EP3265544B1 - Procédé de production d'un substitut de gaz naturel - Google Patents
Procédé de production d'un substitut de gaz naturel Download PDFInfo
- Publication number
- EP3265544B1 EP3265544B1 EP16707530.8A EP16707530A EP3265544B1 EP 3265544 B1 EP3265544 B1 EP 3265544B1 EP 16707530 A EP16707530 A EP 16707530A EP 3265544 B1 EP3265544 B1 EP 3265544B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- bulk
- methanator
- gas
- methanators
- methanated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims description 64
- 238000000034 method Methods 0.000 title claims description 60
- 239000003345 natural gas Substances 0.000 title claims description 14
- 239000007789 gas Substances 0.000 claims description 222
- 239000003054 catalyst Substances 0.000 claims description 68
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 39
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- 239000001257 hydrogen Substances 0.000 claims description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 18
- 230000015572 biosynthetic process Effects 0.000 claims description 15
- 239000001569 carbon dioxide Substances 0.000 claims description 15
- 238000003786 synthesis reaction Methods 0.000 claims description 15
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000002028 Biomass Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000002309 gasification Methods 0.000 claims description 3
- 239000003245 coal Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 239000000203 mixture Substances 0.000 description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000011144 upstream manufacturing Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 5
- 229910002090 carbon oxide Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000002826 coolant Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000011335 coal coke Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/02—Combustion or pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/06—Heat exchange, direct or indirect
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/08—Drying or removing water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/10—Recycling of a stream within the process or apparatus to reuse elsewhere therein
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/14—Injection, e.g. in a reactor or a fuel stream during fuel production
- C10L2290/148—Injection, e.g. in a reactor or a fuel stream during fuel production of steam
Claims (15)
- Procédé de production d'un substitut de gaz naturel comprenant les étapes de : alimentation d'un gaz d'alimentation comprenant de l'hydrogène, du monoxyde de carbone et/ou du dioxyde de carbone en parallèle à un premier réacteur de méthanisation en masse, un second réacteur de méthanisation en masse et un ou plusieurs réacteurs de méthanisation en masse ultérieurs, chaque réacteur de méthanisation en masse contenant un catalyseur de méthanisation de sorte que le gaz d'alimentation est au moins partiellement méthanisé pour former un écoulement de gaz méthanisé, où le premier, le second et au moins un réacteur de méthanisation ultérieurs sont reliés en série de sorte que le gaz d'alimentation vers le second et chacun des un ou plusieurs réacteurs de méthanisation en masse ultérieurs est dilué avec un écoulement de gaz méthanisé récupéré du réacteur de méthanisation en masse précédent, où tout l'écoulement de gaz méthanisé récupéré du premier réacteur de méthanisation en masse est utilisé pour diluer le gaz d'alimentation vers le second réacteur de méthanisation en masse, une partie de l'écoulement de gaz méthanisé récupéré du second ou du un ou plusieurs réacteurs de méthanisation en masse ultérieurs est remise en circulation dans une boucle de recirculation vers le premier réacteur de méthanisation en masse et utilisée pour diluer le gaz d'alimentation alimenté audit premier réacteur de méthanisation en masse, et où au moins un réacteur de méthanisation en masse est localisé à l'extérieur de la boucle de recirculation.
- Procédé selon la revendication 1, le gaz d'alimentation étant un gaz de synthèse désulfurisé obtenu à partir de la gazéification de charbon ou de biomasse.
- Procédé selon la revendication 1 ou la revendication 2, le catalyseur de méthanisation fonctionnant à une température d'entrée située dans la plage de 200 à 450°C, préférablement de 200 à 350°C, plus préférablement de 300 à 350°C.
- Procédé selon l'une quelconque des revendications 1 à 3 mis en oeuvre à une pression située dans la plage de 5 à 80 bars abs.
- Procédé selon l'une quelconque des revendications 1 à 4 dans lequel le procédé fonctionne avec N réacteurs de méthanisation en masse, N se situant dans la plage de 3 à 10, préférablement de 3 à 6.
- Procédé selon la revendication 5, le nombre de réacteurs de méthanisation en masse dans la boucle de recirculation étant de N-1, ou N-2 lorsque N ≥ 4.
- Procédé selon l'une quelconque des revendications 1 à 6 comprenant quatre réacteurs de méthanisation en masse, avec le recyclage de l'écoulement de gaz partiellement méthanisé depuis le second ou le troisième réacteur de méthanisation en masse vers le premier réacteur de méthanisation en masse de sorte qu'il existe un ou deux réacteurs de méthanisation en masse à l'extérieur de la boucle de recirculation.
- Procédé selon l'une quelconque des revendications 1 à 6 comprenant six réacteurs de méthanisation en masse, avec le recyclage de l'écoulement de gaz partiellement méthanisé depuis le quatrième réacteur de méthanisation en masse vers le premier réacteur de méthanisation en masse de sorte qu'il existe deux réacteurs de méthanisation en masse à l'extérieur de la boucle de recirculation.
- Procédé selon l'une quelconque des revendications 1 à 8, dans lequel les écoulements de gaz d'alimentation alimentés au premier, second et un ou plusieurs réacteurs de méthanisation en masse ultérieurs se situent dans la plage de 10 % en volume à 60 % en volume de la charge d'alimentation totale en gaz alimenté.
- Procédé selon l'une quelconque des revendications 1 à 9, dans lequel la boucle de recirculation comprend un compresseur pour l'écoulement de gaz remis en circulation et un pré-dispositif de chauffage pour le chauffage dudit écoulement de gaz dilué avant d'entrer dans le premier réacteur de méthanisation en masse.
- Procédé selon l'une quelconque des revendications 1 à 10 dans lequel la proportion de l'écoulement de gaz méthanisé recyclé vers le premier réacteur de méthanisation en masse est de 40 à 60 % en volume, préférablement de 45 à 55 % en volume, du gaz méthanisé récupéré du second ou des un ou plusieurs réacteurs de méthanisation en masse ultérieurs.
- Procédé selon l'une quelconque des revendications 1 à 11 dans lequel la température de la partie remise en circulation de l'écoulement de gaz méthanisé est ajustée à une température située dans la plage de 100 à 200°C, préférablement de 120 à 180°C.
- Procédé selon l'une quelconque des revendications 1 à 12, dans lequel la vapeur est ajoutée au niveau de l'orifice d'entrée d'au moins le premier réacteur de méthanisation en masse pour diluer de manière supplémentaire le gaz d'entrée.
- Procédé selon l'une quelconque des revendications 1 à 13 comprenant en outre la soumission d'un gaz produit provenant du réacteur de méthanisation en masse final à la méthanisation supplémentaire dans un ou plusieurs réacteurs de méthanisation de finissage et la soumission d'un gaz produit provenant du réacteur de méthanisation de finissage final à une étape de séchage.
- Système de méthanisation pour convertir un gaz d'alimentation contenant de l'hydrogène, du monoxyde de carbone et/ou du dioxyde de carbone en un gaz naturel substitut, ledit train de méthanisation étant adapté pour fonctionner selon le procédé selon l'une quelconque des revendications 1 à 14.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB201503606A GB201503606D0 (en) | 2015-03-03 | 2015-03-03 | Process |
| PCT/GB2016/050478 WO2016139451A1 (fr) | 2015-03-03 | 2016-02-25 | Procédé de production d'un substitut de gaz naturel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3265544A1 EP3265544A1 (fr) | 2018-01-10 |
| EP3265544B1 true EP3265544B1 (fr) | 2018-10-31 |
Family
ID=52876451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16707530.8A Active EP3265544B1 (fr) | 2015-03-03 | 2016-02-25 | Procédé de production d'un substitut de gaz naturel |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP3265544B1 (fr) |
| CN (1) | CN107087415B (fr) |
| GB (2) | GB201503606D0 (fr) |
| WO (1) | WO2016139451A1 (fr) |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US264542A (en) * | 1882-09-19 | Snow-plow | ||
| DE3032123A1 (de) * | 1979-10-22 | 1981-04-30 | Conoco Inc., 74601 Ponca City, Okla. | Verfahren zur herstellung eines methan enthaltenden ersatz-erdgases |
| EP2110425B2 (fr) * | 2008-04-16 | 2022-03-30 | Casale Sa | Procédé et installation pour la production de gaz naturel de substitution |
| US9157043B2 (en) * | 2008-07-16 | 2015-10-13 | Kellogg Brown & Root Llc | Systems and methods for producing substitute natural gas |
| GB201011063D0 (en) * | 2010-07-01 | 2010-08-18 | Davy Process Techn Ltd | Process |
| DE102010032709B4 (de) * | 2010-07-29 | 2016-03-10 | Air Liquide Global E&C Solutions Germany Gmbh | Verfahren zur Herstellung von synthetischem Erdgas |
| CN102010767A (zh) * | 2010-11-30 | 2011-04-13 | 新奥新能(北京)科技有限公司 | 一种合成天然气工艺 |
| CN102660339B (zh) * | 2012-04-27 | 2014-04-30 | 阳光凯迪新能源集团有限公司 | 基于生物质气化与甲烷化的燃气-蒸汽高效联产工艺及系统 |
| CN103666611B (zh) * | 2012-09-19 | 2015-06-10 | 中国石油化工集团公司 | 一种制备替代天然气的系统及方法 |
| CN103740425B (zh) * | 2012-10-17 | 2016-08-17 | 中国石油化工股份有限公司 | 合成气生产替代天然气的方法 |
| CN103773527A (zh) * | 2012-10-25 | 2014-05-07 | 中国石油化工股份有限公司 | 合成气甲烷化制替代天然气的方法 |
| CN102952598A (zh) * | 2012-11-05 | 2013-03-06 | 中国五环工程有限公司 | 基于地下煤气化生产天然气的甲烷化工艺 |
| CN103865600B (zh) * | 2012-12-12 | 2016-06-08 | 中国石油化工股份有限公司 | 一种甲烷化工艺 |
| EP3018190A1 (fr) * | 2014-11-04 | 2016-05-11 | Haldor Topsøe A/S | Procédé de production de gaz riche en méthane |
-
2015
- 2015-03-03 GB GB201503606A patent/GB201503606D0/en not_active Ceased
-
2016
- 2016-02-25 WO PCT/GB2016/050478 patent/WO2016139451A1/fr active Application Filing
- 2016-02-25 EP EP16707530.8A patent/EP3265544B1/fr active Active
- 2016-02-25 CN CN201680003017.XA patent/CN107087415B/zh active Active
- 2016-02-25 GB GB1603252.6A patent/GB2537219B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| GB201603252D0 (en) | 2016-04-13 |
| GB2537219B (en) | 2017-04-26 |
| EP3265544A1 (fr) | 2018-01-10 |
| CN107087415B (zh) | 2020-06-30 |
| GB201503606D0 (en) | 2015-04-15 |
| CN107087415A (zh) | 2017-08-22 |
| WO2016139451A1 (fr) | 2016-09-09 |
| GB2537219A (en) | 2016-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3402773B1 (fr) | Procédé méthanol | |
| EP3402772B1 (fr) | Procédé de synthèse de méthanol | |
| CN108368037B (zh) | 生产甲醛稳定的脲的整合方法 | |
| EP3132009B1 (fr) | Procédé | |
| CN110177772B (zh) | 甲醇、氨和尿素的联合生产 | |
| AU2019269094B2 (en) | Process for synthesising methanol | |
| EP3265545B1 (fr) | Procédé de production d'un substitut au gaz naturel | |
| EP3265544B1 (fr) | Procédé de production d'un substitut de gaz naturel | |
| US11261086B2 (en) | Process for producing methanol and ammonia | |
| EA041436B1 (ru) | Технологическая схема синтеза метанола для крупномасштабного производства |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
| 17P | Request for examination filed |
Effective date: 20170727 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| AX | Request for extension of the european patent |
Extension state: BA ME |
|
| DAV | Request for validation of the european patent (deleted) | ||
| DAX | Request for extension of the european patent (deleted) | ||
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
| INTG | Intention to grant announced |
Effective date: 20180704 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
| RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1059366 Country of ref document: AT Kind code of ref document: T Effective date: 20181115 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602016006816 Country of ref document: DE |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
| REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1059366 Country of ref document: AT Kind code of ref document: T Effective date: 20181031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190228 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190131 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190131 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20190204 Year of fee payment: 10 Ref country code: CH Payment date: 20190125 Year of fee payment: 4 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190201 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190301 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20190128 Year of fee payment: 4 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602016006816 Country of ref document: DE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 602016006816 Country of ref document: DE Representative=s name: BARDEHLE PAGENBERG PARTNERSCHAFT MBB PATENTANW, DE |
|
| 26N | No opposition filed |
Effective date: 20190801 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190225 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20190228 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190228 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190225 |
|
| REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200226 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200229 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200229 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200225 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20160225 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181031 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230119 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20230119 Year of fee payment: 8 |
|
| P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230526 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20240123 Year of fee payment: 9 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240123 Year of fee payment: 9 |