EP3215465A1 - Sorbant à base d'alumine activée poreuse pour l'extraction de lithium - Google Patents

Sorbant à base d'alumine activée poreuse pour l'extraction de lithium

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Publication number
EP3215465A1
EP3215465A1 EP14905588.1A EP14905588A EP3215465A1 EP 3215465 A1 EP3215465 A1 EP 3215465A1 EP 14905588 A EP14905588 A EP 14905588A EP 3215465 A1 EP3215465 A1 EP 3215465A1
Authority
EP
European Patent Office
Prior art keywords
lithium
activated alumina
composition
sorbent
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14905588.1A
Other languages
German (de)
English (en)
Other versions
EP3215465A4 (fr
Inventor
Stephen Harrison
C.V. Krishnamohan SHARMA
M. Scott CONLEY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Simbol Inc
Original Assignee
Simbol Inc
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Filing date
Publication date
Application filed by Simbol Inc filed Critical Simbol Inc
Publication of EP3215465A1 publication Critical patent/EP3215465A1/fr
Publication of EP3215465A4 publication Critical patent/EP3215465A4/fr
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/043—Lithium aluminates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents

Definitions

  • the invention generally relates to the field of selectively removing and recovering lithium from lithium containing solutions. More particularly, the invention relates to a composition, methods of preparing the composition, and methods of using the composition for the selective removal and recovery of lithium ions from a lithium ion containing solution, such as a brine, preferably without the removal of other ions from the solution.
  • a lithium ion containing solution such as a brine
  • geothermal brines can be used to provide a source of electrical power due to the fact that hot geothermal reservoirs are stored at high pressure underground, which when released to atmospheric pressure, can provide a flash steam.
  • the flash steam can be used, for example, to run a power plant.
  • associated binary processes can be used to heat a second fluid, which can provide steam for the generation of electricity without the flashing of the geothermal brine.
  • many geothermal brines contain various useful and valuable elements dissolved therein, which can be recovered and utilized for secondary processes.
  • geothermal brines frequently include various metal ions dissolved therein, particularly alkali and alkaline earth metals, as well as certain transition metals such as manganese, lead, silver and zinc, in varying concentrations, depending upon the source of the brine.
  • metal ions dissolved therein, particularly alkali and alkaline earth metals, as well as certain transition metals such as manganese, lead, silver and zinc, in varying concentrations, depending upon the source of the brine.
  • the economic recovery of metals from natural brines which may vary widely in composition, depends not only on the specific concentration of the desired metal within the brine, but also upon the concentrations of the various interfering ions, particularly silica, calcium and magnesium, because the presence of interfering ions can drastically increase recovery costs as additional steps must be taken to remove the interfering ions.
  • lithium aluminate intercalates [LiX] 0 - 1 [A1(0H) 3 ] 2 , (wherein X is an anion)
  • LAI lithium aluminate intercalates
  • the layered structure facilitates intercalation of anions between the layers, while the positively charged lithium cations diffuse into the hexagonal cavities formed within the two dimensional layer structure that readily accommodate ions the size of lithium.
  • compositions prepared from two-dimensional forms of aluminum hydroxide can be used to extract lithium from brines and other lithium containing solutions
  • Certain embodiments include a sorbent composition for the recovery of lithium from a lithium containing solution.
  • This sorbent composition includes particulate material containing an activated alumina lithium intercalate composition, wherein the activated alumina lithium intercalate composition is produced by infusing a three-dimensionally structured activated alumina with a lithium salt to produce a LiX/Al(OH) 3 solid having a mole fraction of lithium to alumina of up to about 0.33, and wherein X is the anion of the lithium salt.
  • the lithium salt is lithium chloride.
  • the lithium salt is lithium hydroxide.
  • the three-dimensionally structured activated alumina includes one or more of ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ ( ⁇ ), pseudoboehmite, and combinations thereof.
  • the three- dimensionally structured activated alumina comprises ⁇ - ⁇ 1 2 0 3 .
  • the three-dimensionally structured activated alumina comprises pseudoboehmite.
  • the three-dimensionally structured activated alumina comprises ⁇ - ⁇ 1 2 0 3 and pseudoboehmite.
  • the sorbent composition can include particulate material having an average diameter of between about 200 and 800 ⁇ . In other instances, the sorbent composition can include particulate material having an average diameter of between about 400 and 700 ⁇ .
  • Certain embodiments include a method for utilizing a sorbent composition for the recovery of lithium from a lithium containing solution.
  • the method include the steps of providing a sorbent composition in an extraction and recovery apparatus, wherein the sorbent composition has particulate material containing an activated alumina lithium intercalate composition, wherein the activated alumina lithium intercalate composition is produced by infusing a three-dimensionally structured activated alumina with a lithium salt to produce a LiX/Al(OH) 3 solid having a mole fraction of lithium to alumina of up to about 0.33, wherein X is the anion of the lithium salt.
  • the sorbent composition is subjected to washing in the extraction and recovery apparatus with a wash solution containing at least about 50 ppm lithium.
  • the sorbent composition is then contacted with a lithium containing solution, wherein the contacting step is sufficient to extract lithium from the lithium containing solution.
  • the extracted lithium is then recovered by washing the sorbent composition in the extraction and recovery apparatus with the wash solution.
  • the lithium salt of the sorbent composition is lithium chloride.
  • the three-dimensionally structured activated alumina of the sorbent composition includes one or more of ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ ( ⁇ ), pseudoboehmite, and combinations thereof.
  • the three-dimensionally structured activated alumina of the sorbent composition comprises ⁇ - ⁇ 1 2 0 3 .
  • the three-dimensionally structured activated alumina of the sorbent composition comprises pseudoboehmite.
  • the lithium containing solution is obtained from a geothermal brine solution.
  • a method for preparing a composition for the recovery of lithium from a lithium containing brine includes the steps of preparing a solid sorbent composition, which includes an activated alumina lithium intercalate, by contacting or reacting a lithium salt with a three-dimensionally structured porous activated alumina under conditions sufficient to infuse the activated alumina with the lithium salt, wherein the resulting mole ratio of lithium to aluminum is up to about 0.5: 1.
  • the lithium salt is lithium chloride. In other embodiments, the lithium salt is lithium hydroxide. Other lithium salts can include lithium bromide, lithium iodide, lithium carbonate, lithium bicarbonates, and lithium sulfates. In certain embodiments, the step of contacting the lithium salt with the three-dimensionally structured porous activated alumina is performed in the presence of a hydroxide, carbonate, bicarbonate, borate, acetate, phosphate, fluoride, chloride, bromide or iodide of an alkaline or alkaline earth metal, and combinations thereof.
  • the lithium salt is selected from lithium hydroxide or lithium chloride, and the step of contacting the lithium salt with the three- dimensionally structured porous activated alumina is performed in the presence of a carboxylate, sulfonate, carbonate, bicarbonate, borate, acetate, phosphonate, or phosphate.
  • the carboxylate, sulfonate, carbonate, bicarbonate, borate, acetate, phosphonate or phosphate is present as a buffer.
  • the lithium salt is lithium hydroxide, and it is contacted with the three-dimensionally structured porous activated alumina in the presence of lithium chloride.
  • the step of contacting the lithium salt with the three-dimensionally structured porous activated alumina is conducted at a pH of greater than about 10. In certain embodiments, the step of contacting the lithium salt with the three - dimensionally structured porous activated alumina is conducted at a pH of between about 10 and 12, alternatively between about 11 and 12, alternatively between about 11.1 and 11.7. In certain embodiments, the step of contacting the lithium salt with the three-dimensionally structured porous activated alumina is conducted at a pH of between about 11.1 and 11.6, alternatively between about 11.1 and 11.5. In certain embodiments, the step of contacting the lithium salt with the three-dimensionally structured porous activated alumina is conducted at a pH of between about 11.3 and 11.7, alternatively between about 11.5 and 11.7.
  • the alkaline or alkaline earth hydroxide is selected from lithium hydroxide, calcium hydroxide, sodium hydroxide, or potassium hydroxide.
  • the activated alumina is amorphous.
  • the activated alumina is crystalline.
  • the activated alumina is partially crystalline.
  • the activated alumina comprises more than one form of activated alumina (e.g., alpha, gamma, and chi).
  • a composition for the recovery of lithium from a lithium containing solution includes particulate sorbent material that includes an activated alumina lithium intercalate composition, wherein the activated alumina lithium intercalate composition is produced by infusing a three-dimensionally structured porous activated alumina with a lithium salt(s) to produce a LiX/Al(OH) 3 solid having a mole fraction of lithium to aluminum of up to about 0.5, wherein X is the anion of the lithium salt.
  • the lithium salt is lithium chloride. In other embodiments, the lithium salt is lithium hydroxide. Other lithium salts can include lithium bromide, lithium iodide, lithium carbonate, lithium bicarbonates, and lithium sulfates.
  • the particulate material has an average diameter of between about 200 and 800 ⁇ . Alternatively, the particulate material has an average diameter of between about 300 and 500 ⁇ , alternatively between about 400 and 700 ⁇ , alternatively between about 350 and 650 ⁇ .
  • a method for the removal and recovery of lithium from a lithium containing solution includes the step of providing an extraction and recovery apparatus, such as a column, that includes a sorbent composition that includes an activated alumina lithium intercalate composition, wherein the composition is prepared by the steps of contacting a lithium salt with a three-dimensionally structured porous activated alumina and hydrochloric acid under conditions sufficient to infuse the activated alumina with the lithium salt(s), wherein the mole ratio of lithium to aluminum is up to about 0.5: 1.
  • the method further includes the step of washing the sorbent composition with at least one half bed volume of a wash solution comprising at least about 50 ppm lithium.
  • the method further includes the step of supplying a lithium containing solution to the extraction and recovery apparatus, and contacting the lithium containing solution with the sorbent composition, wherein the contacting step is sufficient to extract lithium chloride from the lithium containing solution.
  • the method can also include the step of monitoring the output of the extraction and recovery apparatus to determine the saturation of the sorbent composition; and recovering the extracted lithium chloride by washing the sorbent composition with the wash solution.
  • the lithium salt is lithium chloride. In alternate embodiments, the lithium salt is lithium hydroxide. In certain embodiments, the method further includes the step of contacting the lithium salt and activated alumina in the presence of a hydroxide selected from the group consisting of sodium hydroxide, potassium hydroxide, or calcium hydroxide.
  • Figure 1 is an illustration of an apparatus for use according to one embodiment of the present invention.
  • Figure 2 is a graphical representation showing the loading and unloading of a column that includes a sorbent prepared according to one embodiment of the present invention.
  • Figure 3 is an X-ray powder diffraction pattern of one embodiment of the present invention.
  • Figure 4 is an X-ray powder diffraction pattern of one embodiment of the present invention.
  • Figure 5 is a comparison of the X-ray powder diffraction patterns of several embodiments of the present invention.
  • Figure 6 is a comparison of the X-ray powder diffraction patterns of several embodiments of the present invention.
  • lithium salts can include lithium nitrates, lithium sulfates, lithium bicarbonate, lithium halides (particularly chlorides and bromides), and acid salts.
  • novel methods for the selective extraction of lithium halides from solutions and brines that include said lithium halides are described herein.
  • Three dimensionally structured porous activated alumina is aluminum hydroxide that has been incompletely dehydrated in such a manner that the material produced has a highly porous structure and high surface area.
  • Suitable forms of three-dimensionally structured porous activated alumina for use herein include, but are not limited to, ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ - ⁇ 1 2 0 3 , ⁇ ( ⁇ ), ⁇ 1 4 0 3 ( ⁇ ) 6 (pseudoboehmite), and the like, and combinations thereof.
  • only activated alumina having a metastable or transition form of alumina are utilized to prepare the highly lithiated intercalates of alumina.
  • activated alumina is made using aluminum trihydrate as the starting material.
  • the alumina trihydrate is ground to an average particle size of about 10 microns.
  • This material is flash calcined at 750-930°F for an extremely short time, e.g., for few seconds, which causes rapid drying and the creation of a transition alumina - an amorphous aluminum hydroxide with a very high surface area.
  • up to 50% per weight of water is added to the alumina and spheres are formed by rolling it in a ball-forming pan.
  • additives are included as binding agents or to facilitate a change in the activity of the final alumina.
  • alumina spheres are then cured, which involves rehydrating the alumina spheres by aging under controlled humidity levels and heat for predetermined lengths of time, such as 2 to 4 hours.
  • the conditions for aging like pH of the solution, water purity, and temperature, are very important to determine the pore structure, crush strength, and abrasion properties.
  • the alumina is subjected to calcination to reduce the moisture content (LOI) to approximately 5-10%.
  • LOI moisture content
  • several processes including, but not limited to, an acid-dissolution process, can be used to produce activated alumina from alumina trihydrate and aluminum metal.
  • Certain embodiments of the invention provide a sorbent composition that includes an intercalate material that includes lithium and a three-dimensionally structured porous activated aluminum material for use in the removal and recovery of lithium from solutions, particularly lithium salts from geothermal and other brines.
  • the presently described activated alumina lithium intercalate sorbent composition advantageously provides a controllable and maximum allowable lithium to aluminum ratio, and a favorable structural form of particulate media, thereby providing increased capacity for removal and recovery of lithium.
  • the activated alumina lithium intercalate sorbent composition has a mole fraction of lithium to aluminum in the range of about 0.1 to 0.3, and preferably up to about 0.33.
  • the ratio of lithium to aluminum is critical in stabilizing the structural form of the material and maximizing the number of lithium sites available in the matrix for the loading and unloading of lithium from a brine solution.
  • a three-dimensionally structured porous activated alumina is contacted or reacted with a lithium containing compound, such as a lithium salt, such as for example lithium hydroxide, and in certain other embodiments lithium chloride, to form activated alumina lithium intercalate sorbent materials.
  • a lithium containing compound such as a lithium salt, such as for example lithium hydroxide, and in certain other embodiments lithium chloride
  • the ratio of activated alumina to lithium salt can be 1: 1, alternatively about 1.3: 1, alternatively about 1.4: 1, or alternatively about 1.5: 1.
  • the formation of the three-dimensional structure of the intercalate materials occurs controllably with respect to the growth of the materials, thereby resulting in materials having controlled sizes, shapes, and porosity, as compared with other lithium aluminum intercalate materials that are prepared using two-dimensional alumina.
  • the fact that the rate of reaction between lithium salts and three-dimensional porous activated alumina can be regulated to control the crystal growth of the resulting sorbent media enables greater lithium extraction efficiencies and physical stability, as compared to lithium extraction media derived from two-dimensional alumina related materials.
  • the step of contacting the activated alumina with the lithium hydroxide is done in the presence of a metal halide, particularly an alkali or alkaline earth metal halide, such as sodium chloride or lithium chloride.
  • a metal halide particularly an alkali or alkaline earth metal halide, such as sodium chloride or lithium chloride.
  • the metal halide for example lithium chloride
  • the metal halide may not actually react with either the activated alumina or the lithium salt, but the presence is believed to assist in the preservation of the structural integrity of the resulting compound. It is believed that the metal halide, for example lithium chloride, may act as a surfactant and may assist in preventing agglomeration of the resulting product.
  • the metal chloride is lithium chloride, it can be present in an amount of 1 to 30% by weight.
  • This reaction can further include the presence of a weak acid such as carboxylic acids, for example acetic acid, boric acid, phosphonic acid, phosphoric acid, sulfonic acid, carbonic acid and bicarbonic acid.
  • a weak acid such as carboxylic acids, for example acetic acid, boric acid, phosphonic acid, phosphoric acid, sulfonic acid, carbonic acid and bicarbonic acid.
  • the mole ratio between the LAI, the metal halide, and the weak acid is about 1: 1: 1.
  • the mole ratio of LAI to metal halide is between about 1: 1 and 1: 1.510, alternatively between about 1: 1 and 1:5, alternatively between about 1: 1 and 1: 1.5, alternatively between about 1: 1.1 and 1: 1.4, alternatively between about 1: 1.1 and 1: 1.3.
  • the mole ratio of LAI to weak acid is between about 1: 1 and 1: 10, alternatively between about 1 :2 and 1:5, provided that the mole ratio of LAI to metal halide is at least about 1: 1.1.
  • lithium chloride can be present in an amount of between about 1 and 30% by weight (based upon the amount of lithium salt, such as lithium hydroxide) that has been added, alternatively between about 5 and 25% by weight, alternatively between about 5 and 15% by weight, alternatively between about 15 and 25% by weight.
  • the step of contacting the activated alumina with the lithium salt is done at a pH of greater than about 7, preferably greater than about 10.
  • the pH is between about 7 and 10, alternatively between about 9 and 12, alternatively between about 9 and 11, alternatively between about 10 and 12, or alternatively between about 11 and 13.
  • the pH is between about 7 and 11, or between about 10 and 13.
  • the pH during the contacting step is between about 11 and 12, alternatively between about 11.25 and 11.75, alternatively between about 11 and 11.5, alternatively between about 11.5 and 12.
  • the activated alumina may react with the lithium salt, for example lithium chloride and lithium hydroxide, at different rates to form the new composite materials.
  • Activated alumina materials can include various forms, including amorphous, metastable, crystalline, partially crystalline, and polycrystalline forms.
  • the activated alumina material can include more than one form.
  • certain polymorphic forms of activated alumina may not react with lithium hydroxide to a significant extent, particularly alumina forms that have been heated to temperatures greater than 1000°C, or greater than about 1500°C.
  • certain stable polymorphic forms of alumina may be less reactive with respect to lithium hydroxide, as compared with other polymorphic forms (e.g., ⁇ -alumina).
  • non- activated aluminum oxides may react slowly with lithium hydroxide (sometimes to the extent that it is difficult or impractical to infuse lithium salts into such materials), as compared to activated/meta stable alumina, and have an altered crystal growth of LAI, which can lead to improved cohesive binding crystal growth of LAI, and thereby improve lithium extraction efficiency.
  • the products thereof may exhibit differences in their ability to extract lithium from lithium containing solutions.
  • the activated alumina can have a melting point of greater than about 2000°C, preferably greater than about 2025°C, even more preferably greater than about 2045°C.
  • the pH of the activated alumina can be between about 4 and 10, preferably about 7.0 + 0.5, alternatively between about 7.2 + 0.5.
  • Pore volume of the activated alumina can be about 90A, alternatively between about 75 A and about l loA.
  • Bulk density of the activated alumina can be greater than about 800 kg/m , alternatively about 850 kg/m3.
  • the surface area of the activated alumina can be between about 100 - 600 m /g, alternatively between about 150 - 350 m 2 /g, alternatively between about 230 - 300 m 2 /g.
  • the resulting LAI product can be a particulate material having an average diameter of greater than about 75 ⁇ .
  • the product can be a particulate material having an average diameter of less than about 700 ⁇ .
  • the resulting particulate material has an average diameter of between about 75 and 700 ⁇ , alternatively between about 200 and 400 ⁇ , alternatively between about 300 and 800 ⁇ .
  • brine solution can refer to a naturally occurring or synthetically prepared aqueous solution of alkali and/or alkaline earth metal salt(s), wherein the concentration of salts can vary from trace amounts up to the point of saturation.
  • brines suitable for the methods described herein are aqueous solutions that may include alkali metal or alkaline earth chlorides, bromides, sulfates, borates, acetates, hydroxides, nitrates, and the like, including natural brines.
  • Exemplary elements that may be present in the geothermal brines can include sodium, potassium, calcium, magnesium, lithium, strontium, barium, iron, boron, silicon, manganese, zinc, aluminum, antimony, chromium, cobalt, copper, lead, arsenic, mercury, molybdenum, nickel, silver, gold, thallium, radon, cesium, rubidium, vanadium, sulfur, chlorine, and fluorine, although it is understood that other elements and compounds may also be present.
  • Brines can be obtained from natural sources, such as, Chilean brines, Argentinean brines, Venezuelan brines, Salton Sea brines, geothermal brines, and sea water, or can be obtained from other sources, such as oilfield brines (e.g., Smackover brines), mineral brines (e.g., lithium chloride or potassium chloride containing brines), alkali metal salt brines, and industrial brines, for example, industrial brines recovered from ore leaching, mineral dressing, and the like.
  • oilfield brines e.g., Smackover brines
  • mineral brines e.g., lithium chloride or potassium chloride containing brines
  • alkali metal salt brines e.g., alkali metal salt brines
  • industrial brines for example, industrial brines recovered from ore leaching, mineral dressing, and the like.
  • the methods described herein equally applicable to artificially prepared brine or salt solutions, as well as waste water streams, provided that the salinity of the solution is sufficiently high (for example, having a minimum concentration of at least about 1% by weight common salt), or the concentration of lithium salt is greater than about 50 ppm, preferably at least about 100 ppm. It is understood that, in certain embodiments, the exact concentration of salt sufficient to drive to sorption of lithium into the lithium aluminate is dependent on the exact dissolved metal species and their concentrations present in the solution.
  • the present invention can be used in conjunction with additional methods, including steps designed to first removing silica from the brine.
  • the present brines contemplated for use herein can first be treated by known means, generally known as silica management, to first remove silica and/or iron, prior to the recovery of any lithium.
  • the brine or lithium containing solution can also be filtered or treated to remove solids or other elements that may be present in the solution, prior to the selective recovery of lithium.
  • simulated brine refers to a synthetic brine that has been prepared in an attempt to simulate the brine composition of various geothermal brine test wells found in the Salton Sea (Calif., U.S.).
  • the simulated brine has a composition of about 280 ppm lithium, 63,000 ppm sodium, 20,000 ppm potassium, 33,000 ppm calcium, 130 ppm strontium, 700 ppm zinc, 1700 ppm iron, 450 ppm boron, 50 ppm sulfate, 3 ppm fluoride, 450 ppm ammonium ion, 180 ppm barium, 160 ppm silica (reported as Si0 2 ), and 180,000 ppm chloride.
  • Additional elements such as manganese, aluminum, antimony, bromine, chromium, cobalt, copper, fluorine, lead, arsenic, mercury, molybdenum, nickel, silver, thallium, and vanadium, may also be present in the brine.
  • matrices based upon activated alumina lithium intercalate sorbent compositions can be prepared by mixing the sorbent material with a polymer, plastic, or other organic or inorganic binder material.
  • the matrix preferably includes a polymeric material or binder that can be cross-linked.
  • the resulting matrix can include a major portion of an activated alumina lithium intercalate, prepared according to the methods described herein, and a minor portion that includes polymeric, plastic, or other binder material, which can serve as the matrix binder.
  • the matrix includes between about 75% and 99% by weight of the activated alumina lithium intercalate material, and between about 1% and about 25% by weight of the polymer, plastic or binder material.
  • the matrix can include between about 60 and 80% by weight activated alumina and between about 20 and 40% by weight polymer, plastic or binder, alternatively between about 70 and 90% by weight activated alumina and between about 10 and 30% by weight polymer, plastic or binder.
  • the polymer or plastic binder material employed in the preparation of the matrix materials can be selected from any suitable thermoplastic or thermoset polymer material.
  • Inorganic binder may include, aluminates, silicates, silanes, metal alkoxides, metal hydroxides, titanates, zirconates, phosphate, poly aluminum hydroxyl chlorides, and several other forms of inorganic binders, as well as combinations thereof.
  • the polymer/plastic material and the sorbent composition can be mixed together and sintered at elevated temperature to form the sorbent composition.
  • pressure can be applied to the mixture before, during, or after the sintering process. In certain embodiments, up to 10,000 psi can be applied to the mixture, with or without concurrent heating thereof. In certain embodiments, pressure of at least 2500 psi is applied. In alternate embodiments, increasingly greater pressures are applied to the mixture.
  • the resulting sintered product is typically a solid, which can then be broken into smaller pieces, preferably to form a plurality of particulates, for use in the extraction of lithium.
  • the solid sintered products can be ground to a desired particulate diameter or size. In certain embodiments, the ground sorbent matrix can be separated, using for example sieves, to provide multiple sizes or ranges of diameters of the sorbent matrix particles.
  • the sorbent -polymer matrix can be pressed in a mold on any desired shape or size.
  • the sorbent -polymer matrix can be cured and formed as a sheet or like shape, suitable for use as, for example, a cartridge filter wherein a lithium containing solution is passed over and/or through the sheet for the extraction of the lithium containing ions.
  • lithium infused activated alumina particles can be treated with binder solutions/cross-linkers to further enhance the rigidity of the already existing structures.
  • the activated alumina lithium intercalate sorbent materials prepared according to the above described methods can be washed with a predetermined amount of water to remove a portion of the LiCl from the solids, thereby creating vacant sites that are available to receive lithium halides or other lithium salts from a brine or solution.
  • the sorbent material can then accept lithium chloride ions.
  • the initial wash water preferably includes at least a small concentration of LiCl. In certain embodiments, the wash water includes at least 100 ppm LiCl.
  • the wash water includes at least 150 ppm LiCl. In yet other embodiments, the wash water includes at least 200 ppm LiCl. In certain embodiments, the wash water may include a salt, such as NaCl, KCl, or any other salt or non-ionic solute that may be advantageous for a particular lithium salt extraction process. Typically, chlorides are selected due to their relatively low cost, however it is understood that other halides can also be used. In certain embodiments, divalent and trivalent salts are avoided.
  • the vacant sites in the sorbent material can then be loaded with "new" LiCl or other salts by exposing the sorbent material to the brine or solution that includes LiCl or other lithium salts.
  • the brine or the solution does not include salts that will compete with the extraction of lithium.
  • the lithium ions are captured by the sorbent material and fill the exposed vacancies.
  • the flow of the brine can be stopped.
  • the captured LiCl can then be unloaded from the sorbent material by again washing the sorbent material with wash water, as described herein.
  • the wash water includes a small amount of LiCl present, such as at least 100 ppm of lithium, sufficient to ensure that at least a portion of the capture sites on the LAI matrix are filled with ions to prevent the sorbent material from collapsing.
  • the process can be repeated many times, as desired
  • the loading and unloading of the sorbent material can be monitored by measuring the lithium concentration of the outlet stream from the column.
  • Means for monitoring the concentration of the lithium can include ion selective electrodes, ion chromatography, or spectrometric analysis, such as atomic absorption or inductively coupled plasma spectroscopy, and other means known in the art.
  • the loading process is typically fairly efficient, such that at least 50% of the lithium ions in the brine or solution are captured by the sorbent material, preferably at least 75% of the lithium ions in the brine or solution are captured by the sorbent material. As such, a rapid increase in the lithium ion concentration at the outlet of the sorbent material is indicative of saturation of the column.
  • a sudden decrease in the concentration thereof can be indicative of the removal of a majority of the ions captured by the material.
  • the sorbent material prepared according to the present methods has an extraction capacity suitable for use in brines having a lithium concentration similar to that of the Hudson Collins geothermal brines, i.e., a lithium concentration of about 300 ppm, of at least about 1 mg of lithium per gram of the sorbent material, preferably at least about 2 mg of lithium per gram of the sorbent material, even more preferably at least about 3 mg of lithium per gram of the sorbent material.
  • the extraction capacities may be larger for brines containing higher concentrations of lithium.
  • an alternate sorbent material and method for preparing same are provided.
  • the hydroxyl form of the LAI material prepared as previously described can be neutralized with inorganic acids, such as hydrochloric acid or nitric acid.
  • the hydroxyl form of the LAI material prepared as previously described can be neutralized with a weak acid or buffer, such as carboxylic acids, for example acetic acid, boric acid, phosphonic acid, phosphoric acid, sulfonic acid, carbonic acid and bicarbonic acid, in presence of a metal halide, such as concentrated lithium chloride solution.
  • buffer is used to refer to a composition that is capable of maintaining the pH of a solution within a certain defined range.
  • the neutralization of the intercalate material is preferably conducted such that at equilibrium, the pH is not less than about 2.5, alternatively between about 4 and 6, alternatively between about 3 and 5, alternatively between about 4 and 5.
  • Certain buffers can include weak acids, such as acetic acid.
  • Exemplary LAI acidification buffers can include carboxylates (particularly acetates), sulfonates, phosphates, phosphonates, acetates, borates, carbonates, bicarbonates, and the like.
  • the neutralization is performed at temperatures of less than about 60°C, alternatively at or below about 40°C, alternatively about room temperature.
  • the neutralization step generally includes removing the liquid from the reaction of the activated alumina and lithium salt, adding an aqueous solution that includes the weak acid buffer or dilute strong acid and metal halide, optionally agitating the solution, and monitoring the pH change.
  • the pH is initially high, such as greater than about 10, or in certain embodiments, greater than about 11.
  • the pH decreases to less than about 7, alternatively less than about 6, alternatively less than about 5, or alternatively less than about 4.
  • the solution added for neutralization is removed, the product is washed with water, and dried.
  • This neutralization step can lead to the formation of a high performance chloride form of LAI material having lithium loading capacities of between about 4.0-5.0 mg/L, lithium concentrations in the product cut, 3.5 - 5 wt % and divalent metal impurity of around 1% of lithium carbonate equivalent in the product cut.
  • the product has been shown to be particularly amenable to scale- up.
  • the weak acid buffer solution utilized for the neutralization of the LAI material can include up to about 30% by weight lithium chloride, alternatively between about 2 and 7% by weight lithium chloride, alternatively between about 5 and 12% by weight, alternatively between about 10 and 15% by weight lithium chloride.
  • the LAI can be neutralized with a weak acid buffer, such as acetic acid, in presence of concentrated lithium chloride containing solution.
  • a weak acid buffer such as acetic acid
  • the molar ratio between the LAI material and the acetic acid can range between about 1:0.75 and about 1 : 10.
  • a relatively low concentration of lithium chloride for example up to about 10% by weight, alternatively up to about 5% by weight, alternatively between about 5 and 10% by weight, is required.
  • An excess amount of lithium chloride from the concentrated lithium chloride containing solution may preclude potential intercalation of acetate anions and promote ion exchange between hydroxyl and chloride groups.
  • neutralization with a weak acid buffer may prevent the formation of high molecular weight aluminum hydroxide byproducts that can attract impurities during lithium extraction process.
  • a 30% aqueous lithium chloride solution was utilized. It was found that the amount of the weak acid buffer, for example acetic acid, used to neutralize the LAI, could be between about 1:0.5 and 1: 1.25 molar equivalents, although in certain embodiments the presence of excess weak acid buffer (for example, 5-10 times the required amount) does not result in negative effects, provided the weak acid buffer solution, for example acetic acid, is buffered with a metal chloride solution, such as lithium chloride solution. Acetic acid utilized for the neutralization of the sorbent proceeds normally without dissolving significant quantities of the sorbent material. Performance of the resulting material for the extraction of lithium was not affected.
  • the sorbent material can be prepared using solution that includes an acetic acid buffer and lithium chloride for the neutralization thereof.
  • the neutralization can be carried out in a column.
  • various organic acids can be utilized for the neutralization of the LAI with in presence of metal halides to generate different organic salt byproducts.
  • lithium acetate, sodium acetate, and calcium acetate can be generated as byproducts using acetic acid and lithium chloride, sodium chloride, and calcium chloride as the metal salts, respectively.
  • it may be possible to use other organic acids e.g., methyl sulfonic acid, propionic acid
  • the neutralization of LAI with a weak acid buffer and metal halide offers several advantages over certain other methods for the preparation of the sorbent for material.
  • the product resulting from the acetic acid neutralization demonstrates higher lithium loading capacities (e.g., capacities that are greater than about 4.2 mg/L); reduced impurities in the product cut ( ⁇ 1% LCE); consistent and reliable exchange of hydroxyl groups with chlorides; reduction of unwanted byproducts; the ability to conduct the neutralization on a large scale in a column; the formation of potentially valuable organic-metal salts byproducts (e.g., lithium acetate); and the avoidance of the use of corrosive acids for sorbent synthesis.
  • Apparatus 100 includes first vessel 102 for holding a wash (strip) solution and second vessel 104 for the brine or lithium containing solution.
  • Solenoid valves 103 and 105 are connected to computer 108 and control the input of fluid, i.e., brine or wash solution.
  • Apparatus 100 can further include digital peristaltic pump 106 (DPP).
  • Computer 108 can be coupled to various instruments, such as DPP 106, and solenoid valves 103 and 105, is a component of apparatus 100, and can be programmed to control the action of the DPP and solenoid valves.
  • Apparatus 100 further includes first sorbent material column 110 and second sorbent material column 112. Wash liquids and excess brine are collected in bulk collection vessel 114, and lithium ion produced can be recovered in sequential aliquots in product collection fractionator 116. As is understood, apparatus 100 may also include various heat exchangers, valves, and filters, for the control of the process.
  • Apparatus 100 includes two columns, 110 and 112 respectively, which are preferably packed with the sorbent material, typically as particulate matter, according to the present invention. It is understood that the apparatus can include a single column, or can include multiple columns. Glass wool, filters, or the like can be used at the top and bottom of the column to ensure that the sorbent material, or fines thereof, are not washed out of the column.
  • columns 110 and 112 are operated in parallel, although in certain embodiments the columns can be alternated such that while one column is being loaded, the second column is being unloaded or equally in series.
  • Systems are also contemplated that operate in a merry-go- round system having at least 3 columns, wherein two of the columns are in series and one column is being regenerated. After the first column in series is fully loaded, the first column switches to being regenerated. The second column then becomes the first column in series, and the column that was originally being regenerated becomes the second column in series, thus ensuring complete and efficient use of all the lithium capacity of the sorbent.
  • brine from vessel 104 is supplied via line 122 to solenoid valve 103, and can then be supplied via line 124 to DPP 106.
  • the brine is then supplied from DPP 106 via line 126 to first column 110, where the brine contacts the sorbent material, which is operable to remove lithium ions from said brine.
  • Excess brine solution, and brine solution that has had lithium ions removed therefrom is recovered in collection vessel 114 via line 128.
  • second column 112 which can be saturated with lithium ions, can be unloaded. Wash solution from vessel 102 can be supplied via line 130 to solenoid valve 105, and then supplied to DPP 106 via line 134. Wash solution is then supplied via line 136 to second column 112, where it contacts the sorbent material and removes lithium ions saturated thereon. A wash solution that is rich in lithium, as compared with the wash solution contained in vessel 102, is recovered in product collection fractionator 116, via line 142. Valves 131 and 133 control the flow of the output from first column 110 and second column 112 to collection vessel 114 and product collection fractionator 116, respectively.
  • the first column can then be supplied with wash water for recovery of lithium ions and the second column can then be supplied with a brine solution for the removal of lithium therefrom.
  • FIG. 2 the exemplary performance of a column which includes sorbent material (prepared according to Example 3, below), as shown by the lithium concentration of the liquid exiting the column during the loading and unloading thereof, is provided.
  • the column is loaded with approximately 10.8 mL of a granular sorbent having an average particle diameter of between about 0.3 and 0.8 mm consisting of lithium chloride infused activated alumina lithium intercalate sorbent.
  • approximately 13 bed volumes (i.e., approximately 140 mL, thirteen times the volume of the column) of a simulated brine having a lithium concentration of between about 284 mg/L and about 310 mg/L were supplied to the column.
  • the output stream from the column during loading had a lithium concentration of between about 10 and 50 mg/L, in the first 4 to 5 bed volumes, corresponding to the capture of between about 83% and 96% of the lithium present in the feed solution.
  • Unloading of the column is achieved by supplying approximately 2 bed volumes (i.e., approximately 20 mL) of a lithium strip solution (i.e., a solution having a LiCl concentration of approximately 6,000 mg/L).
  • the output stream had a maximum LiCl concentration of about 21,000 mg/L.
  • the loading and unloading of the column was repeated more than 20 times, with repeatable results of the capture of between approximately 95% of the LiCl present in the brine solution.
  • Figure 2 shows cycles 5 and 6 of a total of 21 consecutive cycles of loading and unloading the column.
  • the Figure shows two full loading-unloading cycles of the sorbent in a column, with lithium concentration of the liquid exiting the column in mg/L plotted on the Y- axis and bed volumes of liquid supplied to the column on the X-axis.
  • Point 10 of Figure 2 indicates the midpoint of an unloading cycle for the column. From point 10 to point 12 of Figure 2, the lithium containing brine (loading solution) is supplied to the column and is replacing the strip solution (unloading solution). Between points 12 and 14 of Figure 2, the brine with substantially lower concentration of lithium is exiting the column.
  • the concentration of lithium in the brine exiting the column is relatively low, typically much less than the concentration of the strip solution.
  • the concentration of lithium exiting the column increases.
  • the solution being fed to the column is switched from the lithium containing brine solution to stripping solution (having a lithium concentration of about 1000 mg/L) and a total of 2 BV is passed through the column.
  • the amount of lithium that is unloaded or stripped from the sorbent in the column is close to the amount of lithium that is extracted from brines, such that lithium extraction efficiency is maximized/optimized, without compromising the structural integrity of the media.
  • the strip solution is switched back to the lithium containing brine loading solution and 20 through 22 to the end of the plot represent another complete cycle.
  • the sorbent in the column is again exposed to the brine solution for the capture of lithium ions.
  • the lithium is loaded onto the sorbent in the column.
  • approximately 1 bed volume of liquid before point 22 on Figure 2 exposure to the brine solution is stopped and the strip solution is applied to the sorbent in the column.
  • the lithium concentration is again at a maximum.
  • the sorbent material is capable of being cycled at least
  • the lithium aluminate intercalate can be prepared as follows. To an appropriately sized metal or plastic container capable of being heated to a temperature of about 100°C, approximately 1 kg of unfractionated Alcoa aluminum trihydrate (Al(OH) 3 ) and LiOH » H 2 0, in a ratio of approximately 2 moles of aluminum to approximately 1.05 moles of lithium, and about 0.8 kg of deionized water are added and mixed.
  • the ratio of activated alumina to lithium hydroxide can generally vary between about 1: 1 and 1.5: 1.
  • the mixture is heated in an oven at a temperature of about 60°C until the hydroxide concentration, as determined by titration, indicates that at least about 93% of the hydroxide present has reacted.
  • the mixture is removed from heat, cooled to room temperature and approximately 0.8 kg of water is added to the mixture.
  • the resulting mixture is then neutralized using hydrochloric acid over a period of at least 2 hours to achieve a pH of between about 6.5 and 7.5.
  • the resulting solid is filtered and dried.
  • Example 2 Preparation of Particulate PVDF/LAI Matrix. Approximately 1.47 g of polyvinylidene fluoride copolymer (Kynarflex 2821) and approximately 27.56g of the LAI powder (as prepared in Example 1, above) were placed in a plastic jar and mixed using a mechanical stirrer, at increasingly higher speeds, 1000 - 5000 rpm, over a period of about five minutes. The resulting mixed matrix powder was placed in a frame having two Teflon lined metal plates.
  • the powder mixture in the press frame was placed in a hydraulic press and subjected to approximately 3500 psi pressure for approximately three minutes, released, subjected to approximately 4000 psi of pressure for approximately three minutes, released, subjected to approximately 5000 psi of pressure and a temperature of about 360°C for approximately three minutes, released, subjected to approximately 10,000 psi of pressure and a temperature of about 360°C for approximately 3 minutes, and released.
  • the assembly was then subjected to approximately 3500 psi of pressure for about two-three minutes.
  • the resulting sintered block was then broken into large granulates using a hammer.
  • the resulting granulates were separated using sieves into three groups consisting of a first group having a diameter of between about 300 and 450 ⁇ , a second fraction having a diameter between about 180 and 300 ⁇ , and a third fraction having a diameter of between about 100 and 180 ⁇ .
  • Example 3 Approximately 10.0 g of activated alumina (Dynamic Adsorbents,
  • Example 4 Activated alumina lithium intercalate composition prepared according to the method described in Example 3, having a diameter of between about 300-800 microns, was tested for extraction of lithium ions from a synthetic geothermal brine (wherein the brine is designed to simulate the geothermal fluids found at the Salton Sea, CA, having lithium concentration of about 300 mg/L) using a column with 1 cm internal diameter.
  • the preliminary loading/unloading was conducted at high temperatures 95°C, which indicates that the loading capacity of the sorbent composite exceeds about 3 - 3.7 g/L. This compares favorably to the materials prepared with two-dimensional alumina, which has a loading capacity of about 1.3 g/L, under the given experimental conditions.
  • sorbent materials generally have capacities at least 50% greater, preferably about 66% greater, or even at least 100% greater than similar materials prepared using two-dimensional alumina materials.
  • Example 5 Approximately 10 g of activated alumina (Dynamic Adsorbents, GA), having a particle size of less than about 400 microns, was initially heated up to 700°C for a period of about three hours to ensure that the material is fully dehydrated and has phase purity prior to adding 50 mL of 10% lithium hydroxide monohydrate solution. The reaction was carried at 80-90°C for 30-40 hours. It is believed that the extended heating of the aluminum oxide (prior to reacting with lithium hydroxide) may prolong the reaction time, and may alter crystal growth properties. The final product had a mass of about 21 g.
  • activated alumina Dynamic Adsorbents, GA
  • Example 6 Approximately 100 g of 8-14 mesh activated alumina granules
  • Example 7 Approximately 20 g of 8-14 mesh activated alumina (Fisher
  • the next two spectra correspond to lithium salt infused activated alumina prepared using activated alumina (Dynamic Adsorbents), and the bottom two spectra correspond to LAI materials deposited on activated alumina using polyaluminum hydroxyl chloride.
  • Example 8 Approximately 10 g of 100 mesh alumina (Sigma-Aldrich, m.p.
  • Example 9 Approximately 11 g of lithium hydroxide monohydrate and 11 g of anhydrous lithium chloride were dissolved in approximately 225 mL of water at room temperature. To this lithium salt solution, approximately 50 g of activated alumina was added slowly and the reactants were kept in an oven at 95°C for 6 hours. The yield of the hydroxyl form of LAI was found to be close to 85 g. A portion of this final product, approximately 30 g was neutralized using about 45 g of a 30% lithium chloride solution mixed with 5 g of acetic acid. The final pH of the solution reached a steady state of about 4.2 in about one hour. The resulting solid product was washed with water and dried.
  • the lithium extraction capability of the final product was tested in a column, as provided for the previous examples, having a lithium extraction capacity in the range of between about 4 and 5 g/L.
  • the final product was analyzed and determined to have an impurity content of about 1% of lithium carbonate equivalent.
  • the top most diffraction pattern in Figure 6 represents the XRPD pattern of materials neutralized using weaker acids, such as is described in Example 9.
  • Comparative Example 1 A resin based lithium aluminate intercalate material was synthesized as described in U.S. Pat. Nos. 4,159,311; 4,348,296; and 4,430,311, wherein a weak base anion exchanger in the free base form, for example, Dowex Marathon WBA, was contacted with a saturated solution of A1C13. The mixture, having a pH of approximately 0, was reacted at between about 50°C and 60°C, and was then titrated with concentrated NH 4 OH to raise the pH to near neutrality, at which point Al(OH) 3 precipitated in and on the resin beads. Excess Al(OH) 3 and NH 4 CI were washed out with water.
  • a weak base anion exchanger in the free base form for example, Dowex Marathon WBA
  • the resin was then heated at about 75°C to 80°C to convert amorphous Al(OH) 3 into gibbsite, which served as a seed for subsequent precipitation.
  • the gibbsite-seeded resin was then reacted with sodium aluminate solution at a pH of about 13 and then titrated with 37% HCl to reduce the pH to near neutral, and to grow Al(OH) 3 on the gibbsite seed.
  • the mixture was then washed with water to remove excess NaCl and Al(OH) 3 and was then heated at about 75°C to 80°C to the conversion of all intra-bead Al(OH) 3 into gibbsite.
  • the gibbsite-loaded resin was then reacted with LiOH at between about 55°C to 60°C to form a 3-layer polytype lithium aluminate (LiAl 2 (OH) 6 0H) within the resin at a pH of about 12.
  • the resin was then titrated with approximately 20% HCl to neutrality, to convert the OH form of the lithium aluminate to the chloride form. Excess lithium aluminate and lithium chloride removed by washing with water.
  • the procedure produced a resin having between about 2 and 4 mmol of aluminum and between about 1 and 2 mmol lithium per mL of resin.
  • the resin based LAI synthesized according to the procedure above was loaded into a column having a diameter of about 2.5 cm, a bed height of about 20 cm, and a bed volume of about 100 cm3. A total of 10 load, wash, and unload cycles were completed, wherein the first 5 cycles were used to optimize flow and volume parameters and the next 5 cycles were run semi- continuously using the optimized parameters. Loading capacity of the resin based LAI using a simulated brine as described herein was about 0.96 g/L.
  • Figure 6 shows a comparison of the x-ray powder diffraction (XRPD) pattern for an LAI sorbent prepared according to Example 9 (top spectra), which utilizes a three- dimensional porous activated alumina wherein the product LAI was neutralized with acetic acid, an LAI sorbent prepared according to Example 3 (middle spectra), which similarly utilizes a three-dimensional porous activated alumina wherein the product LAI was neutralized with HCl, and an LAI sorbent composition made by a similar method using gibbsite, a two-dimensional alumina (bottom spectra).
  • XRPD x-ray powder diffraction
  • the spectra for the LAI product utilizing the three-dimensional porous activated alumina is different than the LAI product prepared using a two-dimensional gibbsite alumina base.
  • the x-ray powder diffraction pattern of the three-dimensional porous activated alumina includes peaks that are not present in the gibbsite based LAI product indicates that a distinct composition of matter is prepared and plays a role in the improved performance. For example, additional peaks are found in the in the XRPD spectra at approximately 15 deg., 28 deg., and 38 deg., as compared with the XRPD of the gibbsite based alumina. Additionally, the main peak at approximately 12 deg. is slightly shifted for the gibbsite based alumina, as compared to the three-dimensional porous activated alumina based LAI.
  • Optional or optionally means that the subsequently described event or circumstances may or may not occur.
  • the description includes instances where the event or circumstance occurs and instances where it does not occur.
  • Ranges may be expressed herein as from about one particular value, and/or to about another particular value. When such a range is expressed, it is to be understood that another embodiment is from the one particular value and/or to the other particular value, along with all combinations within said range.

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Abstract

L'invention concerne un procédé de préparation d'une composition intercalaire de lithium à base d'alumine activée, consistant à mettre en contact une alumine activée poreuse à structure tridimensionnelle avec un sel de lithium dans des conditions suffisantes pour infuser des sels de lithium dans l'alumine activée poreuse à structure tridimensionnelle. L'invention concerne également l'utilisation de la composition intercalaire de lithium à base d'alumine activée dans l'extraction et la récupération sélectives de lithium à partir de solutions contenant du lithium, notamment des saumures.
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US8901032B1 (en) 2010-10-29 2014-12-02 Simbol Inc. Porous activated alumina based sorbent for lithium extraction
EP3700866A4 (fr) 2017-10-26 2021-05-19 International Battery Metals, Ltd. Appareil d'extraction modulaire
CN108187608A (zh) * 2018-02-03 2018-06-22 天津市职业大学 一种结晶性铝盐锂离子吸附剂颗粒及其制备方法
US11253820B2 (en) 2018-03-08 2022-02-22 Ut-Battelle, Llc Lithium extraction composite for recovery of lithium from brines, and process of using said composition
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CN115155510B (zh) * 2022-08-04 2023-11-10 成都开飞高能化学工业有限公司 一种铝盐提锂功能材料的制备方法
US11904297B1 (en) * 2023-01-11 2024-02-20 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorption/separation media
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US5389349A (en) * 1993-05-24 1995-02-14 Bauman; William C. Recovery of lithium values from brines
US8753594B1 (en) * 2009-11-13 2014-06-17 Simbol, Inc. Sorbent for lithium extraction
US10190030B2 (en) * 2009-04-24 2019-01-29 Alger Alternative Energy, Llc Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium
US20140239224A1 (en) * 2009-11-13 2014-08-28 Simbol Inc. Sorbent for Lithium Extraction
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