EP3235917B1 - Alliage d'aluminium pour moulage sous pression - Google Patents
Alliage d'aluminium pour moulage sous pression Download PDFInfo
- Publication number
- EP3235917B1 EP3235917B1 EP16165969.3A EP16165969A EP3235917B1 EP 3235917 B1 EP3235917 B1 EP 3235917B1 EP 16165969 A EP16165969 A EP 16165969A EP 3235917 B1 EP3235917 B1 EP 3235917B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- alloy
- die
- alloy according
- cast alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
- C22C21/04—Modified aluminium-silicon alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/002—Castings of light metals
- B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
Definitions
- the invention relates to a diecasting alloy based on aluminum and silicon, in particular for use in light vehicle structural parts.
- the alloy according to the invention takes account of the ever increasing demands for lightweight construction in the automotive industry.
- the use of a material with higher strength allows the designer to realize thinner-walled and thus lighter structures. In this way, a further step towards low fuel consumption in the automobile can be realized.
- AISi10Mg or AISi7Mg alloys are among the most widely used casting alloys in the industry.
- the EP 1612286 B1 discloses an AISi alloy which already exhibits high elongation values in the cast state without further heat treatment. With this alloy it is possible to obtain good values for the yield strength and the tensile strength of castings as cast, so that the alloy is particularly suitable for the production of safety components in the automotive industry. In this known from the prior art alloy has been shown that by the addition of molybdenum or a combined addition of molybdenum and zirconium, the desired values for the tensile strength and the yield strength can be achieved.
- the EP0687742B1 also discloses an aluminum-silicon based die-casting alloy, which is used in particular in automotive safety components. Unlike the alloy from the EP 1612286 B1 , the produced die castings are subjected to a heat treatment. In the case of this alloy, it has been found that the achieved increased strength values depend to a large extent on the magnesium content and this content therefore has to be tolerated very closely in the production.
- the object of the invention is to develop a high-strength die-cast aluminum alloy which exhibits improved mechanical properties in terms of tensile strength, yield strength and elongation at break.
- the alloy according to the invention is said to have good castability, no increased tendency to adhere, no increased risk of heat cracking, and no restriction as regards mold filling capability.
- the aluminum base may contain at least 50% secondary metal (recycled material).
- the alloy according to the invention contains 0.15-0.5% by weight of iron.
- the alloy according to the invention contains 0.05 to 0.20% by weight of molybdenum.
- the alloy according to the invention contains from 0.05 to 0.20% by weight of zirconium.
- the alloy according to the invention contains 0.3 to 0.5% by weight of manganese.
- the alloy according to the invention contains 0.2 to 0.4% by weight of zinc.
- the alloy according to the invention contains 0.15 to 0.25% by weight of copper.
- the alloy according to the invention contains 8.5 to 10.0% by weight of silicon.
- the alloy according to the invention contains from 0.3 to 0.4% by weight of magnesium.
- the diecasting alloy according to the invention is preferably used for pressure casting of crash-relevant or strength-relevant structural parts in the automotive industry.
- the appropriate strength of an aluminum die casting alloy is achieved in addition to the choice of combination of alloying elements by a targeted heat treatment.
- the alloy according to the invention is subjected to a T6 heat treatment comprising solution heat treatment, air quenching or water quenching and heat aging. It could be determined that compared with the alloy EP 0687742B1 high yield strengths of just over 200 N / mm 2 can be achieved.
- the alloy according to the invention is time-stable after T6 heat treatment, i. there is no self-curing.
- the alloy according to the invention may be subjected to a T7 heat treatment.
- alloy composition according to the invention it is possible to achieve improved values for tensile strength, the yield strength and the elongation at break in die cast parts in the material state T6 or T7.
- the slightly increased iron content is taken into account by a reduction in the manganese content, otherwise there is a risk of sludge formation in the holding furnace at the casting machine.
- the tendency of the alloy to adhere decreases, since both iron and manganese have a positive effect and the reduction of Mn is more than compensated for by the Fe content.
- the MnFe ratio prevents the formation of so-called beta phases, ie plate-shaped AlMnFeSi precipitates, which significantly reduces the ductility of the material.
- Such excretions are known under the microscope as so-called. Iron needles.
- the alpha-AlMnFeSi precipitates are formed very finely in the inventive alloy by the addition of the elements Mo, Zr and Ga, so that their harmful effect on Dehnhong and corrosion tendency can be minimized.
- strontium or sodium leads to a finely crystalline precipitation of the silicon, which results in the formation of a refined eutectic, and also has a positive influence on the strength and elongation of the inventive alloy.
- Grain refining is preferably carried out in the case of the alloy according to the invention.
- the alloy may preferably be supplied with 1 to 30 ppm of phosphorus.
- the alloy may also contain titanium and boron for grain refining, the addition of titanium and boron via a master alloy with 1 to 2% by weight of Ti and 1 to 2% by weight of B, residual aluminum.
- the aluminum master alloy contains 1.3 to 1.8% by weight of Ti and 1.3 to 1.8% by weight of B, and has a Ti / B weight ratio of about 0.8 to 1.2.
- Of the Content of the master alloy in the alloy according to the invention is preferably adjusted to 0.05 to 0.5 wt .-%.
- the weldability could be checked in TIG welding tests.
- punch rivet tests the alloy according to the invention was rivet free of cracks despite its high strength.
- compositions of an exemplary alloy of the EP0687742B1 (Alloy 1) and two embodiments (alloys A, B) of the inventive alloy compared.
- the statements are in wt .-%.
- the mechanical characteristics (R m , R p0.2 and A 5 ) were measured on 3 mm die-cast plates.
- the same T6 heat treatment with air quenching and applied with water quenching The mean value of approx. 30 train tests is shown in each case.
Claims (10)
- Alliage destiné au moulage sous pression sur base d'aluminium-silicium, composé
de 8,5 à 11,5 % en poids de silicium
de 0,1 à 0,5 % en poids de magnésium
de 0,3 à 0,8 % en poids de manganèse
de 0,02 à 0,5 % en poids de fer
de 0,005 à 0,5 % en poids de zinc
de 0,1 à 0,5 % en poids de cuivre
de 0,02 à 0,3 % en poids de molybdène
de 0,02 à 0,3 % en poids de zirconium
de 60 à 120 ppm de gallium
facultativement
de 30 à 300 ppm de strontium ou de 5 à 30 ppm de sodium ou de 1 à 30 ppm de calcium pour le raffinage durable et de 5 à 250 ppm de phosphore et/ou de 0,2 à 0,25 % en poids de titane et de 3 à 50 ppm de bore pour l'affinement des grains, le reste étant de l'aluminium et des impuretés inévitables. - Alliage destiné au moulage sous pression selon la revendication 1, caractérisé par de 0,15 à 0,5 % en poids de fer.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 0,05 à 0,20 % en poids de molybdène.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 0,05 à 0,20 % de zirconium.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 0,3 à 0,5 % de manganèse.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 0,2 à 0,4 % de zinc.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 0,15 à 0,25 % de cuivre.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 8,5 à 10,0 % de silicium.
- Alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes, caractérisé par de 0,3 à 0,4 % de magnésium.
- Utilisation d'un alliage destiné au moulage sous pression selon l'une quelconque des revendications précédentes pour le moulage sous pression de pièces de structures significatives en cas de crash ou en matière de solidité dans la construction automobile.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16165969.3A EP3235917B1 (fr) | 2016-04-19 | 2016-04-19 | Alliage d'aluminium pour moulage sous pression |
CA3021397A CA3021397C (fr) | 2016-04-19 | 2016-05-02 | Alliage de coulee sous pression |
US16/094,324 US20190119791A1 (en) | 2016-04-19 | 2016-05-02 | Die Casting Alloy |
PCT/EP2016/059723 WO2017182102A1 (fr) | 2016-04-19 | 2016-05-02 | Alliage de coulée sous pression |
KR1020187032871A KR102609410B1 (ko) | 2016-04-19 | 2016-05-02 | 다이 캐스팅 합금 |
CN201680084625.8A CN109072353A (zh) | 2016-04-19 | 2016-05-02 | 压铸合金 |
MX2018012786A MX2018012786A (es) | 2016-04-19 | 2016-05-02 | Aleacion para vaciado. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16165969.3A EP3235917B1 (fr) | 2016-04-19 | 2016-04-19 | Alliage d'aluminium pour moulage sous pression |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3235917A1 EP3235917A1 (fr) | 2017-10-25 |
EP3235917B1 true EP3235917B1 (fr) | 2018-08-15 |
Family
ID=55794875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP16165969.3A Active EP3235917B1 (fr) | 2016-04-19 | 2016-04-19 | Alliage d'aluminium pour moulage sous pression |
Country Status (7)
Country | Link |
---|---|
US (1) | US20190119791A1 (fr) |
EP (1) | EP3235917B1 (fr) |
KR (1) | KR102609410B1 (fr) |
CN (1) | CN109072353A (fr) |
CA (1) | CA3021397C (fr) |
MX (1) | MX2018012786A (fr) |
WO (1) | WO2017182102A1 (fr) |
Families Citing this family (13)
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CN112391562B (zh) * | 2019-11-26 | 2021-09-21 | 比亚迪股份有限公司 | 一种铝合金及其制备方法 |
JP7282054B2 (ja) * | 2020-05-19 | 2023-05-26 | 堺アルミ株式会社 | 低熱膨張アルミニウム合金圧延材およびその製造方法 |
MX2022014999A (es) * | 2020-06-01 | 2023-02-09 | Alcoa Usa Corp | Aleaciones de fundicion de al-si-fe. |
CN113862530B (zh) * | 2020-06-30 | 2023-04-07 | 比亚迪股份有限公司 | 一种铝合金及其制备方法 |
CN113862531A (zh) * | 2020-06-30 | 2021-12-31 | 比亚迪股份有限公司 | 一种铝合金及其制备方法 |
CN112831695A (zh) * | 2020-12-30 | 2021-05-25 | 安徽鑫铂铝业股份有限公司 | 一种高抗拉强度大型车辆铝型材及其制备方法 |
DE102021129329A1 (de) | 2021-11-11 | 2023-05-11 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Herstellen einer Aluminium-Legierung sowie Bauteil |
CN115161521B (zh) * | 2022-07-14 | 2023-09-08 | 山西瑞格金属新材料有限公司 | 一种免热处理压铸铝硅锌合金 |
CN115287485A (zh) * | 2022-08-10 | 2022-11-04 | 帅翼驰新材料集团有限公司 | 烘烤后性能可提升的高压铸造铝合金的制作方法 |
CN115821127A (zh) * | 2022-08-10 | 2023-03-21 | 帅翼驰新材料集团有限公司 | 烘烤后性能可提升的高压铸造铝合金 |
CN115181878B (zh) * | 2022-09-14 | 2022-12-23 | 苏州慧金新材料科技有限公司 | 新能源汽车用一体式压铸件铝合金及制备方法和应用 |
CN115896504B (zh) * | 2022-10-27 | 2023-07-04 | 广州致远新材料科技有限公司 | 铝合金材料的制备方法及道闸传动结构件的制备方法 |
CN115386771B (zh) * | 2022-10-27 | 2023-01-06 | 广州致远新材料科技有限公司 | 铝合金材料及道闸传动结构件的压铸方法 |
Citations (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB605282A (en) | 1945-12-01 | 1948-07-20 | Nat Smelting Co | Improvements in or relating to aluminium silicon alloys |
US3211547A (en) | 1961-02-10 | 1965-10-12 | Aluminum Co Of America | Treatment of molten aluminum |
DE1211800B (de) | 1961-02-10 | 1966-03-03 | Aluminum Co Of America | Verfahren zum Raffinieren von fluessigem Aluminium durch fraktionierte Kristallisation |
US4222830A (en) | 1978-12-26 | 1980-09-16 | Aluminum Company Of America | Production of extreme purity aluminum |
DE10351666B3 (de) | 2003-11-05 | 2005-01-27 | Erbslöh Aluminium Gmbh | Aluminiumprodukt |
WO2005071127A1 (fr) | 2004-01-09 | 2005-08-04 | Alcoa Inc. | Alliage la/si/mn/mg pour former des pieces structurales automobiles par coulage et par traitement thermique t5 |
US20050224145A1 (en) | 2002-06-25 | 2005-10-13 | Aluminum Pechiney | Part cast made from aluminum alloy with high hot strength |
EP1612286A2 (fr) | 2004-06-29 | 2006-01-04 | ALUMINIUM RHEINFELDEN GmbH | Alliage d'aluminium pour moulage sous pression |
DE102008055929A1 (de) | 2007-11-08 | 2009-08-27 | Ksm Castings Gmbh | Vorderachsträger für Kraftfahrzeuge |
DE102008055928A1 (de) | 2007-11-08 | 2009-08-27 | Ksm Castings Gmbh | Al-Gusslegierungen |
DE102008046803A1 (de) | 2008-09-11 | 2010-03-25 | Audi Ag | Aluminiumgusslegierung und Verfahren zur Herstellung eines Gussbauteils |
DE102009012073A1 (de) | 2009-03-06 | 2010-09-09 | Daimler Ag | Aluminiumgusslegierung |
DE102010055011A1 (de) | 2010-12-17 | 2012-06-21 | Trimet Aluminium Ag | Gut gießbare, duktile AlSi-Legierung und Verfahren zur Herstellung eines Gussteils unter Verwendung der AlSi-Gusslegierung |
DE102011112005A1 (de) | 2011-08-29 | 2013-02-28 | Audi Ag | Aluminium-Silizium-Legierung |
EP2657360A1 (fr) | 2012-04-26 | 2013-10-30 | Audi Ag | Alliage à coulée sous pression à base d'Al-Si présentant en particulier un aluminium secondaire |
EP2735621A1 (fr) | 2012-11-21 | 2014-05-28 | Georg Fischer Druckguss GmbH & Co. KG | Alliage à coulée sous pression en aluminium |
EP2738273A1 (fr) | 2011-07-25 | 2014-06-04 | Nippon Light Metal, Co. Ltd. | Plaque d'alliage d'aluminium et son procédé de fabrication |
Family Cites Families (4)
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CH689143A5 (de) | 1994-06-16 | 1998-10-30 | Rheinfelden Aluminium Gmbh | Aluminium-Silizium Druckgusslegierung mit hoher Korrosionsbestaendigkeit, insbesondere fuer Sicherheitsbauteile. |
ES2330332T3 (es) * | 2003-01-23 | 2009-12-09 | Aluminium Rheinfelden Gmbh | Aleacion de aluminio fundida a presion. |
DE10352932B4 (de) * | 2003-11-11 | 2007-05-24 | Eads Deutschland Gmbh | Aluminium-Gusslegierung |
EP2653579B1 (fr) | 2012-04-17 | 2014-10-15 | Georg Fischer Druckguss GmbH & Co. KG | Alliage d'aluminium |
-
2016
- 2016-04-19 EP EP16165969.3A patent/EP3235917B1/fr active Active
- 2016-05-02 CN CN201680084625.8A patent/CN109072353A/zh active Pending
- 2016-05-02 MX MX2018012786A patent/MX2018012786A/es unknown
- 2016-05-02 US US16/094,324 patent/US20190119791A1/en not_active Abandoned
- 2016-05-02 WO PCT/EP2016/059723 patent/WO2017182102A1/fr active Application Filing
- 2016-05-02 KR KR1020187032871A patent/KR102609410B1/ko active IP Right Grant
- 2016-05-02 CA CA3021397A patent/CA3021397C/fr active Active
Patent Citations (17)
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---|---|---|---|---|
GB605282A (en) | 1945-12-01 | 1948-07-20 | Nat Smelting Co | Improvements in or relating to aluminium silicon alloys |
US3211547A (en) | 1961-02-10 | 1965-10-12 | Aluminum Co Of America | Treatment of molten aluminum |
DE1211800B (de) | 1961-02-10 | 1966-03-03 | Aluminum Co Of America | Verfahren zum Raffinieren von fluessigem Aluminium durch fraktionierte Kristallisation |
US4222830A (en) | 1978-12-26 | 1980-09-16 | Aluminum Company Of America | Production of extreme purity aluminum |
US20050224145A1 (en) | 2002-06-25 | 2005-10-13 | Aluminum Pechiney | Part cast made from aluminum alloy with high hot strength |
DE10351666B3 (de) | 2003-11-05 | 2005-01-27 | Erbslöh Aluminium Gmbh | Aluminiumprodukt |
WO2005071127A1 (fr) | 2004-01-09 | 2005-08-04 | Alcoa Inc. | Alliage la/si/mn/mg pour former des pieces structurales automobiles par coulage et par traitement thermique t5 |
EP1612286A2 (fr) | 2004-06-29 | 2006-01-04 | ALUMINIUM RHEINFELDEN GmbH | Alliage d'aluminium pour moulage sous pression |
DE102008055929A1 (de) | 2007-11-08 | 2009-08-27 | Ksm Castings Gmbh | Vorderachsträger für Kraftfahrzeuge |
DE102008055928A1 (de) | 2007-11-08 | 2009-08-27 | Ksm Castings Gmbh | Al-Gusslegierungen |
DE102008046803A1 (de) | 2008-09-11 | 2010-03-25 | Audi Ag | Aluminiumgusslegierung und Verfahren zur Herstellung eines Gussbauteils |
DE102009012073A1 (de) | 2009-03-06 | 2010-09-09 | Daimler Ag | Aluminiumgusslegierung |
DE102010055011A1 (de) | 2010-12-17 | 2012-06-21 | Trimet Aluminium Ag | Gut gießbare, duktile AlSi-Legierung und Verfahren zur Herstellung eines Gussteils unter Verwendung der AlSi-Gusslegierung |
EP2738273A1 (fr) | 2011-07-25 | 2014-06-04 | Nippon Light Metal, Co. Ltd. | Plaque d'alliage d'aluminium et son procédé de fabrication |
DE102011112005A1 (de) | 2011-08-29 | 2013-02-28 | Audi Ag | Aluminium-Silizium-Legierung |
EP2657360A1 (fr) | 2012-04-26 | 2013-10-30 | Audi Ag | Alliage à coulée sous pression à base d'Al-Si présentant en particulier un aluminium secondaire |
EP2735621A1 (fr) | 2012-11-21 | 2014-05-28 | Georg Fischer Druckguss GmbH & Co. KG | Alliage à coulée sous pression en aluminium |
Non-Patent Citations (9)
Title |
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"Europäische Norm EN 1706", EUROPÄISCHE NORM EN 1706, March 2010 (2010-03-01), pages 2, 10, 11, 13, XP055582012 |
"Neue Anwendungsbereiche für Strukturbauteile", VDI-FACHMEDIEN, KONSTRUKTION - ONLINE, September 2017 (2017-09-01) |
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15 February 2019 (2019-02-15), Retrieved from the Internet <URL:http:/rheinfelden-alloys.eu/euroguss> |
DAVIS JR: "Alloying: Understanding the Basics.", 2001, article "Aluminum and Aluminum Alloys", pages: 372, 377, 382, 387, XP055549194 |
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LOPER CR ET AL.: "AFS Transactions", 2000, article "Influence of Trace Amounts of Phosphorus in AI Casting Alloys", pages: 667-672,383 |
Also Published As
Publication number | Publication date |
---|---|
WO2017182102A1 (fr) | 2017-10-26 |
CA3021397A1 (fr) | 2017-10-26 |
KR20180132140A (ko) | 2018-12-11 |
MX2018012786A (es) | 2019-06-17 |
CA3021397C (fr) | 2023-05-23 |
KR102609410B1 (ko) | 2023-12-01 |
EP3235917A1 (fr) | 2017-10-25 |
CN109072353A (zh) | 2018-12-21 |
US20190119791A1 (en) | 2019-04-25 |
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