EP3218429A1 - Procédé de production de pièces finies - Google Patents
Procédé de production de pièces finiesInfo
- Publication number
- EP3218429A1 EP3218429A1 EP15797883.4A EP15797883A EP3218429A1 EP 3218429 A1 EP3218429 A1 EP 3218429A1 EP 15797883 A EP15797883 A EP 15797883A EP 3218429 A1 EP3218429 A1 EP 3218429A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polymer
- fiber
- temperature
- fibers
- reinforced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
- B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
- B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2677/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, for preformed parts, e.g. for inserts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/02—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/04—Time
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/12—Pressure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Definitions
- the invention relates to a method for the production of prefabricated parts from at least one multilayer, fiber-reinforced, flat semifinished product structure in which the at least one semifinished product structure is heated and pressed.
- prefabricated parts made of fiber-reinforced polymers are used in areas in which materials with high strength and compared to metals with lower weight are to be used.
- prefabricated parts made of fiber-reinforced polymers are used in the automotive industry in order to reduce the mass of vehicles and thus also the fuel consumption.
- precast parts of fiber-reinforced polymers whose polymer phase surrounding the fibers is also referred to as a matrix are produced from intermediates, for example so-called organic sheets, which are fully impregnated and fully consolidated continuous fiber reinforced thermoplastic polymers with fabric or scrim reinforcement.
- organic sheets individual layers of a laminate completely impregnated with polymer are virtually free of pores, which is also referred to as fully consolidated.
- the organo sheets can be produced from so-called prepregs.
- prepregs a thermoplastic matrix is finely dispersed without completely wetting the reinforcing fibers.
- the prepregs are completely impregnated and consolidated in a subsequent process step. M.
- unidirectionally reinforced tapes In Ostgathe the production of unidirectionally reinforced tapes is described on page 15, which are impregnated and consolidated as single layers and can be layered and processed in a subsequent step into flat semi-finished products.
- the textile processing of the tapes is complex and it is described longer process times compared to the forming of fully impregnated semi-finished products, since the bossma- material is not yet consolidated.
- Forming unidirectional ribbon reinforced semi-finished products requires fully consolidated semi-finished slab assemblies, also referred to as tapelayups, which, after tape making, require the additional step of consolidating multi-layered semi-finished slabs.
- the consolidation phase serves to establish a good bond between the individual reinforcing layers of a composite material.After the impregnation phase and the consolidation phase, ideally a pore-free composite is present
- film stacking methods, prepreg methods and direct methods can also be used can be used, wherein in the direct process, the matrix component and the fiber component are brought together in the pressing process for the production of the semifinished product structure.
- the object of the present invention is to provide a process for the production of prefabricated parts from multilayer, fiber-reinforced, flat semifinished product structures, with which finished parts can be produced more effectively and with consistent or improved mechanical properties.
- a method for producing finished parts from at least one multilayer, fiber-reinforced, flat semifinished product comprising the following steps: a) heating the at least one multilayer, fiber-reinforced, flat semi-finished construction at ambient pressure to a first temperature T a , wherein the at least one multi-layered, fiber-reinforced, flat semi-finished construction comprises at least two superimposed polymer layers and the individual polymer layers are each fiber-reinforced and not materially connected to each other or only partially cohesively connected to each other and the first temperature T a in the event that at least one of the polymer layers semi-crystalline polymer, is higher than a melting temperature Ts of the crystalline polymer according to DIN EN ISO 1 1357-3: 2013-04, and the first temperature T a in the event that the at least two polymer layers no semicrystalline P is higher than a glass transition temperature T g according to DIN EN ISO 1 1357-2: 2013-09 of a polymer which is contained in at least one of the at least two polymer layers,
- the polymer layers are arranged in the form of semi-finished structures that are not or not completely multilayered, such as stacked assemblies.
- a complete consolidation is meant that the fibers are completely wetted.
- a multilayered complete consolidation of the individual polymer layers takes place according to the invention only in the further processing of the individual layers to the finished part, ie in steps a) and b). In the entire manufacturing process of the finished part, therefore, an intermediate step can be omitted, namely the one in which the semi-finished structure is pressed over several layers over a whole area or completely consolidated before the actual finished part is produced.
- the productivity of the manufacturing process for finished parts can be increased since the time required for the separate production of multi-layer completely consolidated semifinished product structures, such as fully consolidated organic sheets, can be saved.
- the finished part is produced from a layer structure comprising at least two polymer layers arranged one above the other, which are each fiber-reinforced in one layer.
- the at least two polymer layers can generally be any single-layer semifinished product known to the person skilled in the art.
- the polymer layers are tapes or ribbons.
- material-locking means that various layers or layers, in particular different layers or layers of a fiber-reinforcing structure, are continuously enclosed by a polymer mass and have only a low pore content. A high pore content would reduce the mechanical properties of the finished part.
- non-cohesively interconnected layers merely overlap one another without a continuous interconnection of interlayer polymer mass between layers.
- the various layers adhere to one another in individual regions of their mutually facing surfaces, which may be due to the fact that layers lying above one another have already been heated as a layer.
- This heating which precedes the process according to the invention, can be carried out under overpressure.
- the polymer of the layers can be partially melted and polymers of adjacent layers can partially fuse together and the layers thus connect partially cohesively, without the separation of the layers would be completely eliminated by fused polymer.
- Steps a) and b) may be preceded by method steps for the production of the at least one multilayer, fiber-reinforced, flat semifinished product structure.
- the production of the at least one multi-layer, fiber-reinforced, flat semi-finished construction may comprise a consolidation, which is carried out only incompletely.
- the at least two polymer layers of the at least one fiber-reinforced, flat semi-finished construction prior to step a) may already be partially bonded together in a materially cohesive manner.
- each of the at least two polymer layers is in each case fully consolidated.
- the at least two polymer layers prior to step a) are each fully consolidated by pressing at a temperature T v in the range of 240 ° C to 280 ° C and a pressure P v of more than 5 bar.
- step a) less than 80% of an area of the first polymer layer which is directed in the direction of the second polymer layer, positively connected to the second polymer layer, preferably less than 70%, particularly preferably less than 50%.
- the required temperature, which is heated in step a) depends on the composition of the polymer of the at least two polymer layers.
- the first temperature T a and the second temperature Tb are locally attributable to the core of the finished part to be produced or the center of the superimposed polymer layers.
- the first temperature T a is higher than the melting temperature T s of the crystalline polymer contained.
- a corresponding method for determining the melting temperature is described in DIN EN ISO 1 1357-3: 2013- 04. If no semicrystalline polymer is contained in the at least one multilayer, fiber-reinforced, flat semifinished product structure, that is to say exclusively amorphous polymers, the first temperature T a is higher than the glass transition temperature T g of at least one polymer contained in at least one polymer layer whose determination in DIN EN ISO 1 1357-2: 2013-09 is described.
- the heating in step a) is carried out at ambient pressure, which is also referred to as atmospheric pressure and is usually about 1 bar.
- the pressing in step b) is carried out at a pressure pb of at least 3 bar absolute.
- the pressure is increased only when the first temperature T a is reached.
- the at least one multilayer, fiber-reinforced, flat semifinished product structure is first heated and the first temperature T a is held for a certain time before the Pressure for pressing is increased, so that a consolidation of the fibers is initially continued at ambient pressure.
- the first temperature T a in step a) is maintained at ambient pressure for a period of at least 5 seconds, preferably at least 30 seconds, more preferably at least 120 seconds.
- multi-layer prefabricated parts can be fully consolidated in the mold, without the prior production of a multi-layer fully consolidated semifinished product structure with construction of a plate and pressing into a multilayer, fully consolidated semi-finished structure or a multilayer, fully consolidated plate.
- the pressure pb is between 3 bar and 50 bar, preferably between 5 bar and 30 bar and particularly preferably between 10 bar and 25 bar.
- the first temperature T a and the second temperature Tb are between 50 ° C and 400 ° C, preferably between 100 ° C and 350 ° C and particularly preferably between 200 ° C and 320 ° C.
- the heating in step a) can be carried out by any method known to the person skilled in the art.
- the heating takes place without contact.
- the heating takes place by means of infrared radiation or in a circulating air oven.
- the second temperature Tb is equal to or higher than the first temperature T a .
- the at least one semifinished product structure is preferably heated in step a) to a temperature which is required during the pressing to produce a completely cohesive connection between the layers of the semifinished product structure. By the pressing process, the temperature of the semi-finished construction can continue to rise.
- the pressing in step b) represents the actual finished part manufacturing step, which includes a consolidation and / or calibration.
- a thickness of the finished part is adjusted by pressing to a range of 1 mm to 4 mm or step b) is followed by a further step, in which the thickness of the finished part in a range of 1 mm to 4 mm is adjusted by pressing.
- the pressing can be done in presses, mold carriers, injection molds and injection molding machines.
- the finished part is cooled after pressing.
- the finished part is additionally injected or back-injected in step b).
- An encapsulation of continuous fiber reinforced plastic sheet-like parts is described for example in Marko Wacker et al., "Welding and encapsulation of Orga- noblechen", KU plastics, Carl Hanser Verlag Kunststoff, born in 1992 (2002), 6.
- injection molding or encapsulation functional elements to the The injection molding or encapsulation can be carried out with a polymer. gene, which is already contained in at least one of the polymer layers, alternatively, another polymer can be used, which is not yet included in the semifinished product structure.
- the injection of the polymer takes place under the usual parameters for injection molding.
- step b) is followed by a step c) in which the finished part is formed by deep-drawing or thermoforming, or the finished part is overmolded or back-injected or elements are injection-molded or sprayed onto the finished part.
- the finished part is formed by deep-drawing or thermoforming, or the finished part is overmolded or back-injected or elements are injection-molded or sprayed onto the finished part.
- ribs can be sprayed on to reinforce the finished part.
- Further elements which can be supplemented by an injection molding process are functional elements such as fixtures for fasteners, clips, force introduction, screw-on domes or threaded receptacles.
- the injected polymer forms a closed skin on the finished part between the functional elements.
- an additional stabilization of the functional elements is achieved by the closed skin between the functional elements.
- the closed skin is thereby formed by forming a thin flow channel between the functional elements and injecting the polymer material into the flow channel.
- the connection between the different polymer layers is further improved.
- the finished part and thus the layer structure can be flooded with polymer, which already a pressure above the ambient pressure, built and a defined surface structure and / or a higher surface quality with respect to, for example, a reduced roughness or better appearance of the finished part is achieved. Furthermore, there is good adhesion between the flooded polymer which then forms a coating and the finished part.
- injection molding, injection molding or spraying polymers are suitable which are injection-moldable.
- the injection moldable polymers may be fiber reinforced with long fibers or short fibers.
- a use of different polymers in the polymer layers of the finished part on the one hand and for encapsulation, injection molding, injection molding or spraying on the other hand is particularly advantageous if certain properties, for example, in terms of surface quality or strength to be achieved.
- Suitable polymers for use in the process according to the invention are in particular thermoplastic polymers.
- the at least two polymer layers each contain at least 50 wt .-%, preferably at least 70 wt .-% and particularly preferably at least 90 wt .-%, each based on the polymer, polyolefins, for example polyethylene or polypropylene, polyvinyl polymers such as polyvinyl chloride, polyvinyl acetals, polyvinyl ethers, polyvinyl lactams or polyvinyl amines, styrene polymers, for example polystyrene, styrene-acrylonitrile copolymers, acrylonitrile-butadiene styrenes, polymers of
- (Meth) acrylic acid for example polyacrylic acid, poly (meth) acrylates, polyacrylates, polymethyl methacrylate, polyacrylamide, polycarbonates, polyoxymethylene, polyphenylene ethers, poly tetrafluoroethylene, polyphenylene sulfide, polyether sulfones, polyether ketones, polyimides, polyquinoxalines, polyquinolines, polybenzimidazoles, polyamides, polyesters or polyurethanes such as polyisocyanates, polyols, polyether polyols or polyester polyols or mixtures thereof. Particularly preferred are polyamides and polyesters such as polybutylene terephthalate.
- Preferred polyamides are PA6, PA12, PA4.6, PA66, PA6.10, PA6.12, PA10.10, PA12.12, PA13.13, PA6.T, PA9.T, PA MXD.6, PA6 / 6.6, PA6 / 6.T, PA6.I / 6.T, PA6 / 6.6 / 6.10, also known as nylon-6, nylon-6.6, nylon-4.6, nylon-6T-copolyamides and nylon-6 / 6.6.
- the at least two polymer layers may contain additives. These are, for example, stabilizers, lubricants, nucleating agents, dyes, hardeners, plasticizers, blends with other polymers or any other additives known to the person skilled in the art.
- the at least two polymer layers contain the same polymer as the matrix material.
- finished parts can also be produced from a plurality of fiber-reinforced polymer layers containing different polymers as matrix material.
- the polymer layers are reinforced with a fibrous structure, wherein the fibrous structure is preferably a woven, knitted, knitted, braided, scrim, nonwoven or unidirectional or bidirectional fiber structure of parallel fibers or disordered fibers, yarns, threads or yarns Includes ropes.
- the fiber structures of the various polymer layers can be arranged parallel to one another, non-oriented or rotated relative to one another. Particularly preferably, the fiber structures are in the form of woven or layered layers of fibers, yarns, threads or ropes.
- the individual layers are particularly preferably rotated by the angle of 90 ° to each other (bidirectional structure).
- the individual layers rotated by an angle of 60 ° to each other and rotated at four layers or multiples of four layers by an angle of 45 ° to each other.
- layers may likewise be twisted relative to each other, wherein the number of layers with fibers of the same orientation may be different in each of the orientations of the fibers, for example four layers in a first direction and one layer in a direction rotated for example by 90 ° (bidirectional structure with preferred direction).
- a quasi-isotropic structure is known in which the fibers of a second layer are rotated by 90 ° to the fiber of a first layer and further fibers of a third layer rotated by 45 ° to the fibers of the second layer.
- all fibers have the same direction.
- fibers of the fiber structure are carbon fibers, glass fibers, aramid fibers, metal fibers, polymer fibers, potassium titanate fibers, boron fibers or mineral fibers, for example basalt fibers.
- Particularly preferred are glass fibers and carbon fibers.
- the proportion of fibers based on the total volume of the semifinished product structure is preferably up to 70% by volume.
- Finished parts that can be produced in this way are, for example, parts of vehicle bodies, structural components for vehicles, such as floors or roofs, component components for vehicles, such as mounting brackets, seat structures, door linings or interior linings.
- the manufactured finished parts can be used for bulkheads, battery carriers, side impact beams, bumper systems, structural inserts or pillar reinforcements in motor vehicles or also for side walls, structural fenders or side members in vehicle bodies.
- the finished parts are also suitable as components for wind turbines or rail vehicles.
- Two fully multi-layer consolidated semi-finished structures were heated in an infrared radiation field to 260 ° C and processed in a component tool by pressing each to a finished part.
- Both semi-finished structures each comprised six polymer layers, each of which was fiber-reinforced.
- the polymer used was PA6.
- In the first semifinished structure four polymer layers were aligned in parallel with respect to their fiber reinforcement, and the two outer polymer layers were parallel to each other and offset by 90 ° from their adjacent layers.
- the second semifinished product structure a total of four polymer layers were aligned in parallel. The two externally calculated second of the six layers were parallel to each other and offset from the adjacent layers by 90 °. It was overmoulded with PA6-GF35.
- the finished parts had a thickness of 1, 5 mm.
- Three multi-layer semi-finished structures whose polymer layers were arranged loosely on top of each other, were heated in an infrared radiation field to 260 ° C and processed in a component tool by pressing to a finished part.
- the polymer used was PA6. Before pressing, the temperature of 260 ° C was maintained between 2.5 minutes and 3 minutes.
- the semi-finished structures each comprised six polymer layers, each of which was fiber-reinforced. In all semi-finished product structures, four polymer layers were aligned parallel with regard to their fiber reinforcement and the two outer polymer layers were mutually parallel and offset by 90 ° relative to the adjacent layer. It was overmoulded with PA6-GF35.
- the finished parts had a thickness of 1, 5 mm.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Moulding By Coating Moulds (AREA)
- Reinforced Plastic Materials (AREA)
- Laminated Bodies (AREA)
Abstract
L'invention concerne un procédé pour la production de pièces finies à partir d'au moins un produit semi-fini multicouche, renforcé par des fibres, plat, comprenant les étapes suivantes consistant à : a) chauffer ledit au moins un produit semi-fini multicouche, renforcé par des fibres, plat, à la pression ambiante à une première température Ta, ledit au moins un produit semi-fini multicouche, renforcé par des fibres, plat, comprenant au moins deux couches polymères disposées l'une sur l'autre et les différentes couches polymères étant à chaque fois renforcées par des fibres et n'étant pas reliées l'une à l'autre par une liaison de matière ou alors seulement reliées partiellement l'une à l'autre par une liaison de matière et, dans le cas où au moins une des couches polymères contient un polymère partiellement cristallin, la première température Ta étant supérieure à une température de fusion Ts du polymère cristallin selon la norme DIN EN ISO 11357-3:2013-04 et, dans le cas où lesdites au moins deux couches polymères ne contiennent pas de polymère partiellement cristallin, la première température Ta étant supérieure à une température de transition vitreuse Tg selon la norme DIN EN ISO 11357-2:2013-09 d'un polymère qui est contenu dans au moins une des au moins deux couches polymères, b) presser le produit semi-fini multicouche, renforcé par des fibres, plat chauffé en une pièce finie à une deuxième température Tb et à une pression pb d'au moins 3 bars.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14193212 | 2014-11-14 | ||
PCT/EP2015/075707 WO2016075010A1 (fr) | 2014-11-14 | 2015-11-04 | Procédé de production de pièces finies |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3218429A1 true EP3218429A1 (fr) | 2017-09-20 |
Family
ID=51897181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15797883.4A Withdrawn EP3218429A1 (fr) | 2014-11-14 | 2015-11-04 | Procédé de production de pièces finies |
Country Status (6)
Country | Link |
---|---|
US (1) | US10632692B2 (fr) |
EP (1) | EP3218429A1 (fr) |
JP (1) | JP2017537005A (fr) |
KR (1) | KR20170084276A (fr) |
CN (1) | CN107107599A (fr) |
WO (1) | WO2016075010A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017178533A1 (fr) * | 2016-04-15 | 2017-10-19 | Basf Se | Dispositif d'entraînement musculaire et son procédé de fabrication |
IT201600099626A1 (it) | 2016-10-05 | 2018-04-05 | Giemme S N C Di Corradini Marco & C | Struttura di materiale multistrato a leggerezza incrementata e relativo manufatto ottenibile. |
EP4070937B1 (fr) * | 2019-12-03 | 2024-07-17 | Mitsubishi Gas Chemical Company, Inc. | Procédé de production d'un article en résine renforcé par des fibres |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3764449A (en) * | 1969-10-06 | 1973-10-09 | Brunswick Corp | Method of making a polyimide and laminated product made therefrom |
US5178964A (en) * | 1989-08-31 | 1993-01-12 | United Technologies Corporation | Fabricating crosslinked polyimide high temperature composites and resins |
JP5672006B2 (ja) * | 2009-09-16 | 2015-02-18 | 東レ株式会社 | バインダー組成物、強化繊維基材、プリフォームおよび繊維強化複合材料とその製造方法 |
DE102009060689B4 (de) * | 2009-12-29 | 2015-12-03 | Airbus Operations Gmbh | Verfahren zur Herstellung eines faserverstärkten Bauteils sowie Vorrichtung zur Durchführung des Verfahrens |
DE102011083162A1 (de) * | 2011-09-21 | 2013-03-21 | Bayerische Motoren Werke Aktiengesellschaft | Mehrlagiges Faserverbundbauteil und Verfahren zum Herstellen desselben |
KR20140107304A (ko) | 2011-12-22 | 2014-09-04 | 데이진 가부시키가이샤 | 성형체의 제조 방법 및 성형체 |
EP2669076A1 (fr) | 2012-05-31 | 2013-12-04 | Basf Se | Procédé pour relier deux éléments en matière plastique pour former un seul composant |
DE102013013497A1 (de) | 2013-08-16 | 2015-02-19 | Leichtbau-Zentrum Sachsen Gmbh | Verfahren zur Herstellung eines Bauteils aus Organoblechen |
-
2015
- 2015-11-04 WO PCT/EP2015/075707 patent/WO2016075010A1/fr active Application Filing
- 2015-11-04 KR KR1020177016380A patent/KR20170084276A/ko unknown
- 2015-11-04 US US15/526,393 patent/US10632692B2/en not_active Expired - Fee Related
- 2015-11-04 EP EP15797883.4A patent/EP3218429A1/fr not_active Withdrawn
- 2015-11-04 CN CN201580061932.XA patent/CN107107599A/zh active Pending
- 2015-11-04 JP JP2017526094A patent/JP2017537005A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JP2017537005A (ja) | 2017-12-14 |
US20180290401A1 (en) | 2018-10-11 |
US10632692B2 (en) | 2020-04-28 |
KR20170084276A (ko) | 2017-07-19 |
CN107107599A (zh) | 2017-08-29 |
WO2016075010A1 (fr) | 2016-05-19 |
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