EP3171230B1 - Composant d'horlogerie a tribologie amelioree - Google Patents
Composant d'horlogerie a tribologie amelioree Download PDFInfo
- Publication number
- EP3171230B1 EP3171230B1 EP15195386.6A EP15195386A EP3171230B1 EP 3171230 B1 EP3171230 B1 EP 3171230B1 EP 15195386 A EP15195386 A EP 15195386A EP 3171230 B1 EP3171230 B1 EP 3171230B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- component
- surface layer
- solution
- pin
- boric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 33
- 239000002344 surface layer Substances 0.000 claims description 30
- 239000004327 boric acid Substances 0.000 claims description 29
- 230000007246 mechanism Effects 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000010410 layer Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 229910003460 diamond Inorganic materials 0.000 claims description 2
- 239000010432 diamond Substances 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 150000002816 nickel compounds Chemical class 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 239000010979 ruby Substances 0.000 claims description 2
- 229910001750 ruby Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims 5
- 229910052681 coesite Inorganic materials 0.000 claims 3
- 229910052906 cristobalite Inorganic materials 0.000 claims 3
- 229910052682 stishovite Inorganic materials 0.000 claims 3
- 229910052905 tridymite Inorganic materials 0.000 claims 3
- 229910052593 corundum Inorganic materials 0.000 claims 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 2
- 229910000851 Alloy steel Inorganic materials 0.000 claims 1
- 229910000881 Cu alloy Inorganic materials 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000000708 deep reactive-ion etching Methods 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000011135 tin Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 208000031968 Cadaver Diseases 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 210000003423 ankle Anatomy 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- -1 étain Chemical compound 0.000 description 2
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910021488 crystalline silicon dioxide Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005459 micromachining Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- OANVFVBYPNXRLD-UHFFFAOYSA-M propyromazine bromide Chemical compound [Br-].C12=CC=CC=C2SC2=CC=CC=C2N1C(=O)C(C)[N+]1(C)CCCC1 OANVFVBYPNXRLD-UHFFFAOYSA-M 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 1
- XCUPBHGRVHYPQC-UHFFFAOYSA-N sulfanylidenetungsten Chemical compound [W]=S XCUPBHGRVHYPQC-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B15/00—Escapements
- G04B15/14—Component parts or constructional details, e.g. construction of the lever or the escape wheel
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B31/00—Bearings; Point suspensions or counter-point suspensions; Pivot bearings; Single parts therefor
- G04B31/08—Lubrication
-
- G—PHYSICS
- G04—HOROLOGY
- G04D—APPARATUS OR TOOLS SPECIALLY DESIGNED FOR MAKING OR MAINTAINING CLOCKS OR WATCHES
- G04D3/00—Watchmakers' or watch-repairers' machines or tools for working materials
- G04D3/0074—Watchmakers' or watch-repairers' machines or tools for working materials for treatment of the material, e.g. surface treatment
- G04D3/0087—Watchmakers' or watch-repairers' machines or tools for working materials for treatment of the material, e.g. surface treatment for components of the escapement mechanism, e.g. lever escapement, escape wheel
Definitions
- the invention relates to a timepiece component comprising at least one self-lubricating surface layer.
- the invention also relates to a clock escapement mechanism comprising at least one such component.
- the invention also relates to a watch movement comprising at least one such escape mechanism.
- the invention further relates to a watch having at least one movement.
- the invention further relates to a method of coating a timepiece component with a self-lubricating surface layer.
- the invention relates to the field of watch mechanism components subjected to intense use, with a high pulse frequency, and a large number of pulses and friction phases during their service, such as exhaust mechanism components.
- the porous metal comprises copper, tin and graphite, and may contain a solid lubricant such as boric acid or salicylic acid, useful in particular during pressing or sintering.
- Boric acid H 3 BO 3 is of particular interest in friction because of its ability to lubricate dry. During friction, the planar crystalline meshes of boric acid tend to self-level into sheets parallel to the surface. This arrangement reduces friction similarly to more well known compounds such as MoS 2 molybdenum sulphide and WS 2 tungsten sulphide.
- the invention aims at a non-lubricated operation of the watch exhaust, in order to reduce maintenance, and to allow high oscillation frequencies.
- the invention relates to a timepiece component comprising at least one self-lubricating surface layer, according to claim 1.
- the invention also relates to a clock escapement mechanism comprising at least one such component.
- the invention also relates to a watch movement comprising at least one such escape mechanism.
- the invention further relates to a watch having at least one movement.
- the invention further relates to a method of coating a timepiece component with a self-lubricating surface layer according to claim 12.
- the invention proposes, at least for the most stressed components of watchmaking mechanisms, to produce them with a dry, self-lubricating surface layer, for which the use of boric acid H 3 BO 3 is preferred, which is of particular interest in friction, because of its ability to lubricate dry.
- the invention relates to a timepiece component 1 comprising at least one self-lubricating surface layer 2.
- this surface layer 2 is a dry layer comprising boric acid H 3 BO 3 and has a thickness of between 10 nanometers and 10 microns.
- this thickness is between 50 nanometers and 1 micrometer.
- this surface layer 2 consists entirely of boric acid.
- the component 1 comprises, under this surface layer 2, a material chosen to provide a very good adhesion of boric acid.
- the component 1 comprises, under the surface layer 2, a substrate which is either composed of silicon oxide SiO 2 or aluminum oxide Al 2 O 3 , or which is covered with a layer intermediate 3 consisting of silicon oxide SiO 2 or Al 2 O 3 aluminum oxide, or DLC, or the like.
- a component 1 which is an escape mechanism component, taken from an escape wheel, an anchor, a rocker, a dart, an ellipse, a pallet, a stop of limitation, a plateau, a quill, a rest, a relaxation, a fork, an ankle.
- the invention also relates to a clock escapement mechanism comprising at least one such component 1.
- this escapement mechanism 10 comprises such a component 1 which is an escape wheel made of silicon oxide or a mixture of silicon and silicon oxide SiO 2 .
- the component 1 is made of silicon by DRIE, and then thermally oxidized.
- the micro-manufacturing of silica or quartz components (crystalline or amorphous SiO 2 ) is not yet completely controlled at present.
- This escape wheel is coated with such a superficial layer 2 of boric acid, and is arranged to cooperate with other components 1 which are ruby paddles each coated with such a surface layer 2 of boric acid.
- the invention also relates to a watch movement 100 comprising at least one such escape mechanism 10.
- the invention also relates to a watch 1000 comprising at least one such movement 100.
- the invention also relates to a method of coating a timepiece component 1 with a self-lubricating surface layer 2.
- the thickness of the boric acid layer H 3 BO 3 can also be controlled by the concentration of the solution.
- the thickness therefore also depends on the concentration of the solution.
- the repetition of the steps makes it possible to increase the thickness, because the dissolution of the boric acid already formed is relatively slow.
- this method is applied to a watch exhaust mechanism component 1, emitting or undergoing more than one pulse per second, chosen from an escapement wheel, an anchor, a pendulum, a dart, a ellipse, a palette, a limit stop, a plateau, a star, a rest, a relaxation, a fork, an ankle.
- the thickness of the boric acid layer is between 50 nanometers and 1 micrometer.
- the components to be coated with boric acid are typically silicon, silicon and silicon oxide, metals or ceramics. These may have a rough or porous surface, so as to promote adhesion.
- the typical concentration of the solution is calculated so as to coat the components with a thin layer, more particularly of the order of 100 nm, of solid boric acid.
- the solubility of the H 3 BO 3 at room temperature being, in the solvent liquids proposed above, higher than the recommended dosage, it is generally not necessary to heat the liquids. However, heating can facilitate dissolution, especially in the case of water that is not flammable.
- H 3 BO 3 powder is advantageously mixed with the solvent and stirred, and ultrasound may also be used.
- the component to be coated is soaked in the solution, or sprinkled, then extracted and allowed to dry, so as to avoid contact with the functional parts, for example deposited on a blotting paper.
- a slight gas blast may be used to hasten the evaporation of the liquid.
- the component 1 In its final state, the component 1 is covered with the desired surface layer 2.
- the component 1 is made to have a mirror-polished surface before coating, interference fringes are visible.
- the small thicknesses of deposited boric acid typically from about 50 nm to 100 nm, do not bring about a marked color change.
- the passage of a sharp object on the surface may leave a trace indicative of the presence of the layer.
- the invention allows a non-lubricated operation of a watch exhaust, to reduce maintenance, and allow high oscillation frequencies.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Lubricants (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15195386.6A EP3171230B1 (fr) | 2015-11-19 | 2015-11-19 | Composant d'horlogerie a tribologie amelioree |
US15/337,060 US20170146955A1 (en) | 2015-11-19 | 2016-10-28 | Timepiece component with improved tribology |
JP2016214141A JP6231644B2 (ja) | 2015-11-19 | 2016-11-01 | トライボロジーが改善された計時器コンポーネント |
CN201611011906.9A CN106919036B (zh) | 2015-11-19 | 2016-11-17 | 具有改进的摩擦的计时器组件 |
RU2016145143A RU2718342C1 (ru) | 2015-11-19 | 2016-11-18 | Часовой компонент с улучшенной самосмазкой |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15195386.6A EP3171230B1 (fr) | 2015-11-19 | 2015-11-19 | Composant d'horlogerie a tribologie amelioree |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3171230A1 EP3171230A1 (fr) | 2017-05-24 |
EP3171230B1 true EP3171230B1 (fr) | 2019-02-27 |
Family
ID=54601699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15195386.6A Active EP3171230B1 (fr) | 2015-11-19 | 2015-11-19 | Composant d'horlogerie a tribologie amelioree |
Country Status (5)
Country | Link |
---|---|
US (1) | US20170146955A1 (ja) |
EP (1) | EP3171230B1 (ja) |
JP (1) | JP6231644B2 (ja) |
CN (1) | CN106919036B (ja) |
RU (1) | RU2718342C1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11392091B2 (en) * | 2017-07-31 | 2022-07-19 | Rolex Sa | Watch pivot device |
EP3968095A1 (fr) * | 2020-09-15 | 2022-03-16 | ETA SA Manufacture Horlogère Suisse | Procédé de fabrication d'un composant de micromécanique, notamment d'un mobile d'horlogerie, avec surface de contact optimisee |
EP3968096A1 (fr) * | 2020-09-15 | 2022-03-16 | ETA SA Manufacture Horlogère Suisse | Composant de micromécanique, notamment un mobile d horlogerie, notamment un mobile d' échappement, avec surface de contact optimisée |
CN113402299A (zh) * | 2021-04-27 | 2021-09-17 | 北京化工大学 | 一种提升石墨材料摩擦性能的方法及制备工艺 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090186783A1 (en) * | 2006-04-28 | 2009-07-23 | Jean Michel Martin | Low Friction Lubrication Assembly |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2159327A (en) * | 1937-03-08 | 1939-05-23 | Chrysler Corp | Bearing |
US2182414A (en) * | 1938-05-14 | 1939-12-05 | Chrysler Corp | Bearing member |
JPS6069197A (ja) * | 1983-09-26 | 1985-04-19 | Seiko Epson Corp | 精密摺動部品 |
CN1022426C (zh) * | 1990-11-27 | 1993-10-13 | 中国科学院金属研究所 | 一种耐磨减摩镀层的复合镀工艺 |
JP3225576B2 (ja) * | 1992-01-28 | 2001-11-05 | 住友電気工業株式会社 | 自己修復性硬質固体潤滑膜で被覆した摺動機械部品 |
EP0885983A1 (en) * | 1997-06-19 | 1998-12-23 | N.V. Bekaert S.A. | Method for coating a substrate with a diamond like nanocomposite composition |
DE19822934C2 (de) * | 1998-05-22 | 2001-11-29 | Daimler Chrysler Ag | Verfahren zum haftenden Aufbringen einer Schmierstoffschicht auf eine freiliegende und tribologisch beanspruchte Oberfläche eines Gegenstandes, Gegenstand mit an einer freiliegenden Oberfläche haftenden Schmierstoffschicht sowie Verwendung eines beschichteten Gegenstandes |
US6755566B2 (en) * | 2001-02-15 | 2004-06-29 | Konrad Damasko | Clockwork |
US8339904B2 (en) * | 2005-06-28 | 2012-12-25 | Eta Sa Manufacture Horlogère Suisse | Reinforced micro-mechanical part |
US7846556B2 (en) * | 2006-09-06 | 2010-12-07 | Uchicago Argonne, Llc | Modulated composite surfaces |
JP2008164582A (ja) * | 2006-12-04 | 2008-07-17 | Seiko Epson Corp | 時計部品、及び当該時計部品を備えた時計 |
US20080145554A1 (en) * | 2006-12-14 | 2008-06-19 | General Electric | Thermal spray powders for wear-resistant coatings, and related methods |
JP2010256267A (ja) * | 2009-04-28 | 2010-11-11 | Seiko Epson Corp | 時計 |
JP5647232B2 (ja) * | 2009-05-18 | 2014-12-24 | ザ スウォッチ グループ リサーチアンド ディベロップメント リミティド. | 微小機械システムに適用される高い摩擦性能を維持しながら微小機械部品をコーティングする方法 |
EP2263971A1 (fr) * | 2009-06-09 | 2010-12-22 | Nivarox-FAR S.A. | Pièce de micromécanique composite et son procédé de fabrication |
CH702576B1 (fr) * | 2010-01-18 | 2014-11-14 | Sigatec Sa | Pièce de micro-mécanique revêtue. |
EP2453038A1 (en) * | 2010-11-16 | 2012-05-16 | The Swatch Group Research and Development Ltd. | Method for coating micromechanical parts with dual diamond coating |
JP5823038B2 (ja) * | 2011-07-21 | 2015-11-25 | ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド | 機能性微小機械アセンブリ |
FR2990433A1 (fr) * | 2012-05-10 | 2013-11-15 | Surfactis Technologies | Compositions catanioniques de recouvrement de surface par des molecules phosphoniques et amines |
EP2767869A1 (fr) * | 2013-02-13 | 2014-08-20 | Nivarox-FAR S.A. | Procédé de fabrication d'une pièce de micromécanique monobloc comportant au moins deux niveaux distincts |
EP2945025B1 (fr) * | 2014-05-16 | 2018-02-07 | Nivarox-FAR S.A. | Mécanisme d'horlogerie à couple de contact sans lubrification |
EP3002637B1 (fr) * | 2014-09-29 | 2018-11-28 | Richemont International S.A. | Système horloger avec des propriétés tribologiques améliorées |
EP3006605A1 (fr) * | 2014-10-08 | 2016-04-13 | The Swatch Group Research and Development Ltd. | Revêtement composite auto-lubrifiant |
-
2015
- 2015-11-19 EP EP15195386.6A patent/EP3171230B1/fr active Active
-
2016
- 2016-10-28 US US15/337,060 patent/US20170146955A1/en not_active Abandoned
- 2016-11-01 JP JP2016214141A patent/JP6231644B2/ja active Active
- 2016-11-17 CN CN201611011906.9A patent/CN106919036B/zh active Active
- 2016-11-18 RU RU2016145143A patent/RU2718342C1/ru active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090186783A1 (en) * | 2006-04-28 | 2009-07-23 | Jean Michel Martin | Low Friction Lubrication Assembly |
Also Published As
Publication number | Publication date |
---|---|
JP2017096932A (ja) | 2017-06-01 |
US20170146955A1 (en) | 2017-05-25 |
EP3171230A1 (fr) | 2017-05-24 |
RU2718342C1 (ru) | 2020-04-02 |
CN106919036B (zh) | 2019-08-09 |
CN106919036A (zh) | 2017-07-04 |
JP6231644B2 (ja) | 2017-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3171230B1 (fr) | Composant d'horlogerie a tribologie amelioree | |
TWI724012B (zh) | 製造微機械時計部件的方法及所述微機械時計部件 | |
EP3204535A1 (fr) | Revetement composite auto-lubrifiant | |
CN102458724A (zh) | 在基材上形成固态润滑剂涂层的方法 | |
RU2674288C2 (ru) | Спусковой механизм часов без смазки | |
CH709665A2 (fr) | Mécanisme d'horlogerie à couple de contact sans lubrification. | |
Hager Jr et al. | The effect of temperature on gross slip fretting wear of cold-sprayed nickel coatings on Ti6Al4V interfaces | |
CH711836A2 (fr) | Composant d'horlogerie comportant une couche superficielle auto-lubrifiante. | |
EP3783445A1 (fr) | Mecanisme regulateur d'horlogerie a haut facteur de qualite et a lubrification minimale | |
EP3141522B1 (fr) | Pièce micromécanique horlogère comprenant une surface lubrifiée et procédé de réalisation d'une telle pièce micromécanique horlogère | |
EP3511780B1 (fr) | Procede de lubrification d'un echappement | |
EP3492621A1 (fr) | Procédé pour améliorer les propriétés de résistance à l'usure d'une pièce mécanique | |
EP3627237B1 (fr) | Composant en materiau micro-usinable pour resonateur à haut facteur de qualité | |
CN114026504B (zh) | 允许限制润滑物质的微机械部件 | |
CH717841A2 (fr) | Mobile d'horlogerie, notamment mobile d'échappement, avec surface de contact revêtue. | |
WO2022058160A1 (fr) | Procede de fabrication d'un composant de micromecanique, notamment d'un mobile d'horlogerie, dont la surface est optimisee | |
WO2023156201A1 (fr) | Pierre d'horlogerie et procede de fabrication d'une telle pierre | |
EP3968096A1 (fr) | Composant de micromécanique, notamment un mobile d horlogerie, notamment un mobile d' échappement, avec surface de contact optimisée | |
CH709609B1 (fr) | Mécanisme d'échappement d'horlogerie sans lubrification. | |
CH717842A2 (fr) | Procédé de fabrication d'un mobile d'horlogerie, avec surface de contact revêtue. | |
CH719428A2 (fr) | Pierre d'horlogerie et procédé de fabrication d'une telle pierre. | |
WO2021005564A1 (fr) | Ensemble horloger d'au moins deux éléments en contact | |
CH710099A2 (fr) | Procédé de renforcement pour composant d'horlogerie. | |
CH718412B1 (fr) | Mouvement horloger comportant au moins une pièce mécanique en bois et procédé de fabrication d'une pièce en bois pour mouvement horloger. | |
CH311864A (fr) | Pièce d'horlogerie à sonnerie. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20171124 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: EXAMINATION IS IN PROGRESS |
|
17Q | First examination report despatched |
Effective date: 20180614 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20181030 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: ICB INGENIEURS CONSEILS EN BREVETS SA, CH Ref country code: AT Ref legal event code: REF Ref document number: 1102274 Country of ref document: AT Kind code of ref document: T Effective date: 20190315 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602015025275 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20190227 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190527 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190627 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190528 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190527 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190627 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1102274 Country of ref document: AT Kind code of ref document: T Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602015025275 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20191128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191119 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20191130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191119 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20151119 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190227 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230611 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20231019 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20231019 Year of fee payment: 9 Ref country code: DE Payment date: 20231019 Year of fee payment: 9 Ref country code: CH Payment date: 20231201 Year of fee payment: 9 |