide catalyst is used, a substituted urea may be used as an accelerator.
- Suitable accelerators include Diuron, Monuron, Fenuron, Chlortoluron, bis-urea of toluenediisocyanate and other substituted homologues.
- the epoxy curing agent may be selected from Dapsone (DDS), Diamino-diphenyl methane (DDM), BF3-amine complex, substituted imidazoles, accelerated anhydrides, metaphenylene diamine, diaminodiphenylether, aromatic polyetheramines, aliphatic amine adducts, aliphatic amine salts, aromatic amine adducts and aromatic amine salts.
- the resins may further contain a dicyandiamide (DICY) curative, a substituted urea accelerator. They may also contain an ethylene vinyl acetate copolymer.
- the resin materials may comprise a toughening agent.
- Suitable toughening agents can be selected from liquid rubber (such as acrylate rubbers, or carboxyl-terminated acrylonitrile rubber), solid rubber (such as solid nitrite rubber, or core-shell rubbers) in the nano or macro size range, thermoplastics (such as poly (EtherSulphone), poly (Imide)), block copolymers (such as styrene-butadiene-methacrylate triblocks), High modulus particles (such as Silica) in the nano or macro size range or blends thereof.
- liquid rubber such as acrylate rubbers, or carboxyl-terminated acrylonitrile rubber
- solid rubber such as solid nitrite rubber, or core-shell rubbers
- thermoplastics such as poly (EtherSulphone), poly (Imide)
- block copolymers such as styrene-butadiene-methacrylate triblocks
- High modulus particles such as Silica
- the reinforcing composite material may comprise any fibrous material such as natural fibres (eg flax, hemp, straw, hay, seagrass, basalt), glass fibre, aramid, PAN or carbon fibre, including mixtures thereof, such as carbon fibres and glass fibres.
- the fibrous reinforcement material may also comprise multiple layers of fibrous material.
- the fibrous reinforcement layers comprises oriented fibres.
- the fibrous material layer may comprise a weight ranging from 55 to 10000 gsm (g/m 2 ), preferably from 100 to 8000 gsm and more preferably from 150 to 4000 gsm.
- the thickness of the fibrous layer may range from 0.05 mm to 10 mm, preferably from 0.1 mm to 8 mm.
- the fibrous material may be unidirectional, woven, chopped, biaxial or triaxial.
- the fibre length may vary from 1 mm to several meters, preferably from 5 mm to 100 mm, more preferably from 10 mm to 100mm or less.
- the fibres in the reinforcing composite are aligned in different directions in the various layers of material employed at any particular location in the reinforcing composite.
- the base section of the composite material which is of uniform thickness may comprise several layers and the orientation of the fibres within the layers may be parallel or at 90° to each other.
- the additional layers of composite material that are provided at the locations where the potential for high stress is perceived may be aligned at 90° to the fibres in the base layer. Table 1 below illustrates how layers of moulding materials based on unidirectional fibres may be laid up with the fibres in differing orientations. Lay up
- the invention is however equally applicable to composites in which the fibres within the layers have a random orientation or are parallel in all the layers.
- the fibres may be provided as a woven fabric.
- the reinforcing composite of the invention may comprise an insulating layer to prevent galvanic coupling between the fibrous reinforcement and a substrate to which the reinforcing composite is attached. This is particularly advantageous for metal substrates and carbon fibre reinforcement to prevent corrosion of the metal.
- the adhesive layer when used may also comprise an insulating layer to prevent galvanic coupling between the substrate material and the fibrous reinforcement material.
- the insulating layer in the adhesive layer may be formed by the adhesive or by another material.
- the insulating layer material in the adhesive may differ from the insulating layer material of the moulding material.
- Insulating layers may comprise a suitable insulating layer material having a conductivity of 1 S.m "1 or less, preferably 0.1 S.m "1 or less, and more preferably of 0.01 S.m "1 or less, or combinations of the aforesaid ranges.
- Suitable insulating materials may comprise glass fibre, flax, hemp, rubber, thermoplastics such as polyamide, or ethylene/vinyl acetate copolymers.
- the insulating material may be in the form of a veil, scrim of fabric.
- Curing of the reinforcing material may take place in a single stage or in multiple stages such as two, three or more stages. Curing may take place following compression moulding or during compression moulding. If curing occurs in multiple stages, one or more stages may coincide with compression moulding.
- typical initial cure cycles for the layer of the fibre reinforced composite include an increase in temperature from ambient to temperatures up to 30 to 200°C, preferably 30 to 160°C, and may be followed by a dwell stage at a fixed temperature ranging from 30 to 200°C, preferably 50 to 160°C, more preferably 80 to 150°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
- the temperature is further increased to temperatures up to 60 to 200°C, preferably 60 to 160°C, followed by a cure stage at a fixed temperature ranging from 60 to 200°C, preferably 60 to 160°C, more preferably 80 to 160°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
- Typical post cure cycles for the moulding material include an increase in temperature from ambient to temperatures up to 30 to 200°C, preferably 30 to 160°C, and may be followed by a dwell stage at a fixed temperature ranging from 30 to 200°C, preferably 50 to 160°C, more preferably 80 to 150°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
- the temperature is further increased to temperatures up to 60 to 200°C, preferably 60 to 160°C, followed by a cure stage at a fixed temperature ranging from 60 to 200°C, preferably 60 to 160°C, more preferably 80 to 160°C for a period of time ranging from 1 s to 10 hours, preferably 10s to 1 hour, 1 mins to 1 hour, 1 mins to 45 mins or 1 mins to 30 mins or 1 to 30 mins and/or combinations of the aforesaid periods.
- the article is moulded in a single step at a temperature ranging from 60 to 200°C, preferably 80 to 160°C over a period of from 20s to 8 minutes, preferably from 40s to 3 minutes, more preferably from 60s to 120s and/or combinations of the aforesaid periods.
- the article may be cured or part cured.
- the part cured article may proceed through to cure during other subsequent production steps such as assembly or coating.
- At least one of the additional layers of composite material that are provided at the positions perceived to be vulnerable to high stress may be off cuts or scrap material, such as material obtained when prepregs are cut to the desired shape to provide the base reinforcement for the structure. In this way wastage can be reduced at the same time as providing the desired increased local reinforcement.
- the off-cuts or scrap may be consolidated in a sheet material.
- the off-cuts or scrap may be cut into multiple fiber elements prior to their consolidation.
- the sheet material may be applied to form protrusions, channels or surfaces of complex curvature.
- the invention can employ a laminate comprising multiple plies of tape material with selected areas comprising additional plies.
- Each ply contains one or more sections of tape (also called courses) placed parallel to each other, and each ply is fused to one or more underlying plies.
- the shape of each ply and the orientation, or angle, of the fibers in the ply relative to fibers in other plies in the laminate are chosen such that the final produced article will have the desired structural characteristics across its surface.
- Layers may be tacked together and the method used to tack layers together and the degree to which they are tacked is another parameter that can vary in different embodiments.
- Methods for tacking the courses to underlying plies could include contact heating, ultrasonic welding, induction welding, laser heating, hot gasses, or other methods of adhering plies to each other. Also, the method could be used with an articulating head or a moving substrate surface, or a combination of the two positioning approaches. Although an embodiment described herein uses a fixed material placement head that is positioned over a flat substrate surface that can move in the x and y directions as well as rotate, the relative motion between the placement head and the substrate surface could also be achieved by moving the placement head or a combination of the two.
- a reinforcing composite comprising a plurality of layers of reinforcing composite material forming a stack wherein at least one layer of the composite material comprises a moulding compound comprising oriented resin impregnated fiber elements, wherein the fiber elements are obtained from off-cuts or scrap material derived from cutting the reinforcing composite material prior to its location in the stack.
- the off-cuts or scrap material are derived from separating off- cuts or scrap material comprising multiple layers of reinforcing composite material. This enables scrap material to be re-used.
- the off-cuts or scrap material are preferably cut into the fiber elements.
- the moulding compound is in the form of a sheet or layer in which the fiber elements are randomly oriented.
- the fiber elements comprise unidirectional fibers.
- the fibre elements are consolidated following orientation.
- the moulding compound layer is employed at one or more locations within the stack that are subject to elevated in-use stress in comparison with other locations within the stack according to an in-use stress evaluation of the stack.
- a moulding compound comprising oriented resin impregnated fiber elements, wherein the fiber elements are obtained from off-cuts or scrap material derived from cutting a reinforcing composite comprising a plurality of layers of reinforcing composite material forming a stack.
- the off-cuts or scrap material is derived from separating off-cuts or scrap material comprising multiple layers of reinforcing composite material.
- the moulding compound may be adapted to form particular aspects of a moulded composite part including one or more of protrusions, rubs, channels and shapes of complex curvature.
- the fiber elements may be consolidated by heating to form a sheet.
- the elements are heated to a temperature of between 60 to 80°C.
- the fibre elements are consolidated following orientation.
- At least one layer of the composite material comprises a moulding compound obtained by means of the method of the present invention comprising the step of locating the moulding compound within the stack.
- Figure 1 shows four reinforcing parts of composite reinforcing material according to an embodiment of the invention.
- Figure 2 is a cross section on the line A-A of Figure 1.
- Figure 3 is a cross section on the line B-B of Figure 1.
- Figure 4 is a cross section on the line C-C of Figure 1 .
- Figure 1 shows 4 parts each having a base section (1 ) from which a section of material has been removed from locations (2).
- Figures 2, 3 and 4 show how the resulting multilayer composite provides additional reinforcement along the lines B-B and localized additional reinforcement at various locations along line A-A and C-C. Figures 2, 3 and 4 also illustrate how the orientation of the fibres in the various layers can be varied as required.
- the materials shown are suitable for lamination to a substrate such as a metal automobile component, to provide structural reinforcement with localized additional reinforcement as shown for parts 1 and 3 in Figures 2 and 4.
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- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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EP2015196382 | 2015-11-25 | ||
PCT/EP2016/078673 WO2017089460A1 (fr) | 2015-11-25 | 2016-11-24 | Perfectionnements apportés ou se rapportant à des composites renforcés de fibres |
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Publication Number | Publication Date |
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EP3380310A1 true EP3380310A1 (fr) | 2018-10-03 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP16801214.4A Withdrawn EP3380310A1 (fr) | 2015-11-25 | 2016-11-24 | Perfectionnements apportés ou se rapportant à des composites renforcés de fibres |
Country Status (1)
Country | Link |
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EP (1) | EP3380310A1 (fr) |
-
2016
- 2016-11-24 EP EP16801214.4A patent/EP3380310A1/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
"Konstruieren mit Faser-Kunststoff-Verbunden 2. Ausgabe", 31 December 2007, SPRINGER, ISBN: 978-3-540-72189-5, article SCHÜRMANN HELMUT: "Konstruieren mit Faser-Kunststoff-Verbunden 2. Ausgabe", pages: 636 - 637, XP055848032 * |
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